File name: Pandora276s1_Tokyo-Sophia_20260101_L2Fit_fout2c2d20231212p1-8.txt File generation date: 20260128T175205.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Masatomo Fujiwara Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 276 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora276_OF_v2d20230804.txt Instrument calibration file used: Pandora276s1_CF_v2d20231212.txt Level 1 file used: Pandora276s1_Tokyo-Sophia_20260101_L1_smca1c2d20231212p1-8.txt Full location name: Sophia University Short location name: Tokyo-Sophia Country of location: Japan Location latitude [deg]: 35.6831 Location longitude [deg]: 139.7317 Location altitude [m]: 45 Local noon date: 20260101 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 195 337 Nominal wavelengths inside fitting window [nm]: 305.0410 305.1817 305.3223 305.4630 305.6036 305.7443 305.8849 306.0255 306.1661 306.3067 306.4473 306.5878 306.7284 306.8689 307.0095 307.1500 307.2905 307.4310 307.5715 307.7120 307.8524 307.9929 308.1333 308.2738 308.4142 308.5546 308.6950 308.8354 308.9757 309.1161 309.2565 309.3968 309.5371 309.6775 309.8178 309.9581 310.0983 310.2386 310.3789 310.5191 310.6594 310.7996 310.9398 311.0800 311.2202 311.3604 311.5006 311.6407 311.7809 311.9210 312.0611 312.2013 312.3414 312.4815 312.6215 312.7616 312.9017 313.0417 313.1817 313.3218 313.4618 313.6018 313.7418 313.8817 314.0217 314.1617 314.3016 314.4415 314.5815 314.7214 314.8613 315.0012 315.1410 315.2809 315.4207 315.5606 315.7004 315.8402 315.9800 316.1198 316.2596 316.3994 316.5392 316.6789 316.8186 316.9584 317.0981 317.2378 317.3775 317.5172 317.6568 317.7965 317.9361 318.0758 318.2154 318.3550 318.4946 318.6342 318.7738 318.9133 319.0529 319.1924 319.3320 319.4715 319.6110 319.7505 319.8900 320.0294 320.1689 320.3083 320.4478 320.5872 320.7266 320.8660 321.0054 321.1448 321.2842 321.4235 321.5629 321.7022 321.8415 321.9808 322.1201 322.2594 322.3987 322.5380 322.6772 322.8165 322.9557 323.0949 323.2341 323.3733 323.5125 323.6517 323.7908 323.9300 324.0691 324.2082 324.3473 324.4864 324.6255 324.7646 324.9037 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20251231T231811.4Z 9496.970965 249 1 4.38 2 76.31 132.10 117.58 346.40 0.00 1 0.00 1 0 25 1.640e-01 1.067e-02 1.110e-01 6.773e-03 5.302562e-01 3.588972e-03 6.096296e-03 -6.000000e+00 9.840740e-02 224.02 -2.00 3.41 -2.00 319.45 0.00e+00 5.359121e-04 1.015925e-03 2.456199e-04 -6.000000e+00 4.383680e-03 280.52 -2.00 20.00 -2.00 318.81 0.00e+00 4.127 0.001 302.00 328.00 3 3.1809e+00 1.0075e-02 4.8689e-02 -6.0000e+00 2.4224e-01 4.8513e-02 1.1864e-02 2.6600e-02 -6.0000e+00 2.6300e-01 -5.8358e-02 9.5100e-03 1.3262e-02 -6.0000e+00 1.5701e-01 2.0580e-02 4.9696e-03 3.8057e-03 -6.0000e+00 6.6125e-02 2.0150e-04 -1.8724e-03 