File name: Pandora194s1_Tokyo-TMU_20220326_L2Fit_fwvt1c1d20211130p1-8.txt File generation date: 20251129T081719.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c1p1-8 Local principal investigator: Shungo KATO Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 194 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora194_OF_v3d20210122.txt Instrument calibration file used: Pandora194s1_CF_v1d20211130.txt Level 1 file used: Pandora194s1_Tokyo-TMU_20220326_L1_smca1c1d20211130p1-8.txt Full location name: Tokyo Metropolitan University (TMU) Short location name: Tokyo-TMU Country of location: Japan Location latitude [deg]: 35.6200 Location longitude [deg]: 139.3834 Location altitude [m]: 135 Local noon date: 20220326 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1613 1762 Nominal wavelengths inside fitting window [nm]: 492.0713 492.1928 492.3143 492.4358 492.5572 492.6787 492.8001 492.9215 493.0429 493.1643 493.2856 493.4070 493.5283 493.6496 493.7709 493.8922 494.0135 494.1347 494.2559 494.3771 494.4983 494.6195 494.7407 494.8618 494.9829 495.1040 495.2251 495.3462 495.4673 495.5883 495.7093 495.8303 495.9513 496.0723 496.1932 496.3142 496.4351 496.5560 496.6769 496.7978 496.9186 497.0395 497.1603 497.2811 497.4019 497.5226 497.6434 497.7641 497.8848 498.0055 498.1262 498.2469 498.3675 498.4882 498.6088 498.7294 498.8500 498.9705 499.0911 499.2116 499.3321 499.4526 499.5731 499.6935 499.8140 499.9344 500.0548 500.1752 500.2955 500.4159 500.5362 500.6566 500.7769 500.8971 501.0174 501.1377 501.2579 501.3781 501.4983 501.6185 501.7386 501.8588 501.9789 502.0990 502.2191 502.3392 502.4593 502.5793 502.6993 502.8193 502.9393 503.0593 503.1792 503.2992 503.4191 503.5390 503.6589 503.7788 503.8986 504.0184 504.1383 504.2581 504.3778 504.4976 504.6173 504.7371 504.8568 504.9765 505.0962 505.2158 505.3355 505.4551 505.5747 505.6943 505.8139 505.9334 506.0530 506.1725 506.2920 506.4115 506.5309 506.6504 506.7698 506.8893 507.0087 507.1280 507.2474 507.3668 507.4861 507.6054 507.7247 507.8440 507.9633 508.0825 508.2018 508.3210 508.4402 508.5594 508.6785 508.7977 508.9168 509.0359 509.1550 509.2741 509.3932 509.5122 509.6312 509.7502 509.8692 509.9882 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20220325T224439.6Z 8119.947680 218 1 49.57 2 65.41 106.17 65.27 197.43 0.00 1 0.00 1 0 15 2.941e-03 2.929e-03 9.283e-04 9.256e-04 1.667432e+03 5.668704e+01 1.136071e+02 -6.000000e+00 1.702542e+02 281.35 -2.00 20.00 -2.00 505.23 0.00e+00 6.694867e-04 2.585988e-05 3.869202e-05 -6.000000e+00 8.401073e-05 281.35 -2.00 20.00 -2.00 500.36 0.00e+00 1.440545e-01 1.890617e-02 1.530617e-02 -6.000000e+00 6.002596e-02 227.52 -2.00 3.40 -2.00 501.95 0.00e+00 2.387 0.000 489.00 513.00 1 6.8062e+00 1.4527e-03 3.7174e-03 -6.0000e+00 4.6078e-03 9.6053e-03 3.7279e-04 3.7342e-04 -6.0000e+00 1.1874e-03 1.5182e-03 -4.2303e-04 1.0582e-04 1.9878e-05 -6.0000e+00 3.4562e-04 1.9337e-02 9.1612e-06 10 0 0 10 0 0 99.92 19.25 0.77 0.01934 0.01640 26 6 1 4 0 1906.230 22.90 15.00 19.25 21.97 14.0 1010.42 -667 -411 -267 -137 207 158 510 423 575 402 19 -35 -217 -59 -424 -226 30 -152 157 93 240 126 265 399 338 142 91 -229 -304 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-62 185 303 328 457 574 611 452 315 142 176 268 369 240 175 274 89 128 9 171 -29 -78 -421 -301 -51 -303 -29 -180 151 134 191 388 158 345 33 -196 -279 -550 -435 900000 SQ 20220325T224735.6Z 8119.949717 220 1 4.78 2 64.84 106.67 65.45 198.10 0.00 1 0.00 1 0 15 3.160e-03 3.150e-03 1.516e-03 1.513e-03 1.693614e+03 9.231487e+01 1.221752e+02 -6.000000e+00 1.828698e+02 281.35 -2.00 20.00 -2.00 505.25 0.00e+00 6.285819e-04 