File name: Pandora194s1_Tokyo-TMU_20220128_L2Fit_fout2c1d20211130p1-8.txt File generation date: 20251129T080220.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Shungo KATO Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 194 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora194_OF_v3d20210122.txt Instrument calibration file used: Pandora194s1_CF_v1d20211130.txt Level 1 file used: Pandora194s1_Tokyo-TMU_20220128_L1_smca1c1d20211130p1-8.txt Full location name: Tokyo Metropolitan University (TMU) Short location name: Tokyo-TMU Country of location: Japan Location latitude [deg]: 35.6200 Location longitude [deg]: 139.3834 Location altitude [m]: 135 Local noon date: 20220128 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 338 Nominal wavelengths inside fitting window [nm]: 305.1230 305.2641 305.4052 305.5463 305.6873 305.8284 305.9694 306.1104 306.2515 306.3925 306.5335 306.6745 306.8154 306.9564 307.0974 307.2383 307.3792 307.5202 307.6611 307.8020 307.9429 308.0838 308.2247 308.3655 308.5064 308.6472 308.7881 308.9289 309.0697 309.2105 309.3513 309.4921 309.6328 309.7736 309.9143 310.0551 310.1958 310.3365 310.4772 310.6179 310.7586 310.8993 311.0399 311.1806 311.3212 311.4619 311.6025 311.7431 311.8837 312.0243 312.1649 312.3054 312.4460 312.5865 312.7271 312.8676 313.0081 313.1486 313.2891 313.4296 313.5701 313.7105 313.8510 313.9914 314.1318 314.2722 314.4127 314.5530 314.6934 314.8338 314.9742 315.1145 315.2549 315.3952 315.5355 315.6758 315.8161 315.9564 316.0967 316.2370 316.3772 316.5175 316.6577 316.7979 316.9382 317.0784 317.2186 317.3587 317.4989 317.6391 317.7792 317.9194 318.0595 318.1996 318.3397 318.4798 318.6199 318.7600 318.9001 319.0401 319.1802 319.3202 319.4602 319.6002 319.7402 319.8802 320.0202 320.1602 320.3002 320.4401 320.5800 320.7200 320.8599 320.9998 321.1397 321.2796 321.4195 321.5593 321.6992 321.8390 321.9789 322.1187 322.2585 322.3983 322.5381 322.6779 322.8176 322.9574 323.0972 323.2369 323.3766 323.5163 323.6560 323.7957 323.9354 324.0751 324.2147 324.3544 324.4940 324.6337 324.7733 324.9129 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220127T225042.8Z 8062.951885 193 1 3.25 2 79.05 122.10 59.22 182.12 0.00 1 0.00 1 0 17 4.121e-01 2.862e-02 3.591e-01 2.116e-02 6.141557e-01 1.111728e-02 6.771537e-03 -6.000000e+00 2.363632e-01 224.59 -2.00 3.40 -2.00 320.82 0.00e+00 1.636887e-02 3.822183e-03 4.467386e-04 -6.000000e+00 1.004392e-02 279.16 -2.00 20.00 -2.00 320.51 0.00e+00 5.077 0.002 302.00 328.00 3 2.1287e+00 3.2059e-02 5.8456e-02 -6.0000e+00 5.8688e-01 3.0090e-01 3.9586e-02 3.0814e-02 -6.0000e+00 6.4112e-01 -4.8966e-01 3.8486e-02 1.6254e-02 -6.0000e+00 3.7698e-01 2.2076e-01 1.9873e-02 5.1814e-03 -6.0000e+00 1.6026e-01 2.1544e-04 -2.8070e-03 