File name: Pandora194s1_Tokyo-TMU_20220308_L2Fit_fout2c1d20211130p1-8.txt File generation date: 20251129T081717.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Shungo KATO Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 194 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora194_OF_v3d20210122.txt Instrument calibration file used: Pandora194s1_CF_v1d20211130.txt Level 1 file used: Pandora194s1_Tokyo-TMU_20220308_L1_smca1c1d20211130p1-8.txt Full location name: Tokyo Metropolitan University (TMU) Short location name: Tokyo-TMU Country of location: Japan Location latitude [deg]: 35.6200 Location longitude [deg]: 139.3834 Location altitude [m]: 135 Local noon date: 20220308 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 338 Nominal wavelengths inside fitting window [nm]: 305.1230 305.2641 305.4052 305.5463 305.6873 305.8284 305.9694 306.1104 306.2515 306.3925 306.5335 306.6745 306.8154 306.9564 307.0974 307.2383 307.3792 307.5202 307.6611 307.8020 307.9429 308.0838 308.2247 308.3655 308.5064 308.6472 308.7881 308.9289 309.0697 309.2105 309.3513 309.4921 309.6328 309.7736 309.9143 310.0551 310.1958 310.3365 310.4772 310.6179 310.7586 310.8993 311.0399 311.1806 311.3212 311.4619 311.6025 311.7431 311.8837 312.0243 312.1649 312.3054 312.4460 312.5865 312.7271 312.8676 313.0081 313.1486 313.2891 313.4296 313.5701 313.7105 313.8510 313.9914 314.1318 314.2722 314.4127 314.5530 314.6934 314.8338 314.9742 315.1145 315.2549 315.3952 315.5355 315.6758 315.8161 315.9564 316.0967 316.2370 316.3772 316.5175 316.6577 316.7979 316.9382 317.0784 317.2186 317.3587 317.4989 317.6391 317.7792 317.9194 318.0595 318.1996 318.3397 318.4798 318.6199 318.7600 318.9001 319.0401 319.1802 319.3202 319.4602 319.6002 319.7402 319.8802 320.0202 320.1602 320.3002 320.4401 320.5800 320.7200 320.8599 320.9998 321.1397 321.2796 321.4195 321.5593 321.6992 321.8390 321.9789 322.1187 322.2585 322.3983 322.5381 322.6779 322.8176 322.9574 323.0972 323.2369 323.3766 323.5163 323.6560 323.7957 323.9354 324.0751 324.2147 324.3544 324.4940 324.6337 324.7733 324.9129 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220308T054407.6Z 8102.238977 358 1 47.21 2 56.93 233.74 24.82 129.04 0.00 1 0.00 1 0 17 2.979e-02 8.824e-03 1.566e-02 3.330e-03 2.969962e-01 1.694286e-03 3.369499e-03 -6.000000e+00 1.713646e-02 226.31 -2.00 3.40 -2.00 318.18 0.00e+00 1.415525e-03 2.787326e-04 8.440500e-05 -6.000000e+00 6.931245e-04 280.06 -2.00 20.00 -2.00 317.84 0.00e+00 1.827 0.000 302.00 328.00 3 4.7743e+00 4.5084e-03 2.3196e-02 -6.0000e+00 4.2751e-02 3.7204e-02 5.0711e-03 1.4444e-02 -6.0000e+00 4.6616e-02 3.6915e-03 3.3643e-03 7.2748e-03 -6.0000e+00 2.7427e-02 -1.4917e-02 1.7416e-03 2.1494e-03 -6.0000e+00 1.1502e-02 4.9721e-04 3.0935e-04 