File name: Pandora194s1_Tokyo-TMU_20220221_L2Fit_fout2c1d20211130p1-8.txt File generation date: 20251129T081307.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Shungo KATO Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 194 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora194_OF_v3d20210122.txt Instrument calibration file used: Pandora194s1_CF_v1d20211130.txt Level 1 file used: Pandora194s1_Tokyo-TMU_20220221_L1_smca1c1d20211130p1-8.txt Full location name: Tokyo Metropolitan University (TMU) Short location name: Tokyo-TMU Country of location: Japan Location latitude [deg]: 35.6200 Location longitude [deg]: 139.3834 Location altitude [m]: 135 Local noon date: 20220221 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 338 Nominal wavelengths inside fitting window [nm]: 305.1230 305.2641 305.4052 305.5463 305.6873 305.8284 305.9694 306.1104 306.2515 306.3925 306.5335 306.6745 306.8154 306.9564 307.0974 307.2383 307.3792 307.5202 307.6611 307.8020 307.9429 308.0838 308.2247 308.3655 308.5064 308.6472 308.7881 308.9289 309.0697 309.2105 309.3513 309.4921 309.6328 309.7736 309.9143 310.0551 310.1958 310.3365 310.4772 310.6179 310.7586 310.8993 311.0399 311.1806 311.3212 311.4619 311.6025 311.7431 311.8837 312.0243 312.1649 312.3054 312.4460 312.5865 312.7271 312.8676 313.0081 313.1486 313.2891 313.4296 313.5701 313.7105 313.8510 313.9914 314.1318 314.2722 314.4127 314.5530 314.6934 314.8338 314.9742 315.1145 315.2549 315.3952 315.5355 315.6758 315.8161 315.9564 316.0967 316.2370 316.3772 316.5175 316.6577 316.7979 316.9382 317.0784 317.2186 317.3587 317.4989 317.6391 317.7792 317.9194 318.0595 318.1996 318.3397 318.4798 318.6199 318.7600 318.9001 319.0401 319.1802 319.3202 319.4602 319.6002 319.7402 319.8802 320.0202 320.1602 320.3002 320.4401 320.5800 320.7200 320.8599 320.9998 321.1397 321.2796 321.4195 321.5593 321.6992 321.8390 321.9789 322.1187 322.2585 322.3983 322.5381 322.6779 322.8176 322.9574 323.0972 323.2369 323.3766 323.5163 323.6560 323.7957 323.9354 324.0751 324.2147 324.3544 324.4940 324.6337 324.7733 324.9129 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220220T220457.1Z 8086.920106 259 1 49.29 2 82.62 108.81 70.19 244.94 0.00 1 0.00 1 0 17 4.351e-01 1.686e-02 2.873e-01 9.169e-03 7.732519e-01 5.157625e-03 7.996494e-03 -6.000000e+00 2.490494e-01 225.48 -2.00 3.40 -2.00 322.11 0.00e+00 1.187616e-02 2.298379e-03 1.047781e-03 -6.000000e+00 1.012648e-02 279.30 -2.00 20.00 -2.00 321.74 0.00e+00 7.207 0.006 302.00 328.00 3 1.6907e-01 1.6858e-02 8.1242e-02 -6.0000e+00 6.2010e-01 6.5967e-01 2.3754e-02 4.0758e-02 -6.0000e+00 6.7689e-01 -9.1555e-01 2.6407e-02 2.3152e-02 -6.0000e+00 3.9850e-01 3.6777e-01 1.2899e-02 8.1088e-03 -6.0000e+00 1.6720e-01 1.7838e-04 -1.8820e-03 