File name: Pandora276s1_Tokyo-Sophia_20260318_L2Fit_fout2c4d20251226p1-8.txt File generation date: 20260330T185838.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Satoshi Inomata Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 276 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora276_OF_v3d20230804.txt Instrument calibration file used: Pandora276s1_CF_v4d20251226.txt Level 1 file used: Pandora276s1_Tokyo-Sophia_20260318_L1_smca1c4d20251226p1-8.txt Full location name: Sophia University Short location name: Tokyo-Sophia Country of location: Japan Location latitude [deg]: 35.6831 Location longitude [deg]: 139.7317 Location altitude [m]: 45 Local noon date: 20260318 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Field calibration based on session 2 First and last pixel inside fitting window: 195 337 Nominal wavelengths inside fitting window [nm]: 305.0492 305.1899 305.3305 305.4712 305.6118 305.7525 305.8931 306.0337 306.1743 306.3149 306.4554 306.5960 306.7366 306.8771 307.0176 307.1582 307.2987 307.4392 307.5796 307.7201 307.8606 308.0010 308.1415 308.2819 308.4223 308.5627 308.7031 308.8435 308.9839 309.1242 309.2646 309.4049 309.5452 309.6855 309.8258 309.9661 310.1064 310.2467 310.3869 310.5272 310.6674 310.8076 310.9479 311.0881 311.2282 311.3684 311.5086 311.6487 311.7889 311.9290 312.0691 312.2092 312.3493 312.4894 312.6295 312.7696 312.9096 313.0497 313.1897 313.3297 313.4697 313.6097 313.7497 313.8897 314.0296 314.1696 314.3095 314.4494 314.5893 314.7292 314.8691 315.0090 315.1489 315.2887 315.4286 315.5684 315.7082 315.8481 315.9879 316.1276 316.2674 316.4072 316.5469 316.6867 316.8264 316.9661 317.1058 317.2455 317.3852 317.5249 317.6645 317.8042 317.9438 318.0835 318.2231 318.3627 318.5023 318.6419 318.7814 318.9210 319.0605 319.2001 319.3396 319.4791 319.6186 319.7581 319.8976 320.0370 320.1765 320.3159 320.4553 320.5948 320.7342 320.8736 321.0129 321.1523 321.2917 321.4310 321.5704 321.7097 321.8490 321.9883 322.1276 322.2669 322.4061 322.5454 322.6846 322.8239 322.9631 323.1023 323.2415 323.3807 323.5199 323.6590 323.7982 323.9373 324.0764 324.2156 324.3547 324.4938 324.6328 324.7719 324.9110 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20260317T222801.9Z 9572.936133 93 1 54.46 2 70.83 105.88 65.16 119.74 0.00 1 0.00 1 0 25 3.480e-02 6.072e-03 3.569e-03 6.115e-04 4.286283e-01 3.243731e-04 4.936118e-03 -6.000000e+00 2.114161e-02 226.94 -2.00 3.41 -2.00 318.14 0.00e+00 8.464825e-04 6.001325e-05 1.278568e-04 -6.000000e+00 9.324963e-04 281.09 -2.00 20.00 -2.00 317.44 0.00e+00 3.010 0.000 302.00 328.00 3 2.0280e+00 8.6839e-04 3.6811e-02 -6.0000e+00 5.2385e-02 3.3201e-02 9.8247e-04 2.1377e-02 -6.0000e+00 5.6727e-02 -2.5485e-02 6.3800e-04 1.0548e-02 -6.0000e+00 3.3801e-02 5.3186e-03 3.2656e-04 3.0929e-03 -6.0000e+00 1.4183e-02 2.0423e-03 -4.7327e-04 1.9243e-05 3.9324e-05 -6.0000e+00 1.1102e-03 -6.3806e-04 0.0000e+00 10 0 0 10 0 0 99.92 26.12 0.43 -0.00064 -0.00419 323 32 1 5 0 168.560 35.00 19.90 26.12 18.98 3.1 1100.00 -10166 -10367 -9312 -12371 -16645 -11589 -6638 -9454 -15157 -7207 -9995 -10870 -4753 -6460 -304 -1906 -686 66 -164 461 2458 99 -879 -101 2032 -570 -905 -1662 -1210 2402 833 1415 1193 -417 -1950 -1724 -1079 283 449 -141 -1038 -875 -600 -298 -538 -398 33 -482 31 753 751 1424 1067 1396 1031 909 982 437 592 1058 1115 1540 1601 1371 505 -393 -56 415 556 1263 400 140 -110 -241 66 -577 -281 -414 -694 -519 -1031 -1340 -1716 -1775 -1234 -839 -509 6 -223 280 362 630 530 822 826 619 230 123 -52 -274 -481 -669 -488 -44 -328 -1057 -960 -504 -388 98 96 65 60 126 165 418 488 439 81 -5 -183 -139 -56 343 670 949 578 754 998 524 287 -22 -177 201 102 -155 -91 -129 -245 -210 -130 -404 -597 -472 -545 -509 -682 -900 -581 -333 -543 -1027 -485 -727 -864 -411 -678 -32 -235 -92 9 -25 73 391 16 -151 -18 386 -116 -187 -337 -238 463 178 308 287 -107 -505 -446 -299 83 156 -54 -448 -377 -269 -136 -249 -185 15 -226 15 365 389 745 605 842 617 564 623 279 373 659 713 992 1128 990 380 -291 -40 309 416 991 348 123 -97 -205 55 -463 -207 -313 -524 -418 -903 -1258 -1685 -1860 -1313 -947 -580 7 -263 319 404 680 538 819 869 695 269 155 -68 -363 -632 -847 -579 -52 -407 -1349 -1245 -687 -544 143 146 101 94 189 240 594 682 631 119 -7 -280 -210 -85 501 965 1352 797 1044 1415 785 449 -36 -293 336 175 -272 -166 -240 -444 -383 -235 -701 -1040 SS 20260317T224902.3Z 9572.950721 102 1 54.44 2 66.76 109.45 61.55 123.77 0.00 1 0.00 1 0 25 1.582e-02 5.926e-03 9.486e-04 2.824e-04 3.604710e-01 1.499367e-04 4.197311e-03 -6.000000e+00 9.611426e-03 226.94 -2.00 3.41 -2.00 317.30 0.00e+00 4.986953e-04 2.182796e-05 8.014379e-05 -6.000000e+00 4.238747e-04 281.09 -2.00 20.00 -2.00 316.60 0.00e+00 2.515 0.000 302.00 328.00 3 1.0844e+00 3.9427e-04 3.0811e-02 -6.0000e+00 2.3816e-02 1.6994e-02 4.4235e-04 1.7916e-02 -6.0000e+00 2.5788e-02 -1.8005e-02 2.6552e-04 8.8247e-03 -6.0000e+00 1.5366e-02 3.2193e-03 1.2950e-04 2.5246e-03 -6.0000e+00 6.4490e-03 9.3141e-03 -2.9339e-04 8.9939e-06 3.4191e-05 -6.0000e+00 5.0466e-04 -1.6893e-03 0.0000e+00 10 0 0 10 0 0 99.97 26.16 0.36 -0.00169 -0.00389 1192 119 1 5 0 45.660 35.25 19.97 26.16 19.69 3.0 1100.00 -3494 -4574 -4369 -5774 -7358 -6362 -4487 -2828 -4105 -3415 -4421 -3427 -1654 -930 -25 -180 181 676 938 919 1508 1079 1200 1049 1098 556 -891 -1074 -371 709 935 1171 847 -688 -2262 -1824 -1193 -228 344 -356 -804 -769 -643 -321 -312 -63 -323 -525 -278 371 883 1222 1075 1239 735 828 901 518 581 731 1058 1507 1369 1056 440 -342 -257 150 671 1153 312 45 -97 -148 -35 -397 -362 -451 -486 -371 -969 -1389 -1781 -1722 -1215 -838 -440 -80 -162 164 381 509 322 