File name: Pandora276s1_Tokyo-Sophia_20260701_L2Fit_fout2c4d20251211p1-8.txt File generation date: 20260701T150040.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Satoshi Inomata Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 276 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora276_OF_v4d20230804.txt Instrument calibration file used: Pandora276s1_CF_v4d20251211.txt Level 1 file used: Pandora276s1_Tokyo-Sophia_20260701_L1_smca1c4d20251211p1-8.txt Full location name: Sophia University Short location name: Tokyo-Sophia Country of location: Japan Location latitude [deg]: 35.6831 Location longitude [deg]: 139.7317 Location altitude [m]: 45 Local noon date: 20260701 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Field calibration based on session 2 First and last pixel inside fitting window: 195 337 Nominal wavelengths inside fitting window [nm]: 305.0492 305.1899 305.3305 305.4712 305.6118 305.7525 305.8931 306.0337 306.1743 306.3149 306.4554 306.5960 306.7366 306.8771 307.0176 307.1582 307.2987 307.4392 307.5796 307.7201 307.8606 308.0010 308.1415 308.2819 308.4223 308.5627 308.7031 308.8435 308.9839 309.1242 309.2646 309.4049 309.5452 309.6855 309.8258 309.9661 310.1064 310.2467 310.3869 310.5272 310.6674 310.8076 310.9479 311.0881 311.2282 311.3684 311.5086 311.6487 311.7889 311.9290 312.0691 312.2092 312.3493 312.4894 312.6295 312.7696 312.9096 313.0497 313.1897 313.3297 313.4697 313.6097 313.7497 313.8897 314.0296 314.1696 314.3095 314.4494 314.5893 314.7292 314.8691 315.0090 315.1489 315.2887 315.4286 315.5684 315.7082 315.8481 315.9879 316.1276 316.2674 316.4072 316.5469 316.6867 316.8264 316.9661 317.1058 317.2455 317.3852 317.5249 317.6645 317.8042 317.9438 318.0835 318.2231 318.3627 318.5023 318.6419 318.7814 318.9210 319.0605 319.2001 319.3396 319.4791 319.6186 319.7581 319.8976 320.0370 320.1765 320.3159 320.4553 320.5948 320.7342 320.8736 321.0129 321.1523 321.2917 321.4310 321.5704 321.7097 321.8490 321.9883 322.1276 322.2669 322.4061 322.5454 322.6846 322.8239 322.9631 323.1023 323.2415 323.3807 323.5199 323.6590 323.7982 323.9373 324.0764 324.2156 324.3547 324.4938 324.6328 324.7719 324.9110 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Column 100: Humidity inside spectrometer box [%], -9=no humidity signal Column 101: Temperature inside spectrometer box [°C], 999=no temperature signal Column 102: Pressure inside spectrometer box [hPa], -9=no pressure signal Columns 103-245: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 246-388: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20260630T210415.6Z 9677.877958 226 1 11.12 2 73.02 73.37 100.87 245.67 0.00 1 0.00 1 0 25 4.145e-01 2.049e-02 2.099e-01 9.060e-03 4.823340e-01 4.971588e-03 5.640753e-03 -6.000000e+00 2.589492e-01 232.59 -2.00 3.41 -2.00 319.53 0.00e+00 5.373859e-03 