2.0912e-04 5.0820e-05 -6.0000e+00 5.2273e-03 1.6613e-02 0.0000e+00 12 9 9 12 1 1 85.12 25.99 0.54 0.01661 0.00254 4 6 1 5 0 873.700 35.00 20.06 25.99 12.39 3.1 1100.00 -48241 -41650 -24045 -7742 -69561 -27883 -77587 -38678 -67494 -52475 -11507 -28052 -21905 -27655 56058 -31780 21822 -3512 -10986 -19516 9512 -11444 -14493 -23261 35509 -18596 6698 3261 -17995 17475 -3111 -9254 -6765 40 -8334 -10037 7752 6675 2733 8009 -2154 886 1588 6280 -3509 -2663 4501 900 3946 11027 -3310 3598 -1260 2192 -1278 1836 2860 -1154 -942 1608 124 921 2092 3231 2409 -1646 981 1588 821 495 1417 1277 1211 -382 815 204 -288 -3329 -1352 -370 -320 -734 -3111 -1820 -897 -616 -907 -633 -391 1106 -897 32 165 3531 94 -664 473 -1046 1131 -363 -547 201 -226 -1030 -489 -927 -640 -226 -1277 -77 255 -152 529 158 90 388 211 344 -202 299 -28 204 -74 -28 385 825 996 482 920 1429 326 284 -170 -272 -129 -38 -6 -69 -163 -881 -461 142 -211 -828 -770 -397 -107 -1700 -442 -2152 -818 -2140 -1560 -243 -778 -680 -1114 1185 -1889 850 -193 -697 -1418 534 -809 -1101 -2074 1900 -1806 513 254 -1712 1212 -296 -1076 -862 5 -1151 -1419 993 1010 471 1549 -521 225 421 1629 -1018 -775 1235 260 1142 3132 -1078 1204 -484 876 -561 815 1291 -544 -437 721 58 460 1055 1763 1388 -980 556 907 508 320 998 950 905 -279 546 135 -178 -2086 -889 -255 -237 -618 -2759 -1707 -889 -610 -950 -682 -422 1143 -893 31 153 3178 94 -710 537 -1283 1468 -486 -703 250 -263 -1194 -591 -1132 -824 -308 -1802 -112 402 -240 837 243 137 563 318 508 -316 464 -45 331 -117 -42 588 1205 1409 695 1355 2309 554 489 -308 -498 -250 -74 -13 -142 -337 -1791 -891 271 -391 SS 20251231T232730.2Z 9496.977433 252 1 12.96 2 74.92 133.79 117.95 348.60 0.00 1 0.00 1 0 25 8.497e-02 7.011e-03 2.170e-02 2.041e-03 4.882251e-01 1.075529e-03 5.612664e-03 -6.000000e+00 5.104922e-02 224.02 -2.00 3.41 -2.00 318.87 0.00e+00 1.088738e-03 2.541979e-04 1.889145e-04 -6.000000e+00 2.271155e-03 280.52 -2.00 20.00 -2.00 318.22 0.00e+00 3.771 0.001 302.00 328.00 3 2.5291e+00 2.9342e-03 4.4510e-02 -6.0000e+00 1.2567e-01 3.6701e-02 3.3782e-03 2.4301e-02 -6.0000e+00 1.3638e-01 -2.8829e-02 2.4663e-03 1.2075e-02 -6.0000e+00 8.1420e-02 6.6955e-03 1.2964e-03 3.6633e-03 -6.0000e+00 3.4344e-02 5.6501e-04 -6.6474e-04 6.3226e-05 4.6783e-05 -6.0000e+00 2.7082e-03 7.4890e-03 0.0000e+00 12 9 1 12 1 1 99.13 25.99 0.34 0.00749 0.00249 34 15 1 5 0 370.220 35.00 20.30 25.99 12.80 3.2 1100.00 -24119 -19216 -26660 -30616 -41690 -5560 -22135 -22375 -44377 -6795 -24503 -26119 -10873 -17695 15231 -6641 329 -4063 -1827 3750 5858 -2263 -7264 -3333 11042 -2410 -2492 524 -5880 4492 2248 -2407 823 227 -4557 -2927 -1257 894 427 834 -2174 -922 -714 817 -1522 -1380 1527 -408 607 3511 -383 1911 358 1756 379 1711 1572 -39 -293 1205 434 1228 2364 1985 708 -406 229 