File name: Pandora194s1_Tokyo-TMU_20220328_L2Fit_fout2c1d20211130p1-8.txt File generation date: 20251129T081958.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Shungo KATO Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 194 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora194_OF_v3d20210122.txt Instrument calibration file used: Pandora194s1_CF_v1d20211130.txt Level 1 file used: Pandora194s1_Tokyo-TMU_20220328_L1_smca1c1d20211130p1-8.txt Full location name: Tokyo Metropolitan University (TMU) Short location name: Tokyo-TMU Country of location: Japan Location latitude [deg]: 35.6200 Location longitude [deg]: 139.3834 Location altitude [m]: 135 Local noon date: 20220328 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 338 Nominal wavelengths inside fitting window [nm]: 305.1230 305.2641 305.4052 305.5463 305.6873 305.8284 305.9694 306.1104 306.2515 306.3925 306.5335 306.6745 306.8154 306.9564 307.0974 307.2383 307.3792 307.5202 307.6611 307.8020 307.9429 308.0838 308.2247 308.3655 308.5064 308.6472 308.7881 308.9289 309.0697 309.2105 309.3513 309.4921 309.6328 309.7736 309.9143 310.0551 310.1958 310.3365 310.4772 310.6179 310.7586 310.8993 311.0399 311.1806 311.3212 311.4619 311.6025 311.7431 311.8837 312.0243 312.1649 312.3054 312.4460 312.5865 312.7271 312.8676 313.0081 313.1486 313.2891 313.4296 313.5701 313.7105 313.8510 313.9914 314.1318 314.2722 314.4127 314.5530 314.6934 314.8338 314.9742 315.1145 315.2549 315.3952 315.5355 315.6758 315.8161 315.9564 316.0967 316.2370 316.3772 316.5175 316.6577 316.7979 316.9382 317.0784 317.2186 317.3587 317.4989 317.6391 317.7792 317.9194 318.0595 318.1996 318.3397 318.4798 318.6199 318.7600 318.9001 319.0401 319.1802 319.3202 319.4602 319.6002 319.7402 319.8802 320.0202 320.1602 320.3002 320.4401 320.5800 320.7200 320.8599 320.9998 321.1397 321.2796 321.4195 321.5593 321.6992 321.8390 321.9789 322.1187 322.2585 322.3983 322.5381 322.6779 322.8176 322.9574 323.0972 323.2369 323.3766 323.5163 323.6560 323.7957 323.9354 324.0751 324.2147 324.3544 324.4940 324.6337 324.7733 324.9129 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220327T213343.9Z 8121.898424 124 1 15.93 2 79.00 94.41 64.25 151.00 0.00 1 0.00 1 0 17 3.450e-01 1.020e-02 1.791e-01 5.502e-03 5.986011e-01 2.888763e-03 6.366381e-03 -6.000000e+00 1.989578e-01 227.67 -2.00 3.40 -2.00 321.01 0.00e+00 8.067128e-03 1.055616e-03 5.085403e-04 -6.000000e+00 8.029146e-03 281.53 -2.00 20.00 -2.00 320.67 0.00e+00 5.052 0.002 302.00 328.00 3 1.4488e+00 8.5285e-03 5.8200e-02 -6.0000e+00 4.9785e-01 1.2478e-01 1.1193e-02 3.0732e-02 -6.0000e+00 5.4270e-01 -1.7404e-01 1.2455e-02 1.6588e-02 -6.0000e+00 3.1898e-01 5.9785e-02 6.3341e-03 5.3778e-03 -6.0000e+00 1.3312e-01 4.6014e-04 -6.9224e-04 