6.0960e-04 6.3732e-05 -6.0000e+00 1.1569e-02 7.5995e-03 -1.5873e-04 12 9 9 12 1 1 999.00 17.76 0.63 0.00760 -0.01349 1 7 1 5 0 1533.350 21.38 15.05 17.76 11.24 12.7 1002.69 900000 -160742 -16773 -148851 900000 -44262 -121540 -195395 -169779 -9812 -5822 900000 -51883 123291 -27427 -11760 -1291 -39160 18205 -28412 30991 -55715 40521 93282 56861 -46043 -39400 -18119 52567 88030 9935 104389 55196 24883 65198 8 76313 31060 6650 13715 9113 52626 7723 37259 982 42397 30443 12059 13739 22372 10662 11692 27366 13333 29316 3945 11015 10296 8627 13865 3524 31602 7380 14708 5059 -3808 13012 -980 5839 4445 4358 7589 347 -6666 -7333 -2631 -3421 -3742 -4815 4316 -3118 -1718 -4654 -2080 -3320 -1244 24 -1150 -2315 -6693 1998 -1782 -1132 -3951 -4066 784 -4133 -472 1288 -270 -1439 368 -419 -612 735 -454 -1948 124 -1103 377 268 2510 -1249 -165 -947 -1782 422 -1065 3771 -472 3613 1956 2788 1913 -547 -60 489 1179 1284 922 -650 -1194 812 62 -58 -516 244 -96 356 710 -1280 -2524 900000 -8740 -346 -6698 900000 -913 -3418 -11723 -7958 -202 -120 900000 -1391 2543 -962 -412 -45 -2181 601 -1524 895 -3677 1003 1924 1173 -2659 -2113 -785 1193 1816 492 2368 2277 1386 2286 1 2676 1986 631 1358 1015 4016 972 3612 142 4197 3516 1741 2040 3276 1935 2291 4910 2887 5502 960 2476 2272 1904 2974 908 6974 2359 4763 1816 -1445 4160 -380 2385 1875 1953 3315 156 -2975 -3267 -1020 -1305 -1544 -2354 2072 -1854 -1118 -3325 -1533 -2646 -1029 21 -1005 -2009 -5735 1457 -1270 -794 -3089 -3667 786 -4618 -569 1583 -324 -1593 361 -436 -616 781 -515 -2387 162 -1617 560 429 3993 -2011 -249 -1371 -2570 618 -1679 5977 -790 5658 2998 4100 2958 -836 -89 724 1763 2172 1731 -1235 -2392 1681 138 -127 -1169 557 -223 795 1601 -2769 -5284 SS 20220127T230013.5Z 8062.958490 199 1 14.47 2 77.43 123.70 59.35 184.59 0.00 1 0.00 1 0 17 2.848e-01 1.101e-02 1.638e-01 6.370e-03 5.588222e-01 3.312709e-03 6.070256e-03 -6.000000e+00 1.633849e-01 224.59 -2.00 3.40 -2.00 320.67 0.00e+00 8.890342e-03 1.111836e-03 4.103113e-04 -6.000000e+00 6.738897e-03 279.16 -2.00 20.00 -2.00 320.35 0.00e+00 4.469 0.001 302.00 328.00 3 2.3161e+00 9.4386e-03 5.1844e-02 -6.0000e+00 4.0572e-01 9.5744e-02 1.1954e-02 2.8063e-02 -6.0000e+00 4.4302e-01 -1.4771e-01 1.2731e-02 1.5201e-02 -6.0000e+00 2.6045e-01 5.5144e-02 6.6188e-03 4.9457e-03 -6.0000e+00 1.0964e-01 3.4896e-04 -5.2212e-04 1.9024e-04 5.6632e-05 -6.0000e+00 7.9738e-03 7.4769e-03 -6.5334e-05 12 9 9 12 1 1 96.93 17.77 0.43 0.00748 0.00355 11 9 1 5 0 1190.740 21.48 15.01 17.77 11.78 12.6 1003.27 -98335 -114541 -123543 -106325 900000 -48771 -101161 -19258 -74106 -122160 -86954 8486 -72388 -51600 -18234 42434 9556 -7572 -39131 -18288 13239 -5978 -17042 -310 -31316 -40215 -25317 -27858 -3864 1623 -11755 -2730 7529 -1725 -21027 -7499 -9721 1953 