File name: Pandora276s1_Tokyo-Sophia_20260102_L2Fit_fout2c4d20251211p1-8.txt File generation date: 20260331T150457.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Masatomo Fujiwara Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 276 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora276_OF_v2d20230804.txt Instrument calibration file used: Pandora276s1_CF_v4d20251211.txt Level 1 file used: Pandora276s1_Tokyo-Sophia_20260102_L1_smca1c4d20251211p1-8.txt Full location name: Sophia University Short location name: Tokyo-Sophia Country of location: Japan Location latitude [deg]: 35.6831 Location longitude [deg]: 139.7317 Location altitude [m]: 45 Local noon date: 20260102 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Field calibration based on session 2 First and last pixel inside fitting window: 195 337 Nominal wavelengths inside fitting window [nm]: 305.0492 305.1899 305.3305 305.4712 305.6118 305.7525 305.8931 306.0337 306.1743 306.3149 306.4554 306.5960 306.7366 306.8771 307.0176 307.1582 307.2987 307.4392 307.5796 307.7201 307.8606 308.0010 308.1415 308.2819 308.4223 308.5627 308.7031 308.8435 308.9839 309.1242 309.2646 309.4049 309.5452 309.6855 309.8258 309.9661 310.1064 310.2467 310.3869 310.5272 310.6674 310.8076 310.9479 311.0881 311.2282 311.3684 311.5086 311.6487 311.7889 311.9290 312.0691 312.2092 312.3493 312.4894 312.6295 312.7696 312.9096 313.0497 313.1897 313.3297 313.4697 313.6097 313.7497 313.8897 314.0296 314.1696 314.3095 314.4494 314.5893 314.7292 314.8691 315.0090 315.1489 315.2887 315.4286 315.5684 315.7082 315.8481 315.9879 316.1276 316.2674 316.4072 316.5469 316.6867 316.8264 316.9661 317.1058 317.2455 317.3852 317.5249 317.6645 317.8042 317.9438 318.0835 318.2231 318.3627 318.5023 318.6419 318.7814 318.9210 319.0605 319.2001 319.3396 319.4791 319.6186 319.7581 319.8976 320.0370 320.1765 320.3159 320.4553 320.5948 320.7342 320.8736 321.0129 321.1523 321.2917 321.4310 321.5704 321.7097 321.8490 321.9883 322.1276 322.2669 322.4061 322.5454 322.6846 322.8239 322.9631 323.1023 323.2415 323.3807 323.5199 323.6590 323.7982 323.9373 324.0764 324.2156 324.3547 324.4938 324.6328 324.7719 324.9110 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20260101T235301.1Z 9497.995152 316 1 54.81 2 71.33 138.50 114.11 339.92 0.00 1 0.00 1 0 17 2.261e-01 1.922e-02 4.834e-02 3.712e-03 4.595053e-01 1.958310e-03 5.259420e-03 -6.000000e+00 1.358956e-01 224.03 -2.00 3.41 -2.00 319.21 0.00e+00 3.946422e-03 5.047433e-04 5.332681e-04 -6.000000e+00 6.041577e-03 280.46 -2.00 20.00 -2.00 318.57 0.00e+00 3.086 0.000 302.00 328.00 3 5.0951e+00 5.3917e-03 3.8132e-02 -6.0000e+00 3.3457e-01 1.3013e-01 6.2692e-03 2.2773e-02 -6.0000e+00 3.6301e-01 -1.1144e-01 4.6113e-03 1.1985e-02 -6.0000e+00 2.1671e-01 5.0410e-02 2.3954e-03 