2.8267e-04 1.1110e-04 -6.0000e+00 1.2167e-02 1.9910e-02 -1.2543e-04 12 8 8 10 0 0 -10.32 17.11 0.47 0.01991 0.00577 83 18 1 5 0 593.740 20.77 15.01 17.11 7.24 12.8 1002.06 -163225 -63575 -72460 -102693 -74663 -115165 -171536 -192610 -47593 -161673 -140122 -89683 -104871 -74376 -41385 96112 -58132 -59191 -11768 38931 48726 -20551 -3098 -47577 -19819 6799 -54235 -46607 -49439 -16178 -11055 21372 -15407 9690 -23889 27651 19145 -11372 24569 1514 33916 18064 23091 14766 37659 22940 20451 23969 6393 34884 8129 35556 39587 29110 19573 23255 28340 -1056 16841 15496 15985 22185 12964 14983 3429 14766 7480 13829 12534 14639 13922 1354 4657 -1433 3991 -4568 -3110 -4005 3297 2627 3343 -2680 -2240 148 -2066 1946 1448 -924 1267 -1606 -5224 -7328 -4247 -1897 -2574 -1737 -12 -422 -1247 -437 -2442 -1430 -691 -2816 -2429 -1956 -3018 -1636 -210 -341 52 1420 -293 -1058 -1593 27 579 664 1075 1615 1955 2089 1436 462 321 312 1095 940 -18 116 -295 847 37 -457 -243 5 350 -286 -138 -325 42 -773 -4256 -663 -810 -1502 -728 -1591 -4182 -5949 -425 -3679 -2733 -1312 -2387 -1632 -807 859 -1701 -1876 -239 475 515 -418 -53 -1276 -403 105 -1499 -1174 -1366 -381 -305 504 -576 276 -893 629 529 -499 879 76 1323 866 1088 768 1592 1156 1097 1305 442 2183 741 2702 3114 2681 2030 2349 2686 -129 1671 1579 1758 2618 1924 2384 619 2350 1311 2460 2577 3285 3311 363 1141 -339 799 -919 -620 -899 825 791 1159 -1102 -981 67 -1022 974 755 -497 649 -797 -2517 -3472 -2005 -982 -1581 -1251 -10 -393 -1210 -402 -2071 -1079 -501 -2208 -2024 -1717 -2887 -1707 -245 -454 75 2082 -431 -1507 -2199 36 820 996 1678 2496 2898 2968 1993 627 424 401 1454 1420 -31 230 -634 1917 90 -1201 -672 15 1005 -826 -385 -848 103 -1810 SS 20220220T221553.1Z 8086.927698 262 1 48.83 2 80.53 110.51 72.20 246.76 0.00 1 0.00 1 0 17 4.643e-01 1.034e-02 1.042e-01 3.030e-03 6.521291e-01 1.618740e-03 6.861338e-03 -6.000000e+00 2.657923e-01 225.48 -2.00 3.40 -2.00 321.47 0.00e+00 1.101078e-02 6.559202e-04 6.925218e-04 -6.000000e+00 1.080562e-02 279.30 -2.00 20.00 -2.00 321.14 0.00e+00 5.790 0.003 302.00 328.00 3 3.0286e-02 4.9801e-03 6.5711e-02 -6.0000e+00 6.6179e-01 2.0694e-01 7.0676e-03 3.3942e-02 -6.0000e+00 7.2236e-01 -2.8822e-01 8.3167e-03 1.9043e-02 -6.0000e+00 4.2528e-01 1.0827e-01 4.1032e-03 6.4485e-03 -6.0000e+00 1.7846e-01 9.0811e-04 -9.6152e-04 9.0898e-05 7.9885e-05 -6.0000e+00 1.2982e-02 1.9246e-02 -1.1485e-04 12 8 8 10 0 0 19.47 17.11 0.33 0.01925 0.01202 209 45 1 5 0 233.590 20.77 15.10 17.11 8.70 12.6 1005.64 -189361 -97820 -144670 -140247 -139971 -167378 -129563 -186938 -130556 -168994 -116429 -112393 -63424 -72518 -51751 -26505 -47999 -32707 -62569 -21922 -9866 -34716 -12456 -45504 -30395 -59930 -33645 -44872 -11653 -10146 -17730 -810 -3089 -3779 -15344 -8483 -6621 -1558 