File name: Pandora192s1_Tokyo-Sophia_20250512_L2Fit_fout2c5d20240824p1-8.txt File generation date: 20250716T145155.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Satoshi Inomata Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 192 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora192_OF_v3d20210309.txt Instrument calibration file used: Pandora192s1_CF_v5d20240824.txt Level 1 file used: Pandora192s1_Tokyo-Sophia_20250512_L1_smca1c5d20240824p1-8.txt Full location name: Sophia University Short location name: Tokyo-Sophia Country of location: Japan Location latitude [deg]: 35.6831 Location longitude [deg]: 139.7317 Location altitude [m]: 45 Local noon date: 20250512 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 199 341 Nominal wavelengths inside fitting window [nm]: 305.0359 305.1770 305.3181 305.4592 305.6003 305.7414 305.8825 306.0235 306.1646 306.3056 306.4467 306.5877 306.7287 306.8697 307.0107 307.1516 307.2926 307.4336 307.5745 307.7155 307.8564 307.9973 308.1382 308.2791 308.4200 308.5609 308.7017 308.8426 308.9834 309.1243 309.2651 309.4059 309.5467 309.6875 309.8283 309.9690 310.1098 310.2505 310.3913 310.5320 310.6727 310.8134 310.9541 311.0948 311.2355 311.3761 311.5168 311.6574 311.7981 311.9387 312.0793 312.2199 312.3605 312.5011 312.6416 312.7822 312.9227 313.0633 313.2038 313.3443 313.4848 313.6253 313.7658 313.9063 314.0467 314.1872 314.3276 314.4681 314.6085 314.7489 314.8893 315.0297 315.1701 315.3104 315.4508 315.5911 315.7314 315.8718 316.0121 316.1524 316.2927 316.4330 316.5732 316.7135 316.8537 316.9940 317.1342 317.2744 317.4146 317.5548 317.6950 317.8352 317.9753 318.1155 318.2556 318.3957 318.5359 318.6760 318.8161 318.9561 319.0962 319.2363 319.3763 319.5164 319.6564 319.7964 319.9364 320.0764 320.2164 320.3564 320.4964 320.6363 320.7763 320.9162 321.0561 321.1960 321.3359 321.4758 321.6157 321.7555 321.8954 322.0352 322.1751 322.3149 322.4547 322.5945 322.7343 322.8741 323.0138 323.1536 323.2933 323.4331 323.5728 323.7125 323.8522 323.9919 324.1316 324.2713 324.4109 324.5506 324.6902 324.8298 324.9694 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250512T015450.1Z 9263.079747 401 1 48.84 2 19.90 148.91 164.31 351.15 0.00 1 0.00 1 0 33 1.843e-02 1.390e-02 5.783e-03 2.918e-03 1.633140e-01 1.595027e-03 1.983353e-03 -6.000000e+00 1.161827e-02 231.06 -2.00 3.41 -2.00 316.29 0.00e+00 1.274608e-03 1.811657e-04 3.959742e-04 -6.000000e+00 5.184141e-04 286.25 -2.00 20.00 -2.00 315.50 0.00e+00 1.063 0.000 302.00 328.00 3 5.9687e+00 4.1741e-03 1.3377e-02 -6.0000e+00 2.8998e-02 5.2079e-02 4.6585e-03 8.0057e-03 -6.0000e+00 3.1338e-02 -1.0996e-02 2.6520e-03 3.8698e-03 -6.0000e+00 1.8682e-02 -5.0258e-03 1.1607e-03 1.0881e-03 -6.0000e+00 7.6511e-03 3.9681e-04 