File name: Pandora192s1_Tokyo-Sophia_20250419_L2Fit_fout2c5d20240824p1-8.txt File generation date: 20250716T144453.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Satoshi Inomata Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 192 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora192_OF_v3d20210309.txt Instrument calibration file used: Pandora192s1_CF_v5d20240824.txt Level 1 file used: Pandora192s1_Tokyo-Sophia_20250419_L1_smca1c5d20240824p1-8.txt Full location name: Sophia University Short location name: Tokyo-Sophia Country of location: Japan Location latitude [deg]: 35.6831 Location longitude [deg]: 139.7317 Location altitude [m]: 45 Local noon date: 20250419 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 199 341 Nominal wavelengths inside fitting window [nm]: 305.0359 305.1770 305.3181 305.4592 305.6003 305.7414 305.8825 306.0235 306.1646 306.3056 306.4467 306.5877 306.7287 306.8697 307.0107 307.1516 307.2926 307.4336 307.5745 307.7155 307.8564 307.9973 308.1382 308.2791 308.4200 308.5609 308.7017 308.8426 308.9834 309.1243 309.2651 309.4059 309.5467 309.6875 309.8283 309.9690 310.1098 310.2505 310.3913 310.5320 310.6727 310.8134 310.9541 311.0948 311.2355 311.3761 311.5168 311.6574 311.7981 311.9387 312.0793 312.2199 312.3605 312.5011 312.6416 312.7822 312.9227 313.0633 313.2038 313.3443 313.4848 313.6253 313.7658 313.9063 314.0467 314.1872 314.3276 314.4681 314.6085 314.7489 314.8893 315.0297 315.1701 315.3104 315.4508 315.5911 315.7314 315.8718 316.0121 316.1524 316.2927 316.4330 316.5732 316.7135 316.8537 316.9940 317.1342 317.2744 317.4146 317.5548 317.6950 317.8352 317.9753 318.1155 318.2556 318.3957 318.5359 318.6760 318.8161 318.9561 319.0962 319.2363 319.3763 319.5164 319.6564 319.7964 319.9364 320.0764 320.2164 320.3564 320.4964 320.6363 320.7763 320.9162 321.0561 321.1960 321.3359 321.4758 321.6157 321.7555 321.8954 322.0352 322.1751 322.3149 322.4547 322.5945 322.7343 322.8741 323.0138 323.1536 323.2933 323.4331 323.5728 323.7125 323.8522 323.9919 324.1316 324.2713 324.4109 324.5506 324.6902 324.8298 324.9694 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250418T210430.1Z 9239.878126 226 1 49.94 2 78.65 84.34 70.73 207.03 0.00 1 0.00 1 0 25 4.191e-01 2.599e-02 3.528e-01 2.114e-02 6.064282e-01 1.236271e-02 1.038910e-02 -6.000000e+00 2.644939e-01 229.41 -2.00 3.41 -2.00 321.55 0.00e+00 2.051616e-02 6.396256e-03 1.142104e-02 -6.000000e+00 1.354607e-02 284.00 -2.00 20.00 -2.00 320.96 0.00e+00 4.911 0.002 302.00 328.00 3 4.2931e+00 4.4309e-02 7.1303e-02 -6.0000e+00 6.5513e-01 4.6412e-01 5.4439e-02 5.2933e-02 -6.0000e+00 7.0991e-01 -7.2416e-01 4.1704e-02 3.2485e-02 -6.0000e+00 4.2387e-01 2.9730e-01 1.9958e-02 1.5065e-02 -6.0000e+00 1.7404e-01 2.6895e-05 