File name: Pandora194s1_Tokyo-TMU_20240522_L2Fit_fout2c10d20220901p1-8.txt File generation date: 20240522T144831.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Shungo KATO Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 194 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora194_OF_v3d20210122.txt Instrument calibration file used: Pandora194s1_CF_v10d20220901.txt Level 1 file used: Pandora194s1_Tokyo-TMU_20240522_L1_smca1c10d20220901p1-8.txt Full location name: Tokyo Metropolitan University (TMU) Short location name: Tokyo-TMU Country of location: Japan Location latitude [deg]: 35.6200 Location longitude [deg]: 139.3834 Location altitude [m]: 135 Local noon date: 20240522 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: cso0 "Modification of session 8 for new VP" First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0446 305.1858 305.3270 305.4682 305.6094 305.7505 305.8917 306.0328 306.1740 306.3151 306.4562 306.5973 306.7384 306.8795 307.0205 307.1616 307.3026 307.4437 307.5847 307.7257 307.8667 308.0077 308.1487 308.2896 308.4306 308.5715 308.7125 308.8534 308.9943 309.1352 309.2761 309.4170 309.5578 309.6987 309.8395 309.9804 310.1212 310.2620 310.4028 310.5436 310.6844 310.8251 310.9659 311.1066 311.2474 311.3881 311.5288 311.6695 311.8102 311.9509 312.0915 312.2322 312.3728 312.5135 312.6541 312.7947 312.9353 313.0759 313.2165 313.3570 313.4976 313.6381 313.7787 313.9192 314.0597 314.2002 314.3407 314.4812 314.6216 314.7621 314.9025 315.0430 315.1834 315.3238 315.4642 315.6046 315.7449 315.8853 316.0257 316.1660 316.3063 316.4467 316.5870 316.7273 316.8676 317.0078 317.1481 317.2884 317.4286 317.5688 317.7090 317.8493 317.9895 318.1296 318.2698 318.4100 318.5501 318.6903 318.8304 318.9705 319.1106 319.2507 319.3908 319.5309 319.6709 319.8110 319.9510 320.0911 320.2311 320.3711 320.5111 320.6511 320.7910 320.9310 321.0710 321.2109 321.3508 321.4907 321.6306 321.7705 321.9104 322.0503 322.1901 322.3300 322.4698 322.6097 322.7495 322.8893 323.0291 323.1688 323.3086 323.4484 323.5881 323.7278 323.8676 324.0073 324.1470 324.2867 324.4263 324.5660 324.7057 324.8453 324.9849 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240521T215042.3Z 8907.910211 230 1 9.73 2 64.08 82.59 131.78 277.51 0.00 1 0.00 1 0 17 3.593e-02 8.536e-03 1.325e-02 2.074e-03 3.407548e-01 1.061690e-03 3.867825e-03 -6.000000e+00 2.097162e-02 231.60 -2.00 3.40 -2.00 318.44 0.00e+00 1.922666e-03 1.866211e-04 1.059571e-04 -6.000000e+00 8.263631e-04 286.83 -2.00 20.00 -2.00 318.13 0.00e+00 2.274 0.000 302.00 328.00 3 2.9438e+00 2.8593e-03 2.8447e-02 -6.0000e+00 5.3011e-02 -8.3259e-02 3.2012e-03 1.7183e-02 -6.0000e+00 5.7425e-02 2.7545e-02 2.2438e-03 8.5308e-03 -6.0000e+00 3.3639e-02 -1.9657e-02 1.1965e-03 2.4617e-03 -6.0000e+00 1.4147e-02 1.9735e-03 -5.3111e-05 5.9525e-05 2.5104e-05 -6.0000e+00 9.6613e-04 1.4097e-02 -8.9663e-05 12 9 1 12 1 1 90.95 20.21 0.34 0.01410 0.01370 22 25 1 5 0 422.540 23.93 15.00 20.21 26.09 11.8 1007.94 -6783 -11207 -11563 -12831 -13926 -8501 -11706 -12099 -11064 -10396 -12094 -6996 -5452 -7073 -240 519 -2401 -2540 1092 1533 -1022 630 394 -749 -1569 -3463 -3262 -3436 -2784 428 1677 914 1007 -1556 -4380 -3198 -2127 -874 -1014 -175 -482 -978 -1241 228 650 446 1048 703 55 2139 2041 1782 2069 1424 1414 470 683 362 -89 317 1446 2148 3148 2910 1129 -175 -705 -644 812 1078 694 844 312 184 -669 -1500 -2347 -2113 -1658 -1566 -1185 -1545 -2290 -1294 -523 -400 182 753 1111 413 685 -487 -883 -795 -631 -238 443 633 254 -734 -1470 -1750 -1277 -908 -1282 -846 -849 -560 226 763 1263 928 922 391 