File name: Pandora194s1_Tokyo-TMU_20220303_L2Fit_fout2c1d20211130p1-8.txt File generation date: 20251129T081830.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Shungo KATO Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 194 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora194_OF_v3d20210122.txt Instrument calibration file used: Pandora194s1_CF_v1d20211130.txt Level 1 file used: Pandora194s1_Tokyo-TMU_20220303_L1_smca1c1d20211130p1-8.txt Full location name: Tokyo Metropolitan University (TMU) Short location name: Tokyo-TMU Country of location: Japan Location latitude [deg]: 35.6200 Location longitude [deg]: 139.3834 Location altitude [m]: 135 Local noon date: 20220303 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 338 Nominal wavelengths inside fitting window [nm]: 305.1230 305.2641 305.4052 305.5463 305.6873 305.8284 305.9694 306.1104 306.2515 306.3925 306.5335 306.6745 306.8154 306.9564 307.0974 307.2383 307.3792 307.5202 307.6611 307.8020 307.9429 308.0838 308.2247 308.3655 308.5064 308.6472 308.7881 308.9289 309.0697 309.2105 309.3513 309.4921 309.6328 309.7736 309.9143 310.0551 310.1958 310.3365 310.4772 310.6179 310.7586 310.8993 311.0399 311.1806 311.3212 311.4619 311.6025 311.7431 311.8837 312.0243 312.1649 312.3054 312.4460 312.5865 312.7271 312.8676 313.0081 313.1486 313.2891 313.4296 313.5701 313.7105 313.8510 313.9914 314.1318 314.2722 314.4127 314.5530 314.6934 314.8338 314.9742 315.1145 315.2549 315.3952 315.5355 315.6758 315.8161 315.9564 316.0967 316.2370 316.3772 316.5175 316.6577 316.7979 316.9382 317.0784 317.2186 317.3587 317.4989 317.6391 317.7792 317.9194 318.0595 318.1996 318.3397 318.4798 318.6199 318.7600 318.9001 319.0401 319.1802 319.3202 319.4602 319.6002 319.7402 319.8802 320.0202 320.1602 320.3002 320.4401 320.5800 320.7200 320.8599 320.9998 321.1397 321.2796 321.4195 321.5593 321.6992 321.8390 321.9789 322.1187 322.2585 322.3983 322.5381 322.6779 322.8176 322.9574 323.0972 323.2369 323.3766 323.5163 323.6560 323.7957 323.9354 324.0751 324.2147 324.3544 324.4940 324.6337 324.7733 324.9129 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220302T235416.5Z 8096.996025 136 1 3.24 2 60.00 125.77 66.48 123.97 0.00 1 0.00 1 0 17 2.062e-02 9.258e-03 1.205e-02 3.945e-03 3.001279e-01 2.000797e-03 3.453969e-03 -6.000000e+00 1.183742e-02 226.03 -2.00 3.40 -2.00 317.12 0.00e+00 1.282046e-03 2.540359e-04 6.265476e-05 -6.000000e+00 4.796396e-04 279.80 -2.00 20.00 -2.00 316.81 0.00e+00 1.992 0.000 302.00 328.00 3 2.9841e+00 5.2397e-03 2.4518e-02 -6.0000e+00 2.9511e-02 2.1535e-02 5.8664e-03 1.4601e-02 -6.0000e+00 3.2193e-02 6.5526e-03 3.5791e-03 7.2908e-03 -6.0000e+00 1.8945e-02 -1.4694e-02 1.7792e-03 2.1069e-03 -6.0000e+00 7.9432e-03 2.5607e-03 -3.5310e-04 