File name: Pandora276s1_Tokyo-Sophia_20260312_L2Fit_fout2c4d20251211p1-8.txt File generation date: 20260331T153040.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Satoshi Inomata Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 276 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora276_OF_v3d20230804.txt Instrument calibration file used: Pandora276s1_CF_v4d20251211.txt Level 1 file used: Pandora276s1_Tokyo-Sophia_20260312_L1_smca1c4d20251211p1-8.txt Full location name: Sophia University Short location name: Tokyo-Sophia Country of location: Japan Location latitude [deg]: 35.6831 Location longitude [deg]: 139.7317 Location altitude [m]: 45 Local noon date: 20260312 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Field calibration based on session 2 First and last pixel inside fitting window: 195 337 Nominal wavelengths inside fitting window [nm]: 305.0492 305.1899 305.3305 305.4712 305.6118 305.7525 305.8931 306.0337 306.1743 306.3149 306.4554 306.5960 306.7366 306.8771 307.0176 307.1582 307.2987 307.4392 307.5796 307.7201 307.8606 308.0010 308.1415 308.2819 308.4223 308.5627 308.7031 308.8435 308.9839 309.1242 309.2646 309.4049 309.5452 309.6855 309.8258 309.9661 310.1064 310.2467 310.3869 310.5272 310.6674 310.8076 310.9479 311.0881 311.2282 311.3684 311.5086 311.6487 311.7889 311.9290 312.0691 312.2092 312.3493 312.4894 312.6295 312.7696 312.9096 313.0497 313.1897 313.3297 313.4697 313.6097 313.7497 313.8897 314.0296 314.1696 314.3095 314.4494 314.5893 314.7292 314.8691 315.0090 315.1489 315.2887 315.4286 315.5684 315.7082 315.8481 315.9879 316.1276 316.2674 316.4072 316.5469 316.6867 316.8264 316.9661 317.1058 317.2455 317.3852 317.5249 317.6645 317.8042 317.9438 318.0835 318.2231 318.3627 318.5023 318.6419 318.7814 318.9210 319.0605 319.2001 319.3396 319.4791 319.6186 319.7581 319.8976 320.0370 320.1765 320.3159 320.4553 320.5948 320.7342 320.8736 321.0129 321.1523 321.2917 321.4310 321.5704 321.7097 321.8490 321.9883 322.1276 322.2669 322.4061 322.5454 322.6846 322.8239 322.9631 323.1023 323.2415 323.3807 323.5199 323.6590 323.7982 323.9373 324.0764 324.2156 324.3547 324.4938 324.6328 324.7719 324.9110 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20260311T215425.0Z 9566.912789 205 1 8.62 2 79.24 102.21 65.81 191.02 0.00 1 0.00 1 0 25 5.726e-01 3.848e-02 3.027e-01 1.393e-02 8.180508e-01 7.955894e-03 1.086883e-02 -6.000000e+00 3.525055e-01 226.56 -2.00 3.41 -2.00 321.15 0.00e+00 8.043576e-03 3.615044e-03 9.408640e-03 -6.000000e+00 1.642608e-02 280.71 -2.00 20.00 -2.00 320.63 0.00e+00 5.158 0.002 302.00 328.00 3 3.0985e+00 2.5757e-02 7.8317e-02 -6.0000e+00 8.7318e-01 7.6444e-01 3.2598e-02 6.7777e-02 -6.0000e+00 9.4771e-01 -1.0586e+00 2.6831e-02 3.2311e-02 -6.0000e+00 5.6045e-01 4.4728e-01 1.2924e-02 8.0151e-03 -6.0000e+00 2.3386e-01 5.1372e-05 -2.0326e-03 3.9395e-04 2.2844e-04 -6.0000e+00 1.8509e-02 5.8622e-03 0.0000e+00 12 9 9 12 1 1 -4013.66 25.96 0.77 0.00586 -0.00941 3 3 1 5 0 2152.530 35.00 19.87 25.96 12.52 3.2 1100.00 -62821 -68200 -11331 22480 -81028 900000 900000 -107315 -90124 900000 -170079 -122052 27560 -129392 900000 -64497 56328 -5829 -50018 33295 900000 -21884 -68680 -23069 900000 183345 8468 130049 -9059 900000 152965 107317 -4546 82064 -24356 95638 284065 185732 120895 104566 28040 35532 25489 124863 9269 11170 60112 12605 46260 142404 16582 34430 41927 46728 27303 62341 54470 10188 10346 44573 3449 6615 30281 49671 21145 -13910 7916 23181 12775 4640 22287 13599 9786 514 12706 -7420 10913 1573 -3397 -5943 3266 1819 -3378 -5073 -5609 -2632 -6199 -5994 -2698 3653 -6909 -1080 -196 11370 -3289 -2426 -6487 -5829 -3385 430 -1370 158 -1048 -6180 -144 -4680 -3365 -1807 -1549 1449 -1029 -646 103 2556 -1060 1497 1854 -582 2000 2767 2512 1249 135 462 4468 2608 -971 1190 4699 3788 1041 -2040 -1496 650 631 -471 1573 -499 -2336 -1136 -709 -325 -867 -1705 -2187 -210 305 -2499 900000 900000 -3839 -2779 900000 -12167 -6022 374 -10693 900000 -4057 1181 -244 -3393 986 900000 -1053 -5167 -1110 900000 2488 322 1764 -393 900000 2075 2184 -321 2561 -2148 2465 3854 2520 3280 3830 2435 3037 2490 4574 1082 1288 4322 1505 4142 5217 2340 4484 5518 6276 4667 7697 7316 2087 2035 6047 716 1436 5834 8828 5365 -4632 2341 6101 4056 1625 7147 4948 3645 197 4310 -2517 3169 510 -1291 -2485 1471 956 -2075 -3404 -4012 -1928 -4506 -4459 -1937 2599 -5164 -719 -126 6773 -2536 -1983 -6477 -6144 -3841 484 -1504 169 -1033 -6183 -140 -5043 -3800 -2003 -1894 1944 -1477 -1003 165 3943 -1642 2189 2695 -894 3136 4441 4017 1950 203 670 6459 3715 -1408 1750 6899 6398 1891 -4158 -3036 1377 1421 -1128 3789 -1167 -5513 -2710 -1580 -671 -1829 SS 20260311T215906.5Z 9566.916047 208 1 54.55 2 78.31 102.93 66.00 192.09 0.00 1 0.00 1 0 25 5.387e-01 1.249e-02 1.239e-01 1.741e-03 7.784755e-01 9.615170e-04 8.575964e-03 -6.000000e+00 3.266162e-01 226.56 -2.00 3.41 -2.00 320.64 0.00e+00 4.614858e-03 4.074035e-04 8.462794e-04 -6.000000e+00 1.441068e-02 280.71 -2.00 20.00 -2.00 320.09 0.00e+00 4.780 0.002 302.00 328.00 3 1.8778e+00 2.9855e-03 6.1997e-02 -6.0000e+00 8.0866e-01 1.5717e-01 3.9524e-03 4.0180e-02 -6.0000e+00 8.7614e-01 -1.9878e-01 3.9313e-03 2.2066e-02 -6.0000e+00 5.2208e-01 7.5139e-02 1.9185e-03 9.1881e-03 -6.0000e+00 2.1903e-01 2.9070e-04 -1.0482e-03 4.8057e-05 1.1110e-04 -6.0000e+00 1.7182e-02 2.9226e-03 0.0000e+00 12 8 8 10 0 0 97.84 25.96 0.54 0.00292 -0.00495 123 12 1 5 0 443.450 35.00 19.97 25.96 12.59 3.2 1100.00 -236080 -98529 -138185 -92143 -218131 16646 -71103 -168571 -255772 -124824 -147508 -193708 -112914 -121659 33770 -84566 -36903 -44647 -49055 -39085 105375 -42594 -63976 -62346 73572 -37931 -32545 -17842 -37713 59558 19164 -15529 -1876 11400 -8933 6985 13753 10990 17017 4057 -6154 -3708 -511 17210 -1896 -7094 9756 52 7365 17157 -983 4727 4227 6541 3659 8416 6657 777 3512 5757 1697 2484 3316 5993 2221 -1974 1141 4480 -459 1761 3063 1253 -272 563 1089 -1001 -485 -1951 -2596 -773 -173 -351 -1798 -2502 -1682 -815 -497 -157 -462 1344 -601 828 455 2035 280 -174 -588 -389 -335 -216 25 -407 -891 -770 -703 -1780 -1602 -478 -371 111 -49 -25 7 -40 -66 558 404 455 253 342 233 5 387 734 835 692 185 581 953 878 218 -324 -504 301 35 -284 202 -161 -221 -160 -217 -281 -320 -3242 -411 -938 -398 -3198 28 -252 -1769 -7183 -1144 -1878 -4215 -1552 -2416 183 -1852 -589 -872 -1099 -843 554 -1005 -1955 -2021 662 -1101 -917 -436 -1159 768 446 -625 -77 447 -435 294 588 567 1002 324 -623 -401 -57 1668 -228 -928 1121 7 979 2260 -174 809 809 1340 828 1906 1580 196 844 1337 423 671 1009 2005 834 -726 412 1638 -194 823 1560 682 -150 292 515 -440 -199 -830 -1240 -428 -104 -243 -1305 -1971 -1401 -713 -424 -137 -405 1123 -519 666 358 1634 238 -173 -639 -456 -431 -269 31 -468 -1001 -839 -793 -2020 -1925 -611 -493 157 -73 -41 12 -66 -104 844 642 707 411 574 389 9 597 1143 1251 1004 265 857 1474 1470 391 -633 -1008 609 76 -623 454 -366 -502 -351 -467 -592 -648 SS 20260311T220421.7Z 9566.919695 211 1 54.53 2 77.28 103.75 66.23 193.30 0.00 1 0.00 1 0 25 4.397e-01 9.713e-03 4.982e-02 1.337e-03 7.291361e-01 7.302949e-04 8.025455e-03 -6.000000e+00 2.666344e-01 226.56 -2.00 3.41 -2.00 320.34 0.00e+00 3.130072e-03 2.795252e-04 5.252115e-04 -6.000000e+00 1.176196e-02 280.71 -2.00 20.00 -2.00 319.76 0.00e+00 4.418 0.001 302.00 328.00 3 1.7973e+00 2.1879e-03 5.7471e-02 -6.0000e+00 6.6017e-01 9.7403e-02 2.8043e-03 3.7288e-02 -6.0000e+00 7.1519e-01 -1.0763e-01 2.7020e-03 1.9671e-02 -6.0000e+00 4.2618e-01 3.4561e-02 1.3484e-03 7.4093e-03 -6.0000e+00 1.7884e-01 4.6951e-04 -8.7339e-04 3.7617e-05 8.7352e-05 -6.0000e+00 1.4024e-02 1.3796e-03 0.0000e+00 12 8 8 10 0 0 98.01 25.96 0.53 0.00138 -0.00518 185 19 1 5 0 294.710 35.00 20.00 25.96 12.93 3.2 1100.00 -167524 -129840 -96024 -100835 -174558 -137984 -87729 -147124 -206277 -79159 -125499 -142716 -87320 -90790 -10481 -71059 -29769 -16359 -42237 -23715 21774 -37743 -45953 -41597 14421 -21776 -34056 -27533 -29550 11922 5743 -9142 -4664 -247 -15851 -4065 3256 8953 2175 -111 -4929 -2964 -1892 8367 -2382 -2284 5177 378 3969 8931 1141 2243 2785 4161 2990 4208 3617 -4 1232 3375 810 2463 2842 3945 2009 -736 623 2303 407 1854 1880 945 -246 -253 462 -341 -470 -1444 -2306 -1014 -574 -960 -1495 -1908 -1716 -1076 -632 50 -82 1170 170 851 510 1377 403 284 -211 -83 -182 -334 -177 -563 -573 -368 -430 -1611 -1256 -859 -416 233 9 72 21 38 2 476 581 606 65 40 -67 -3 85 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