File name: Pandora276s1_Tokyo-Sophia_20260319_L2Fit_fout2c4d20251211p1-8.txt File generation date: 20260331T152653.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Satoshi Inomata Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 276 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora276_OF_v3d20230804.txt Instrument calibration file used: Pandora276s1_CF_v4d20251211.txt Level 1 file used: Pandora276s1_Tokyo-Sophia_20260319_L1_smca1c4d20251211p1-8.txt Full location name: Sophia University Short location name: Tokyo-Sophia Country of location: Japan Location latitude [deg]: 35.6831 Location longitude [deg]: 139.7317 Location altitude [m]: 45 Local noon date: 20260319 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Field calibration based on session 2 First and last pixel inside fitting window: 195 337 Nominal wavelengths inside fitting window [nm]: 305.0492 305.1899 305.3305 305.4712 305.6118 305.7525 305.8931 306.0337 306.1743 306.3149 306.4554 306.5960 306.7366 306.8771 307.0176 307.1582 307.2987 307.4392 307.5796 307.7201 307.8606 308.0010 308.1415 308.2819 308.4223 308.5627 308.7031 308.8435 308.9839 309.1242 309.2646 309.4049 309.5452 309.6855 309.8258 309.9661 310.1064 310.2467 310.3869 310.5272 310.6674 310.8076 310.9479 311.0881 311.2282 311.3684 311.5086 311.6487 311.7889 311.9290 312.0691 312.2092 312.3493 312.4894 312.6295 312.7696 312.9096 313.0497 313.1897 313.3297 313.4697 313.6097 313.7497 313.8897 314.0296 314.1696 314.3095 314.4494 314.5893 314.7292 314.8691 315.0090 315.1489 315.2887 315.4286 315.5684 315.7082 315.8481 315.9879 316.1276 316.2674 316.4072 316.5469 316.6867 316.8264 316.9661 317.1058 317.2455 317.3852 317.5249 317.6645 317.8042 317.9438 318.0835 318.2231 318.3627 318.5023 318.6419 318.7814 318.9210 319.0605 319.2001 319.3396 319.4791 319.6186 319.7581 319.8976 320.0370 320.1765 320.3159 320.4553 320.5948 320.7342 320.8736 321.0129 321.1523 321.2917 321.4310 321.5704 321.7097 321.8490 321.9883 322.1276 322.2669 322.4061 322.5454 322.6846 322.8239 322.9631 323.1023 323.2415 323.3807 323.5199 323.6590 323.7982 323.9373 324.0764 324.2156 324.3547 324.4938 324.6328 324.7719 324.9110 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20260319T014013.0Z 9574.069594 211 1 28.30 2 39.67 152.42 38.45 152.23 0.00 1 0.00 1 0 17 7.765e-03 6.227e-03 2.486e-04 1.773e-04 1.815949e-01 9.609524e-05 2.184182e-03 -6.000000e+00 4.721299e-03 227.02 -2.00 3.41 -2.00 314.73 0.00e+00 2.185616e-04 7.887002e-06 1.912150e-05 -6.000000e+00 2.081425e-04 281.19 -2.00 20.00 -2.00 314.19 0.00e+00 1.298 0.000 302.00 328.00 3 9.6329e-01 2.4502e-04 1.5798e-02 -6.0000e+00 1.1701e-02 1.6046e-02 2.7105e-04 9.0638e-03 -6.0000e+00 1.2666e-02 -2.6689e-03 1.5527e-04 4.4681e-03 -6.0000e+00 7.5474e-03 -1.5911e-03 6.7064e-05 