File name: Pandora194s1_Tokyo-TMU_20211228_L2Fit_fout2c1d20211130p1-8.txt File generation date: 20251129T080224.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Shungo KATO Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 194 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora194_OF_v3d20210122.txt Instrument calibration file used: Pandora194s1_CF_v1d20211130.txt Level 1 file used: Pandora194s1_Tokyo-TMU_20211228_L1_smca1c1d20211130p1-8.txt Full location name: Tokyo Metropolitan University (TMU) Short location name: Tokyo-TMU Country of location: Japan Location latitude [deg]: 35.6200 Location longitude [deg]: 139.3834 Location altitude [m]: 135 Local noon date: 20211228 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 338 Nominal wavelengths inside fitting window [nm]: 305.1230 305.2641 305.4052 305.5463 305.6873 305.8284 305.9694 306.1104 306.2515 306.3925 306.5335 306.6745 306.8154 306.9564 307.0974 307.2383 307.3792 307.5202 307.6611 307.8020 307.9429 308.0838 308.2247 308.3655 308.5064 308.6472 308.7881 308.9289 309.0697 309.2105 309.3513 309.4921 309.6328 309.7736 309.9143 310.0551 310.1958 310.3365 310.4772 310.6179 310.7586 310.8993 311.0399 311.1806 311.3212 311.4619 311.6025 311.7431 311.8837 312.0243 312.1649 312.3054 312.4460 312.5865 312.7271 312.8676 313.0081 313.1486 313.2891 313.4296 313.5701 313.7105 313.8510 313.9914 314.1318 314.2722 314.4127 314.5530 314.6934 314.8338 314.9742 315.1145 315.2549 315.3952 315.5355 315.6758 315.8161 315.9564 316.0967 316.2370 316.3772 316.5175 316.6577 316.7979 316.9382 317.0784 317.2186 317.3587 317.4989 317.6391 317.7792 317.9194 318.0595 318.1996 318.3397 318.4798 318.6199 318.7600 318.9001 319.0401 319.1802 319.3202 319.4602 319.6002 319.7402 319.8802 320.0202 320.1602 320.3002 320.4401 320.5800 320.7200 320.8599 320.9998 321.1397 321.2796 321.4195 321.5593 321.6992 321.8390 321.9789 322.1187 322.2585 322.3983 322.5381 322.6779 322.8176 322.9574 323.0972 323.2369 323.3766 323.5163 323.6560 323.7957 323.9354 324.0751 324.2147 324.3544 324.4940 324.6337 324.7733 324.9129 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20211227T223305.2Z 8031.939643 271 1 45.34 2 83.55 124.77 42.81 206.33 0.00 1 0.00 1 0 17 7.306e-01 4.762e-02 4.929e-01 3.868e-02 8.762136e-01 2.256194e-02 9.439074e-03 -6.000000e+00 4.242482e-01 223.92 -2.00 3.40 -2.00 322.20 0.00e+00 2.009529e-02 8.590057e-03 8.629959e-04 -6.000000e+00 1.860985e-02 280.24 -2.00 20.00 -2.00 321.85 0.00e+00 8.063 0.008 302.00 328.00 3 1.0595e+00 7.0690e-02 9.0499e-02 -6.0000e+00 1.0490e+00 1.5435e+00 8.1119e-02 4.2851e-02 -6.0000e+00 1.1496e+00 -1.9318e+00 6.0734e-02 2.2189e-02 -6.0000e+00 6.7197e-01 7.5601e-01 3.4763e-02 7.3788e-03 -6.0000e+00 2.8630e-01 2.3669e-05 -4.1194e-03 