File name: Pandora194s1_Tokyo-TMU_20240401_L2Fit_fout2c10d20220901p1-8.txt File generation date: 20240401T145141.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Shungo KATO Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 194 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora194_OF_v3d20210122.txt Instrument calibration file used: Pandora194s1_CF_v10d20220901.txt Level 1 file used: Pandora194s1_Tokyo-TMU_20240401_L1_smca1c10d20220901p1-8.txt Full location name: Tokyo Metropolitan University (TMU) Short location name: Tokyo-TMU Country of location: Japan Location latitude [deg]: 35.6200 Location longitude [deg]: 139.3834 Location altitude [m]: 135 Local noon date: 20240401 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: cso0 "Modification of session 8 for new VP" First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0446 305.1858 305.3270 305.4682 305.6094 305.7505 305.8917 306.0328 306.1740 306.3151 306.4562 306.5973 306.7384 306.8795 307.0205 307.1616 307.3026 307.4437 307.5847 307.7257 307.8667 308.0077 308.1487 308.2896 308.4306 308.5715 308.7125 308.8534 308.9943 309.1352 309.2761 309.4170 309.5578 309.6987 309.8395 309.9804 310.1212 310.2620 310.4028 310.5436 310.6844 310.8251 310.9659 311.1066 311.2474 311.3881 311.5288 311.6695 311.8102 311.9509 312.0915 312.2322 312.3728 312.5135 312.6541 312.7947 312.9353 313.0759 313.2165 313.3570 313.4976 313.6381 313.7787 313.9192 314.0597 314.2002 314.3407 314.4812 314.6216 314.7621 314.9025 315.0430 315.1834 315.3238 315.4642 315.6046 315.7449 315.8853 316.0257 316.1660 316.3063 316.4467 316.5870 316.7273 316.8676 317.0078 317.1481 317.2884 317.4286 317.5688 317.7090 317.8493 317.9895 318.1296 318.2698 318.4100 318.5501 318.6903 318.8304 318.9705 319.1106 319.2507 319.3908 319.5309 319.6709 319.8110 319.9510 320.0911 320.2311 320.3711 320.5111 320.6511 320.7910 320.9310 321.0710 321.2109 321.3508 321.4907 321.6306 321.7705 321.9104 322.0503 322.1901 322.3300 322.4698 322.6097 322.7495 322.8893 323.0291 323.1688 323.3086 323.4484 323.5881 323.7278 323.8676 324.0073 324.1470 324.2867 324.4263 324.5660 324.7057 324.8453 324.9849 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240401T001736.2Z 8857.012225 335 1 34.87 2 46.15 123.35 90.23 233.45 0.00 1 0.00 1 0 17 1.777e-02 8.165e-03 5.642e-03 1.498e-03 2.390461e-01 7.464180e-04 2.669296e-03 -6.000000e+00 1.006820e-02 228.07 -2.00 3.40 -2.00 317.83 0.00e+00 1.578300e-03 1.107018e-04 5.913558e-05 -6.000000e+00 4.063644e-04 281.99 -2.00 20.00 -2.00 317.46 0.00e+00 1.441 0.000 302.00 328.00 3 3.7109e+00 1.9868e-03 1.8476e-02 -6.0000e+00 2.5218e-02 -5.4926e-02 2.2344e-03 1.1581e-02 -6.0000e+00 2.7545e-02 3.0837e-02 1.4029e-03 5.7564e-03 -6.0000e+00 1.6194e-02 -2.2198e-02 7.0275e-04 