1.2642e-03 -6.0000e+00 3.1696e-03 4.6053e-02 -3.6711e-04 5.7026e-06 2.0237e-05 -6.0000e+00 2.4767e-04 -5.8939e-03 0.0000e+00 10 0 0 10 0 0 99.99 26.72 0.38 -0.00589 -0.00865 2872 288 1 5 0 9.850 35.50 20.01 26.72 25.27 3.0 1100.00 336 -1003 -1859 -2509 -2405 -969 321 1383 1006 -247 -1238 -496 434 596 579 257 -208 441 663 798 1019 621 800 909 892 501 -432 -788 46 732 1202 1413 1099 -224 -1852 -1356 -876 -299 175 -547 -1120 -1089 -895 -865 -830 -494 -858 -840 -455 9 639 934 874 1018 537 639 777 493 447 765 979 1324 1201 822 349 -408 -367 96 611 1248 265 -53 -55 -105 53 -222 -218 -229 -210 -118 -807 -1306 -1609 -1611 -1143 -784 -433 -59 -209 93 312 459 286 588 973 776 440 236 126 -156 -344 -660 -371 42 -188 -895 -810 -572 -565 75 146 157 41 84 111 250 439 370 77 -64 -199 -188 -43 342 687 1141 795 818 943 621 415 14 -183 220 57 -127 -169 -167 -231 -279 -190 -470 -719 120 -364 -688 -951 -832 -312 104 484 385 -94 -476 -192 178 253 273 123 -105 226 348 429 554 340 442 489 500 289 -250 -436 25 381 631 776 636 -126 -1089 -779 -501 -183 119 -410 -884 -905 -730 -711 -680 -400 -713 -676 -354 7 499 765 720 873 476 577 679 431 404 688 862 1225 1139 819 349 -388 -336 87 547 1213 262 -56 -58 -108 54 -214 -199 -204 -188 -109 -796 -1362 -1736 -1769 -1279 -901 -525 -72 -255 114 371 519 307 620 999 856 495 281 154 -192 -420 -781 -433 50 -226 -1113 -1021 -751 -749 101 203 222 56 112 140 305 541 452 99 -86 -268 -255 -57 451 891 1400 967 977 1160 779 529 19 -246 293 79 -180 -243 -245 -342 -411 -281 -676 -1013 SS 20260319T014041.6Z 9574.069927 211 2 28.30 2 39.63 152.60 38.41 152.41 0.00 1 0.00 1 0 25 1.612e-02 8.217e-03 5.136e-03 2.200e-03 1.859946e-01 1.157958e-03 2.204125e-03 -6.000000e+00 9.801529e-03 227.02 -2.00 3.41 -2.00 316.56 0.00e+00 -4.369024e-04 1.401174e-04 8.987217e-05 -6.000000e+00 4.321171e-04 281.19 -2.00 20.00 -2.00 315.86 0.00e+00 1.297 0.000 302.00 328.00 3 4.7351e+00 3.0131e-03 1.5926e-02 -6.0000e+00 2.4291e-02 3.9771e-02 3.3698e-03 9.3247e-03 -6.0000e+00 2.6296e-02 1.6765e-03 1.9636e-03 4.5708e-03 -6.0000e+00 1.5669e-02 -1.4926e-03 9.1220e-04 1.3383e-03 -6.0000e+00 6.5800e-03 1.0408e-03 -6.0632e-04 7.2192e-05 1.9220e-05 -6.0000e+00 5.1420e-04 -5.5472e-03 0.0000e+00 11 8 0 10 0 0 99.01 26.73 0.74 -0.00555 -0.01010 2872 288 1 5 0 9.850 35.50 20.01 26.73 25.27 3.0 1100.00 2610 -979 1531 742 -1334 -679 10389 5618 4155 4438 1771 3737 114 127 -1640 144 1314 744 -555 -904 2436 533 -222 592 1973 -418 -2480 -3573 -1631 2471 175 331 458 -2048 -3797 -1975 -1976 -666 358 -1024 -1501 -1410 -1339 -1020 -1154 -1133 -1317 -1700 -1475 448 53 192 1556 982 720 102 1010 298 735 1223 1225 1205 2328 1415 806 -938 -1305 1345 -251 1610 1046 688 780 197 882 416 523 -102 -35 37 -457 -830 -1178 -1445 -650 -358 -515 441 23 252 534 617 566 655 1024 580 -42 -28 262 -425 -728 -1054 -552 -306 -639 -1344 -1637 -689 -950 264 -56 209 98 -473 -358 94 183 438 -265 -446 -194 149 177 566 980 1470 915 369 1233 517 375 -16 -646 866 564 433 540 14 56 -313 -646 -304 -1387 431 -180 277 128 -216 -103 1449 896 736 822 339 712 24 30 -430 40 376 219 -170 -285 754 185 -79 216 741 -166 -994 -1380 -579 807 59 117 170 -792 -1450 -727 -770 -291 182 -608 -984 -884 -862 -725 -819 -795 -905 -1134 -953 281 34 131 1095 725 549 80 792 236 571 942 964 999 2035 1306 748 -836 -1081 1039 -203 1394 993 690 792 196 823 356 405 -75 -26 29 -401 -799 -1222 -1587 -752 -400 -611 537 28 301 658 695 583 639 1009 616 -49 -36 353 -580 -953 -1293 -641 -358 -794 -1787 -2292 -997 -1308 376 -84 314 143 -654 -502 122 232 565 -365 -655 -295 228 265 815 1338 1896 1131 450 1537 684 520 -24 -948 1289 880 711 917 23 89 -499 -1106 -503 -2268 SS 20260319T014433.8Z 9574.072613 214 1 3.40 2 39.27 154.01 38.04 153.82 0.00 1 0.00 1 0 17 7.567e-03 6.264e-03 1.034e-03 7.778e-04 1.814067e-01 4.226505e-04 2.188565e-03 -6.000000e+00 4.601000e-03 227.02 -2.00 3.41 -2.00 314.44 0.00e+00 2.012049e-04 3.287398e-05 1.729717e-05 -6.000000e+00 2.028406e-04 281.19 -2.00 20.00 -2.00 313.92 0.00e+00 1.291 0.000 302.00 328.00 3 1.8273e+00 1.0750e-03 1.5735e-02 -6.0000e+00 1.1403e-02 2.7122e-02 1.1894e-03 9.0546e-03 -6.0000e+00 1.2344e-02 -4.2477e-03 6.8183e-04 4.4687e-03 -6.0000e+00 7.3551e-03 -1.0463e-03 2.9135e-04 1.2640e-03 -6.0000e+00 3.0888e-03 1.9486e-02 -4.7158e-04 2.4972e-05 2.0696e-05 -6.0000e+00 2.4137e-04 -5.7566e-03 0.0000e+00 12 1 1 12 1 1 99.43 26.74 0.39 -0.00576 -0.00930 48 79 1 5 0 69.290 35.50 20.01 26.74 25.79 3.0 1100.00 257 -1026 -1703 -2159 -2078 -910 18 1304 1091 -664 -949 -625 355 488 772 339 -275 422 737 587 969 384 859 930 758 669 -482 -575 146 543 1296 1499 1198 -172 -1763 -1357 -927 -237 173 -582 -1131 -1109 -992 -828 -785 -456 -726 -707 -533 -65 732 932 961 1122 469 634 694 593 449 703 929 1314 1156 844 411 -324 -502 -107 555 1115 213 -44 -10 -104 78 -245 -149 -311 -193 -164 -780 -1374 -1585 -1671 -1112 -781 -514 -111 -283 104 222 441 348 574 984 860 359 229 163 -163 -455 -653 -327 -86 -171 -847 -804 -492 -568 51 38 188 -13 151 155 259 490 370 116 -81 -184 -186 31 395 744 1050 916 841 977 484 481 47 -150 186 14 -67 -91 -230 -272 -288 -285 -525 -705 101 -417 -706 -853 -789 -341 7 502 436 -282 -407 -271 155 236 393 179 -146 228 407 332 555 222 498 535 455 412 -298 -339 83 297 713 863 697 -103 -1042 -817 -564 -157 124 -450 -906 -907 -832 -700 -662 -380 -611 -575 -434 -52 597 772 811 986 414 569 630 538 403 629 848 1224 1118 834 408 -314 -463 -97 514 1059 217 -46 -10 -108 78 -238 -135 -270 -168 -150 -750 -1416 -1710 -1810 -1241 -905 -614 -136 -344 126 257 490 373 597 1035 945 413 274 202 -203 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