File name: Pandora276s1_Tokyo-Sophia_20260614_L2Fit_fout2c4d20251211p1-8.txt File generation date: 20260614T145325.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Satoshi Inomata Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 276 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora276_OF_v3d20230804.txt Instrument calibration file used: Pandora276s1_CF_v4d20251211.txt Level 1 file used: Pandora276s1_Tokyo-Sophia_20260614_L1_smca1c4d20251211p1-8.txt Full location name: Sophia University Short location name: Tokyo-Sophia Country of location: Japan Location latitude [deg]: 35.6831 Location longitude [deg]: 139.7317 Location altitude [m]: 45 Local noon date: 20260614 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Field calibration based on session 2 First and last pixel inside fitting window: 195 337 Nominal wavelengths inside fitting window [nm]: 305.0492 305.1899 305.3305 305.4712 305.6118 305.7525 305.8931 306.0337 306.1743 306.3149 306.4554 306.5960 306.7366 306.8771 307.0176 307.1582 307.2987 307.4392 307.5796 307.7201 307.8606 308.0010 308.1415 308.2819 308.4223 308.5627 308.7031 308.8435 308.9839 309.1242 309.2646 309.4049 309.5452 309.6855 309.8258 309.9661 310.1064 310.2467 310.3869 310.5272 310.6674 310.8076 310.9479 311.0881 311.2282 311.3684 311.5086 311.6487 311.7889 311.9290 312.0691 312.2092 312.3493 312.4894 312.6295 312.7696 312.9096 313.0497 313.1897 313.3297 313.4697 313.6097 313.7497 313.8897 314.0296 314.1696 314.3095 314.4494 314.5893 314.7292 314.8691 315.0090 315.1489 315.2887 315.4286 315.5684 315.7082 315.8481 315.9879 316.1276 316.2674 316.4072 316.5469 316.6867 316.8264 316.9661 317.1058 317.2455 317.3852 317.5249 317.6645 317.8042 317.9438 318.0835 318.2231 318.3627 318.5023 318.6419 318.7814 318.9210 319.0605 319.2001 319.3396 319.4791 319.6186 319.7581 319.8976 320.0370 320.1765 320.3159 320.4553 320.5948 320.7342 320.8736 321.0129 321.1523 321.2917 321.4310 321.5704 321.7097 321.8490 321.9883 322.1276 322.2669 322.4061 322.5454 322.6846 322.8239 322.9631 323.1023 323.2415 323.3807 323.5199 323.6590 323.7982 323.9373 324.0764 324.2156 324.3547 324.4938 324.6328 324.7719 324.9110 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20260613T210941.0Z 9660.881725 126 1 53.44 2 71.19 74.42 54.71 81.59 0.00 1 0.00 1 0 17 2.299e-01 1.933e-02 4.323e-02 3.642e-03 4.496954e-01 1.984181e-03 5.105034e-03 -6.000000e+00 1.433064e-01 232.69 -2.00 3.41 -2.00 319.36 0.00e+00 1.896180e-03 5.416561e-04 8.405183e-04 -6.000000e+00 6.454932e-03 289.32 -2.00 20.00 -2.00 318.55 0.00e+00 3.063 0.000 302.00 328.00 3 5.0862e+00 5.6356e-03 3.8517e-02 -6.0000e+00 3.5875e-01 2.7457e-02 6.6033e-03 2.3306e-02 -6.0000e+00 3.8627e-01 -6.5388e-02 4.7854e-03 1.1548e-02 -6.0000e+00 2.2986e-01 3.3737e-02 2.4573e-03 3.4390e-03 -6.0000e+00 9.6012e-02 8.8283e-05 -2.3172e-04 1.1743e-04 4.5126e-05 -6.0000e+00 7.3482e-03 -2.4428e-03 0.0000e+00 12 9 8 11 8 0 99.94 27.72 0.84 -0.00244 -0.00418 18 2 1 5 0 2968.700 36.25 20.00 27.72 31.08 10.1 983.10 -60651 -48138 -48996 10743 -62986 900000 -20137 -72956 -40843 23334 -54685 -61967 -29839 -33938 83917 -21155 14523 10884 -13659 -3277 102334 -25085 -19436 -15174 124627 -8740 1911 19632 -26454 58177 13822 8241 -3372 8826 -4439 -923 11125 16723 8798 -1516 -1594 -1453 -4669 9428 -7504 -7190 12800 1683 243 21173 392 72 2633 3847 4020 4820 6403 -3290 -516 10674 -225 -1560 5106 7135 1328 -7381 -3744 3105 -1571 -236 2757 1840 224 1236 1609 -1724 639 -2118 -2902 -667 -37 664 -3023 -3560 -1970 -1624 -1545 -273 -367 1495 -3764 -128 272 7141 826 -452 -1403 -657 -901 -641 824 261 42 -381 1084 -2289 -1574 -1030 -92 41 498 452 166 54 -859 1328 726 212 842 137 -513 1365 728 223 1309 492 461 -363 2496 1409 -151 -889 -946 -44 -543 261 2269 -1234 -18 -1075 -580 -244 -204 -1919 -1523 -1645 194 -2237 900000 -522 -3226 -1595 514 -2757 -3653 -1483 -2109 1907 -1577 835 700 -1193 -270 3016 -2681 -2022 -1600 3452 -959 190 1596 -3335 3223 1305 928 -472 1150 -656 -132 1517 2500 1699 -346 -407 -398 -1379 2477 -2364 -2279 3339 493 73 5924 131 26 1015 1565 1715 2113 2826 -1604 -242 4452 -108 -812 2726 4040 755 -4482 -2115 1788 -926 -153 1902 1350 168 886 1072 -1084 394 -1309 -1907 -443 -28 557 -2649 -3349 -1945 -1704 -1709 -309 -417 1621 -4057 -124 246 6456 778 -480 -1577 -818 -1211 -871 1056 311 47 -428 1261 -2925 -2107 -1452 -128 61 802 710 260 87 -1313 1886 1023 310 1287 221 -852 2200 1147 341 1892 686 666 -532 3530 2195 -257 -1506 -1670 -81 -993 499 4386 -2517 -36 -2153 -1111 -472 -383 SS 20260613T211521.4Z 9660.885664 129 1 54.80 2 70.08 75.14 53.60 82.25 0.00 1 0.00 1 0 17 1.251e-01 1.262e-02 2.448e-02 2.436e-03 4.265543e-01 1.320766e-03 4.834886e-03 -6.000000e+00 7.764292e-02 232.69 -2.00 3.41 -2.00 318.90 0.00e+00 -2.251077e-05 3.105060e-04 3.441682e-04 -6.000000e+00 3.469369e-03 289.32 -2.00 20.00 -2.00 318.07 0.00e+00 2.903 0.000 302.00 328.00 3 4.6600e+00 3.6812e-03 3.6464e-02 -6.0000e+00 1.9454e-01 -7.5148e-03 4.2356e-03 2.1981e-02 -6.0000e+00 2.0947e-01 -3.1547e-02 2.9176e-03 1.0589e-02 -6.0000e+00 1.2486e-01 1.4476e-02 1.5052e-03 2.8632e-03 -6.0000e+00 5.2221e-02 1.6560e-04 -5.2679e-04 7.8230e-05 3.6524e-05 -6.0000e+00 3.9995e-03 -4.3420e-05 0.0000e+00 12 9 8 11 32 0 99.91 27.73 0.60 -0.00004 -0.00400 28 3 1 5 0 1957.080 36.25 20.01 27.73 31.36 10.0 984.31 -32793 -32634 -36708 -9628 -26450 10735 -11632 -32772 -26542 13619 68708 -39227 -23327 -29328 27175 4321 10948 -1004 -9909 -5802 42781 -18053 -6756 -11484 45459 -4999 -6476 9575 -12339 25665 14543 4861 -5252 -1923 -7506 -2673 2344 6516 4771 -1047 -1182 -1030 -3064 4790 -3910 -3392 