File name: Pandora276s1_Tokyo-Sophia_20260615_L2Fit_fout2c4d20251211p1-8.txt File generation date: 20260615T145504.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Satoshi Inomata Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 276 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora276_OF_v3d20230804.txt Instrument calibration file used: Pandora276s1_CF_v4d20251211.txt Level 1 file used: Pandora276s1_Tokyo-Sophia_20260615_L1_smca1c4d20251211p1-8.txt Full location name: Sophia University Short location name: Tokyo-Sophia Country of location: Japan Location latitude [deg]: 35.6831 Location longitude [deg]: 139.7317 Location altitude [m]: 45 Local noon date: 20260615 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Field calibration based on session 2 First and last pixel inside fitting window: 195 337 Nominal wavelengths inside fitting window [nm]: 305.0492 305.1899 305.3305 305.4712 305.6118 305.7525 305.8931 306.0337 306.1743 306.3149 306.4554 306.5960 306.7366 306.8771 307.0176 307.1582 307.2987 307.4392 307.5796 307.7201 307.8606 308.0010 308.1415 308.2819 308.4223 308.5627 308.7031 308.8435 308.9839 309.1242 309.2646 309.4049 309.5452 309.6855 309.8258 309.9661 310.1064 310.2467 310.3869 310.5272 310.6674 310.8076 310.9479 311.0881 311.2282 311.3684 311.5086 311.6487 311.7889 311.9290 312.0691 312.2092 312.3493 312.4894 312.6295 312.7696 312.9096 313.0497 313.1897 313.3297 313.4697 313.6097 313.7497 313.8897 314.0296 314.1696 314.3095 314.4494 314.5893 314.7292 314.8691 315.0090 315.1489 315.2887 315.4286 315.5684 315.7082 315.8481 315.9879 316.1276 316.2674 316.4072 316.5469 316.6867 316.8264 316.9661 317.1058 317.2455 317.3852 317.5249 317.6645 317.8042 317.9438 318.0835 318.2231 318.3627 318.5023 318.6419 318.7814 318.9210 319.0605 319.2001 319.3396 319.4791 319.6186 319.7581 319.8976 320.0370 320.1765 320.3159 320.4553 320.5948 320.7342 320.8736 321.0129 321.1523 321.2917 321.4310 321.5704 321.7097 321.8490 321.9883 322.1276 322.2669 322.4061 322.5454 322.6846 322.8239 322.9631 323.1023 323.2415 323.3807 323.5199 323.6590 323.7982 323.9373 324.0764 324.2156 324.3547 324.4938 324.6328 324.7719 324.9110 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20260615T022325.9Z 9662.099605 290 1 54.31 2 12.99 161.19 8.54 155.65 0.00 1 0.00 1 0 17 1.002e-02 7.736e-03 1.881e-03 1.358e-03 1.685338e-01 7.498094e-04 1.990057e-03 -6.000000e+00 6.216050e-03 232.75 -2.00 3.41 -2.00 314.65 0.00e+00 3.796331e-05 6.126861e-05 1.762550e-05 -6.000000e+00 2.778276e-04 289.43 -2.00 20.00 -2.00 313.99 0.00e+00 1.026 0.000 302.00 328.00 3 5.8205e+00 1.9324e-03 1.3466e-02 -6.0000e+00 1.5576e-02 4.3026e-02 2.1289e-03 8.5624e-03 -6.0000e+00 1.6771e-02 -8.9844e-03 1.2164e-03 4.1623e-03 -6.0000e+00 9.9965e-03 2.7841e-03 5.2037e-04 1.1362e-03 -6.0000e+00 4.1811e-03 4.7207e-04 -4.2332e-04 4.3729e-05 1.8187e-05 -6.0000e+00 3.2014e-04 -1.1329e-04 0.0000e+00 11 9 0 11 32 0 99.95 27.35 0.53 -0.00011 -0.00329 26 3 1 5 0 2088.800 36.00 20.00 27.35 28.15 10.0 973.49 377 -1462 -1883 -2246 -2372 1593 252 426 -421 319 -1850 -1531 -211 63 2527 -293 126 714 -533 480 3256 -338 -660 -205 3468 391 -204 -212 -1311 2128 1336 1819 485 135 -2408 -1704 -659 452 457 -612 -1007 -1329 -1160 -127 -1823 -1099 -93 -924 -677 1441 583 676 786 1007 375 1076 1178 320 576 1532 993 1377 1111 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-752 -808 SS 20260615T032358.7Z 9662.141652 327 1 5.86 2 15.42 219.48 12.01 232.24 0.00 1 0.00 1 0 17 1.195e-02 8.978e-03 6.847e-03 5.051e-03 1.678970e-01 2.798224e-03 2.007215e-03 -6.000000e+00 7.413340e-03 232.75 -2.00 3.41 -2.00 314.53 0.00e+00 3.570477e-04 2.239901e-04 6.509431e-05 -6.000000e+00 3.313759e-04 289.44 -2.00 20.00 -2.00 313.90 0.00e+00 1.037 0.000 302.00 328.00 3 5.5604e+00 7.2034e-03 1.3549e-02 -6.0000e+00 1.8576e-02 4.1644e-02 7.9342e-03 8.5863e-03 -6.0000e+00 2.0002e-02 -8.8406e-03 4.5344e-03 4.1745e-03 -6.0000e+00 1.1922e-02 1.8119e-03 1.9310e-03 1.1995e-03 -6.0000e+00 4.9860e-03 6.0610e-04 -8.6476e-04 1.6312e-04 1.9396e-05 -6.0000e+00 3.8183e-04 6.3656e-04 0.0000e+00 12 9 1 12 1 1 999.00 27.64 0.63 0.00064 -0.00586 1 2 1 5 0 2928.980 36.25 20.00 27.64 31.20 9.9 984.08 -1073 -398 -2826 -2046 -1673 -1420 233 -916 400 2802 -4087 -1869 -150 394 1941 -1213 1170 -275 -505 1310 3170 -946 897 1567 3557 39 -46 -236 535 3251 2828 1618 1823 -302 -2845 -2210 -207 -426 -264 -701 -1370 -595 -897 -838 -693 -2608 -1085 -40 88 959 1025 991 971 642 -469 592 1321 -502 -53 1743 673 324 1318 1724 57 -1243 -1571 542 579 654 1067 31 34 -527 -235 -426 228 -877 -642 1169 153 -870 -2604 -1446 -1381 -1304 -959 -83 -360 219 -233 1633 580 1121 1052 824 788 35 395 945 -330 -70 -739 -281 -284 -627 -1179 -427 197 -191 349 405 340 -610 633 -700 -67 389 314 -710 -597 271 -28 -84 1200 1500 674 32 921 637 3 -213 164 -155 -104 5 776 -416 10 -867 112 -301 -757 -413 -163 -1107 -809 -601 -480 79 -341 160 1138 -1654 -804 -63 181 966 -624 610 -149 -280 729 1757 -546 513 917 2117 23 -27 -140 296 1677 1478 894 1050 -180 -1683 -1275 -124 -273 -186 -536 -1092 -495 -766 -721 -594 -2251 -900 -34 71 759 829 841 818 565 -428 544 1217 -470 -49 1575 629 304 1303 1687 56 -1230 -1439 490 537 629 1060 33 36 -551 -243 -403 204 -782 -572 1046 145 -911 -2826 -1562 -1583 -1525 -1182 -100 -441 270 -271 1784 612 1169 1112 890 889 41 492 1176 -397 -82 -834 -319 -342 -771 -1464 -549 262 -256 484 565 461 -814 800 -837 -82 481 395 -921 -804 365 -38 -108 1501 1856 801 38 1102 803 4 -278 217 -203 -142 7 1097 -609 14 -1276 159 -416 -1074 SS 20260615T032745.6Z 9662.144277 330 1 4.92 2 15.92 222.11 12.61 234.80 0.00 1 0.00 1 0 17 7.714e-03 6.578e-03 1.366e-03 1.076e-03 1.630645e-01 5.994965e-04 1.935357e-03 -6.000000e+00 4.788180e-03 232.75 -2.00 3.41 -2.00 314.15 0.00e+00 2.358878e-04 4.459686e-05 1.477982e-05 -6.000000e+00 2.139931e-04 289.44 -2.00 20.00 -2.00 313.55 0.00e+00 1.040 0.000 302.00 328.00 3 3.0520e+00 1.5385e-03 1.3384e-02 -6.0000e+00 1.1998e-02 2.3500e-02 1.6904e-03 8.3025e-03 -6.0000e+00 1.2918e-02 -2.3479e-03 9.6969e-04 4.0296e-03 -6.0000e+00 7.7001e-03 -1.6562e-03 4.0967e-04 1.1121e-03 -6.0000e+00 3.2210e-03 7.5502e-03 -4.5654e-04 3.4635e-05 1.8435e-05 -6.0000e+00 2.4658e-04 -7.2004e-04 0.0000e+00 12 9 1 12 1 1 95.62 27.66 0.37 -0.00072 -0.00415 21 24 1 5 0 223.350 36.25 20.01 27.66 31.41 9.9 984.60 525 -1026 -1612 -2284 -1775 -420 156 1439 780 136 -1282 -717 470 126 510 300 -384 287 573 500 1093 777 959 755 969 629 -365 -503 293 852 1495 1325 978 -327 -1822 -1251 -1104 -211 172 -604 -1287 -1061 -875 -979 -936 -593 -1003 -912 -519 335 648 1033 1050 928 412 777 846 569 555 754 949 1385 1259 966 469 -433 -300 153 639 1190 237 -204 -141 -213 85 -308 -316 -172 -232 -314 -720 -1240 -1670 -1664 -1120 -789 -569 -205 -398 93 446 377 58 682 994 746 323 230 139 -128 -321 -536 -321 89 -145 -985 -760 -553 -501 11 65 -39 153 43 70 495 403 257 254 68 -116 -61 -137 447 783 1201 853 776 1063 757 336 30 -228 132 51 -65 -223 -165 -273 -413 -308 -509 -695 222 -471 -748 -1009 -748 -165 62 617 348 64 -608 -342 224 63 269 170 -218 165 337 301 664 473 589 459 611 408 -236 -310 175 505 888 789 611 -201 -1145 -768 -689 -143 126 -476 -1083 -906 -765 -862 -821 -513 -850 -769 -436 275 544 875 903 831 369 706 776 523 504 683 878 1306 1229 958 478 -418 -283 142 588 1155 238 -211 -147 -224 87 -295 -291 -153 -207 -292 -699 -1284 -1758 -1849 -1279 -912 -677 -251 -493 112 525 416 61 705 1038 813 367 270 168 -156 -383 -615 -361 100 -170 -1210 -954 -704 -649 14 89 -53 204 56 86 596 475 311 318 86 -154 -80 -179 577 980 1459 1017 909 1278 936 425 37 -295 171 68 -88 -315 -233 -390 -584 -435 -698 -959