1.0047e-04 2.3172e-05 -6.0000e+00 8.3317e-04 1.4983e-02 7.7597e-05 12 9 1 12 1 1 99.98 18.06 0.18 0.01498 0.01731 14 3 1 5 0 3135.260 21.79 15.03 18.06 15.07 13.2 1001.81 -3 -14267 -1973 -6515 -8005 -3952 -12766 3248 -16819 -3798 -6675 -5216 -1213 -4385 631 -3400 1605 -1220 9864 1153 2733 1227 1543 -639 -2765 -1107 -3271 -1032 -3464 421 1395 -485 3174 -4294 -602 -2027 -1628 1198 1614 -1355 -1753 4 -1190 129 764 204 219 -814 -431 779 1903 1033 1145 1066 1056 828 -656 527 -1280 1378 1713 3251 2540 1032 470 -759 -304 166 1453 1111 1073 1210 -398 880 -725 -839 -2857 -1089 -1546 -1457 -883 -2295 -1428 -1809 135 -120 613 60 856 539 -856 -810 -813 34 -1156 63 661 386 -544 -723 -1575 -1673 -68 -717 -1458 -647 -1150 -59 931 787 998 738 877 312 159 -101 579 572 588 623 1766 883 -5 259 -665 131 -261 124 -53 -412 -192 -924 -282 -460 -50 49 264 125 -293 -61 -455 220 0 -1181 -142 -446 -512 -245 -949 231 -1578 -318 -581 -491 -128 -555 86 -522 246 -201 1515 199 465 213 278 -125 -575 -230 -672 -195 -649 79 284 -110 737 -1044 -134 -479 -437 373 593 -575 -796 2 -569 61 360 96 101 -374 -197 366 951 555 650 631 639 512 -413 322 -785 837 1103 2247 1908 809 352 -532 -204 115 1108 944 965 1098 -356 730 -554 -577 -1880 -718 -1139 -1214 -814 -2320 -1506 -1848 145 -137 721 71 986 582 -943 -816 -781 34 -1273 70 806 508 -726 -917 -1850 -2016 -81 -840 -1833 -844 -1581 -84 1408 1267 1646 1192 1330 438 209 -130 770 809 887 966 2689 1320 -7 356 -880 179 -358 179 -75 -624 -300 -1487 -468 -808 -93 93 511 244 -564 -113 -811 379 SS 20220308T054905.6Z 8102.242426 361 1 39.74 2 57.75 234.84 24.05 131.13 0.00 1 0.00 1 0 17 3.254e-02 9.393e-03 2.705e-02 5.102e-03 3.036043e-01 2.563157e-03 3.430650e-03 -6.000000e+00 1.872022e-02 226.31 -2.00 3.40 -2.00 318.36 0.00e+00 1.985996e-03 4.478558e-04 9.295830e-05 -6.000000e+00 7.570929e-04 280.06 -2.00 20.00 -2.00 318.04 0.00e+00 1.867 0.000 302.00 328.00 3 5.1882e+00 6.8403e-03 2.3713e-02 -6.0000e+00 4.6702e-02 3.8726e-02 7.7085e-03 1.4786e-02 -6.0000e+00 5.0923e-02 3.2024e-03 5.2549e-03 7.4624e-03 -6.0000e+00 2.9961e-02 -1.1364e-02 2.7720e-03 2.1998e-03 -6.0000e+00 1.2566e-02 3.1121e-04 2.4487e-04 1.5170e-04 2.2159e-05 -6.0000e+00 9.1005e-04 1.4548e-02 9.0730e-05 12 9 9 12 1 1 99.99 18.07 0.40 0.01455 0.01639 14 4 1 5 0 2637.350 21.79 14.99 18.07 15.32 13.2 1002.34 1707 -528 -1854 -10598 -6146 -9711 927 -5463 -17688 1618 -18401 -1785 -12395 -192 -449 -376 1933 -2547 -1038 1729 2087 5818 224 -4432 -4494 -3317 1601 3823 -1063 -414 1283 3968 -3446 -4192 -2683 -3330 -1160 2815 -1125 -1285 -3675 1366 1282 1390 -137 -1319 223 -1675 2650 647 2455 1935 854 1423 1464 -790 -188 -159 -373 864 1491 3152 2485 2241 567 827 -599 1426 1002 1607 1051 369 890 -653 -1432 -1908 -2454 -1565 -1651 -1187 -1294 -1600 -1093 -862 292 -270 152 591 722 -88 -214 -1899 -891 -5 -1255 178 203 -779 -697 -507 -1849 -1137 -673 -1025 -1088 -411 -35 -168 467 894 874 1047 705 -42 340 202 1353 838 1155 770 1081 1432 237 637 -922 -612 -127 -747 306 -226 -332 -1360 -412 -257 -663 -122 322 26 601 135 -432 -243 94 -32 -111 -633 -322 -585 55 -386 -1522 117 -1639 -148 -1338 -21 -57 -52 274 -397 -166 277 333 897 38 -831 -881 -653 291 639 -181 -73 245 809 -806 -961 -577 -750 -291 811 -399 -513 -1600 587 564 614 -61 -597 98 -737 1118 290 1162 983 463 800 841 -473 -112 -93 -216 503 918 2082 1787 1663 408 548 -387 934 738 1306 910 325 757 -530 -1060 -1276 -1548 -998 -1173 -953 -1158 -1553 -1110 -927 332 -328 173 678 885 -102 -226 -1873 -830 -5 -1341 209 266 -1009 -908 -687 -2332 -1325 -784 -1284 -1455 -571 -51 -233 690 1398 1405 1642 1044 -64 478 280 1912 1267 1687 1161 1612 2278 367 934 -1308 -823 -170 -1062 465 -367 -558 -2144 -667 -440 -1199 -227 606 50 1115 242 -747 -409 SS 20220308T055754.4Z 8102.248547 367 1 49.44 2 59.23 236.74 22.75 135.13 0.00 1 0.00 1 0 17 4.255e-02 8.736e-03 3.876e-02 5.791e-03 3.123779e-01 2.939650e-03 3.531191e-03 -6.000000e+00 2.447297e-02 226.31 -2.00 3.40 -2.00 318.89 0.00e+00 2.098606e-03 5.903465e-04 1.097097e-04 -6.000000e+00 9.898534e-04 280.06 -2.00 20.00 -2.00 318.56 0.00e+00 1.947 0.000 302.00 328.00 3 4.9298e+00 7.9209e-03 2.4637e-02 -6.0000e+00 6.1054e-02 1.5508e-02 8.9949e-03 1.5296e-02 -6.0000e+00 6.6573e-02 1.4136e-02 6.5073e-03 7.7548e-03 -6.0000e+00 3.9169e-02 -1.5662e-02 3.4535e-03 2.3150e-03 -6.0000e+00 1.6426e-02 3.7149e-04 3.7798e-04 1.7662e-04 2.5294e-05 -6.0000e+00 1.1899e-03 1.4608e-02 6.8261e-05 11 8 0 10 0 0 99.98 18.09 0.79 0.01461 0.01745 78 17 1 5 0 633.710 21.79 15.00 18.09 15.83 13.1 1003.28 -16653 13481 -9280 -13629 2349 -16600 -4138 -2155 -4972 -21980 -3484 -15358 1431 -2934 -1619 11875 -2239 4724 1049 1347 -2519 6546 -3298 -5306 2689 -8610 -1118 -5171 -2484 1632 726 2227 -4112 -5092 -3304 -4384 -6377 -743 -1445 -1990 119 180 62 -353 869 74 289 -343 1141 3172 2260 4002 1331 2356 881 749 537 -1268 1323 1583 3492 3092 3341 1686 -943 -1065 -1410 1712 1808 386 260 -1089 319 -752 -197 -1018 -1074 -1610 -799 -1545 -1288 -1349 -1463 72 -832 641 173 276 446 -179 -324 -1577 -329 -1651 204 -171 424 323 -147 -530 -1381 -950 181 -1487 -1466 -768 -649 -415 906 722 875 493 284 478 -63 322 59 1180 -109 584 913 923 1181 199 -282 -202 908 -883 -5 -792 -965 -103 -245 -24 -467 192 488 3 206 -579 -274 104 -898 574 -491 -686 93 -801 -193 -111 -283 -1512 -202 -1112 103 -259 -161 1122 -256 531 128 169 -328 783 -454 -787 385 -1405 -164 -746 -340 225 111 370 -777 -946 -575 -806 -1365 -180 -417 -649 41 64 23 -129 316 27 104 -122 403 1145 886 1650 596 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