File name: Pandora194s1_Tokyo-TMU_20220212_L2Fit_fout2c1d20211130p1-8.txt File generation date: 20251129T081021.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Shungo KATO Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 194 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora194_OF_v3d20210122.txt Instrument calibration file used: Pandora194s1_CF_v1d20211130.txt Level 1 file used: Pandora194s1_Tokyo-TMU_20220212_L1_smca1c1d20211130p1-8.txt Full location name: Tokyo Metropolitan University (TMU) Short location name: Tokyo-TMU Country of location: Japan Location latitude [deg]: 35.6200 Location longitude [deg]: 139.3834 Location altitude [m]: 135 Local noon date: 20220212 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 338 Nominal wavelengths inside fitting window [nm]: 305.1230 305.2641 305.4052 305.5463 305.6873 305.8284 305.9694 306.1104 306.2515 306.3925 306.5335 306.6745 306.8154 306.9564 307.0974 307.2383 307.3792 307.5202 307.6611 307.8020 307.9429 308.0838 308.2247 308.3655 308.5064 308.6472 308.7881 308.9289 309.0697 309.2105 309.3513 309.4921 309.6328 309.7736 309.9143 310.0551 310.1958 310.3365 310.4772 310.6179 310.7586 310.8993 311.0399 311.1806 311.3212 311.4619 311.6025 311.7431 311.8837 312.0243 312.1649 312.3054 312.4460 312.5865 312.7271 312.8676 313.0081 313.1486 313.2891 313.4296 313.5701 313.7105 313.8510 313.9914 314.1318 314.2722 314.4127 314.5530 314.6934 314.8338 314.9742 315.1145 315.2549 315.3952 315.5355 315.6758 315.8161 315.9564 316.0967 316.2370 316.3772 316.5175 316.6577 316.7979 316.9382 317.0784 317.2186 317.3587 317.4989 317.6391 317.7792 317.9194 318.0595 318.1996 318.3397 318.4798 318.6199 318.7600 318.9001 319.0401 319.1802 319.3202 319.4602 319.6002 319.7402 319.8802 320.0202 320.1602 320.3002 320.4401 320.5800 320.7200 320.8599 320.9998 321.1397 321.2796 321.4195 321.5593 321.6992 321.8390 321.9789 322.1187 322.2585 322.3983 322.5381 322.6779 322.8176 322.9574 323.0972 323.2369 323.3766 323.5163 323.6560 323.7957 323.9354 324.0751 324.2147 324.3544 324.4940 324.6337 324.7733 324.9129 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220211T224432.1Z 8077.947594 194 1 19.65 2 77.34 117.47 118.73 352.77 0.00 1 0.00 1 0 17 3.402e-01 1.214e-02 2.169e-01 7.038e-03 5.973679e-01 3.702702e-03 6.475903e-03 -6.000000e+00 1.945930e-01 225.05 -2.00 3.40 -2.00 320.85 0.00e+00 7.044646e-03 1.305134e-03 4.820062e-04 -6.000000e+00 7.914946e-03 279.01 -2.00 20.00 -2.00 320.53 0.00e+00 4.440 0.001 302.00 328.00 3 2.5789e+00 1.0857e-02 5.2880e-02 -6.0000e+00 4.8406e-01 1.2611e-01 1.4018e-02 3.0245e-02 -6.0000e+00 5.2840e-01 -1.4997e-01 1.5273e-02 1.6392e-02 -6.0000e+00 3.1118e-01 5.0026e-02 7.8209e-03 5.3463e-03 -6.0000e+00 1.3079e-01 2.5910e-04 -5.6367e-04 