645 881 722 369 158 -41 -225 -415 -714 -404 25 -296 -942 -793 -547 -506 137 128 139 30 100 148 374 531 463 110 -72 -250 -208 -54 413 672 969 738 834 930 536 342 -48 -160 205 53 -133 -113 -158 -224 -264 -182 -424 -598 -310 -457 -452 -588 -711 -647 -426 -293 -477 -420 -570 -466 -250 -163 -5 -37 41 160 215 220 367 267 305 282 313 166 -271 -316 -105 198 278 382 280 -241 -792 -634 -442 -90 151 -172 -436 -420 -364 -185 -181 -37 -186 -302 -159 216 513 762 683 834 520 574 637 368 407 510 754 1141 1077 853 365 -276 -206 119 533 1009 277 42 -92 -136 -31 -338 -295 -354 -397 -322 -879 -1353 -1821 -1805 -1348 -954 -509 -96 -194 191 429 549 336 655 934 814 435 200 -54 -299 -529 -875 -480 30 -359 -1223 -1048 -737 -702 197 190 212 46 148 210 517 719 647 158 -105 -378 -313 -79 597 955 1311 994 1121 1277 773 512 -73 -247 328 86 -224 -192 -275 -391 -454 -308 -711 -980 SS 20260317T225529.9Z 9572.955207 106 1 54.44 2 65.53 110.59 60.47 125.07 0.00 1 0.00 1 0 25 1.252e-02 5.885e-03 6.679e-04 2.369e-04 3.449980e-01 1.261136e-04 4.031574e-03 -6.000000e+00 7.606365e-03 226.94 -2.00 3.41 -2.00 317.00 0.00e+00 3.738924e-04 1.698051e-05 6.900532e-05 -6.000000e+00 3.355276e-04 281.09 -2.00 20.00 -2.00 316.31 0.00e+00 2.398 0.000 302.00 328.00 3 8.8035e-01 3.2977e-04 2.9405e-02 -6.0000e+00 1.8847e-02 1.5455e-02 3.6916e-04 1.7119e-02 -6.0000e+00 2.0410e-02 -1.7656e-02 2.1784e-04 8.4318e-03 -6.0000e+00 1.2161e-02 3.5579e-03 1.0410e-04 2.3897e-03 -6.0000e+00 5.1025e-03 1.3086e-02 -5.5634e-04 7.5597e-06 3.2981e-05 -6.0000e+00 3.9947e-04 6.7127e-05 0.0000e+00 10 0 0 10 0 0 93.66 26.17 0.38 0.00007 -0.00411 1292 129 1 5 0 42.130 35.00 20.05 26.17 20.28 3.1 1100.00 -2158 -3332 -3730 -4701 -5879 -4657 -3059 -1966 -2242 -2261 -3440 -2334 -805 -158 445 309 194 973 1061 1168 1502 865 699 785 930 153 -801 -1218 -414 268 721 1103 665 -604 -2223 -1718 -1251 -267 275 -249 -754 -702 -375 -293 -308 8 -366 -430 -195 341 833 1157 1031 1231 728 797 825 484 422 727 978 1403 1358 909 415 -307 -334 158 657 1225 243 -20 -85 -112 -93 -367 -291 -387 -478 -362 -958 -1451 -1761 -1691 -1190 -886 -448 -66 -153 128 375 521 356 603 869 731 405 162 33 -270 -424 -706 -351 63 -246 -953 -807 -606 -497 138 116 119 38 105 158 324 542 430 105 -57 -229 -191 -8 395 642 985 714 854 926 525 345 -35 -154 224 45 -108 -126 -136 -233 -272 -216 -450 -600 -245 -425 -495 -610 -719 -544 -367 -258 -327 -351 -513 -365 -139 -32 94 74 50 262 279 318 418 245 203 240 302 48 -257 -407 -132 85 240 374 246 -235 -866 -663 -483 -111 127 -128 -411 -408 -225 -179 -189 5 -224 -260 -118 209 509 758 691 872 517 583 615 363 313 534 735 1072 1081 746 349 -261 -270 125 545 1074 227 -19 -81 -104 -84 -314 -237 -315 -388 -313 -904 -1424 -1816 -1793 -1337 -1024 -528 -78 -181 152 429 569 374 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