File name: Pandora276s1_Tokyo-Sophia_20260319_L2Fit_fwvt1c2d20231212p1-8.txt File generation date: 20260319T145850.7Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Satoshi Inomata Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 276 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora276_OF_v3d20230804.txt Instrument calibration file used: Pandora276s1_CF_v2d20231212.txt Level 1 file used: Pandora276s1_Tokyo-Sophia_20260319_L1_smca1c2d20231212p1-8.txt Full location name: Sophia University Short location name: Tokyo-Sophia Country of location: Japan Location latitude [deg]: 35.6831 Location longitude [deg]: 139.7317 Location altitude [m]: 45 Local noon date: 20260319 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 1619 1769 Nominal wavelengths inside fitting window [nm]: 492.0861 492.2068 492.3274 492.4481 492.5687 492.6893 492.8099 492.9304 493.0510 493.1715 493.2920 493.4125 493.5330 493.6535 493.7739 493.8944 494.0148 494.1352 494.2555 494.3759 494.4963 494.6166 494.7369 494.8572 494.9775 495.0977 495.2180 495.3382 495.4584 495.5786 495.6988 495.8190 495.9391 496.0593 496.1794 496.2995 496.4196 496.5396 496.6597 496.7797 496.8997 497.0197 497.1397 497.2596 497.3796 497.4995 497.6194 497.7393 497.8592 497.9791 498.0989 498.2187 498.3386 498.4584 498.5781 498.6979 498.8176 498.9374 499.0571 499.1768 499.2964 499.4161 499.5358 499.6554 499.7750 499.8946 500.0142 500.1337 500.2533 500.3728 500.4923 500.6118 500.7313 500.8507 500.9702 501.0896 501.2090 501.3284 501.4478 501.5671 501.6865 501.8058 501.9251 502.0444 502.1637 502.2829 502.4022 502.5214 502.6406 502.7598 502.8789 502.9981 503.1172 503.2364 503.3555 503.4746 503.5936 503.7127 503.8317 503.9507 504.0697 504.1887 504.3077 504.4266 504.5456 504.6645 504.7834 504.9023 505.0212 505.1400 505.2588 505.3777 505.4965 505.6152 505.7340 505.8528 505.9715 506.0902 506.2089 506.3276 506.4462 506.5649 506.6835 506.8021 506.9207 507.0393 507.1579 507.2764 507.3949 507.5135 507.6320 507.7504 507.8689 507.9873 508.1058 508.2242 508.3426 508.4609 508.5793 508.6976 508.8160 508.9343 509.0526 509.1708 509.2891 509.4073 509.5256 509.6438 509.7619 509.8801 509.9983 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20260319T005558.9Z 9574.038876 181 1 54.34 2 44.84 137.83 43.71 137.74 0.00 1 0.00 1 0 15 2.821e-03 2.818e-03 8.627e-04 8.614e-04 2.885900e+03 4.946158e+01 2.079907e+02 -6.000000e+00 1.484986e+02 281.19 -2.00 20.00 -2.00 505.26 0.00e+00 5.572958e-04 2.316750e-05 3.274309e-05 -6.000000e+00 7.744675e-05 281.19 -2.00 20.00 -2.00 500.46 0.00e+00 1.270941e-01 1.668829e-02 2.130932e-02 -6.000000e+00 5.493053e-02 227.02 -2.00 3.41 -2.00 502.05 0.00e+00 1.408 0.000 489.00 513.00 1 8.1930e+00 1.2732e-03 2.8123e-03 -6.0000e+00 4.1922e-03 -5.2243e-03 3.3607e-04 5.1651e-04 -6.0000e+00 1.1138e-03 4.3460e-04 4.6466e-04 7.1357e-05 2.8803e-05 -6.0000e+00 2.4011e-04 7.0764e-03 -9.8907e-06 10 0 0 10 0 0 99.74 26.55 1.55 0.00708 0.01030 15 2 1 4 0 3622.260 35.50 20.00 26.55 23.06 3.0 1100.00 -579 -515 -178 -272 261 59 477 219 -147 411 129 -51 -266 -161 146 -136 -239 306 182 161 112 193 83 183 55 444 579 -195 -114 -523 -282 -121 64 -399 -43 670 216 -159 -87 -344 137 84 220 205 403 -82 8 257 -137 -81 -575 -306 -641 -448 -318 -154 -236 237 -3 -7 480 -28 301 147 224 -107 338 -291 138 -104 135 44 465 -80 -344 -371 309 -221 -2 -291 -393 5 -85 226 -396 143 -294 -341 10 -76 387 388 -59 36 204 159 482 -210 -652 -413 -33 113 -56 -425 -251 53 -145 -200 42 239 -400 -275 -31 443 229 464 71 145 190 248 317 -90 -81 -176 -114 295 196 124 425 422 -304 -20 259 -50 -44 63 -152 -171 -34 -262 -36 184 244 442 -127 71 -725 -379 14 -11 900000 -559 -508 -179 -277 265 61 502 228 -152 426 132 -52 -271 -161 146 -137 -245 314 189 168 117 202 87 191 58 466 604 -203 -116 -527 -282 -121 64 -410 -46 705 225 -164 -89 -348 141 85 226 214 424 -85 9 265 -139 -81 -573 -297 -618 -436 -313 -156 -240 243 -3 -7 486 -29 310 152 228 -108 339 -290 135 -100 132 43 453 -80 -339 -370 300 -212 -2 -280 -382 5 -83 220 -394 140 -289 -334 9 -75 380 387 -59 37 206 157 475 -202 -625 -388 -31 107 -54 -422 -251 53 -143 -197 41 233 -393 -274 -31 448 233 464 71 147 191 250 314 -88 -80 -172 -112 289 192 121 414 412 -297 -19 247 -48 -42 60 -149 -168 -33 -259 -36 182 243 444 -128 72 -718 -370 14 -10 900000 SQ 20260319T014110.6Z 9574.070262 212 1 15.07 2 39.58 152.77 38.36 152.58 0.00 1 0.00 1 0 15 1.990e-03 1.986e-03 8.196e-04 8.183e-04 2.011947e+03 4.582174e+01 1.516607e+02 -6.000000e+00 1.047381e+02 281.19 -2.00 20.00 -2.00 505.28 0.00e+00 4.258835e-04 2.195749e-05 2.415931e-05 -6.000000e+00 5.450065e-05 281.19 -2.00 20.00 -2.00 500.51 0.00e+00 1.038123e-02 1.564156e-02 1.418262e-02 -6.000000e+00 3.828521e-02 227.02 -2.00 3.41 -2.00 502.10 0.00e+00 1.296 0.000 489.00 513.00 1 6.8318e+00 1.1962e-03 2.2869e-03 -6.0000e+00 2.9291e-03 3.2203e-03 3.1175e-04 3.6296e-04 -6.0000e+00 7.6554e-04 1.7433e-03 1.4838e-03 6.7643e-05 2.0408e-05 -6.0000e+00 1.6858e-04 4.0512e-03 -2.1873e-05 12 1 1 12 1 1 99.99 26.73 1.54 0.00405 0.01434 19 7 1 4 0 752.990 35.50 20.01 26.73 25.36 3.0 1100.00 -354 -441 -130 -19 232 198 244 166 -44 252 -68 12 -178 -295 6 25 -101 -148 -148 166 198 164 135 212 24 414 279 -86 -269 -449 -25 45 66 -372 137 288 144 -21 54 -82 -10 135 -114 223 158 163 77 76 20 -233 -421 -326 -175 -266 -289 -139 -196 58 225 130 275 40 84 157 178 89 137 70 -154 -254 -117 151 135 -211 -240 -99 170 -113 -108 -302 -127 -95 -93 -28 -94 123 -98 -112 172 211 296 190 57 217 53 137 314 -37 -578 -327 29 16 -21 -366 -411 -115 -227 115 -49 54 -371 35 0 122 282 354 195 74 114 48 50 141 128 -79 -55 135 -122 171 288 133 -190 -155 79 -30 131 -27 -198 -26 43 -133 188 169 231 265 41 36 -356 -470 -174 83 -140 -342 -436 -129 -20 238 207 256 175 -46 260 -70 13 -181 -295 6 25 -104 -152 -154 173 206 171 141 221 26 434 292 -89 -276 -451 -25 45 66 -387 144 304 149 -22 56 -84 -10 139 -117 231 166 168 80 78 21 -235 -417 -319 -170 -261 -284 -139 -198 59 228 131 278 41 86 161 180 90 136 69 -152 -250 -114 148 132 -210 -238 -97 165 -110 -104 -290 -122 -92 -91 -27 -92 121 -97 -110 170 208 294 189 57 218 53 135 308 -36 -553 -306 28 16 -20 -362 -413 -115 -227 113 -48 53 -368 35 0 122 283 357 198 75 115 48 50 139 125 -78 -54 132 -120 169 284 130 -187 -149 76 -29 125 -26 -192 -26 43 -131 186 167 231 266 41 36 -351 -455 -166 79 -134 SQ 20260319T014448.5Z 9574.072784 215 1 5.82 2 39.25 154.10 38.02 153.92 0.00 1 0.00 1 0 15 2.061e-03 2.053e-03 9.510e-05 9.499e-05 1.672840e+03 5.246145e+00 1.242951e+02 -6.000000e+00 1.084839e+02 281.19 -2.00 20.00 -2.00 505.28 0.00e+00 4.886792e-04 2.548753e-06 2.795309e-05 -6.000000e+00 5.645103e-05 281.19 -2.00 20.00 -2.00 500.56 0.00e+00 -7.179510e-03 1.809725e-03 1.274443e-02 -6.000000e+00 3.965802e-02 227.02 -2.00 3.41 -2.00 502.14 0.00e+00 1.290 0.000 489.00 513.00 1 4.8806e-01 1.3839e-04 2.2353e-03 -6.0000e+00 3.0341e-03 -1.0839e-02 3.6062e-05 3.1702e-04 -6.0000e+00 7.9306e-04 9.9393e-01 1.6317e-03 7.8857e-06 1.7819e-05 -6.0000e+00 1.7463e-04 4.4723e-03 -3.0124e-05 10 0 0 10 0 0 99.84 26.74 1.52 0.00447 0.01579 1270 127 2 4 0 4.580 35.50 20.01 26.74 25.79 3.0 1100.00 -390 -349 -305 63 328 205 279 313 84 165 122 18 -142 -385 -101 68 75 -115 -198 113 132 172 270 97 160 275 307 -172 -228 -248 -19 124 18 -357 18 211 51 -6 -18 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