File name: Pandora276s1_Tokyo-Sophia_20260604_L2Fit_fwvt1c4d20251211p1-8.txt File generation date: 20260604T144646.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c4p1-8 Local principal investigator: Satoshi Inomata Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 276 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora276_OF_v3d20230804.txt Instrument calibration file used: Pandora276s1_CF_v4d20251211.txt Level 1 file used: Pandora276s1_Tokyo-Sophia_20260604_L1_smca1c4d20251211p1-8.txt Full location name: Sophia University Short location name: Tokyo-Sophia Country of location: Japan Location latitude [deg]: 35.6831 Location longitude [deg]: 139.7317 Location altitude [m]: 45 Local noon date: 20260604 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Field calibration based on session 2 First and last pixel inside fitting window: 1619 1769 Nominal wavelengths inside fitting window [nm]: 492.0866 492.2073 492.3279 492.4485 492.5691 492.6897 492.8103 492.9308 493.0514 493.1719 493.2924 493.4129 493.5333 493.6538 493.7742 493.8946 494.0150 494.1354 494.2558 494.3761 494.4964 494.6168 494.7370 494.8573 494.9776 495.0978 495.2181 495.3383 495.4585 495.5787 495.6988 495.8190 495.9391 496.0592 496.1793 496.2994 496.4194 496.5395 496.6595 496.7795 496.8995 497.0195 497.1395 497.2594 497.3793 497.4993 497.6191 497.7390 497.8589 497.9787 498.0986 498.2184 498.3382 498.4579 498.5777 498.6974 498.8172 498.9369 499.0566 499.1762 499.2959 499.4155 499.5352 499.6548 499.7744 499.8939 500.0135 500.1330 500.2526 500.3721 500.4916 500.6110 500.7305 500.8499 500.9694 501.0888 501.2081 501.3275 501.4469 501.5662 501.6855 501.8048 501.9241 502.0434 502.1627 502.2819 502.4011 502.5203 502.6395 502.7587 502.8778 502.9970 503.1161 503.2352 503.3543 503.4733 503.5924 503.7114 503.8304 503.9494 504.0684 504.1874 504.3063 504.4252 504.5442 504.6631 504.7819 504.9008 505.0197 505.1385 505.2573 505.3761 505.4949 505.6136 505.7324 505.8511 505.9698 506.0885 506.2072 506.3258 506.4445 506.5631 506.6817 506.8003 506.9189 507.0374 507.1560 507.2745 507.3930 507.5115 507.6300 507.7484 507.8669 507.9853 508.1037 508.2221 508.3405 508.4588 508.5771 508.6955 508.8138 508.9321 509.0503 509.1686 509.2868 509.4050 509.5232 509.6414 509.7596 509.8777 509.9958 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20260604T003423.2Z 9651.023879 5 1 5.93 2 30.19 107.52 116.44 257.09 0.00 1 0.00 1 0 15 1.991e-03 1.985e-03 8.057e-05 8.046e-05 1.974860e+03 4.615913e+00 1.410393e+02 -6.000000e+00 1.078473e+02 288.40 -2.00 20.00 -2.00 505.26 0.00e+00 3.483037e-04 2.202142e-06 2.099013e-05 -6.000000e+00 5.565293e-05 288.40 -2.00 20.00 -2.00 500.49 0.00e+00 -1.811500e-02 1.556840e-03 1.362260e-02 -6.000000e+00 3.888285e-02 232.23 -2.00 3.41 -2.00 502.07 0.00e+00 1.156 0.000 489.00 513.00 1 9.8760e-01 1.1904e-04 2.0765e-03 -6.0000e+00 2.9737e-03 -5.9582e-03 3.1472e-05 3.3430e-04 -6.0000e+00 7.8946e-04 6.1611e-01 1.2160e-03 6.6860e-06 1.7516e-05 -6.0000e+00 1.6959e-04 -4.6217e-04 4.0994e-05 10 0 0 10 0 0 99.73 27.71 1.50 -0.00046 0.00797 1242 124 1 4 0 4.770 36.25 20.01 27.71 32.74 9.9 989.56 -342 -339 -288 55 317 172 245 272 49 168 117 21 -178 -350 -58 90 80 -146 -188 118 123 180 301 116 142 239 284 -174 -237 -206 8 147 24 -365 1 224 43 -11 -7 -42 -141 52 85 153 122 155 144 184 -79 -211 -395 -422 -129 -98 -240 -249 -127 32 159 151 216 125 197 61 60 140 130 38 -307 -294 -143 85 231 -212 -331 -149 107 6 -237 -259 -242 -162 -42 -151 -155 33 -115 -130 41 155 238 189 125 80 148 117 215 -83 -526 -362 -15 -10 -38 -488 -333 -147 -135 13 18 -111 -98 -21 -15 86 303 395 398 138 115 90 169 191 251 -70 45 122 49 227 440 -12 -163 -161 -59 38 162 -135 -151 78 61 -80 110 206 198 199 122 -141 -435 -369 -173 -36 