257 1013 1166 569 393 -109 -146 592 -282 -53 -1534 -1112 -526 -996 -1332 -1948 -1766 -1289 -812 -95 -293 -497 547 251 752 702 1064 956 685 -65 198 -93 -354 -329 -646 -131 -215 -239 -866 -978 -717 -436 135 -3 180 -25 52 202 227 919 328 82 29 -323 -324 -112 393 581 963 481 448 914 547 497 28 -370 272 -41 -53 -71 -264 -137 -258 -115 -382 -284 -581 -505 -801 -944 -1361 -124 -617 -699 -1934 -220 -1009 -1206 -508 -1078 803 -506 26 -365 -172 351 554 -236 -828 -391 1204 -288 -302 67 -783 557 287 -367 136 40 -839 -533 -243 197 104 238 -722 -301 -244 282 -545 -500 542 -150 226 1327 -162 866 166 864 200 926 815 -21 -153 661 230 695 1457 1255 472 -270 147 166 696 840 453 313 -87 -113 448 -208 -36 -1040 -798 -401 -826 -1182 -1809 -1751 -1291 -862 -106 -322 -548 609 264 770 681 1024 983 752 -77 254 -124 -478 -425 -807 -159 -259 -289 -1119 -1281 -954 -620 200 -5 280 -39 80 297 329 1307 482 122 46 -516 -510 -172 598 846 1395 678 637 1336 847 804 47 -644 478 -74 -101 -135 -511 -266 -492 -216 -709 -511 SS 20251231T234312.9Z 9496.988343 263 1 54.53 2 72.68 136.74 118.42 352.35 0.00 1 0.00 1 0 25 3.687e-02 6.006e-03 1.879e-03 3.077e-04 4.353555e-01 1.615360e-04 5.047747e-03 -6.000000e+00 2.215465e-02 224.02 -2.00 3.41 -2.00 318.21 0.00e+00 7.820154e-04 3.084846e-05 1.325715e-04 -6.000000e+00 9.855854e-04 280.52 -2.00 20.00 -2.00 317.54 0.00e+00 3.310 0.001 302.00 328.00 3 7.7287e-01 4.3114e-04 3.9202e-02 -6.0000e+00 5.4540e-02 1.6568e-02 4.8885e-04 2.1502e-02 -6.0000e+00 5.9187e-02 -2.3622e-02 3.2177e-04 1.0674e-02 -6.0000e+00 3.5335e-02 6.0458e-03 1.6649e-04 3.1403e-03 -6.0000e+00 1.4906e-02 5.4550e-03 -6.6892e-04 9.6202e-06 4.1411e-05 -6.0000e+00 1.1753e-03 7.0381e-03 0.0000e+00 10 0 0 10 0 0 99.80 26.01 0.37 0.00704 0.00201 1313 131 1 5 0 41.520 35.00 20.06 26.01 13.45 3.2 1100.00 -11846 -9749 -10698 -11346 -17244 -16064 -12587 -11396 -12080 -8494 -10247 -8672 -5888 -4372 -1556 -1518 -895 -426 -53 336 609 -358 -182 86 697 -755 -1925 -2204 -1521 -42 340 483 455 -432 -2267 -1630 -1038 118 706 57 -476 -290 -147 -180 -91 187 -36 -134 50 701 884 1312 1220 1450 878 840 885 464 462 721 1210 1647 1663 1285 765 47 -29 336 680 1172 370 -16 -34 -195 -110 -444 -471 -660 -641 -491 -1096 -1452 -1689 -1726 -1243 -907 -488 -23 -107 224 424 659 429 581 781 662 313 100 -13 -218 -400 -711 -455 -103 -326 -1047 -945 -676 -441 135 156 165 67 200 212 356 469 388 86 -106 -288 -193 -26 384 650 936 679 809 939 626 387 38 -164 182 14 -149 -120 -127 -245 -235 -182 -393 -582 -521 -476 -555 -581 -882 -791 -631 -629 -749 -547 -708 -641 -491 -429 -160 -179 -116 -59 -8 51 96 -58 -30 15 131 -138 -360 -440 -294 -8 66 105 109 -110 -585 -418 -285 34 244 21 -190 -124 -66 -82 -42 87 -17 -63 24 344 434 698 661 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