3.7515e-04 1.0213e-04 1.6823e-05 -6.0000e+00 6.3054e-04 2.4370e-03 0.0000e+00 12 8 8 10 0 0 99.98 18.33 0.73 0.00244 0.00526 28 6 1 5 0 1743.780 22.71 15.01 18.33 27.40 29.7 1004.16 1807 998 -408 -1297 -3014 -3591 -775 -4661 -2521 -4097 -3953 -1819 -3180 750 838 145 2471 1440 2999 2289 2098 1188 859 1838 903 183 -724 -735 -3059 -2181 -1343 -2330 -542 -3230 -3631 -5617 -4556 -1929 48 951 305 1543 1277 1279 1051 608 1142 -777 -158 -842 139 823 974 747 807 950 935 214 67 -46 1156 2071 3107 2558 1798 -39 -1069 -981 -538 888 1289 1060 1193 261 -245 -2913 -3902 -5083 -4411 -2586 -3372 -2052 -1975 -1093 -300 937 1723 1592 1849 1325 112 -1533 -2169 -2475 -1592 -658 -170 633 1061 257 -484 -1875 -2074 -1848 -1384 -293 -553 665 1203 2006 2430 1852 1252 -106 -548 -1496 -800 -169 199 1064 753 1589 966 229 82 -342 -565 -1456 -1048 -557 -593 -788 -751 -289 13 634 823 844 706 227 -432 -973 -710 363 215 -90 -274 -626 -710 -151 -1013 -576 -987 -957 -439 -831 207 255 47 824 497 1044 819 761 436 318 692 372 77 -304 -294 -1184 -810 -500 -913 -217 -1336 -1469 -2307 -1975 -925 26 581 204 1069 909 917 753 433 788 -529 -104 -554 93 571 704 560 619 739 732 168 52 -36 925 1734 2721 2322 1617 -34 -866 -772 -439 776 1207 1035 1166 250 -220 -2591 -3203 -4022 -3544 -2208 -3187 -1968 -2017 -1170 -339 1112 2131 2023 2335 1619 129 -1736 -2281 -2524 -1660 -731 -195 773 1339 323 -581 -2276 -2458 -2248 -1774 -372 -737 913 1715 2959 3662 2787 1814 -146 -735 -1926 -1019 -222 276 1547 1069 2352 1402 321 109 -436 -697 -1818 -1353 -750 -827 -1126 -1098 -436 21 1036 1311 1366 1147 364 -718 -1586 -1149 SS 20250512T035718.5Z 9263.164798 473 1 50.06 2 24.86 230.50 152.09 64.32 0.00 1 0.00 1 0 33 2.035e-02 1.494e-02 6.667e-03 3.316e-03 1.722104e-01 1.812598e-03 2.066179e-03 -6.000000e+00 1.283087e-02 231.07 -2.00 3.41 -2.00 316.31 0.00e+00 1.707497e-03 2.079177e-04 4.178165e-04 -6.000000e+00 5.724542e-04 286.26 -2.00 20.00 -2.00 315.52 0.00e+00 1.102 0.000 302.00 328.00 3 6.2687e+00 4.7387e-03 1.3913e-02 -6.0000e+00 3.2025e-02 7.2127e-02 5.2915e-03 8.3735e-03 -6.0000e+00 3.4607e-02 -1.5912e-02 3.0156e-03 4.0451e-03 -6.0000e+00 2.0631e-02 -3.5905e-03 1.3219e-03 1.2352e-03 -6.0000e+00 8.4509e-03 2.7555e-04 4.9298e-04 1.1568e-04 1.5903e-05 -6.0000e+00 6.9621e-04 1.3322e-03 0.0000e+00 12 8 8 10 0 0 99.98 18.78 0.54 0.00133 0.00504 13 3 1 5 0 3849.930 23.11 15.01 18.78 31.98 30.0 1023.37 -1581 3350 -104 1604 -4864 -3748 -2008 -1293 -1834 -3832 -3755 -4765 -3039 -957 334 950 1050 793 3697 3792 3802 1286 2240 -842 627 1437 214 -1664 -2759 -1922 -1515 -1767 -140 -3828 -5041 -6779 -4881 -2600 -432 1864 117 1255 934 1780 1547 1062 853 -1419 -222 -1111 335 793 710 1546 817 716 349 931 -26 -275 1389 2184 2799 2520 2021 -366 -506 -1439 -680 618 1574 1475 925 