2.0684e-04 6.4431e-05 -6.0000e+00 9.5102e-03 1.5546e-02 -5.2838e-05 12 9 9 12 1 1 98.40 17.23 0.42 0.01555 0.01131 11 6 1 5 0 1622.470 20.87 15.16 17.23 9.76 12.5 1011.33 -81817 -115734 -141268 -120825 -113049 43823 -29201 -132586 -55811 -134464 -126830 -103474 -66662 2920 -45452 -9067 29225 -10985 -47192 -55462 -11612 -24937 -13534 -24939 -12181 -28781 -10304 -44101 -9058 -866 -14038 9192 -16406 23687 -10407 -9129 4617 -12323 15802 2478 9408 -7019 9228 -484 -4113 5999 3034 9444 822 12115 5084 11324 5264 6010 6349 287 2531 -3598 -1433 415 159 7712 7220 8441 1342 5769 -2522 156 1768 471 2722 -69 1736 -368 551 -3345 -4559 -2901 -3258 275 -1133 -412 -1776 -717 -606 -644 1009 -1275 2792 -612 -422 -2318 -152 -2648 -597 1483 942 742 -495 -541 -2194 -1976 -612 -1419 -1760 -2372 -332 -882 1420 340 1181 998 -100 -290 -730 370 -129 894 232 662 1485 611 876 -308 1068 -737 5 -507 293 465 -306 -323 -446 -221 -785 145 448 -16 189 -55 -175 -267 -715 -1588 -2556 -1658 -1340 301 -200 -2316 -487 -2684 -2532 -2001 -1164 36 -1123 -180 441 -271 -1781 -2360 -319 -787 -399 -873 -393 -1126 -332 -1967 -298 -30 -674 410 -1047 1008 -600 -545 276 -1049 1215 248 956 -891 1039 -61 -556 753 404 1225 122 1754 879 2020 1080 1299 1416 70 603 -891 -341 99 41 2096 2225 2763 469 1868 -893 58 732 221 1321 -34 817 -163 218 -1263 -1711 -1159 -1527 146 -698 -278 -1296 -550 -496 -506 810 -1054 2374 -505 -323 -1708 -110 -2135 -541 1384 1013 881 -607 -631 -2361 -1929 -579 -1438 -1906 -2718 -397 -1149 2007 536 1967 1678 -164 -451 -1084 538 -196 1427 392 1117 2414 965 1334 -456 1499 -1016 6 -789 509 885 -572 -633 -924 -486 -1836 344 1080 -38 444 -123 -369 -543 SS 20220211T224919.2Z 8077.950917 197 1 48.62 2 76.48 118.28 118.83 353.94 0.00 1 0.00 1 0 17 2.709e-01 7.759e-03 3.960e-02 1.279e-03 5.647167e-01 6.742729e-04 6.146816e-03 -6.000000e+00 1.549473e-01 225.05 -2.00 3.40 -2.00 320.77 0.00e+00 7.198550e-03 2.334223e-04 4.463230e-04 -6.000000e+00 6.303510e-03 279.01 -2.00 20.00 -2.00 320.43 0.00e+00 4.176 0.001 302.00 328.00 3 3.6919e-01 1.9605e-03 4.9833e-02 -6.0000e+00 3.8544e-01 5.2511e-02 2.5148e-03 2.8660e-02 -6.0000e+00 4.2076e-01 -6.4670e-02 2.7381e-03 1.5576e-02 -6.0000e+00 2.4779e-01 1.1015e-02 1.4079e-03 5.0677e-03 -6.0000e+00 1.0414e-01 3.1888e-03 -4.9291e-04 3.8468e-05 6.0202e-05 -6.0000e+00 7.5737e-03 1.6049e-02 -6.1809e-05 11 8 0 10 0 0 96.15 17.25 0.29 0.01605 0.01234 368 80 1 5 0 132.080 20.87 14.97 17.25 10.05 12.6 1012.48 -92275 -84196 -69519 -89600 -92503 -101053 -94662 -97755 -76363 -90224 -78130 -57117 -60539 -35266 -24132 -17147 -19281 -11061 -14035 -8522 -11224 -10703 -16813 -22314 -21008 -18727 -16842 -23431 -10830 -11490 -6679 -1354 -3991 -4181 -6350 -8163 -5317 -2168 -3659 -2080 -3729 -2542 -376 14 1372 2139 2111 