File name: Pandora194s1_Tokyo-TMU_20240416_L2Fit_fout2c10d20220901p1-8.txt File generation date: 20240416T145318.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Shungo KATO Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 194 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora194_OF_v3d20210122.txt Instrument calibration file used: Pandora194s1_CF_v10d20220901.txt Level 1 file used: Pandora194s1_Tokyo-TMU_20240416_L1_smca1c10d20220901p1-8.txt Full location name: Tokyo Metropolitan University (TMU) Short location name: Tokyo-TMU Country of location: Japan Location latitude [deg]: 35.6200 Location longitude [deg]: 139.3834 Location altitude [m]: 135 Local noon date: 20240416 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: cso0 "Modification of session 8 for new VP" First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0446 305.1858 305.3270 305.4682 305.6094 305.7505 305.8917 306.0328 306.1740 306.3151 306.4562 306.5973 306.7384 306.8795 307.0205 307.1616 307.3026 307.4437 307.5847 307.7257 307.8667 308.0077 308.1487 308.2896 308.4306 308.5715 308.7125 308.8534 308.9943 309.1352 309.2761 309.4170 309.5578 309.6987 309.8395 309.9804 310.1212 310.2620 310.4028 310.5436 310.6844 310.8251 310.9659 311.1066 311.2474 311.3881 311.5288 311.6695 311.8102 311.9509 312.0915 312.2322 312.3728 312.5135 312.6541 312.7947 312.9353 313.0759 313.2165 313.3570 313.4976 313.6381 313.7787 313.9192 314.0597 314.2002 314.3407 314.4812 314.6216 314.7621 314.9025 315.0430 315.1834 315.3238 315.4642 315.6046 315.7449 315.8853 316.0257 316.1660 316.3063 316.4467 316.5870 316.7273 316.8676 317.0078 317.1481 317.2884 317.4286 317.5688 317.7090 317.8493 317.9895 318.1296 318.2698 318.4100 318.5501 318.6903 318.8304 318.9705 319.1106 319.2507 319.3908 319.5309 319.6709 319.8110 319.9510 320.0911 320.2311 320.3711 320.5111 320.6511 320.7910 320.9310 321.0710 321.2109 321.3508 321.4907 321.6306 321.7705 321.9104 322.0503 322.1901 322.3300 322.4698 322.6097 322.7495 322.8893 323.0291 323.1688 323.3086 323.4484 323.5881 323.7278 323.8676 324.0073 324.1470 324.2867 324.4263 324.5660 324.7057 324.8453 324.9849 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240415T232205.1Z 8871.973670 204 1 48.95 2 51.91 106.53 112.31 31.68 0.00 1 0.00 1 0 17 2.389e-02 8.370e-03 8.418e-03 1.868e-03 2.717026e-01 9.230480e-04 3.047483e-03 -6.000000e+00 1.358624e-02 229.23 -2.00 3.40 -2.00 318.15 0.00e+00 1.597176e-03 1.496717e-04 7.332006e-05 -6.000000e+00 5.463748e-04 283.36 -2.00 20.00 -2.00 317.79 0.00e+00 1.617 0.000 302.00 328.00 3 4.5875e+00 2.4687e-03 2.0979e-02 -6.0000e+00 3.4121e-02 -5.5342e-02 2.7784e-03 1.3340e-02 -6.0000e+00 3.7246e-02 2.7864e-02 1.8128e-03 6.6155e-03 -6.0000e+00 2.1878e-02 -2.2447e-02 9.3279e-04 1.8848e-03 -6.0000e+00 8.9917e-03 7.8571e-04 2.1159e-04 5.4452e-05 1.8771e-05 -6.0000e+00 6.4043e-04 9.6646e-03 -2.9305e-05 11 8 0 10 0 0 99.49 19.89 0.44 0.00966 0.01125 33 7 1 5 0 1483.120 23.64 15.00 19.89 25.07 10.4 1006.73 -8439 -1052 -4849 -3407 -11372 -4784 -7166 -7314 -6328 -6798 -3341 -9495 -3377 -3449 383 -1466 -2772 2192 677 2610 -729 368 135 1996 -38 -2726 -1201 -4304 -848 -986 1332 11 906 -694 -5104 -1918 -3089 1182 -1016 -612 -1035 -1237 80 -214 783 751 681 795 -47 1076 1399 1712 1167 1656 918 1635 152 2 650 0 2107 1488 3360 2558 801 -253 -837 -664 717 916 519 1165 270 411 -509 -1450 -1550 -2283 -896 -1367 -1153 -1413 -2145 -1529 -979 -78 -147 848 652 682 -19 -589 -727 -1423 -645 -312 742 515 36 -832 -1249 -1571 -1481 -729 -1191 -730 -744 -770 137 573 1236 1013 908 316 91 -242 244 582 660 1185 1071 1099 547 359 62 -449 255 -67 271 14 -189 -755 -717 -270 -237 -57 19 411 -92 29 -266 -302 -373 -621 -80 -394 -258 -831 -312 -505 -579 -553 -628 -296 -923 -351 -419 52 -224 -452 355 117 459 -135 67 25 385 -8 -603 -261 -912 -163 -189 268 3 218 -174 -1253 -448 -801 345 -365 -254 -471 -591 39 -106 384 369 330 377 -22 506 697 914 664 987 567 1024 98 1 407 0 1352 1040 2285 1864 587 -172 -588 -459 529 696 431 997 231 337 -389 -1104 -1072 -1535 -635 -1104 -950 -1286 -2087 -1552 -1062 -90 -178 1046 803 802 -21 -588 -669 -1303 -629 -337 885 681 50 -1134 -1589 -1840 -1665 -856 -1526 -979 -1046 -1133 193 863 1939 1593 1365 482 129 -325 331 829 1012 1750 1602 1759 854 537 88 -612 331 -90 391 22 -306 -1155 -1121 -442 -413 -104 35 777 -174 54 -471 -515 -632 SS 20240415T234835.2Z 8871.992075 217 1 27.28 2 46.82 111.90 109.44 37.00 0.00 1 0.00 1 0 17 1.934e-02 8.551e-03 9.876e-03 2.775e-03 2.507695e-01 1.382601e-03 2.822526e-03 -6.000000e+00 1.100252e-02 229.23 -2.00 3.40 -2.00 317.72 0.00e+00 1.530632e-03 1.993716e-04 5.802038e-05 -6.000000e+00 4.422582e-04 283.36 -2.00 20.00 -2.00 317.37 0.00e+00 1.459 0.000 302.00 328.00 3 5.0432e+00 3.6735e-03 1.9105e-02 -6.0000e+00 2.7633e-02 -3.8160e-02 4.1250e-03 1.2270e-02 -6.0000e+00 3.0158e-02 2.6603e-02 2.5542e-03 6.0661e-03 -6.0000e+00 1.7715e-02 -2.2052e-02 1.2710e-03 1.7201e-03 -6.0000e+00 7.2842e-03 5.9499e-04 5.5085e-04 8.0271e-05 1.7595e-05 -6.0000e+00 5.1833e-04 8.0514e-03 5.0034e-05 12 9 1 12 1 1 99.99 20.02 0.46 0.00805 0.01219 15 6 1 5 0 1704.340 23.72 15.00 20.02 27.22 10.3 1007.58 -2044 -4910 -4557 -9218 -544 -6708 -2953 -5529 -4155 -4001 -8319 -617 -5038 -470 -2616 -19 1585 -378 1320 701 3341 -1769 1838 -405 374 754 -395 -552 -1963 -869 -252 1750 2066 -1913 -1473 -3766 -118 -610 1413 -972 -1003 -224 -730 350 -943 221 367 -910 497 498 1494 1432 2092 859 1089 431 988 -581 352 203 1200 2653 1862 3206 529 560 -1561 -717 636 662 1510 189 669 28 -547 -1184 -539 -2225 -1283 -1338 -1304 -1591 -2232 -1520 -802 -305 384 389 998 553 744 -1186 -952 -911 -936 55 556 624 -23 -465 -1195 -1582 -940 -1027 -928 -1001 -671 -701 459 449 1417 1090 521 191 -244 93 -535 1013 988 809 1039 649 904 250 288 -179 -271 91 -235 136 -517 -85 -762 -178 -464 74 299 218 147 -146 -50 -195 -634 -190 -520 -494 -988 -48 -592 -264 -567 -468 -472 -1013 -71 -686 -71 -463 -4 311 -79 282 156 741 -409 417 -99 95 198 -105 -138 -467 -202 -62 458 585 -578 -414 -1061 -35 -213 581 -475 -486 -113 -380 182 -497 115 188 -506 267 270 847 792 1214 531 689 280 648 -385 226 131 793 1867 1436 2587 433 420 -1108 -495 467 552 1357 179 624 25 -460 -896 -404 -1627 -988 -1060 -1158 -1557 -2332 -1653 -930 -345 455 473 1203 640 863 -1273 -935 -879 -968 63 698 793 -31 -606 -1459 -1944 -1104 -1271 -1142 -1296 -906 -989 676 705 2305 1776 814 276 -325 117 -687 1351 1421 1235 1602 988 1333 353 387 -250 -363 125 -318 196 -785 -130 -1207 -294 -818 125 516 384 259 -250 -89 -337 -1092 SS 20240415T235659.2Z 8871.997908 223 1 23.84 2 45.24 113.76 108.45 38.62 0.00 1 0.00 1 0 25 1.867e-02 9.158e-03 9.508e-03 2.914e-03 2.456224e-01 1.450666e-03 2.758644e-03 -6.000000e+00 1.062134e-02 229.23 -2.00 3.40 -2.00 317.53 0.00e+00 1.076067e-03 1.999565e-04 5.502414e-05 -6.000000e+00 4.269824e-04 283.36 -2.00 20.00 -2.00 317.18 0.00e+00 1.418 0.000 302.00 328.00 3 5.1131e+00 3.8391e-03 1.8620e-02 -6.0000e+00 2.6676e-02 -3.5176e-02 4.3039e-03 1.2002e-02 -6.0000e+00 2.9114e-02 2.2936e-02 2.6366e-03 5.9206e-03 -6.0000e+00 1.7102e-02 -1.8898e-02 1.3047e-03 1.6705e-03 -6.0000e+00 7.0316e-03 5.8264e-04 4.3583e-04 8.4334e-05 1.7399e-05 -6.0000e+00 5.0042e-04 7.7546e-03 1.5423e-05 12 9 1 12 1 1 99.94 20.07 0.43 0.00775 0.01103 11 5 1 5 0 1986.210 23.83 15.00 20.07 27.78 10.4 1007.31 -4045 -6347 -4436 -2904 -5592 -7661 -5113 -2578 -4145 -2179 -6473 -2989 -4535 -1094 944 -1074 267 1374 2195 1912 2112 -1025 -1390 -220 -962 66 -1447 -783 -1742 932 1226 2354 3213 -976 -2705 -2915 -1770 1626 -159 342 -1008 -1283 -864 -581 893 1162 201 -359 -922 226 956 1160 2108 705 815 1787 349 278 557 879 1530 1848 2856 2503 201 -238 -1280 -967 829 931 444 1095 151 393 -762 -813 -1993 -2400 -948 -1045 -1598 -1548 -2280 -1849 -896 -605 89 345 1288 666 48 -393 -945 -939 -617 -426 762 1081 43 -833 -862 -1816 -1068 -775 -791 -880 -1318 -976 469 1046 956 1154 1076 332 -337 -482 -48 368 1139 1189 1214 1181 1053 -8 373 -130 -603 -115 -436 -397 59 -321 -594 -148 -17 -606 109 243 228 -19 -20 -375 -639 -426 -754 -531 -322 -566 -751 -514 -283 -516 -279 -855 -390 -674 -181 176 -224 57 304 501 454 511 -253 -351 -58 -268 19 -418 -212 -444 228 317 652 956 -310 -816 -863 -566 589 -71 159 -518 -690 -477 -323 488 634 109 -190 -480 117 519 673 1280 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