File name: Pandora276s1_Tokyo-Sophia_20260604_L2Fit_fout2c4d20251211p1-8.txt File generation date: 20260604T144821.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Satoshi Inomata Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 276 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora276_OF_v3d20230804.txt Instrument calibration file used: Pandora276s1_CF_v4d20251211.txt Level 1 file used: Pandora276s1_Tokyo-Sophia_20260604_L1_smca1c4d20251211p1-8.txt Full location name: Sophia University Short location name: Tokyo-Sophia Country of location: Japan Location latitude [deg]: 35.6831 Location longitude [deg]: 139.7317 Location altitude [m]: 45 Local noon date: 20260604 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Field calibration based on session 2 First and last pixel inside fitting window: 195 337 Nominal wavelengths inside fitting window [nm]: 305.0492 305.1899 305.3305 305.4712 305.6118 305.7525 305.8931 306.0337 306.1743 306.3149 306.4554 306.5960 306.7366 306.8771 307.0176 307.1582 307.2987 307.4392 307.5796 307.7201 307.8606 308.0010 308.1415 308.2819 308.4223 308.5627 308.7031 308.8435 308.9839 309.1242 309.2646 309.4049 309.5452 309.6855 309.8258 309.9661 310.1064 310.2467 310.3869 310.5272 310.6674 310.8076 310.9479 311.0881 311.2282 311.3684 311.5086 311.6487 311.7889 311.9290 312.0691 312.2092 312.3493 312.4894 312.6295 312.7696 312.9096 313.0497 313.1897 313.3297 313.4697 313.6097 313.7497 313.8897 314.0296 314.1696 314.3095 314.4494 314.5893 314.7292 314.8691 315.0090 315.1489 315.2887 315.4286 315.5684 315.7082 315.8481 315.9879 316.1276 316.2674 316.4072 316.5469 316.6867 316.8264 316.9661 317.1058 317.2455 317.3852 317.5249 317.6645 317.8042 317.9438 318.0835 318.2231 318.3627 318.5023 318.6419 318.7814 318.9210 319.0605 319.2001 319.3396 319.4791 319.6186 319.7581 319.8976 320.0370 320.1765 320.3159 320.4553 320.5948 320.7342 320.8736 321.0129 321.1523 321.2917 321.4310 321.5704 321.7097 321.8490 321.9883 322.1276 322.2669 322.4061 322.5454 322.6846 322.8239 322.9631 323.1023 323.2415 323.3807 323.5199 323.6590 323.7982 323.9373 324.0764 324.2156 324.3547 324.4938 324.6328 324.7719 324.9110 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20260604T003406.8Z 9651.023690 4 1 10.59 2 30.24 107.45 116.39 257.06 0.00 1 0.00 1 0 17 7.570e-03 6.310e-03 3.511e-04 2.695e-04 1.712475e-01 1.493111e-04 2.030919e-03 -6.000000e+00 4.690822e-03 232.23 -2.00 3.41 -2.00 314.33 0.00e+00 2.273616e-04 1.149103e-05 1.635027e-05 -6.000000e+00 2.090675e-04 288.40 -2.00 20.00 -2.00 313.72 0.00e+00 1.157 0.000 302.00 328.00 3 9.7525e-01 3.8340e-04 1.4534e-02 -6.0000e+00 1.1744e-02 1.4253e-02 4.2171e-04 8.7012e-03 -6.0000e+00 1.2650e-02 -1.3518e-03 2.4161e-04 4.2267e-03 -6.0000e+00 7.5386e-03 -2.0480e-03 1.0261e-04 