1.6372e-04 6.1328e-05 -6.0000e+00 9.6521e-03 2.5198e-02 -9.3935e-05 12 9 9 12 1 1 93.15 18.92 0.48 0.02520 0.02000 22 16 1 5 0 684.880 22.61 15.00 18.92 19.26 14.1 1001.82 -124854 -62944 -116510 -62149 -109231 -136657 -72835 -135753 -148287 -64766 -61754 -82612 -105684 -69114 -35963 -56576 -38117 6636 -5458 -30657 7971 -20729 -30892 -16940 -23311 -44513 -26530 -30426 -7856 -43932 -11223 -14797 -4091 -9257 -9528 -3897 -14991 -5621 -434 1845 -2651 2280 2624 957 5383 1049 4210 -3037 10223 5590 15655 6449 8646 5773 2690 2104 -2750 -588 2800 2403 3345 4167 7535 6058 3573 2870 2286 3797 3971 2776 2293 504 -121 -2174 -1346 -1460 -996 -1602 -1761 -2579 -1314 -2290 -381 -993 -752 116 -823 1140 104 -176 -344 -1189 -1160 -954 -1041 294 1407 -178 -324 -1074 -969 -1273 -460 -1049 -1693 -1271 -918 -343 540 292 911 492 48 -676 -447 126 445 803 922 667 781 1271 162 572 -316 -179 1082 -237 -442 -145 51 -313 -129 -264 -504 244 397 -54 -119 152 -182 -355 -1522 -460 -1477 -424 -1119 -1866 -568 -2185 -2893 -569 -572 -1168 -2474 -1449 -733 -1639 -1022 125 -123 -921 162 -567 -978 -491 -750 -1815 -897 -1061 -232 -2168 -482 -770 -211 -497 -496 -203 -1005 -413 -36 170 -277 241 289 110 609 128 513 -414 1289 807 2276 1128 1600 1164 579 466 -640 -131 596 529 795 1113 2195 1918 1148 902 731 1289 1538 1214 1064 238 -55 -932 -516 -515 -347 -613 -793 -1374 -790 -1533 -266 -677 -547 88 -657 898 81 -128 -257 -848 -834 -751 -859 277 1503 -212 -393 -1246 -1019 -1228 -436 -1068 -1846 -1454 -1117 -451 782 469 1412 770 73 -1066 -671 188 691 1319 1455 1059 1313 2052 256 865 -465 -254 1562 -386 -743 -267 100 -643 -281 -612 -1143 565 934 -129 -274 356 -406 -767 SS 20220327T213826.6Z 8121.901696 127 1 4.93 2 78.04 95.11 63.80 152.06 0.00 1 0.00 1 0 17 2.643e-01 1.224e-02 2.444e-01 8.202e-03 5.689462e-01 4.295977e-03 6.163546e-03 -6.000000e+00 1.525112e-01 227.67 -2.00 3.40 -2.00 320.52 0.00e+00 7.403942e-03 1.384993e-03 3.895644e-04 -6.000000e+00 6.427877e-03 281.53 -2.00 20.00 -2.00 320.20 0.00e+00 4.680 0.002 302.00 328.00 3 1.6833e+00 1.2275e-02 5.4190e-02 -6.0000e+00 3.8156e-01 1.0116e-01 1.5331e-02 2.8851e-02 -6.0000e+00 4.1593e-01 -1.0570e-01 1.6068e-02 1.5277e-02 -6.0000e+00 2.4450e-01 2.7783e-02 8.3808e-03 4.8393e-03 -6.0000e+00 1.0224e-01 5.2440e-04 -7.8220e-04 2.3844e-04 5.3117e-05 -6.0000e+00 7.4145e-03 2.2225e-02 -1.6970e-04 12 9 9 12 1 1 -97.89 18.93 0.30 0.02223 0.01635 5 13 1 5 0 791.100 22.61 15.00 18.93 19.52 14.0 1002.52 -112194 3631 -19898 -90778 25398 -82642 -59843 -106785 -99593 -71232 900000 -62560 -105366 78275 -64513 32980 -25809 -3434 -20046 -26959 -3947 -5469 21544 -19613 -9066 -44169 -778 -21927 -9161 27159 -28888 8435 -12930 913 4041 4635 9472 -18305 1508 -9080 -459 -8648 -1833 2809 30 10562 -278 5675 -5698 10496 