3768 294 261 -1823 2655 2782 5227 12671 14074 7450 3538 10951 4694 6016 7658 9073 5662 2657 1966 -671 1156 487 3995 6848 8415 8678 4453 4083 1150 3104 2723 3686 4084 2643 1900 -2450 -2241 -4925 -3631 -1659 659 1037 502 -1667 -2204 -1243 -1387 -2 669 857 859 374 -597 -2933 -2248 -2018 -1223 225 885 544 -360 -657 -1801 -1187 -880 -1473 -1654 -1543 -956 -665 232 385 425 555 520 -250 -368 90 27 503 453 864 1493 1164 637 -195 -648 -451 719 430 175 316 -268 -311 -392 -292 -453 200 205 68 57 -50 -350 -65 -3052 -709 -1710 -1469 -1353 -2113 -1183 -3264 -1368 -2678 -1188 -1389 -647 -1071 -778 -363 -915 -589 -1613 -389 -154 -690 -204 -1076 -637 -1722 -741 -1109 -222 -226 -524 -26 -114 -140 -612 -331 -290 -77 210 19 19 -141 206 223 423 988 1127 669 351 1107 564 786 1066 1319 878 433 322 -110 184 80 695 1321 1820 2028 1087 978 288 823 828 1241 1447 951 657 -814 -669 -1393 -1009 -498 229 424 237 -893 -1266 -753 -898 -1 466 601 587 242 -363 -1737 -1338 -1324 -924 196 882 603 -413 -718 -1806 -1073 -778 -1393 -1670 -1641 -1083 -820 318 586 630 834 836 -385 -542 132 41 813 768 1461 2429 1830 975 -290 -936 -630 1025 688 319 578 -528 -646 -865 -687 -1129 508 531 177 144 -119 -785 -141 SS 20220220T222434.1Z 8086.933728 267 1 48.72 2 78.88 111.89 73.81 248.17 0.00 1 0.00 1 0 17 3.397e-01 7.990e-03 5.508e-02 1.626e-03 5.802949e-01 8.674151e-04 6.213821e-03 -6.000000e+00 1.945120e-01 225.48 -2.00 3.40 -2.00 321.09 0.00e+00 8.175704e-03 3.238558e-04 5.146238e-04 -6.000000e+00 7.907024e-03 279.30 -2.00 20.00 -2.00 320.74 0.00e+00 5.005 0.002 302.00 328.00 3 -9.2898e-02 2.5856e-03 5.7095e-02 -6.0000e+00 4.8431e-01 8.1196e-02 3.4238e-03 2.9759e-02 -6.0000e+00 5.2863e-01 -1.0679e-01 3.8725e-03 1.6416e-02 -6.0000e+00 3.1122e-01 3.0417e-02 1.9629e-03 5.4678e-03 -6.0000e+00 1.3061e-01 2.3299e-03 -6.9157e-04 4.9982e-05 6.3847e-05 -6.0000e+00 9.4999e-03 1.8749e-02 -1.1187e-04 11 8 0 10 0 0 10.09 17.12 0.32 0.01875 0.01355 360 78 1 5 0 135.310 20.77 15.04 17.12 9.96 12.8 1008.81 -126499 -59317 -120372 -114106 -117666 -139538 -94387 -119344 -92734 -117195 -82078 -82421 -64760 -41919 -51463 -10657 -31936 -4478 -22732 -20639 -21031 -18963 -18241 -35382 -9723 -24131 -18215 -27221 -20635 -14890 -14653 1614 -8362 -405 -11331 -5968 -8776 -2817 -1168 -3597 -159 -817 4088 -1063 4098 3212 3187 6298 2276 6030 4879 5829 4598 3844 1730 -313 351 -1844 42 1301 3701 4632 5196 4750 2342 2586 761 2904 1468 2400 1402 223 379 -1737 -796 -3213 -2533 -2225 -968 -657 -697 -1376 -1985 -308 -1074 154 559 535 922 -29 -109 -1695 -1167 -1292 -807 359 949 565 -226 -238 -1449 -894 -759 -1629 -1465 -1375 -491 -143 931 565 687 512 67 -93 -210 318 353 794 476 459 1044 923 526 -127 -572 -659 716 81 -149 -26 -278 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