3220 3023 4420 3373 5208 4844 2815 1917 138 -675 -1524 -821 770 3227 4190 4866 3827 2133 1836 458 1677 2543 2003 1416 524 -261 -1331 -2174 -2258 -2426 -1348 -459 -358 -721 -1741 -1924 -1354 -704 192 390 996 818 406 -200 -1353 -1454 -1135 -565 217 1091 584 -189 -652 -1575 -1246 -446 -1432 -1518 -1382 -689 -29 589 636 738 700 387 -102 65 169 389 795 475 493 902 924 235 -38 -760 -667 474 107 -107 -148 -459 -445 -185 -290 -480 -83 336 5 -17 64 -14 292 -879 -831 -607 -894 -892 -1077 -1030 -1219 -831 -1176 -974 -706 -1009 -588 -488 -374 -479 -277 -387 -232 -315 -302 -528 -785 -765 -687 -603 -885 -378 -464 -308 -69 -232 -242 -364 -501 -365 -174 -356 -227 -450 -322 -49 2 184 293 298 465 460 721 618 1027 1037 652 464 35 -172 -385 -203 192 852 1236 1605 1367 767 640 162 628 1074 951 716 269 -129 -617 -917 -874 -921 -546 -214 -196 -451 -1214 -1430 -1063 -587 168 354 904 725 339 -156 -1004 -1076 -910 -515 206 1170 692 -230 -758 -1678 -1328 -465 -1458 -1647 -1575 -829 -37 837 994 1221 1163 622 -155 94 241 576 1244 784 820 1455 1437 356 -55 -1073 -906 650 162 -183 -275 -912 -922 -403 -618 -1083 -191 788 12 -39 140 -31 632 SS 20220211T225956.2Z 8077.958289 200 1 48.54 2 74.60 120.09 119.00 356.55 0.00 1 0.00 1 0 17 1.699e-01 7.373e-03 2.250e-02 9.357e-04 5.040194e-01 4.847138e-04 5.542632e-03 -6.000000e+00 9.717444e-02 225.05 -2.00 3.40 -2.00 320.37 0.00e+00 5.768628e-03 1.512439e-04 3.324433e-04 -6.000000e+00 3.952123e-03 279.01 -2.00 20.00 -2.00 320.06 0.00e+00 3.696 0.001 302.00 328.00 3 4.2594e-01 1.3768e-03 4.4112e-02 -6.0000e+00 2.4173e-01 2.4373e-02 1.6887e-03 2.5212e-02 -6.0000e+00 2.6386e-01 -2.4087e-02 1.7179e-03 1.3377e-02 -6.0000e+00 1.5539e-01 -6.4528e-03 9.0296e-04 4.2541e-03 -6.0000e+00 6.5316e-02 5.0792e-03 -4.4025e-04 2.8108e-05 5.0351e-05 -6.0000e+00 4.7488e-03 1.5508e-02 -4.1447e-05 11 8 0 10 0 0 96.63 17.28 0.34 0.01551 0.01220 441 95 1 5 0 110.040 20.96 15.08 17.28 11.25 12.5 1015.67 -62760 -38240 -58661 -47997 -54558 -64176 -57157 -69820 -46171 -62408 -35990 -42678 -23672 -23203 -21610 -10920 -13947 -6276 -7963 743 -6501 -7504 -7226 -13497 -10216 -15883 -10735 -14586 -7244 -6456 -2991 305 -4360 -3001 -7480 -3495 -2588 -1628 -1688 -3368 -2574 -2684 -765 -64 2017 2056 1787 2015 870 3520 2820 3936 3381 2655 2018 338 -656 -1709 -547 428 3101 3725 4209 2761 1187 1088 223 1924 1750 1582 1081 354 -2 -1065 -1354 -2014 -1997 -1342 -611 -563 -808 -1794 -1864 -1033 -754 276 443 760 703 100 -115 -1187 -629 -795 -397 352 894 415 -385 -611 -1454 -1071 -505 -1328 -1620 -1250 -681 -76 570 621 720 655 415 -20 35 249 439 890 374 374 850 793 332 -27 -551 -564 613 11 -82 -215 -476 -506 -315 -315 -482 -73 280 -30 56 27 54 260 -765 -406 -778 -533 -606 -798 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