File name: Pandora276s1_Tokyo-Sophia_20260306_L2Fit_fwvt1c4d20251226p1-8.txt File generation date: 20260330T185232.8Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c4p1-8 Local principal investigator: Satoshi Inomata Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 276 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora276_OF_v3d20230804.txt Instrument calibration file used: Pandora276s1_CF_v4d20251226.txt Level 1 file used: Pandora276s1_Tokyo-Sophia_20260306_L1_smca1c4d20251226p1-8.txt Full location name: Sophia University Short location name: Tokyo-Sophia Country of location: Japan Location latitude [deg]: 35.6831 Location longitude [deg]: 139.7317 Location altitude [m]: 45 Local noon date: 20260306 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Field calibration based on session 2 First and last pixel inside fitting window: 1619 1769 Nominal wavelengths inside fitting window [nm]: 492.0866 492.2073 492.3279 492.4485 492.5691 492.6897 492.8103 492.9308 493.0514 493.1719 493.2924 493.4129 493.5333 493.6538 493.7742 493.8946 494.0150 494.1354 494.2558 494.3761 494.4964 494.6168 494.7370 494.8573 494.9776 495.0978 495.2181 495.3383 495.4585 495.5787 495.6988 495.8190 495.9391 496.0592 496.1793 496.2994 496.4194 496.5395 496.6595 496.7795 496.8995 497.0195 497.1395 497.2594 497.3793 497.4993 497.6191 497.7390 497.8589 497.9787 498.0986 498.2184 498.3382 498.4579 498.5777 498.6974 498.8172 498.9369 499.0566 499.1762 499.2959 499.4155 499.5352 499.6548 499.7744 499.8939 500.0135 500.1330 500.2526 500.3721 500.4916 500.6110 500.7305 500.8499 500.9694 501.0888 501.2081 501.3275 501.4469 501.5662 501.6855 501.8048 501.9241 502.0434 502.1627 502.2819 502.4011 502.5203 502.6395 502.7587 502.8778 502.9970 503.1161 503.2352 503.3543 503.4733 503.5924 503.7114 503.8304 503.9494 504.0684 504.1874 504.3063 504.4252 504.5442 504.6631 504.7819 504.9008 505.0197 505.1385 505.2573 505.3761 505.4949 505.6136 505.7324 505.8511 505.9698 506.0885 506.2072 506.3258 506.4445 506.5631 506.6817 506.8003 506.9189 507.0374 507.1560 507.2745 507.3930 507.5115 507.6300 507.7484 507.8669 507.9853 508.1037 508.2221 508.3405 508.4588 508.5771 508.6955 508.8138 508.9321 509.0503 509.1686 509.2868 509.4050 509.5232 509.6414 509.7596 509.8777 509.9958 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20260305T215316.3Z 9560.911994 258 1 11.23 2 81.19 103.69 87.63 257.06 0.00 1 0.00 1 0 22 2.667e-03 2.647e-03 1.319e-03 1.318e-03 3.698103e+03 7.652856e+01 2.796224e+02 -6.000000e+00 1.398719e+02 280.42 -2.00 20.00 -2.00 505.30 0.00e+00 2.098965e-03 3.536641e-05 1.072039e-04 -6.000000e+00 7.298375e-05 280.42 -2.00 20.00 -2.00 500.59 0.00e+00 5.989069e-01 2.507640e-02 2.699289e-02 -6.000000e+00 5.161989e-02 226.23 -2.00 3.41 -2.00 502.16 0.00e+00 6.174 0.004 489.00 513.00 1 6.2265e+00 1.9159e-03 9.4735e-03 -6.0000e+00 3.9438e-03 -9.0047e-03 4.9605e-04 7.7503e-04 -6.0000e+00 1.0392e-03 1.4885e-03 1.1808e-02 1.0921e-04 4.7441e-05 -6.0000e+00 2.2631e-04 -1.2000e-02 -4.0189e-04 12 1 1 12 1 1 84.55 25.98 1.40 -0.01200 0.06991 4 2 1 4 0 2245.270 35.00 20.09 25.98 12.86 3.2 1100.00 -666 -438 86 -95 265 84 343 525 -187 366 95 152 -411 -369 -172 -131 -7 16 2 93 209 190 143 128 309 442 559 -37 -321 -668 -112 18 125 -265 -170 290 -50 -136 -127 -119 -83 141 188 166 241 196 199 328 -115 -94 -203 -448 -286 -459 -190 109 -190 101 246 293 351 186 183 31 -47 93 280 210 -84 -583 -283 -50 426 -13 -342 -211 145 -370 -71 -494 -595 -323 -86 -429 -248 -11 -26 -113 -89 71 132 235 114 313 115 94 387 -167 -855 -463 -80 194 -75 -256 -290 4 12 -157 -114 17 -386 87 48 158 418 436 414 103 392 308 485 182 207 8 56 114 178 52 258 195 -233 -200 127 75 -107 -261 -374 144 30 -308 -15 199 142 131 171 -114 -198 -36 -204 -171 -164 -632 -418 84 -96 266 84 352 534 -190 370 96 152 -406 -364 -170 -130 -7 16 2 95 214 195 147 132 317 452 578 -38 -323 -660 -110 17 124 -270 -177 301 -51 -138 -129 -120 -84 144 191 172 249 202 204 336 -117 -93 -199 -437 -276 -449 -189 110 -195 102 249 299 359 190 187 31 -48 94 279 209 -83 -569 -277 -48 417 -13 -341 -209 142 -363 -69 -477 -579 -314 -83 -420 -243 -10 -26 -112 -87 70 131 234 116 314 115 93 378 -162 -819 -440 -76 183 -72 -252 -290 4 12 -154 -112 17 -387 87 49 160 425 445 421 106 398 312 489 181 204 8 56 114 180 51 259 194 -232 -197 124 73 -103 -255 -372 143 31 -313 -15 204 144 134 175 -117 -202 -36 -202 -169 -162 SQ 20260305T220423.8Z 9560.919719 263 1 1.92 2 79.00 105.41 89.80 258.62 0.00 1 0.00 1 0 15 2.543e-03 2.529e-03 9.010e-04 9.003e-04 3.155819e+03 5.155288e+01 2.320041e+02 -6.000000e+00 1.333885e+02 280.42 -2.00 20.00 -2.00 505.31 0.00e+00 1.815807e-03 2.413863e-05 9.973667e-05 -6.000000e+00 6.953377e-05 280.42 -2.00 20.00 -2.00 500.66 0.00e+00 4.330458e-01 1.710967e-02 2.666909e-02 -6.000000e+00 4.897554e-02 226.23 -2.00 3.41 -2.00 502.22 0.00e+00 5.054 0.002 489.00 513.00 1 4.0020e+00 1.3071e-03 7.9184e-03 -6.0000e+00 3.7453e-03 -1.3316e-02 3.3910e-04 6.9621e-04 -6.0000e+00 9.8089e-04 1.6429e-02 2.9529e-03 7.4487e-05 4.1179e-05 -6.0000e+00 2.1562e-04 2.4139e-02 -2.3950e-04 12 1 1 12 1 1 71.22 25.98 1.45 0.02414 0.04462 8 26 1 4 0 212.530 35.00 19.85 25.98 13.29 3.2 1100.00 -425 -532 -328 191 450 322 333 287 33 122 20 -39 -85 -444 72 22 157 114 -20 92 32 158 288 136 313 424 401 -219 -184 -423 -412 25 -68 -507 19 240 92 29 -8 19 46 84 42 218 213 211 184 393 -138 -110 -676 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312 101 -60 -465 -343 -204 -63 -306 SQ 20260305T220902.9Z 9560.922950 266 1 21.64 2 78.09 106.14 90.71 259.27 0.00 1 0.00 1 0 15 2.350e-03 2.339e-03 2.187e-04 2.185e-04 2.982721e+03 1.248081e+01 2.142744e+02 -6.000000e+00 1.233414e+02 280.42 -2.00 20.00 -2.00 505.29 0.00e+00 1.755617e-03 5.871653e-06 9.651221e-05 -6.000000e+00 6.441056e-05 280.42 -2.00 20.00 -2.00 500.59 0.00e+00 4.198714e-01 4.205098e-03 2.630543e-02 -6.000000e+00 4.574684e-02 226.23 -2.00 3.41 -2.00 502.16 0.00e+00 4.698 0.002 489.00 513.00 1 3.7627e+00 3.2060e-04 7.4209e-03 -6.0000e+00 3.4906e-03 -9.8536e-03 8.4504e-05 6.6229e-04 -6.0000e+00 9.2757e-04 2.1999e-02 3.7361e-04 1.8120e-05 3.9561e-05 -6.0000e+00 2.0005e-04 2.4279e-03 2.8431e-05 12 1 1 12 1 1 99.94 25.98 1.44 0.00243 0.00502 170 43 1 4 0 126.540 35.00 19.85 25.98 13.39 3.1 1100.00 -501 -478 -345 53 386 234 322 329 115 199 123 14 -171 -366 -107 96 54 -66 -132 133 150 201 284 183 180 292 393 -132 -291 -327 -116 26 -25 -415 22 215 83 10 24 -48 -86 77 131 135 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