1120 -1157 -2869 -3427 -5060 -3756 -3247 -3259 -2558 -1713 -868 202 1099 1131 1978 1951 1505 365 -1083 -2751 -3208 -2103 -1188 109 699 910 524 -989 -1963 -1926 -1924 -912 -987 -469 954 1032 2126 2215 2162 1055 336 -1167 -1505 -1198 -128 964 1761 1067 1248 1172 330 -45 -818 -1139 -1461 -966 -1074 -920 -1049 -503 28 43 682 886 886 673 225 -1 -899 -1110 -324 699 -23 327 -973 -701 -389 -266 -407 -899 -886 -1159 -778 -265 101 306 353 274 1273 1332 1352 469 815 -324 254 587 87 -659 -1046 -701 -559 -682 -55 -1583 -2057 -2799 -2108 -1247 -235 1120 78 865 662 1262 1097 748 588 -969 -146 -732 223 550 515 1153 628 559 275 726 -21 -216 1109 1828 2463 2294 1820 -317 -427 -1193 -583 545 1479 1443 911 1065 -1097 -2526 -2774 -3971 -2978 -2776 -3061 -2591 -1760 -935 229 1312 1418 2522 2478 1848 423 -1213 -2892 -3280 -2195 -1325 125 862 1163 664 -1208 -2378 -2271 -2330 -1157 -1271 -630 1316 1487 3161 3379 3280 1548 462 -1574 -1936 -1529 -168 1327 2434 1523 1770 1688 460 -60 -1042 -1407 -1816 -1242 -1449 -1285 -1501 -732 42 65 1067 1425 1449 1104 365 -1 -1455 -1793 SS 20250512T040155.4Z 9263.168002 476 1 49.18 2 25.59 232.42 151.29 65.69 0.00 1 0.00 1 0 17 1.656e-02 1.211e-02 1.951e-03 9.826e-04 1.600277e-01 5.365025e-04 1.932074e-03 -6.000000e+00 1.044495e-02 231.07 -2.00 3.41 -2.00 316.35 0.00e+00 1.250826e-03 6.161186e-05 3.781826e-04 -6.000000e+00 4.659347e-04 286.26 -2.00 20.00 -2.00 315.56 0.00e+00 1.108 0.000 302.00 328.00 3 3.8981e+00 1.4008e-03 1.3606e-02 -6.0000e+00 2.6070e-02 3.6146e-02 1.5627e-03 7.8239e-03 -6.0000e+00 2.8171e-02 -8.8257e-03 8.9211e-04 3.7597e-03 -6.0000e+00 1.6794e-02 -6.6780e-03 3.9048e-04 1.0481e-03 -6.0000e+00 6.8805e-03 3.0517e-03 3.4907e-04 3.4431e-05 1.5997e-05 -6.0000e+00 5.6664e-04 8.5624e-05 0.0000e+00 12 8 8 10 0 0 99.99 18.80 0.52 0.00009 0.00271 342 75 1 5 0 143.780 23.11 15.00 18.80 32.55 29.9 1025.84 1386 751 14 -1675 -2397 -3072 -2091 -1439 -2326 -2593 -4686 -3355 -1841 -723 731 700 1665 1926 2277 2598 1650 1958 1249 1591 949 560 -519 -2068 -1998 -2715 -1343 -1143 -1071 -2492 -4781 -5228 -4242 -2030 164 666 835 771 933 798 1135 869 520 237 -589 -242 121 778 1185 999 1087 943 673 226 76 424 1400 2235 2544 2279 1019 111 -954 -1314 64 1023 1262 1245 969 587 -616 -1948 -3579 -4105 -3564 -2856 -2500 -2288 -1904 -1252 -301 802 1267 1750 1613 1232 305 -792 -1719 -2072 -1284 -584 323 668 672 120 -699 -1570 -1824 -1409 -1320 -943 -558 309 992 1725 1991 1522 918 307 -549 -760 -477 173 474 978 1118 1244 989 413 164 -525 -798 -778 -682 -676 -872 -771 -737 -174 126 421 653 564 580 145 -219 -612 -720 269 171 3 -374 -497 -605 -414 -303 -532 -618 -1147 -825 -475 -203 223 228 560 663 800 929 603 715 463 602 373 225 -207 -801 -731 -968 -477 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