1.6540e-03 -6.0000e+00 6.6763e-03 2.3637e-03 4.9591e-04 4.3936e-05 1.6353e-05 -6.0000e+00 4.7614e-04 6.4194e-03 3.3189e-05 12 9 1 12 1 1 100.00 19.31 0.39 0.00642 0.01015 251 77 1 5 0 138.320 23.01 15.00 19.31 22.04 9.8 993.83 -3945 -4097 -4689 -3411 -7919 -4982 -5822 -2160 -2679 -4628 -5147 -5820 -2616 -3178 -282 -2227 -59 1614 1539 866 -507 1403 260 -69 -1045 -883 -1249 -1197 -714 -318 1732 1059 1761 -1231 -2292 -2340 -2015 -333 -166 -458 -1313 -725 -672 -92 613 489 372 -1 -188 238 1235 1249 1545 1631 984 1159 -68 99 122 843 1411 2144 2997 2110 842 -293 -738 -768 846 1111 824 630 205 468 -286 -863 -1990 -1585 -961 -1320 -1157 -1667 -2316 -1958 -850 -53 155 574 667 458 173 -583 -1035 -882 -498 -228 307 626 104 -682 -1057 -1680 -1390 -484 -1143 -1000 -951 -621 16 705 1059 975 1101 342 -46 -132 139 577 879 876 902 1154 772 454 206 -315 -132 237 201 -110 -253 -657 -587 -509 -85 -194 195 356 71 44 -249 -424 -488 -330 -378 -448 -333 -720 -416 -515 -206 -285 -527 -582 -677 -331 -468 -46 -411 -11 311 309 182 -110 296 56 -16 -253 -221 -313 -283 -157 -69 389 260 464 -343 -603 -602 -564 -107 -64 -206 -648 -372 -355 -49 323 259 193 -1 -94 119 644 697 908 1006 627 751 -45 66 79 542 937 1525 2298 1729 689 -222 -521 -531 618 919 743 592 192 420 -240 -652 -1377 -1046 -668 -1040 -1021 -1624 -2408 -2127 -891 -59 182 690 798 525 202 -621 -1014 -846 -509 -258 383 781 136 -875 -1268 -2051 -1626 -591 -1388 -1276 -1269 -863 23 1085 1698 1563 1677 485 -60 -180 191 833 1241 1311 1369 1719 1121 631 300 -438 -175 321 293 -171 -375 -997 -908 -825 -145 -347 357 665 133 81 -438 -722 -825 SS 20240401T011410.8Z 8857.051514 369 1 49.88 2 37.53 140.19 99.52 240.96 0.00 1 0.00 1 0 17 8.396e-02 2.190e-02 5.920e-02 1.642e-02 2.266973e-01 8.165277e-03 2.470979e-03 -6.000000e+00 4.758994e-02 228.07 -2.00 3.40 -2.00 317.81 0.00e+00 2.775285e-03 1.169859e-03 5.510766e-05 -6.000000e+00 1.919927e-03 282.00 -2.00 20.00 -2.00 317.41 0.00e+00 1.260 0.000 302.00 328.00 3 7.6170e+00 2.1705e-02 1.6647e-02 -6.0000e+00 1.1920e-01 2.0402e-02 2.4417e-02 1.0820e-02 -6.0000e+00 1.3018e-01 -2.0997e-04 1.5077e-02 5.3566e-03 -6.0000e+00 7.6539e-02 -9.4139e-03 7.4520e-03 1.5278e-03 -6.0000e+00 3.1567e-02 5.5989e-05 -1.0934e-05 4.9192e-04 1.5446e-05 -6.0000e+00 2.2492e-03 4.8278e-03 8.3082e-05 12 8 8 10 0 0 99.96 19.51 -0.63 0.00483 0.00475 14 3 1 5 0 3562.380 23.22 15.00 19.51 22.84 9.9 992.84 58670 -6406 864 -9485 -21848 -20695 -19983 11745 11786 -11460 -8278 29315 -28834 -7289 -12142 12157 -10707 13678 17465 6381 3832 -2412 -5905 12119 -1658 -4061 8085 -5960 2942 -1912 9611 -9215 -2563 19968 1720 13476 -417 3986 -3781 -1301 -4906 -1282 -2911 912 3389 2151 1844 -164 -3074 448 1799 2660 1406 1337 4821 -515 2016 -1646 -499 2989 1480 1771 3457 2385 -1001 -1816 3003 