900000 -329 -331 -287 55 324 177 256 283 51 173 119 21 -180 -349 -59 90 81 -149 -196 124 129 188 314 121 148 249 295 -180 -241 -206 8 147 24 -376 1 232 44 -12 -7 -43 -144 53 88 158 126 161 149 188 -80 -211 -391 -411 -124 -96 -237 -250 -130 32 161 153 220 127 201 62 60 140 129 37 -302 -286 -139 83 227 -209 -330 -147 104 6 -228 -249 -233 -158 -41 -148 -153 33 -113 -129 40 153 236 189 126 81 148 116 211 -80 -503 -342 -14 -9 -37 -486 -334 -147 -135 12 18 -108 -96 -21 -15 87 307 401 404 141 116 90 168 187 247 -69 44 121 48 224 432 -12 -160 -157 -57 37 154 -129 -146 77 61 -80 109 205 198 201 122 -142 -434 -360 -167 -35 900000 SQ 20260604T003429.3Z 9651.023950 5 2 5.93 2 30.17 107.54 116.46 257.10 0.00 1 0.00 1 0 15 1.987e-03 1.981e-03 8.978e-05 8.967e-05 1.958003e+03 5.135539e+00 1.402576e+02 -6.000000e+00 1.076204e+02 288.40 -2.00 20.00 -2.00 505.26 0.00e+00 3.493111e-04 2.454451e-06 2.108672e-05 -6.000000e+00 5.553595e-05 288.40 -2.00 20.00 -2.00 500.50 0.00e+00 -1.438389e-02 1.733838e-03 1.344329e-02 -6.000000e+00 3.880143e-02 232.23 -2.00 3.41 -2.00 502.08 0.00e+00 1.156 0.000 489.00 513.00 1 1.2027e+00 1.3259e-04 2.0688e-03 -6.0000e+00 2.9675e-03 -5.3168e-03 3.5052e-05 3.3097e-04 -6.0000e+00 7.8782e-04 4.9677e-01 1.2239e-03 7.4570e-06 1.7412e-05 -6.0000e+00 1.6923e-04 -3.2109e-04 3.9265e-05 10 0 0 10 0 0 99.89 27.71 1.50 -0.00032 0.00817 1242 124 1 4 0 4.770 36.25 20.01 27.71 32.74 9.9 989.56 -349 -347 -312 55 304 201 270 271 67 135 87 3 -148 -364 -57 81 80 -140 -190 132 150 158 277 94 148 246 290 -179 -240 -211 7 151 11 -385 -6 194 32 -15 -6 -35 -85 93 130 159 139 170 168 165 -92 -201 -407 -432 -104 -86 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-362 -154 -37 900000 SQ 20260604T003435.3Z 9651.024019 5 3 5.93 2 30.15 107.57 116.48 257.11 0.00 1 0.00 1 0 15 1.969e-03 1.963e-03 8.520e-05 8.510e-05 1.966429e+03 4.869170e+00 1.404895e+02 -6.000000e+00 1.066614e+02 288.40 -2.00 20.00 -2.00 505.26 0.00e+00 3.627899e-04 2.328561e-06 2.190874e-05 -6.000000e+00 5.504098e-05 288.40 -2.00 20.00 -2.00 500.49 0.00e+00 -1.425846e-02 1.645530e-03 1.358704e-02 -6.000000e+00 3.845525e-02 232.23 -2.00 3.41 -2.00 502.08 0.00e+00 1.156 0.000 489.00 513.00 1 1.0992e+00 1.2581e-04 2.0794e-03 -6.0000e+00 2.9410e-03 -5.5670e-03 3.3287e-05 3.3290e-04 -6.0000e+00 7.8078e-04 5.5081e-01 1.2053e-03 7.0738e-06 1.7633e-05 -6.0000e+00 1.6773e-04 -4.3554e-04 4.0976e-05 10 0 0 10 0 0 99.76 27.71 1.50 -0.00044 0.00792 1242 124 1 4 0 4.770 36.25 20.00 27.71 32.74 9.9 989.56 -361 -348 -309 54 325 193 279 298 76 161 118 20 -154 -365 -77 78 65 -127 -193 128 134 163 245 95 141 229 277 -185 -247 -222 21 131 16 -368 -19 209 37 -11 -28 -56 -86 100 135 194 122 168 148 168 -97 -210 -391 -413 -116 -99 -241 -243 -139 26 150 130 184 109 206 82 66 123 135 46 -290 -287 -139 66 209 -232 -331 -160 104 2 -234 -236 -259 -155 -35 -117 -115 61 -94 -120 39 119 227 189 105 75 151 114 209 -65 -517 -335 -15 -10 -64 -470 -306 -139 -128 -1 1 -92 -107 -3 -19 96 288 408 384 124 97 96 157 194 286 -40 33 121 46 197 412 -30 -191 -182 -55 38 160 -169 -189 49 74 -57 141 222 194 197 133 -126 -418 -362 -157 -42 900000 -347 -339 -307 54 331 199 290 312 80 166 121 21 -154 -366 -77 78 66 -131 -200 134 140 170 255 99 147 240 289 -191 -251 -221 21 130 16 -378 -20 218 38 -11 -29 -57 -88 102 139 200 127 175 152 172 -99 -210 -386 -401 -112 -96 -238 -244 -141 26 153 132 186 112 209 83 67 124 135 45 -287 -281 -135 64 205 -229 -329 -158 102 2 -225 -226 -250 -150 -34 -114 -113 60 -94 -119 39 118 224 188 106 76 151 113 206 -63 -496 -318 -14 -10 -62 -467 -309 -140 -128 -1 1 -90 -106 -3 -19 97 290 412 391 126 98 96 156 191 280 -40 33 119 46 194 407 -30 -187 -177 -53 36 153 -163 -184 48 73 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