5.0415e-03 -6.0000e+00 9.1469e-02 8.1257e-05 -6.0761e-04 1.1760e-04 6.0749e-05 -6.0000e+00 7.2052e-03 -3.7848e-03 0.0000e+00 12 9 8 11 32 0 99.98 26.03 -0.10 -0.00378 -0.00835 28 3 1 5 0 1957.340 35.00 19.91 26.03 14.52 3.1 1100.00 -53870 -57707 -62797 1406 -57911 77315 36512 -31474 -87556 -4472 -50809 -62236 -32524 -32618 121051 -24368 437 10237 -13263 924 54937 -8026 -7970 -26757 73491 1466 -9447 9548 -6791 57971 19654 -12753 2171 13950 -9821 6942 6165 22797 13733 9708 -4132 -455 -4453 -163 -3596 -6198 16147 2555 1355 22699 -3964 4759 764 1175 3086 7087 4332 -1565 1786 3878 3142 1479 6647 7157 1051 -5661 -28 -3431 -1023 -415 -144 3143 -41 -1789 1481 -37 2059 -2179 -4254 -1019 -1321 76 -2650 -3374 -2197 -2187 -796 -857 -1857 1817 -2249 639 792 1597 2269 448 24 -1470 -502 -528 812 607 -625 -1328 269 -1673 -1187 -1155 502 55 175 -36 643 445 -248 614 1218 -119 868 623 363 300 -74 313 1777 668 75 -170 2214 1664 -190 -1046 -642 123 -102 -601 1697 72 -588 -761 -967 -874 173 -1950 -2469 -2976 34 -2382 868 634 -1174 -5676 -147 -2777 -4145 -1884 -2291 2191 -2179 34 771 -1340 84 2983 -822 -831 -3516 3725 158 -1142 933 -767 3526 1928 -1957 318 1914 -1692 1005 960 3450 2695 2309 -1145 -130 -1386 -50 -1153 -2060 4752 789 430 6640 -1469 1754 316 516 1391 3160 2020 -773 839 1773 1486 763 3579 4159 673 -3487 -17 -2171 -670 -275 -104 2314 -32 -1335 995 -25 1258 -1351 -2845 -682 -1012 65 -2517 -3176 -2172 -2298 -869 -966 -2122 1944 -2360 605 762 1506 2254 466 28 -1826 -666 -711 1032 768 -747 -1582 330 -2062 -1534 -1580 722 80 275 -59 1045 695 -367 917 1777 -181 1282 966 575 469 -112 489 2620 953 103 -237 3214 2649 -311 -1815 -1154 215 -189 -1172 3334 147 -1204 -1528 -1863 -1602 324 SS 20260102T000232.1Z 9498.001761 319 1 54.62 2 70.08 140.40 114.70 342.01 0.00 1 0.00 1 0 25 6.425e-02 7.247e-03 1.201e-02 1.354e-03 4.380960e-01 7.109311e-04 5.054576e-03 -6.000000e+00 3.861953e-02 224.03 -2.00 3.41 -2.00 318.66 0.00e+00 8.262677e-04 1.564590e-04 1.586652e-04 -6.000000e+00 1.716946e-03 280.46 -2.00 20.00 -2.00 318.00 0.00e+00 2.903 0.000 302.00 328.00 3 3.5520e+00 1.9275e-03 3.6077e-02 -6.0000e+00 9.5081e-02 4.0622e-02 2.2090e-03 2.1717e-02 -6.0000e+00 1.0316e-01 -1.8636e-02 1.5596e-03 1.0829e-02 -6.0000e+00 6.1586e-02 3.7797e-03 8.1828e-04 3.2396e-03 -6.0000e+00 2.5994e-02 4.8244e-04 -3.8258e-04 4.2766e-05 4.1698e-05 -6.0000e+00 2.0476e-03 -3.6510e-03 0.0000e+00 11 8 0 10 0 0 99.99 26.06 0.47 -0.00365 -0.00653 238 24 1 5 0 229.460 35.00 19.84 26.06 14.45 3.1 1100.00 -27074 -18428 -19152 -7759 -31105 -9743 -3320 -7828 -37546 -3447 -17825 -21414 -12094 -10482 6215 -7647 -903 -1559 -3418 -1148 8242 -3273 -3252 -5514 7405 -2525 -4608 -2412 -3122 8009 1116 -1960 786 -1512 -4365 -877 -968 1802 1921 1177 -2815 -1048 -1370 1471 -883 -1023 1547 -306 -110 3944 5 