1.455032e-03 1.570331e-03 -6.000000e+00 1.160057e-02 290.79 -2.00 20.00 -2.00 318.72 0.00e+00 3.371 0.001 302.00 328.00 3 4.6307e+00 1.4281e-02 4.2141e-02 -6.0000e+00 6.4832e-01 5.8838e-02 1.6835e-02 2.5260e-02 -6.0000e+00 6.9837e-01 -6.9607e-02 1.2662e-02 1.3489e-02 -6.0000e+00 4.1560e-01 3.5752e-02 6.5749e-03 5.1770e-03 -6.0000e+00 1.7337e-01 9.6699e-05 -1.5889e-03 2.8658e-04 7.3060e-05 -6.0000e+00 1.3376e-02 1.9723e-03 0.0000e+00 12 9 9 12 1 1 999.00 28.02 0.81 0.00197 -0.00997 2 2 1 5 0 3703.800 36.50 20.00 28.02 31.90 9.9 985.49 15.4 29.77 1006.74 -21972 -7617 27593 33284 -3189 -16740 900000 -26182 -31429 20536 -58442 -57795 82491 -17986 900000 -39825 -10171 -15166 -25656 -22841 275558 -43608 -28432 -37706 339594 6688 -26891 22468 -20684 62973 49534 -3133 -13859 -11094 -20869 19277 13579 37115 2851 -5581 16706 -1248 -1722 13731 -11337 -3787 21659 -1665 6765 18500 1428 5666 6168 725 -1110 5241 3486 -5431 5910 12073 3782 -3315 6574 7454 1325 -1965 -3009 4512 1801 -569 3688 786 2903 166 -4742 66 -26 -4435 -4997 -2008 -299 1748 -4086 -4212 -795 -1302 764 -1223 470 1461 -2871 -282 378 3886 -143 -183 -1047 -1610 -932 -269 1416 -215 383 -517 301 -2381 -1993 -975 -20 -498 1449 345 610 -680 -550 886 1443 -890 1169 130 275 1317 1376 168 621 1133 392 -164 2025 -277 243 -997 -1224 511 1097 -965 2371 -975 93 -1286 -1381 -626 659 -353 -122 332 374 -49 -282 900000 -547 -757 345 -2065 -2227 1020 -747 900000 -2654 -620 -1058 -2130 -1937 2434 -4307 -2712 -4129 2999 514 -2921 1468 -2064 2837 2844 -349 -1922 -1587 -3281 2026 1619 4032 519 -1174 3152 -304 -443 3120 -3377 -1064 4782 -471 1798 4560 448 1861 2184 290 -475 2176 1503 -2564 2463 4721 1658 -1682 3336 3747 738 -1115 -1672 2331 1018 -367 2505 580 2109 120 -3344 40 -15 -2565 -3082 -1361 -229 1360 -3686 -4066 -791 -1287 781 -1320 502 1503 -2913 -279 350 3443 -140 -187 -1219 -1974 -1227 -358 1778 -253 449 -606 367 -2954 -2600 -1335 -27 -740 2280 540 954 -1101 -840 1268 2025 -1315 1782 210 453 2117 2145 256 900 1670 561 -238 3068 -440 391 -1717 -2203 948 2017 -1906 4683 -1922 193 -2638 -2717 -1165 1243 SS 20260630T211045.2Z 9677.882467 230 1 54.73 2 71.75 74.20 102.03 246.49 0.00 1 0.00 1 0 17 7.774e-02 8.044e-03 1.246e-02 1.329e-03 4.611157e-01 7.207172e-04 5.233384e-03 -6.000000e+00 4.822016e-02 232.59 -2.00 3.41 -2.00 318.74 0.00e+00 9.561099e-04 1.632266e-04 2.943931e-04 -6.000000e+00 2.168710e-03 290.79 -2.00 20.00 -2.00 317.89 0.00e+00 3.151 0.000 302.00 328.00 3 3.2993e+00 1.9938e-03 3.9499e-02 -6.0000e+00 1.2072e-01 1.5129e-02 2.2870e-03 2.3686e-02 -6.0000e+00 1.2996e-01 -3.2616e-02 1.5638e-03 1.1462e-02 -6.0000e+00 7.7545e-02 1.1288e-02 8.1107e-04 3.1994e-03 -6.0000e+00 3.2494e-02 4.7983e-04 -7.3116e-04 4.1702e-05 4.0270e-05 -6.0000e+00 2.4848e-03 -3.6334e-04 0.0000e+00 11 8 0 10 0 0 88.21 28.02 0.43 -0.00036 -0.00586 73 7 1 5 0 749.580 