6312 -6759 -7641 -3935 1967 8374 -3459 1854 7031 4646 12010 4183 6971 8802 4901 5260 5026 2807 1627 -85 -1326 4380 -934 3452 4294 4579 4613 1926 3093 1589 3608 1902 2414 634 522 -839 -3374 -2247 -5258 -1294 -1394 -1569 15 -1235 -1914 -2483 -747 416 -305 1007 820 1067 -2511 -1392 -2010 -1232 -654 506 177 311 -227 -1334 -1566 -1478 -15 -1696 -1427 -819 -633 -181 604 86 726 858 286 35 787 553 247 547 494 589 1681 1051 330 56 -547 -363 1018 -342 277 294 -343 -573 -201 -250 -261 -387 152 -281 -72 140 -131 269 -1388 -2134 -2580 -1741 900000 -413 -1542 -155 -1104 -3034 -1620 74 -1843 -1378 -430 632 220 -226 -1701 -670 354 -193 -635 -10 -1458 -2098 -1132 -1263 -144 65 -650 -161 444 -111 -1580 -512 -773 165 608 -844 -1044 -550 271 1113 -533 279 1030 721 1812 738 1325 1798 1123 1271 1255 732 430 -22 -349 1115 -271 1082 1504 1720 1722 712 1127 624 1577 947 1270 342 271 -410 -1525 -918 -2158 -547 -687 -907 10 -816 -1356 -1880 -595 347 -267 876 699 853 -1931 -995 -1432 -942 -568 501 202 390 -293 -1665 -1783 -1531 -15 -1833 -1641 -985 -808 -248 834 132 1172 1394 451 52 1104 839 358 839 799 961 2651 1610 492 87 -831 -529 1487 -511 461 535 -669 -1169 -430 -526 -582 -889 354 -661 -164 302 -267 574 SS 20220127T230458.1Z 8062.961783 202 1 13.71 2 76.63 124.51 59.45 185.81 0.00 1 0.00 1 0 17 2.592e-01 1.051e-02 1.240e-01 4.183e-03 5.371945e-01 2.179472e-03 5.881124e-03 -6.000000e+00 1.482762e-01 224.59 -2.00 3.40 -2.00 320.48 0.00e+00 7.450738e-03 7.026355e-04 3.787485e-04 -6.000000e+00 6.030211e-03 279.16 -2.00 20.00 -2.00 320.17 0.00e+00 4.220 0.001 302.00 328.00 3 1.8058e+00 6.2254e-03 4.9251e-02 -6.0000e+00 3.6850e-01 5.8870e-02 7.7298e-03 2.6979e-02 -6.0000e+00 4.0217e-01 -7.0979e-02 8.0355e-03 1.4492e-02 -6.0000e+00 2.3691e-01 1.7006e-02 4.2078e-03 4.6799e-03 -6.0000e+00 9.9831e-02 7.5062e-04 -1.6985e-04 1.2418e-04 5.3293e-05 -6.0000e+00 7.2443e-03 6.3527e-03 2.0040e-05 12 9 9 12 1 1 99.94 17.77 0.41 0.00635 0.00508 25 20 1 5 0 520.320 21.48 14.96 17.77 11.99 12.5 1003.13 -65091 -88979 34278 -57066 -64310 -123908 -96871 -86766 -90431 -92835 -82409 -32465 -70271 -49839 -21660 -16068 18364 -8877 23426 -16681 -2703 -13667 -17863 -6453 -23629 -2158 -31614 11261 -14791 -7397 -7654 -9798 -44 -14189 2779 -5997 9466 -4480 -7243 -2871 -6023 4388 -4923 5123 2899 5786 2215 2925 4429 2049 8586 2583 8690 4403 3664 824 -1150 -63 -4839 2328 1180 6847 5216 3706 1812 987 1914 849 2623 1712 1969 -627 -134 108 -3873 -1847 -2925 551 -1661 -1144 -1019 -2434 -1754 -2057 -772 20 1241 658 578 638 -1735 -622 -1829 -448 -1435 928 997 290 -219 -1679 -933 -1241 -122 -1162 -1837 -846 -828 292 36 971 804 910 925 -609 -120 118 1153 379 853 404 1356 740 -4 506 -574 -138 270 -56 -244 -609 -242 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