5305 992 -693 10436 -982 -561 -125 2061 1734 3179 3723 -1189 1750 -379 -27 608 3261 4875 620 -4326 -1105 1293 -13 423 1703 196 606 -122 880 -932 490 -1062 -2469 -1036 -379 240 -2449 -2807 -1396 -1098 -791 1245 -62 771 -1706 158 31 884 2192 -124 -584 -457 1028 546 -343 -412 -268 -320 -780 -1713 -1478 -628 407 -384 157 483 146 -157 -452 592 506 465 373 -126 -431 572 127 532 995 1083 804 273 984 803 634 -795 -536 -169 -197 87 983 -698 -19 -518 -428 -366 -185 -1122 -1256 -1544 -302 -924 252 -362 -1409 -1198 443 1355 -2461 -1435 -2272 1408 320 832 -92 -1057 -622 2907 -2295 -795 -1509 3618 -691 -917 1124 -1750 2525 1731 713 -938 -349 -1430 -487 438 1359 1103 -301 -381 -356 -1128 1665 -1496 -1298 1863 364 -262 3652 -411 -233 -56 962 855 1602 1913 -644 910 -200 -14 350 1996 3166 399 -2859 -680 840 -9 303 1324 163 506 -99 662 -652 337 -719 -1644 -763 -315 206 -2360 -2705 -1415 -1184 -898 1433 -69 872 -1863 158 32 865 2236 -134 -669 -582 1305 705 -454 -507 -309 -370 -952 -2242 -1916 -853 583 -565 247 785 237 -245 -664 864 729 690 552 -197 -692 901 196 786 1483 1544 1109 381 1445 1213 1030 -1305 -912 -300 -350 163 1883 -1388 -37 -1014 -804 -657 -340 SS 20260613T211954.7Z 9660.888828 132 1 54.03 2 69.18 75.71 52.71 82.79 0.00 1 0.00 1 0 17 6.197e-02 8.677e-03 1.256e-02 1.688e-03 4.147576e-01 9.116885e-04 4.701410e-03 -6.000000e+00 3.844954e-02 232.69 -2.00 3.41 -2.00 318.51 0.00e+00 1.248143e-03 1.908607e-04 2.228263e-04 -6.000000e+00 1.718044e-03 289.32 -2.00 20.00 -2.00 317.67 0.00e+00 2.786 0.000 302.00 328.00 3 4.1329e+00 2.5034e-03 3.5130e-02 -6.0000e+00 9.6338e-02 -2.5065e-03 2.8523e-03 2.1259e-02 -6.0000e+00 1.0373e-01 -2.6803e-02 1.8887e-03 1.0304e-02 -6.0000e+00 6.1830e-02 9.8668e-03 9.6934e-04 2.9974e-03 -6.0000e+00 2.5861e-02 3.1598e-04 -4.4237e-04 5.3650e-05 3.6718e-05 -6.0000e+00 1.9806e-03 -1.3882e-04 0.0000e+00 11 8 0 10 0 0 99.65 27.75 0.55 -0.00014 -0.00346 46 5 1 5 0 1174.520 36.25 20.00 27.75 31.54 10.0 984.81 -14705 -8614 -19080 -17006 -21713 -318 1397 -28357 -27915 7328 -14653 -21023 -6353 -15580 10069 -3340 7619 -749 -6323 -1699 15582 -7206 -5694 -5273 17568 -3745 -5256 1529 -4750 10114 4465 2312 -1666 -1045 -3428 -1077 747 2231 2494 -493 -1515 -2463 -1750 813 -2183 -2515 1645 180 -946 4905 -214 -32 926 2279 430 2039 1945 -863 247 2538 753 1314 2271 2506 681 -2215 -635 1305 204 1026 744 214 512 143 472 436 331 -602 -1339 -502 -494 -312 -1843 -2150 -1563 -927 -512 173 -131 314 -755 374 612 1921 644 203 -481 -133 -129 -416 -60 -624 -698 -206 -56 -1222 -1261 -725 -303 -112 316 187 50 80 112 373 522 285 254 63 -150 323 161 419 716 885 323 463 1358 712 412 -378 -355 290 87 -85 434 -360 -36 -521 -454 -454 -416 -552 -343 -886 -756 -951 -11 50 -1507 -1640 324 -846 -1398 -420 -1344 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