36.50 20.00 28.02 32.26 10.0 987.54 15.4 29.80 1006.80 -23503 -31577 -12583 -13394 -25847 3441 -20176 -23122 -40831 -1610 -23700 -21419 -8329 -17255 19601 -8863 1093 -4237 -14857 743 14733 -8224 -7597 -5964 15728 -3778 -5928 966 -7006 8240 -31 -937 -1142 -2784 -4730 -1525 -599 2992 2614 -836 -2126 -495 -406 1559 -1903 -1252 1479 -75 426 4176 1002 1967 525 1872 938 1726 1760 -558 489 2885 715 1447 2367 2487 1018 -808 -673 714 466 1307 733 690 -263 120 224 -524 -455 -915 -1297 -860 -583 -1039 -1868 -2027 -1481 -902 -183 37 -93 344 -255 260 538 1263 396 341 -192 7 -160 -200 -486 -594 -613 -194 -97 -1049 -1030 -665 -710 112 232 143 149 137 -54 548 419 527 204 106 -50 162 41 378 881 913 490 549 996 650 375 -94 -223 96 11 -238 260 -226 -234 -127 -286 -484 -622 -688 -1142 -398 -420 -868 84 -662 -872 -2053 -59 -1146 -1105 -439 -1196 1120 -775 96 -423 -1762 79 1409 -1008 -959 -789 1794 -500 -811 133 -1020 1055 -5 -148 -201 -525 -907 -284 -119 669 704 -251 -727 -179 -154 593 -759 -501 579 -30 173 1697 416 883 259 976 483 916 958 -312 268 1533 399 859 1427 1623 699 -554 -445 467 326 948 588 550 -213 99 173 -396 -317 -624 -938 -654 -476 -957 -1789 -2079 -1525 -986 -199 41 -105 376 -279 263 539 1241 417 379 -230 8 -210 -265 -620 -737 -748 -234 -117 -1360 -1345 -916 -1001 163 362 224 232 214 -80 796 601 777 305 167 -77 257 64 559 1297 1286 701 789 1453 995 596 -159 -377 170 19 -436 489 -437 -454 -242 -522 -877 -1097 SS 20260630T211950.7Z 9677.888781 236 1 5.61 2 69.97 75.36 103.65 247.64 0.00 1 0.00 1 0 17 1.275e-01 1.222e-02 7.655e-02 7.297e-03 4.245937e-01 3.942113e-03 4.806227e-03 -6.000000e+00 7.907048e-02 232.58 -2.00 3.41 -2.00 318.63 0.00e+00 5.277747e-06 8.619571e-04 4.441682e-04 -6.000000e+00 3.557294e-03 290.79 -2.00 20.00 -2.00 317.77 0.00e+00 2.888 0.000 302.00 328.00 3 4.2504e+00 1.0855e-02 3.6261e-02 -6.0000e+00 1.9796e-01 6.8184e-03 1.2436e-02 2.1851e-02 -6.0000e+00 2.1313e-01 -1.6714e-02 8.3818e-03 1.0500e-02 -6.0000e+00 1.2717e-01 6.7257e-03 4.3252e-03 2.8309e-03 -6.0000e+00 5.3266e-02 2.4985e-04 -4.9211e-04 2.3154e-04 3.5065e-05 -6.0000e+00 4.0758e-03 1.9847e-03 0.0000e+00 12 9 9 12 1 1 999.00 28.03 0.59 0.00198 -0.00171 2 3 1 5 0 1868.100 36.50 19.99 28.03 32.89 9.9 989.41 15.4 29.93 1006.99 -32503 -37029 3824 -4764 -8682 92957 -45551 -3616 -32427 29112 -44506 -4141 12757 -23496 32910 -9548 14078 1840 -9511 3974 31543 -5570 -7199 -4789 23255 -3449 -6061 2989 -6439 22356 -1720 -4574 3949 960 -10177 2597 -3494 2180 7796 1573 -4077 -2974 -4378 1756 -5276 -1549 2394 421 -2285 7011 306 -148 1443 3217 2640 1156 4539 -1211 1673 2847 1567 1190 1950 3742 -625 259 -2093 -1459 -302 -1718 1798 1089 1023 -608 1339 -1676 344 1047 -1960 -625 798 -787 -1788 -1807 -118 -1684 0 489 249 943 -699 96 573 217 -448 -1069 -3 -409 -395 -753 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