1.1456e-04 2.3746e-05 -6.0000e+00 5.7652e-04 2.2075e-02 1.6696e-04 12 9 1 12 1 1 95.02 18.35 0.33 0.02207 0.01942 3 14 1 5 0 765.570 21.98 15.00 18.35 18.44 13.2 996.29 -3620 -658 -5557 -6084 -7234 -1669 3587 -3648 -8757 -7951 -4212 -5812 1507 -2080 -490 -328 838 822 922 1748 1928 2406 1457 568 -32 -3323 -2094 -2199 880 1692 1202 4657 -72 -4408 -5400 -2243 -840 1427 388 109 -914 -715 -516 1078 483 -39 -130 293 -694 1403 567 2435 1386 557 1442 208 -307 -850 798 1210 2832 1870 2755 1114 265 -309 -1016 -264 392 514 152 457 460 601 -715 -1804 -2078 -188 -1198 -1069 -1188 -1898 -1513 -1518 -484 138 -224 325 694 -40 115 -347 -940 -121 -357 521 377 -147 -1143 -1013 -1747 -1210 -110 -1210 -1150 -795 -595 -416 739 731 1359 1012 1394 725 419 667 672 1326 467 539 750 1160 225 1 124 -836 1110 -352 -116 -293 -870 -805 -216 -328 -646 -17 402 227 -452 159 -216 -237 -411 -77 -675 -676 -748 -165 370 -455 -1243 -1141 -588 -905 254 -385 -102 -73 194 200 233 453 500 624 398 166 -10 -1076 -648 -640 241 478 374 1532 -24 -1509 -1939 -814 -315 624 188 60 -537 -435 -297 661 299 -24 -79 174 -418 862 351 1580 962 407 1068 148 -221 -606 591 907 2072 1508 2378 943 230 -249 -793 -212 328 478 150 455 445 546 -635 -1459 -1580 -143 -1025 -971 -1204 -1973 -1649 -1659 -561 169 -271 394 816 -47 131 -361 -940 -125 -405 619 472 -189 -1500 -1324 -2113 -1433 -130 -1466 -1484 -1070 -796 -586 1047 1101 2089 1527 2070 999 569 888 925 1836 696 787 1084 1707 322 1 169 -1097 1420 -485 -163 -440 -1294 -1223 -340 -520 -1084 -29 672 384 -754 265 -347 -371 SS 20220303T001155.9Z 8097.008286 142 1 15.45 2 57.16 129.68 63.59 127.38 0.00 1 0.00 1 0 17 1.609e-02 8.152e-03 5.443e-03 1.721e-03 2.765354e-01 8.710665e-04 3.165134e-03 -6.000000e+00 9.244597e-03 226.03 -2.00 3.40 -2.00 317.29 0.00e+00 1.457733e-03 1.158381e-04 6.099987e-05 -6.000000e+00 3.742563e-04 279.80 -2.00 20.00 -2.00 316.97 0.00e+00 1.838 0.000 302.00 328.00 3 3.1524e+00 2.2840e-03 2.2602e-02 -6.0000e+00 2.3048e-02 2.4045e-02 2.5558e-03 1.3425e-02 -6.0000e+00 2.5136e-02 8.4291e-03 1.5660e-03 6.6972e-03 -6.0000e+00 1.4792e-02 -1.4440e-02 7.7942e-04 1.9386e-03 -6.0000e+00 6.2075e-03 2.5977e-03 5.3530e-04 5.0490e-05 2.1818e-05 -6.0000e+00 4.4984e-04 1.5003e-02 1.1472e-04 12 9 1 12 1 1 99.84 18.43 0.32 0.01500 0.01903 21 15 1 5 0 694.060 22.09 15.00 18.43 19.45 13.2 998.85 -472 -3134 -4787 -7652 -2962 -4270 -1407 -3363 -542 -3976 -5361 -4829 -1174 -428 -667 998 540 685 1659 859 500 708 1221 -860 -619 -1508 -2416 -2425 -976 1444 1198 1915 -409 -3872 -2596 -3364 -1079 -468 -144 -902 -843 -46 -405 680 346 318 -98 -519 206 1459 1210 1156 1647 824 1322 464 557 65 319 1237 1787 2397 2734 1270 -146 -142 -563 1431 1407 130 879 53 6 -511 -685 -1178 -1655 -1155 -1197 -1086 -1282 -2663 -1761 -1094 -843 -151 426 474 339 208 -48 -924 -395 -226 -473 236 622 149 -517 -675 -1403 -1085 -111 -1121 -1511 -840 -575 -38 616 711 963 712 619 453 366 602 676 1109 836 538 1048 996 499 557 -351 -206 511 101 -314 -307 -584 -632 -274 -378 -420 3 62 -137 -135 -65 -219 -30 -51 -369 -563 -840 -285 -419 -147 -402 -68 -522 -718 -702 -191 -80 -141 223 127 168 418 225 131 186 332 -229 -172 -429 -670 -693 -266 398 360 566 -131 -1247 -785 -1069 -382 -196 -71 -462 -459 -26 -232 387 198 180 -55 -285 112 814 725 738 1104 579 945 341 410 48 228 893 1363 1827 2236 1080 -119 -116 -443 1139 1156 120 852 52 6 -464 -566 -952 -1256 -887 -1021 -966 -1269 -2679 -1846 -1210 -998 -188 511 574 401 246 -52 -995 -403 -238 -509 282 764 198 -695 -861 -1776 -1279 -131 -1431 -1927 -1114 -796 -54 886 1082 1498 1082 884 635 479 773 897 1562 1262 786 1516 1498 725 770 -466 -279 679 134 -449 -464 -857 -947 -424 -618 -725 5 105 -236 -227 -113 -364 -48 SS 20220303T001719.2Z 8097.012028 146 1 49.36 2 56.33 130.93 62.73 128.47 0.00 1 0.00 1 0 17 2.040e-02 7.941e-03 1.028e-02 2.523e-03 2.735443e-01 1.275358e-03 3.099638e-03 -6.000000e+00 1.172123e-02 226.03 -2.00 3.40 -2.00 317.91 0.00e+00 1.485690e-03 1.962590e-04 7.153672e-05 -6.000000e+00 4.744767e-04 279.80 -2.00 20.00 -2.00 317.58 0.00e+00 1.798 0.000 302.00 328.00 3 4.3123e+00 3.3795e-03 2.2189e-02 -6.0000e+00 2.9223e-02 4.2658e-02 3.7992e-03 1.3251e-02 -6.0000e+00 3.1869e-02 8.4963e-03 2.4474e-03 6.6496e-03 -6.0000e+00 1.8754e-02 -1.7107e-02 1.2521e-03 1.9527e-03 -6.0000e+00 7.8709e-03 8.4315e-04 5.3038e-04 7.5440e-05 2.0672e-05 -6.0000e+00 5.7029e-04 1.4730e-02 1.2560e-04 11 8 0 10 0 0 99.87 18.45 0.33 0.01473 0.01872 46 10 1 5 0 1072.820 22.09 15.00 18.45 19.62 13.4 999.20 -3222 -6284 -8610 -4025 -7029 -1781 -6247 -4166 -6412 -6979 -3425 -3475 698 -1490 715 -1052 290 -3393 3741 2564 679 2255 1206 478 -308 -1851 -2320 -4020 -1272 -319 2540 1957 305 -3913 -3293 -2391 -1810 940 -87 -595 -173 -335 -1308 131 268 327 438 -232 275 1343 1152 1636 1372 1232 469 500 182 -500 -281 425 2047 2359 2969 1234 238 -378 -874 736 1261 1164 437 637 581 -73 -985 -1024 -2130 -857 -1057 -1353 -1219 -2333 -1727 -1210 -777 172 80 813 491 203 -32 -1034 -274 -574 -455 191 936 201 -539 -945 -1517 -647 -408 -1298 -1296 -665 -671 -14 464 809 1008 801 711 138 464 325 310 1032 666 400 958 725 452 378 -279 -323 679 10 -107 -607 -478 -850 -350 -72 -249 -114 207 58 83 -59 -399 -70 -249 -531 -805 -326 -538 -130 -522 -382 -648 -719 -342 -379 84 -213 113 -182 52 -654 698 498 135 440 247 104 -71 -437 -532 -878 -261 -67 564 476 80 -1037 -824 -618 -530 319 -35 -272 -84 -168 -675 67 137 165 216 -113 133 666 612 922 818 764 299 325 119 -324 -179 274 1375 1718 2313 1003 185 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