1439 6278 5023 2148 8762 -1573 4100 -5440 2881 -464 7740 8504 1784 7266 362 3375 1069 1689 64 3019 2108 -26 2851 -2386 137 -2056 -1955 -1787 172 837 -1048 -1956 -2394 -1549 -1737 -146 1347 1194 1949 -243 -240 -3425 112 -900 -855 596 41 -288 -429 -588 -824 -1968 -1766 -1608 -627 -1165 -814 -736 802 621 759 102 67 -518 -363 1746 331 2162 93 603 1242 1361 1004 -450 -129 -379 -9 -152 312 -293 -936 235 -468 -190 -55 66 102 -386 94 -295 193 -55 -1631 29 -159 -1122 203 -901 -622 -1964 -1832 -1025 900000 -1101 -3707 626 -2373 527 -825 -96 -705 -1056 -123 -175 551 -800 -348 -2472 -28 -964 -374 890 -1987 465 -972 59 246 297 666 -2049 165 -1256 -63 -1369 -283 424 5 1562 -47 939 -1112 1897 316 1441 1261 587 2319 -473 1167 -1670 804 -138 2302 2836 650 2673 141 1355 402 678 30 1521 1132 -14 1459 -1190 60 -930 -871 -784 86 488 -711 -1473 -1925 -1315 -1449 -127 1195 1068 1683 -201 -201 -2796 89 -782 -781 619 48 -349 -528 -745 -951 -2101 -1865 -1809 -743 -1462 -1001 -980 1163 993 1190 161 109 -805 -536 2516 505 3433 147 956 2047 2164 1549 -676 -186 -529 -12 -240 510 -526 -1797 465 -921 -398 -122 150 235 -898 210 -629 389 -108 SS 20220327T214320.0Z 8121.905092 130 1 49.35 2 77.05 95.84 63.34 153.18 0.00 1 0.00 1 0 17 2.425e-01 8.096e-03 5.062e-02 1.938e-03 5.287898e-01 1.024863e-03 5.734644e-03 -6.000000e+00 1.399415e-01 227.67 -2.00 3.40 -2.00 320.68 0.00e+00 6.836087e-03 3.433335e-04 3.927730e-04 -6.000000e+00 5.645275e-03 281.53 -2.00 20.00 -2.00 320.33 0.00e+00 4.347 0.001 302.00 328.00 3 1.0096e+00 2.9740e-03 5.0443e-02 -6.0000e+00 3.5018e-01 5.8778e-02 3.7132e-03 2.7018e-02 -6.0000e+00 3.8168e-01 -6.9156e-02 3.8737e-03 1.4372e-02 -6.0000e+00 2.2434e-01 1.3322e-02 2.0051e-03 4.5808e-03 -6.0000e+00 9.3650e-02 1.4916e-03 -1.5630e-04 5.9288e-05 5.2940e-05 -6.0000e+00 6.7864e-03 2.4010e-02 -4.7348e-05 11 8 0 10 0 0 99.56 18.94 0.35 0.02401 0.02284 162 35 1 5 0 304.570 22.61 15.00 18.94 19.77 14.0 1002.81 -74929 -79305 -63296 -90805 -73703 -100088 -62960 -75894 -63305 -83916 -80735 -67213 -39978 -30823 -23441 -23465 -19968 -23037 -10045 -12471 -14383 -9422 -16932 -14877 -12256 -20883 -21906 -17332 -23205 -2661 3933 -3036 -118 -5807 -4366 -6015 -2617 -2754 -487 -4392 -244 -1259 -1414 861 1617 3109 2765 3061 4859 4153 4120 4876 5165 2676 2232 933 -234 -678 -748 987 2237 4734 5013 3792 1611 1228 1028 2057 2121 1523 1441 236 -229 -761 -1726 -3058 -2744 -1870 -481 -704 -720 -1885 -1949 -1096 -611 -250 503 530 1084 501 -375 -1519 -1394 -970 -861 307 1082 377 -210 -884 -1407 -1175 -176 -1434 -1438 -1068 -581 28 710 728 518 373 197 -45 -43 502 616 1028 528 562 1003 1032 154 24 -766 -655 453 -81 -71 -281 -505 -420 -121 -252 -536 14 284 -24 97 51 -35 182 -811 -995 -685 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