1.1364e-03 1.1764e-04 -6.0000e+00 2.2068e-02 1.5023e-02 -1.7050e-04 12 9 9 12 1 1 56.40 16.65 0.46 0.01502 -0.01593 13 3 1 5 0 3225.640 20.25 15.31 16.65 5.56 12.0 1006.12 900000 148027 124676 -76191 900000 900000 176332 -4626 -52409 53844 -70256 289 -35386 -18932 110350 67992 91837 -36623 12900 31967 14746 20530 212499 900000 900000 256677 -33566 -48989 900000 197224 287448 107939 199871 -50785 -6304 -29386 900000 900000 900000 900000 13395 104679 -29835 -14747 -7650 188304 40444 333302 33263 80498 75762 16670 1308 30998 127092 34913 46641 145866 -25479 29608 -15279 52433 5977 141002 8421 11094 -6208 9718 25340 12085 48408 33371 30354 65372 -29775 36103 -36601 -6748 1293 69359 12478 -2274 15250 -9806 11346 35 -3487 -6955 6356 9800 5932 -14267 -27113 -699 6046 -558 9711 -5932 -154 -7618 11611 -15227 4556 6064 -3830 -3302 -5971 1946 -3904 -842 267 732 3319 -2224 -1856 -1855 808 -943 308 4728 7219 4086 2190 195 -2668 -81 -4221 -55 93 1640 4158 377 730 -2698 -236 -1110 740 526 -860 843 -1450 220 900000 5572 4693 -10277 900000 900000 6637 -174 -2630 2027 -3746 11 -2109 -1247 4154 2792 3457 -4637 971 1860 908 1054 7999 900000 900000 9662 -1953 -3185 900000 7424 10820 4063 7524 -6082 -431 -2413 900000 900000 900000 900000 1008 3940 -3573 -1514 -733 7088 2491 12546 2390 3857 4148 1768 170 3076 4784 3226 3671 5491 -3662 2432 -2091 4127 859 5790 1326 1837 -1239 1756 4388 2638 7653 6029 5256 7136 -7397 4213 -8818 -1346 287 9399 3476 -822 4937 -4282 4228 15 -1627 -3377 2632 3689 2166 -6122 -13574 -303 2913 -345 6397 -5203 -134 -6882 7823 -11865 2744 3743 -2782 -2523 -5057 1692 -4144 -999 347 994 4397 -3022 -2431 -2430 1076 -1356 457 6673 9510 5291 2802 247 -3394 -98 -5529 -79 156 3105 8452 854 1766 -7251 -656 -3193 2114 1504 -2406 2159 -3505 492 SS 20211227T224357.9Z 8031.947198 274 1 49.09 2 81.76 126.52 43.88 209.89 0.00 1 0.00 1 0 17 4.582e-01 1.952e-02 2.831e-01 1.014e-02 7.659615e-01 5.657142e-03 8.002028e-03 -6.000000e+00 2.609747e-01 223.92 -2.00 3.40 -2.00 321.98 0.00e+00 1.745576e-02 2.406800e-03 9.525887e-04 -6.000000e+00 1.066512e-02 280.24 -2.00 20.00 -2.00 321.62 0.00e+00 6.546 0.004 302.00 328.00 3 1.0014e+00 1.7970e-02 7.5136e-02 -6.0000e+00 6.4757e-01 7.1424e-01 2.4568e-02 3.9638e-02 -6.0000e+00 7.0744e-01 -9.8076e-01 2.6324e-02 2.2497e-02 -6.0000e+00 4.1696e-01 3.9962e-01 1.3072e-02 7.8514e-03 -6.0000e+00 1.7579e-01 1.3644e-04 -1.9469e-03 3.0423e-04 1.0557e-04 -6.0000e+00 1.2812e-02 1.3878e-02 -1.2920e-04 12 8 8 10 0 0 79.60 16.66 0.48 0.01388 -0.00075 51 11 1 5 0 962.280 20.25 15.20 16.66 6.22 11.9 1007.32 -159031 -59687 -44084 -101048 67722 197037 -136562 -134225 -160283 -184933 -79452 -69541 -104474 -30192 -16680 34662 -58945 15169 36997 66586 -8318 124190 900000 -53808 -39771 -74954 -44146 -47507 -9093 -18489 48693 -25054 36189 55432 44317 66024 33021 35084 26612 28213 4635 14127 28125 54097 46397 47898 12114 17157 8265 27417 29203 34440 22832 26280 28368 21050 19009 5115 7869 21964 17001 27943 28969 16680 9769 10778 7158 15701 15563 10139 12724 2578 1288 4099 -985 -6785 2812 -4972 214 4633 662 -1965 -4442 123 -1786 573 -400 -505 621 -2449 -1687 -5418 -3404 -4906 -4907 -1051 -1648 -520 -3091 -483 -2680 -997 950 -2863 -220 -3331 -1933 -1434 152 164 270 -133 379 -1680 -269 -442 1106 1246 554 1987 1687 1432 2361 466 415 860 729 284 134 457 457 123 -511 -590 -224 427 499 342 33 -524 -969 -887 -6157 -934 -634 -2270 669 1948 -3314 -3136 -4754 -6814 -1071 -1062 -3098 -570 -345 498 -2384 314 632 838 -209 1228 900000 -1886 -1179 -3099 -1309 -1452 -204 -548 919 -1171 1008 1245 1036 1246 950 1135 1076 1242 275 800 1441 2188 2085 2415 827 1289 719 2141 2483 3030 2415 2806 3001 2393 2161 642 933 2302 2034 3425 4038 2886 1835 1971 1380 2980 3354 2566 3296 734 350 985 -222 -1489 561 -1194 59 1452 250 -849 -2099 59 -923 305 -223 -284 337 -1288 -822 -2625 -1649 -2697 -3178 -776 -1432 -502 -3178 -463 -2374 -776 697 -2298 -183 -3026 -1863 -1517 180 220 394 -200 562 -2438 -370 -609 1566 1868 874 3081 2523 2056 3257 634 548 1100 967 429 235 892 968 278 -1238 -1530 -611 1188 1406 965 89 -1346 -2329 -2031 SS 20211227T230032.0Z 8031.958704 279 1 48.46 2 79.10 129.28 45.71 215.02 0.00 1 0.00 1 0 25 4.457e-01 9.105e-03 5.868e-02 1.674e-03 6.367924e-01 8.960316e-04 6.777778e-03 -6.000000e+00 2.538620e-01 223.92 -2.00 3.40 -2.00 321.29 0.00e+00 9.941250e-03 3.502659e-04 6.083422e-04 -6.000000e+00 1.037119e-02 280.24 -2.00 20.00 -2.00 320.95 0.00e+00 5.096 0.002 302.00 328.00 3 -2.2659e-01 2.6881e-03 5.9272e-02 -6.0000e+00 6.2992e-01 1.2546e-01 3.7277e-03 3.2582e-02 -6.0000e+00 6.8816e-01 -1.6971e-01 4.3728e-03 1.8433e-02 -6.0000e+00 4.0559e-01 5.7595e-02 2.1858e-03 6.2830e-03 -6.0000e+00 1.7091e-01 2.2596e-03 -1.0382e-03 5.0301e-05 7.2684e-05 -6.0000e+00 1.2457e-02 1.2930e-02 -1.5198e-04 11 8 0 10 0 0 17.37 16.68 0.33 0.01293 0.00513 387 84 1 5 0 125.190 20.25 15.31 16.68 8.22 12.1 1015.21 -160339 -152993 -120293 -165135 -114988 -158154 -119994 -149217 -131900 -132148 -152575 -113599 -90928 -57243 -59176 -29060 -40498 -29703 -17837 -36092 -14928 -36708 -11832 -33096 -22210 -38417 -45286 -30161 -40609 -10808 -14514 4616 -6945 -15610 -11313 -17182 -5147 -8895 4707 -1803 788 1398 -254 6655 -163 7045 2258 8868 5784 6961 7264 5168 7492 3451 6158 1345 1069 -961 -569 2068 2793 6571 6094 6410 4019 3777 1146 2464 3756 1703 2517 834 481 -1419 -2191 -3281 -4019 -1330 -1175 605 -680 -1385 -1378 -1452 -834 -321 925 610 878 137 -19 -2001 -2165 -1431 -1557 455 872 589 -67 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