File name: Pandora276s1_Tokyo-Sophia_20260703_L2Fit_fout2c4d20251211p1-8.txt File generation date: 20260703T150827.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Satoshi Inomata Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 276 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora276_OF_v4d20230804.txt Instrument calibration file used: Pandora276s1_CF_v4d20251211.txt Level 1 file used: Pandora276s1_Tokyo-Sophia_20260703_L1_smca1c4d20251211p1-8.txt Full location name: Sophia University Short location name: Tokyo-Sophia Country of location: Japan Location latitude [deg]: 35.6831 Location longitude [deg]: 139.7317 Location altitude [m]: 45 Local noon date: 20260703 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Field calibration based on session 2 First and last pixel inside fitting window: 195 337 Nominal wavelengths inside fitting window [nm]: 305.0492 305.1899 305.3305 305.4712 305.6118 305.7525 305.8931 306.0337 306.1743 306.3149 306.4554 306.5960 306.7366 306.8771 307.0176 307.1582 307.2987 307.4392 307.5796 307.7201 307.8606 308.0010 308.1415 308.2819 308.4223 308.5627 308.7031 308.8435 308.9839 309.1242 309.2646 309.4049 309.5452 309.6855 309.8258 309.9661 310.1064 310.2467 310.3869 310.5272 310.6674 310.8076 310.9479 311.0881 311.2282 311.3684 311.5086 311.6487 311.7889 311.9290 312.0691 312.2092 312.3493 312.4894 312.6295 312.7696 312.9096 313.0497 313.1897 313.3297 313.4697 313.6097 313.7497 313.8897 314.0296 314.1696 314.3095 314.4494 314.5893 314.7292 314.8691 315.0090 315.1489 315.2887 315.4286 315.5684 315.7082 315.8481 315.9879 316.1276 316.2674 316.4072 316.5469 316.6867 316.8264 316.9661 317.1058 317.2455 317.3852 317.5249 317.6645 317.8042 317.9438 318.0835 318.2231 318.3627 318.5023 318.6419 318.7814 318.9210 319.0605 319.2001 319.3396 319.4791 319.6186 319.7581 319.8976 320.0370 320.1765 320.3159 320.4553 320.5948 320.7342 320.8736 321.0129 321.1523 321.2917 321.4310 321.5704 321.7097 321.8490 321.9883 322.1276 322.2669 322.4061 322.5454 322.6846 322.8239 322.9631 323.1023 323.2415 323.3807 323.5199 323.6590 323.7982 323.9373 324.0764 324.2156 324.3547 324.4938 324.6328 324.7719 324.9110 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Column 100: Humidity inside spectrometer box [%], -9=no humidity signal Column 101: Temperature inside spectrometer box [°C], 999=no temperature signal Column 102: Pressure inside spectrometer box [hPa], -9=no pressure signal Columns 103-245: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 246-388: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20260702T215006.4Z 9679.909797 246 1 13.06 2 64.12 79.29 87.78 244.73 0.00 1 0.00 1 0 17 3.158e-02 9.025e-03 1.062e-02 3.228e-03 3.308676e-01 1.748897e-03 3.816439e-03 -6.000000e+00 1.958352e-02 232.56 -2.00 3.41 -2.00 317.31 0.00e+00 3.324676e-04 2.602087e-04 1.144598e-04 -6.000000e+00 8.815242e-04 290.96 -2.00 20.00 -2.00 316.44 0.00e+00 2.277 0.000 302.00 328.00 3 4.4755e+00 4.6523e-03 2.8434e-02 -6.0000e+00 4.9023e-02 4.1696e-02 5.2116e-03 1.6887e-02 -6.0000e+00 5.2775e-02 -1.6202e-02 3.0929e-03 8.1406e-03 -6.0000e+00 3.1493e-02 5.8845e-03 1.4937e-03 2.2100e-03 -6.0000e+00 1.3199e-02 4.0122e-04 -4.5530e-04 1.0352e-04 2.9270e-05 -6.0000e+00 1.0092e-03 -9.8719e-05 0.0000e+00 12 9 1 12 41 1 98.53 27.55 0.43 -0.00010 -0.00352 6 3 1 5 0 1865.420 36.00 20.01 27.55 27.57 9.9 969.99 15.9 26.78 1005.81 -9736 -10434 -1891 -5074 -12595 -2461 -4434 -10450 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-442 -105 -837 -954 -696 -800 -761 -2297 -1651 -1645 -1029 -164 -77 -398 119 -289 777 -134 718 631 129 -89 -131 -353 -247 -268 -817 -880 -179 -682 -1334 -1311 -97 -722 -147 92 145 316 290 -394 451 1310 548 802 394 -55 458 -131 550 1466 1997 1026 653 1922 1567 902 -306 -290 292 578 -755 456 -1122 -794 -796 -812 -1311 -560 SS 20260702T215421.1Z 9679.912745 249 1 5.48 2 63.28 79.83 88.53 245.36 0.00 1 0.00 1 0 17 1.025e-02 5.980e-03 2.740e-03 1.133e-03 3.199111e-01 6.166694e-04 3.696785e-03 -6.000000e+00 6.358367e-03 232.56 -2.00 3.41 -2.00 316.68 0.00e+00 3.122966e-04 7.756822e-05 9.176396e-05 -6.000000e+00 2.862232e-04 290.96 -2.00 20.00 -2.00 315.82 0.00e+00 2.211 0.000 302.00 328.00 3 1.8557e+00 1.6228e-03 2.7516e-02 -6.0000e+00 1.5917e-02 2.2672e-02 1.8084e-03 1.6230e-02 -6.0000e+00 1.7135e-02 -1.3799e-02 1.0448e-03 7.8323e-03 -6.0000e+00 1.0225e-02 3.0976e-03 4.8545e-04 2.1290e-03 -6.0000e+00 4.2854e-03 6.0400e-03 -4.7290e-04 3.6282e-05 2.9352e-05 -6.0000e+00 3.2769e-04 1.6914e-04 0.0000e+00 12 1 1 12 1 1 96.52 27.56 0.35 0.00017 -0.00338 43 44 1 5 0 124.540 36.25 20.01 27.56 28.00 9.9 971.69 16.0 26.85 1005.80 -621 -934 -1897 -3822 -5082 -1792 -2631 -601 -2029 -1804 -2744 -2209 -848 -143 575 676 322 618 245 639 1641 -151 603 399 1589 328 -1437 -802 -397 279 492 799 721 -764 -2351 -1945 -1019 -248 602 -117 -292 -394 -722 -559 -345 -103 -620 -592 -327 317 830 968 1167 1151 822 673 1094 545 586 962 1111 1692 1584 1107 550 -281 -424 -78 772 1193 155 -52 -104 -26 -144 -387 -592 -705 -756 -424 -1127 -1289 -1666 -1622 -1211 -733 -198 24 -23 35 324 203 50 271 969 583 205 128 63 -202 -370 -742 -396 -137 -414 -1095 -817 -443 -424 165 339 272 212 253 94 288 430 309 145 -61 -46 5 91 562 596 999 613 806 869 447 302 -116 -173 76 175 -210 -4 -105 -362 -303 -130 -460 -648 -85 -142 -301 -596 -745 -268 -379 -94 -354 -334 -528 -445 -173 -34 142 186 95 179 75 201 524 -50 202 140 548 119 -530 -284 -143 99 172 303 295 -309 -949 -778 -433 -114 308 -66 -176 -241 -459 -360 -223 -66 -397 -374 -205 200 548 654 805 839 601 507 836 419 445 726 858 1330 1298 969 474 -243 -347 -65 644 1056 147 -50 -101 -24 -131 -348 -506 -576 -638 -379 -1062 -1304 -1771 -1773 -1361 -850 -234 29 -28 41 373 