1453 637 1145 681 1495 1831 485 774 771 1782 1572 1920 2135 906 -1009 -355 822 313 1053 909 325 -237 -696 23 -286 -111 -1137 -747 -938 -1139 -1010 -1914 -1863 -1544 -811 -493 -124 -371 653 61 825 171 1387 960 728 163 77 -14 -145 -51 -616 -448 -269 -336 -1033 -1036 -634 -301 293 156 181 252 14 168 362 376 195 73 -73 -355 -149 -171 350 611 1022 710 539 1150 670 352 -154 -382 244 80 -303 129 -28 -83 -240 -296 -378 -483 -904 -640 -706 -250 -1191 -293 -99 -271 -1948 -137 -861 -1165 -695 -709 422 -684 -83 -155 -369 -127 851 -385 -395 -728 918 -362 -682 -341 -433 1012 164 -335 144 -299 -883 -171 -203 388 494 357 -998 -392 -537 573 -356 -415 614 -124 -45 1613 2 648 310 591 371 837 1045 281 441 436 1023 894 1191 1430 635 -705 -237 542 221 760 720 273 -202 -572 17 -214 -76 -767 -528 -693 -960 -890 -1854 -1924 -1585 -880 -562 -146 -438 741 66 871 171 1349 991 784 187 98 -18 -191 -68 -764 -552 -329 -406 -1333 -1408 -857 -432 428 245 281 389 22 247 530 541 290 109 -113 -564 -233 -260 512 899 1433 964 735 1660 1002 569 -249 -645 428 141 -566 247 -53 -156 -462 -547 -668 -873 SS 20260102T001833.5Z 9498.012888 329 1 3.48 2 68.08 143.72 115.55 345.59 0.00 1 0.00 1 0 17 6.752e-02 1.239e-02 4.300e-02 8.307e-03 3.991452e-01 4.364852e-03 4.646326e-03 -6.000000e+00 4.056912e-02 224.04 -2.00 3.41 -2.00 318.00 0.00e+00 1.697464e-03 7.843907e-04 1.484410e-04 -6.000000e+00 1.804383e-03 280.46 -2.00 20.00 -2.00 317.33 0.00e+00 2.655 0.000 302.00 328.00 3 4.1213e+00 1.1584e-02 3.2939e-02 -6.0000e+00 9.9878e-02 4.9106e-02 1.3106e-02 1.9819e-02 -6.0000e+00 1.0839e-01 -3.6502e-02 8.4021e-03 9.8162e-03 -6.0000e+00 6.4704e-02 1.3242e-02 4.2891e-03 3.1796e-03 -6.0000e+00 2.7294e-02 3.6398e-04 -6.4407e-04 2.6292e-04 3.9527e-05 -6.0000e+00 2.1520e-03 -2.2012e-04 0.0000e+00 12 9 9 12 33 1 999.00 26.10 0.26 -0.00022 -0.00506 1 3 1 5 0 1736.310 35.00 20.21 26.10 14.08 3.1 1100.00 12178 -32872 -39165 -14315 -19847 6673 1276 -28551 -12393 -8118 -16007 -12489 -13830 -10628 9781 -133 3739 -3204 -5436 319 -1584 2459 3651 -3366 11956 -3804 7631 -46 -6611 11977 -149 -7055 1062 8784 -5898 2318 -5365 6253 3802 -536 -2059 546 -784 -717 -1070 1724 5709 193 -391 4189 451 2432 -466 3204 1805 1779 859 537 2498 44 3760 -1306 1490 1850 2472 -601 -2299 -192 421 -1849 1382 1288 -1267 -552 -821 -1923 -2232 -2265 -993 24 -1680 -1779 -3699 -2001 -1776 47 -802 844 1000 -462 -1005 -205 651 301 1313 1403 1113 407 -451 592 20 48 999 -289 -604 -427 -1805 -786 -171 752 -417 218 293 238 -237 481 401 -51 -599 -172 1207 12 897 132 1334 803 -838 691 1464 1491 -682 -86 78 183 -493 85 122 -588 -924 17 -205 -492 30 543 -2583 -3427 -951 -1302 324 68 -2267 -924 -618 -1375 -1113 -1434 -1266 1117 -17 512 -503 -921 53 -275 415 624 -649 2096 -812 1461 -9 -1378 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