1.1693e-03 -6.0000e+00 3.1545e-03 5.3013e-02 -3.6408e-04 8.6691e-06 1.9143e-05 -6.0000e+00 2.4190e-04 -3.0083e-03 0.0000e+00 12 1 1 12 1 1 99.91 27.71 0.39 -0.00301 -0.00574 405 209 1 5 0 26.070 36.25 20.01 27.71 32.74 9.9 989.38 518 -894 -1669 -2221 -2253 -715 355 1334 969 -248 -1090 -556 476 499 540 152 -213 386 551 693 966 579 838 914 813 448 -415 -836 99 760 1177 1448 1141 -241 -1890 -1336 -868 -248 186 -528 -1138 -1089 -836 -888 -794 -469 -877 -769 -416 48 677 988 862 1020 515 656 799 535 478 699 947 1336 1156 819 354 -365 -404 38 605 1172 175 -82 -81 -119 95 -238 -269 -242 -244 -156 -801 -1327 -1648 -1615 -1090 -768 -414 -127 -252 91 325 493 261 551 976 781 463 234 117 -165 -327 -627 -351 45 -229 -931 -820 -600 -576 85 126 137 27 121 115 295 459 394 130 -14 -131 -139 -20 362 729 1128 800 895 992 599 414 -3 -186 205 15 -174 -156 -210 -260 -328 -196 -477 -696 211 -377 -715 -951 -881 -274 138 530 421 -108 -482 -247 224 247 282 82 -120 213 310 399 563 339 495 535 496 281 -260 -501 58 437 681 840 695 -145 -1166 -805 -531 -165 135 -413 -922 -927 -707 -758 -675 -394 -744 -629 -339 38 553 819 751 897 455 588 724 485 429 626 866 1248 1121 810 351 -351 -380 34 556 1137 177 -85 -85 -122 97 -228 -247 -215 -217 -145 -784 -1353 -1760 -1774 -1236 -905 -491 -156 -311 109 382 556 276 565 1011 846 524 276 143 -202 -394 -725 -396 51 -270 -1150 -1038 -773 -757 114 171 188 37 158 144 353 549 484 162 -19 -173 -185 -27 465 909 1393 969 1064 1184 738 522 -3 -241 273 20 -244 -222 -300 -376 -471 -279 -677 -968 SS 20260604T003815.6Z 9651.026569 7 1 12.12 2 29.44 108.51 117.18 257.56 0.00 1 0.00 1 0 17 7.625e-03 6.332e-03 3.023e-04 2.330e-04 1.699871e-01 1.292423e-04 2.020423e-03 -6.000000e+00 4.724967e-03 232.23 -2.00 3.41 -2.00 314.31 0.00e+00 2.215221e-04 9.894634e-06 1.816164e-05 -6.000000e+00 2.105846e-04 288.40 -2.00 20.00 -2.00 313.70 0.00e+00 1.148 0.000 302.00 328.00 3 8.3052e-01 3.3175e-04 1.4428e-02 -6.0000e+00 1.1829e-02 1.5598e-02 3.6487e-04 8.6479e-03 -6.0000e+00 1.2742e-02 -1.3073e-03 2.0909e-04 4.2027e-03 -6.0000e+00 7.5934e-03 -2.0635e-03 8.8766e-05 1.1633e-03 -6.0000e+00 3.1775e-03 6.1957e-02 -3.5621e-04 7.4940e-06 1.9012e-05 -6.0000e+00 2.4365e-04 -3.2257e-03 0.0000e+00 12 1 1 12 1 1 99.93 27.72 0.39 -0.00323 -0.00590 549 248 1 5 0 22.030 36.25 20.01 27.72 32.98 10.0 990.81 453 -836 -1635 -2335 -2251 -739 189 1335 1008 -37 -1207 -502 419 445 586 162 -281 412 637 761 995 667 851 936 836 485 -461 -744 69 745 1231 1429 1144 -179 -1909 -1372 -882 -301 129 -539 -1172 -1078 -874 -856 -813 -453 -866 -829 -409 54 696 1009 838 979 524 666 767 499 496 698 933 1317 1157 838 337 -383 -394 -5 605 1202 204 -39 -111 -113 45 -189 -244 -242 -207 -111 -851 -1300 -1627 -1609 -1099 -805 -405 -137 -222 89 331 454 280 566 998 764 449 243 116 -122 -344 -643 -317 47 -243 -926 -814 -586 -550 60 100 168 30 110 122 291 466 383 84 -46 -150 -189 -73 366 661 1179 882 865 973 637 427 34 -139 183 29 -177 -197 -224 -249 -301 -222 -486 -698 187 -356 -707 -1011 -888 -286 74 534 441 -16 -538 -225 198 222 308 88 -159 228 360 440 583 393 505 551 513 306 -291 -447 40 430 715 831 698 -108 -1180 -829 -541 -201 94 -422 -951 -919 -740 -732 -692 -380 -735 -679 -334 43 568 836 729 860 462 596 694 452 445 623 852 1228 1120 827 333 -368 -370 -5 554 1162 206 -41 -116 -118 45 -181 -224 -214 -183 -103 -830 -1320 -1730 -1760 -1240 -944 -490 -168 -272 109 388 510 295 593 1029 824 506 292 141 -149 -412 -758 -365 53 -285 -1138 -1024 -751 -718 79 135 230 41 142 152 354 553 467 107 -59 -198 -251 -97 468 838 1446 1059 1020 1181 797 546 44 -182 241 39 -247 -278 -324 -357 -438 -314 -684 -963 SS 20260604T004242.8Z 9651.029663 10 1 14.30 2 28.59 109.69 118.02 258.11 0.00 1 0.00 1 0 17 7.616e-03 6.349e-03 2.838e-04 2.199e-04 1.685524e-01 1.217855e-04 1.999596e-03 -6.000000e+00 4.719645e-03 232.23 -2.00 3.41 -2.00 314.27 0.00e+00 2.178231e-04 9.311504e-06 1.827172e-05 -6.000000e+00 2.103487e-04 288.40 -2.00 20.00 -2.00 313.67 0.00e+00 1.138 0.000 302.00 328.00 3 8.9267e-01 3.1267e-04 1.4303e-02 -6.0000e+00 1.1816e-02 1.5526e-02 3.4390e-04 8.5649e-03 -6.0000e+00 1.2727e-02 -1.5139e-03 1.9700e-04 4.1603e-03 -6.0000e+00 7.5849e-03 -1.8910e-03 8.3540e-05 1.1515e-03 -6.0000e+00 3.1739e-03 5.8949e-02 -3.8310e-04 7.0637e-06 1.9001e-05 -6.0000e+00 2.4338e-04 -3.1696e-03 0.0000e+00 12 1 1 12 1 1 99.73 27.75 0.39 -0.00317 -0.00605 602 230 1 5 0 23.710 36.25 20.01 27.75 33.32 10.1 992.44 436 -893 -1495 -2278 -2334 -695 210 1467 1009 -152 -1185 -565 482 426 591 189 -315 362 599 660 1002 551 887 945 873 441 -427 -736 86 709 1206 1479 1092 -290 -1891 -1322 -852 -284 207 -536 -1158 -1095 -923 -899 -777 -472 -823 -812 -444 33 701 987 840 991 509 630 754 507 439 725 976 1322 1188 764 323 -415 -403 41 624 1190 221 -25 -87 -93 91 -202 -236 -217 -259 -114 -846 -1320 -1626 -1616 -1080 -825 -436 -117 -218 52 312 515 266 608 971 735 407 243 124 -160 -343 -628 -309 81 -200 -929 -799 -580 -595 35 114 151 31 112 124 256 486 415 114 -56 -205 -143 -41 342 708 1170 837 872 997 680 432 28 -143 161 61 -153 -201 -195 -276 -321 -219 -466 -729 183 -387 -658 -956 -939 -274 84 597 428 -68 -538 -257 221 216 315 104 -174 203 344 388 595 329 533 564 542 271 -263 -449 51 415 709 869 674 -177 -1137 -807 -527 -192 152 -424 -949 -916 -790 -776 -668 -400 -705 -672 -366 27 577 825 716 878 452 569 687 463 397 653 897 1242 1158 760 322 -402 -381 37 574 1158 224 -26 -92 -95 90 -194 -218 -193 -232 -107 -829 -1348 -1738 -1777 -1225 -951 -517 -143 -269 62 367 581 282 624 1005 796 461 286 151 -197 -413 -726 -348 92 -236 -1146 -1010 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