4.229986e-05 3.541507e-05 -6.000000e+00 9.025275e-05 281.35 -2.00 20.00 -2.00 500.43 0.00e+00 1.328172e-01 3.071311e-02 1.394058e-02 -6.000000e+00 6.451587e-02 227.52 -2.00 3.40 -2.00 502.02 0.00e+00 2.337 0.000 489.00 513.00 1 5.6494e+00 2.3578e-03 3.6032e-03 -6.0000e+00 4.9518e-03 1.0613e-02 6.0566e-04 3.5977e-04 -6.0000e+00 1.2772e-03 4.8680e-03 6.2385e-04 1.7277e-04 1.9895e-05 -6.0000e+00 3.7130e-04 2.2801e-02 -6.4092e-05 12 1 1 12 1 1 99.89 19.26 0.75 0.02280 0.02713 4 12 1 4 0 919.380 22.90 15.00 19.26 22.11 14.0 1010.47 -755 -402 -345 -164 236 260 381 565 451 175 235 -27 -112 -382 -160 -209 -243 117 -82 -231 153 -67 225 453 285 174 122 -214 -123 -264 -563 -404 210 273 -3 137 78 165 92 -5 155 287 135 585 476 374 487 135 -2 -542 -546 -664 -705 -552 -151 -197 5 203 -77 227 384 149 107 247 209 11 -134 212 -303 47 -335 -253 -29 -146 -62 -285 -349 -257 -253 -249 16 -369 -262 -263 6 -127 -35 -101 189 240 322 168 430 297 277 182 -47 -315 -33 -668 -592 -336 -89 -90 -399 -407 -384 -353 -46 -97 -94 182 575 108 246 678 667 398 470 532 -166 267 131 63 -18 503 210 -40 206 145 -187 -410 -392 -66 -137 -342 -159 171 80 144 427 402 241 215 -73 -454 -245 -507 -492 900000 -747 -392 -346 -165 243 272 394 586 467 180 243 -28 -113 -384 -160 -210 -249 122 -85 -242 161 -70 236 476 301 184 127 -220 -127 -267 -565 -408 216 280 -4 143 81 170 94 -5 158 295 140 610 499 392 505 138 -2 -547 -538 -645 -683 -542 -151 -197 5 207 -79 231 392 153 109 252 211 11 -132 211 -299 46 -327 -248 -29 -146 -62 -282 -341 -248 -243 -239 15 -359 -256 -260 6 -124 -34 -99 186 237 321 170 435 300 277 178 -45 -304 -31 -632 -564 -327 -87 -90 -392 -398 -381 -348 -45 -96 -92 180 575 109 250 688 677 403 470 524 -163 258 127 61 -17 488 204 -39 199 143 -182 -395 -373 -63 -131 -333 -154 167 79 143 425 403 236 211 -73 -449 -237 -484 -478 900000 SQ 20220325T225145.4Z 8119.952609 223 1 50.28 2 64.03 107.40 65.70 199.05 0.00 1 0.00 1 0 15 3.331e-03 3.300e-03 1.405e-03 1.402e-03 1.854363e+03 8.629118e+01 1.206501e+02 -6.000000e+00 1.927914e+02 281.35 -2.00 20.00 -2.00 505.24 0.00e+00 6.745990e-04 3.903926e-05 3.874853e-05 -6.000000e+00 9.511904e-05 281.35 -2.00 20.00 -2.00 500.38 0.00e+00 1.172249e-01 2.850673e-02 1.764354e-02 -6.000000e+00 6.794156e-02 227.52 -2.00 3.40 -2.00 501.98 0.00e+00 2.270 0.000 489.00 513.00 1 7.4260e+00 2.1820e-03 3.6388e-03 -6.0000e+00 5.2159e-03 1.2192e-02 5.6481e-04 4.0723e-04 -6.0000e+00 1.3433e-03 8.3174e-04 -1.1152e-03 1.6008e-04 2.0052e-05 -6.0000e+00 3.9136e-04 1.7384e-02 5.6245e-05 10 0 0 10 0 0 99.87 19.28 0.73 0.01738 0.00965 16 3 1 4 0 3142.140 23.01 15.00 19.28 22.53 14.0 1011.22 -887 -433 -565 -35 251 289 497 480 619 343 -42 -198 -255 49 -115 -403 189 108 186 -26 91 338 0 -7 294 328 334 -111 -293 -516 -441 -66 -156 211 -234 98 147 -22 -243 193 156 491 258 166 394 372 465 37 -293 -168 -375 -519 -749 -526 -287 -23 -9 243 182 428 251 182 264 241 472 9 -253 -225 -290 162 -497 -435 -110 -229 -293 -259 -268 -146 -277 -258 -190 -525 -418 -91 -122 -303 -449 -22 27 61 427 384 266 484 259 -62 -360 -274 -564 -431 -453 10 -320 -251 -211 -530 63 -206 -14 -209 -120 242 427 383 465 554 409 354 521 555 168 133 511 443 262 219 474 118 152 91 -37 -292 -342 23 -461 -16 -361 -301 220 390 163 198 352 30 -86 -76 -549 -674 -436 900000 -873 -432 -579 -37 270 298 519 504 647 356 -43 -201 -254 52 -121 -401 190 111 194 -28 97 358 0 -8 314 349 352 -115 -298 -515 -435 -65 -158 219 -248 104 155 -23 -252 198 161 508 270 176 417 393 487 38 -298 -167 -364 -496 -715 -508 -283 -23 -9 250 187 440 259 188 273 249 480 9 -252 -221 -281 155 -478 -421 -108 -225 -288 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