692 1579 1703 506 -470 -1173 647 -2678 1340 -1964 -1290 -1296 -3485 -4193 -1893 578 -2822 1557 1312 1230 681 2523 -1342 -578 -1961 -357 1079 -2827 -1955 64 726 -363 -4490 -299 -2388 529 -1609 -2030 -3449 -1934 -3016 1802 1767 3372 2391 197 1565 -1695 -386 -1960 -956 2195 3406 2758 1460 898 1032 1235 260 -784 2280 -589 -1662 -2688 -2882 -536 -503 718 505 1490 799 1006 -256 -67 -460 -2600 3367 -778 100 -1152 -2653 -2320 -2293 1082 1195 -1529 -1050 2582 -5079 -1196 -2398 2077 -2401 2483 3170 1337 839 -554 -1539 2735 -447 -1153 2025 -1623 685 -459 2169 -2710 -761 4855 468 3159 -121 1288 -1574 -612 -2600 -683 -1623 495 1796 1156 974 -86 -1616 227 943 1475 831 827 2948 -337 1300 -1092 -321 1854 965 1240 2582 1906 -818 -1369 1985 454 1097 1337 438 -427 -1066 555 -2203 948 -1295 -804 -849 -2628 -3565 -1725 544 -2875 1627 1473 1456 834 3027 -1602 -630 -1964 -321 930 -2692 -2038 73 901 -478 -5995 -357 -2670 550 -1792 -2465 -4469 -2580 -4241 2536 2642 5184 3707 298 2147 -2196 -514 -2667 -1355 3247 5290 4386 2315 1391 1522 1724 348 -1010 2903 -826 -2510 -4279 -4680 -865 -847 1270 935 2799 1543 1938 -484 -122 -813 -4643 SS 20240401T013036.1Z 8857.062917 379 1 16.91 2 35.53 146.19 102.35 242.99 0.00 1 0.00 1 0 17 1.359e-02 8.753e-03 3.936e-03 1.781e-03 2.045918e-01 8.859844e-04 2.321088e-03 -6.000000e+00 7.701257e-03 228.07 -2.00 3.40 -2.00 316.54 0.00e+00 9.226492e-04 9.728124e-05 3.404406e-05 -6.000000e+00 3.107339e-04 282.00 -2.00 20.00 -2.00 316.20 0.00e+00 1.228 0.000 302.00 328.00 3 4.3735e+00 2.3134e-03 1.5775e-02 -6.0000e+00 1.9290e-02 -4.5862e-02 2.5903e-03 9.9243e-03 -6.0000e+00 2.1068e-02 2.3952e-02 1.5125e-03 4.9096e-03 -6.0000e+00 1.2386e-02 -1.6723e-02 7.0472e-04 1.3884e-03 -6.0000e+00 5.1078e-03 1.5919e-03 5.1170e-04 5.0718e-05 1.5375e-05 -6.0000e+00 3.6408e-04 5.0321e-03 5.0919e-05 12 9 1 12 1 1 99.96 19.55 0.26 0.00503 0.00888 19 13 1 5 0 845.060 23.22 15.00 19.55 23.89 10.1 996.14 -3311 -1938 -2721 -3543 -4614 -3551 -4106 -332 -1622 -3004 -4036 -1613 -588 -592 649 -821 -433 120 1416 1469 1323 1425 1732 892 90 -246 -684 -1297 -642 406 1958 2146 2338 -1680 -3010 -2082 -1375 81 297 -318 -860 -424 -826 -300 293 480 74 311 -303 339 1007 934 1576 1283 859 1226 745 623 56 370 1491 2166 2447 2047 481 -352 -946 -638 277 593 484 587 205 362 -222 -934 -2128 -1945 -1321 -1280 -1389 -1885 -2147 -1820 -939 -654 -71 477 1069 551 215 -831 -1098 -703 -946 -24 482 728 138 -545 -1139 -1270 -1482 -756 -843 -607 -931 -421 136 707 936 1057 1269 652 -19 -58 264 488 839 1132 1137 1214 870 334 369 -492 140 253 284 130 -70 -549 -869 -434 -373 -230 157 305 74 38 -234 -621 -659 -589 -372 -537 -661 -769 -552 -671 -58 -321 -632 -842 -331 -132 -151 186 -260 -142 37 441 473 435 462 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