1.7226e-03 7.4358e-04 4.7002e-04 -6.0000e+00 1.4827e-02 3.7240e-03 0.0000e+00 12 9 8 11 8 0 76.97 18.13 0.80 0.00372 0.01667 14 3 1 5 0 3566.690 22.40 15.00 18.13 25.48 29.5 989.87 -63150 -94778 -32053 900000 -64931 -110391 -28261 106897 -168395 131974 134067 900000 -47662 900000 -52248 -68873 68526 -59953 228839 62118 55801 -25337 -59345 900000 -3132 900000 900000 965 900000 -14043 141901 -34241 29509 -11477 -36681 18360 15092 21814 -7691 40999 20497 2628 44166 -580 9661 15986 28449 34666 10047 -2543 28149 38884 17371 10407 7181 14341 29658 -7399 16289 4732 21840 9881 12735 21644 15780 -1776 -724 8096 15287 9138 10233 -309 6732 13801 -536 10443 1991 -13280 -7206 -1684 -3061 -8060 8570 -3494 5801 -4714 -2071 4193 -3365 1402 -4701 -349 -5660 -3581 -6678 -3037 1935 -949 -1286 -1581 -1599 -742 -1532 -1341 -4231 2847 -1926 -2689 1091 -811 233 239 43 1300 -2652 -1424 -2918 2386 45 4557 1825 487 414 1868 1798 1185 687 182 -32 2189 -1189 611 -156 -198 964 -311 1660 -1013 -171 -501 -252 -810 -980 -1566 -3600 -690 900000 -1671 -4030 -582 2201 -9694 2718 2761 900000 -1215 900000 -2254 -4057 1411 -4027 4712 1342 1261 -1234 -3783 900000 -109 900000 900000 31 900000 -615 2922 -2521 1276 -774 -3116 888 793 1221 -637 2381 1580 257 2985 -64 990 1587 2569 3038 1172 -356 3121 4188 2477 1665 1213 2264 4082 -1410 2480 821 3385 1906 2664 4516 3626 -484 -194 2044 3885 2719 3228 -111 2207 3971 -163 2620 520 -4181 -2390 -614 -1304 -4044 3957 -1941 3119 -2979 -1332 2591 -2228 854 -2951 -198 -3314 -2145 -4601 -2324 1620 -917 -1326 -1631 -1559 -663 -1311 -1156 -3949 2630 -1993 -3037 1305 -1091 335 357 64 1856 -3781 -1966 -4163 3377 68 6821 2797 737 606 2676 2487 1604 936 264 -52 3815 -2325 1249 -331 -446 2262 -769 4128 -2610 -432 -1256 -599 -1856 -2237 SS 20250418T214800.9Z 9239.908343 251 1 30.31 2 69.82 90.58 75.16 215.52 0.00 1 0.00 1 0 25 1.031e-01 1.238e-02 1.569e-02 1.410e-03 4.048911e-01 7.634779e-04 5.246816e-03 -6.000000e+00 6.463495e-02 229.42 -2.00 3.41 -2.00 319.60 0.00e+00 3.012304e-03 2.213826e-04 3.101822e-03 -6.000000e+00 2.874937e-03 284.00 -2.00 20.00 -2.00 318.86 0.00e+00 2.869 0.000 302.00 328.00 3 2.4819e+00 2.1754e-03 3.6856e-02 -6.0000e+00 1.6079e-01 -1.4413e-02 2.5522e-03 2.5037e-02 -6.0000e+00 1.7406e-01 -4.3059e-02 1.8788e-03 1.2528e-02 -6.0000e+00 1.0376e-01 1.0724e-02 9.5306e-04 3.4984e-03 -6.0000e+00 4.2527e-02 1.5801e-03 8.4845e-04 4.9333e-05 6.6211e-05 -6.0000e+00 3.5272e-03 3.0344e-03 0.0000e+00 12 9 9 12 1 1 90.19 18.24 0.45 0.00303 0.00941 109 39 1 5 0 275.510 22.61 15.00 18.24 27.48 29.5 998.09 -31060 -25298 -35473 -39437 -30182 -38496 -28967 -40788 -34094 -29316 -31813 -21860 -21655 -11638 -11117 -10396 -2905 -4954 1549 913 169 -1573 -5666 -3587 -4081 -1893 -2013 -5987 -5918 -9882 -5821 -3403 -1971 -3960 -5844 -7411 -6830 -3226 -238 2399 2496 2173 2554 2539 3053 1894 2415 1921 -198 794 1523 2140 2943 2838 2167 1455 1428 -293 516 215 1701 2487 4132 3298 2121 927 -510 -394 1027 1165 1674 1232 857 357 -1014 -3310 -5042 -5222 -4407 -3398 -2680 -1894 -1765 -1257 -339 976 1831 1949 1680 1191 25 -1119 -2305 -2660 -1788 -591 362 652 533 -142 -1206 -2177 -2098 -1590 -1145 -831 -496 555 1406 1957 1959 1320 634 -226 -981 -956 -434 81 682 1072 1344 1387 971 480 -78 -735 -873 -1023 -547 -380 -836 -693 -665 -265 95 431 695 675 526 100 -134 -595 -513 -749 -648 -1055 -1198 -792 -1068 -760 -1315 -1237 -1080 -1264 -856 -979 -566 -634 -670 -191 -357 111 68 13 -126 -487 -317 -381 -179 -191 -579 -565 -1011 -622 -395 -246 -525 -787 -1029 -1024 -540 -46 517 596 556 679 691 839 531 676 543 -58 239 487 734 1075 1100 883 615 613 -128 222 93 758 1184 2104 1803 1193 514 -278 -217 599 748 1159 810 564 249 -668 -2045 -2965 -3052 -2732 -2344 -2072 -1465 -1476 -1116 -318 961 1875 2044 1758 1208 24 -1016 -2020 -2355 -1684 -612 416 820 706 -188 -1529 -2607 -2416 -1855 -1403 -1075 -677 796 1961 2916 3082 2128 1008 -344 -1423 -1337 -607 117 1034 1684 2128 2162 1476 706 -121 -1099 -1285 -1555 -814 -608 -1429 -1236 -1237 -517 180 848 1402 1378 1071 199 -278 -1203 -1032 SS 20250418T215331.9Z 9239.912175 254 1 49.21 2 68.70 91.39 75.80 216.54 0.00 1 0.00 1 0 33 8.621e-02 1.216e-02 1.103e-02 9.972e-04 3.896222e-01 5.418395e-04 5.014496e-03 -6.000000e+00 5.402255e-02 229.42 -2.00 3.41 -2.00 319.60 0.00e+00 2.883999e-03 1.552806e-04 3.027605e-03 -6.000000e+00 2.402956e-03 284.01 -2.00 20.00 -2.00 318.85 0.00e+00 2.728 0.000 302.00 328.00 3 2.2083e+00 1.5565e-03 3.5442e-02 -6.0000e+00 1.3439e-01 -1.0701e-02 1.8219e-03 2.4540e-02 -6.0000e+00 1.4548e-01 -3.3506e-02 1.3193e-03 1.2148e-02 -6.0000e+00 8.6724e-02 4.1687e-03 6.6690e-04 3.3256e-03 -6.0000e+00 3.5544e-02 2.4139e-03 7.3040e-04 3.5338e-05 7.2141e-05 -6.0000e+00 2.9482e-03 3.2124e-03 0.0000e+00 12 8 8 10 0 0 18.63 18.26 0.36 0.00321 0.00870 284 62 1 5 0 173.230 22.61 15.00 18.26 27.77 29.5 999.70 -28551 -21987 -25505 -15708 -33521 -27664 -35457 -29875 -22583 -23841 -25718 -28658 -17945 -14598 -5369 -3763 -3342 -510 -998 688 -1215 -1660 267 -2209 -1530 -4426 -4749 -7518 -8947 -5976 -5247 -2242 -3804 -4596 -6762 -6596 -5888 -2922 320 526 2025 2360 2649 2932 2263 2445 1722 857 314 404 1758 1443 2478 1775 1675 1671 932 485 -388 456 1411 2928 3778 3345 2478 419 -625 -994 646 1782 1503 1898 721 195 -1059 -3303 -4559 -5445 -4294 -3298 -2474 -1890 -1815 -1024 -119 1129 1789 2032 1974 1250 269 -1243 -2118 -2590 -1630 -649 357 726 461 -107 -1258 -2182 -1870 -1802 -1307 -1086 -466 420 1335 1964 1856 1470 468 -220 -915 -1015 -324 87 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