222 53 284 1047 650 241 161 83 -260 -469 -901 -467 -162 -503 -1386 -1057 -600 -591 237 502 403 310 358 131 387 566 419 202 -88 -66 8 131 800 831 1322 804 1049 1185 623 436 -171 -263 116 276 -342 -7 -177 -600 -506 -215 -732 -1032 SS 20260702T215908.4Z 9679.916070 252 1 54.50 2 62.32 80.45 89.38 246.06 0.00 1 0.00 1 0 17 1.033e-02 5.957e-03 1.461e-03 5.363e-04 3.102309e-01 2.914603e-04 3.583147e-03 -6.000000e+00 6.405708e-03 232.56 -2.00 3.41 -2.00 316.87 0.00e+00 2.193243e-04 3.862120e-05 6.883583e-05 -6.000000e+00 2.882819e-04 290.96 -2.00 20.00 -2.00 316.01 0.00e+00 2.141 0.000 302.00 328.00 3 2.6991e+00 7.6890e-04 2.6680e-02 -6.0000e+00 1.6036e-02 2.8409e-02 8.5775e-04 1.5775e-02 -6.0000e+00 1.7261e-02 -7.7004e-03 4.9852e-04 7.6095e-03 -6.0000e+00 1.0301e-02 -8.6553e-05 2.3521e-04 2.0678e-03 -6.0000e+00 4.3184e-03 2.8086e-03 -2.3108e-04 1.7207e-05 2.8403e-05 -6.0000e+00 3.3005e-04 -1.7342e-03 0.0000e+00 10 0 0 10 0 0 99.98 27.56 0.37 -0.00173 -0.00347 458 46 1 5 0 118.980 36.25 20.00 27.56 28.65 9.9 975.09 16.0 26.95 1005.76 -2391 -1422 -1626 -3680 -5275 -798 -1801 -146 -1977 -849 -2507 -2218 -348 -1173 1624 -785 201 422 -31 840 1774 227 359 114 1422 -291 -923 -726 -583 1183 993 976 817 -707 -2855 -1913 -1232 -126 530 -376 -983 -802 -577 -418 -577 -338 -482 -615 -272 402 787 1108 766 1030 759 905 903 597 594 964 1119 1514 1424 1129 412 -499 -185 87 663 1166 399 37 -191 -191 15 -297 -316 -397 -447 -351 -805 -1289 -1697 -1659 -1175 -793 -392 -50 -198 149 217 514 325 699 862 615 342 154 36 -263 -364 -747 -457 -26 -243 -1014 -852 -666 -473 76 92 144 79 125 106 345 504 388 141 -44 -165 -149 17 327 689 1007 716 787 1007 621 366 -92 -131 214 73 -121 -26 -150 -268 -305 -270 -433 -626 -285 -185 -219 -487 -659 -101 -218 -19 -293 -132 -407 -377 -65 -252 356 -196 53 117 -9 252 539 71 115 35 460 -99 -317 -240 -184 393 320 341 308 -280 -1134 -748 -513 -56 257 -200 -583 -475 -353 -259 -360 -210 -297 -373 -163 243 497 745 521 737 567 694 668 443 460 742 835 1196 1155 976 364 -426 -157 72 543 1049 377 35 -184 -187 14 -261 -268 -321 -372 -305 -753 -1280 -1749 -1814 -1305 -935 -467 -61 -245 179 255 578 340 735 898 701 400 191 48 -339 -466 -929 -537 -31 -302 -1298 -1103 -904 -651 111 136 220 119 183 145 459 683 521 200 -64 -239 -216 25 458 951 1372 939 1025 1371 874 528 -134 -196 332 115 -195 -44 -247 -445 -516 -443 -707 -998 SS 20260702T231338.4Z 9679.967806 302 1 55.84 2 47.26 90.53 103.10 256.40 0.00 1 0.00 1 0 17 2.342e-02 1.180e-02 4.436e-03 2.244e-03 2.241971e-01 1.222220e-03 2.616987e-03 -6.000000e+00 1.453173e-02 232.56 -2.00 3.41 -2.00 316.05 0.00e+00 2.763650e-04 1.334194e-04 1.018626e-04 -6.000000e+00 6.539150e-04 290.97 -2.00 20.00 -2.00 315.24 0.00e+00 1.471 0.000 302.00 328.00 3 6.1526e+00 3.1906e-03 1.8693e-02 -6.0000e+00 3.6378e-02 5.4370e-02 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