12 164 402 661 834 782 882 899 502 320 296 -407 -114 136 93 -123 -271 -597 -783 -131 -284 -333 172 242 -7 -31 -186 -313 900000 -299 -580 -627 -669 -662 -370 -561 -658 -667 -658 -783 -456 -408 -642 -24 58 -296 -332 146 213 -149 90 58 -119 -268 -627 -591 -593 -456 69 293 180 218 -357 -975 -698 -508 -222 -312 -62 -189 -406 -536 98 282 196 453 302 24 930 956 908 1028 755 777 268 396 209 -51 180 847 1361 2174 2161 850 -124 -475 -433 589 820 577 726 268 151 -510 -1120 -1621 -1426 -1210 -1209 -1032 -1494 -2209 -1302 -562 -460 218 863 1261 483 737 -486 -886 -799 -640 -269 523 829 350 -994 -1862 -2178 -1518 -1133 -1624 -1122 -1184 -768 328 1189 1948 1446 1465 581 16 231 575 932 1263 1245 1411 1406 765 467 440 -581 -156 193 136 -194 -451 -962 -1304 -229 -499 -612 321 462 -14 -57 -328 -564 900000 SS 20240521T215612.7Z 8907.914036 233 1 17.81 2 62.97 83.32 132.85 278.40 0.00 1 0.00 1 0 17 4.511e-02 9.729e-03 3.393e-02 4.482e-03 3.301487e-01 2.230395e-03 3.613159e-03 -6.000000e+00 2.586793e-02 231.60 -2.00 3.40 -2.00 318.82 0.00e+00 1.584031e-03 4.371357e-04 1.127116e-04 -6.000000e+00 1.031544e-03 286.83 -2.00 20.00 -2.00 318.46 0.00e+00 2.188 0.000 302.00 328.00 3 4.7601e+00 6.0632e-03 2.7269e-02 -6.0000e+00 6.5337e-02 -6.9554e-02 6.8649e-03 1.6351e-02 -6.0000e+00 7.1200e-02 3.5461e-02 4.9232e-03 8.0973e-03 -6.0000e+00 4.1745e-02 -2.4501e-02 2.6114e-03 2.3134e-03 -6.0000e+00 1.7064e-02 3.5370e-04 3.2593e-04 1.3037e-04 2.2058e-05 -6.0000e+00 1.2102e-03 1.2710e-02 -2.9715e-05 12 9 9 12 1 1 99.26 20.22 0.51 0.01271 0.01516 6 4 1 5 0 2542.800 23.93 15.00 20.22 26.28 11.8 1008.28 -5839 213 10836 -19030 11007 -11649 -3994 -4958 9390 -23155 -17908 7761 -7831 8153 -20909 -5439 -6221 -4730 3406 908 2976 221 1785 -2954 -277 -409 -4965 1072 -1554 24 -3573 4278 -3334 -3565 -3988 1468 4079 -25 1972 -1508 -1406 -1890 -1914 1082 157 158 838 2094 -436 1517 634 1203 1642 1338 2349 -485 547 -1599 -625 350 16 1827 2873 3846 1565 -270 -1097 508 1012 2521 1501 771 1231 848 -1232 -1587 -152 -1393 -1692 -1125 -2399 -412 -2744 -1086 -1833 195 647 501 867 314 143 -985 -941 -946 -564 -21 93 1364 -989 -507 -1741 -1406 -1339 -805 -1285 -276 -856 -951 996 594 1503 911 695 658 -593 31 51 113 702 845 1425 1016 1049 -64 293 -694 -474 -272 227 -81 -170 -820 -649 -589 -95 52 459 270 545 -55 222 -198 -993 -230 9 422 -948 366 -468 -159 -225 415 -1498 -1104 390 -534 563 -2267 -568 -699 -554 389 111 366 28 228 -421 -41 -63 -801 155 -219 3 -569 699 -649 -717 -758 262 783 -6 553 -512 -523 -743 -710 435 64 65 339 827 -176 615 278 518 750 650 1168 -255 290 -861 -327 181 9 1058 1808 2567 1063 -173 -669 304 659 1840 1205 647 1017 672 -920 -1066 -92 -835 -1102 -834 -2036 -379 -2525 -1035 -1892 211 734 584 1002 349 147 -1019 -904 -909 -586 -22 111 1778 -1383 -685 -2213 -1631 -1489 -938 -1631 -364 -1195 -1397 1410 909 2406 1475 1082 952 -870 43 72 169 1035 1309 2209 1546 1549 -99 430 -980 -644 -383 346 -124 -272 -1358 -1105 -1055 -181 95 861 517 1036 -101 424 -364 -1832 SS 20240521T220105.8Z 8907.917428 236 1 9.33 2 61.98 83.97 133.80 279.21 0.00 1 0.00 1 0 17 6.434e-02 1.156e-02 4.514e-02 6.964e-03 3.187114e-01 3.490097e-03 3.523423e-03 -6.000000e+00 3.689286e-02 231.60 -2.00 3.40 -2.00 318.51 0.00e+00 1.720893e-03 6.278505e-04 9.897366e-05 -6.000000e+00 1.471220e-03 286.83 -2.00 20.00 -2.00 318.15 0.00e+00 2.118 0.000 302.00 328.00 3 4.9885e+00 9.4067e-03 2.6396e-02 -6.0000e+00 9.3183e-02 -6.7719e-02 1.0599e-02 1.5820e-02 -6.0000e+00 1.0155e-01 3.4418e-02 7.2822e-03 7.8044e-03 -6.0000e+00 5.9538e-02 -2.4973e-02 3.8160e-03 2.2196e-03 -6.0000e+00 2.4335e-02 3.0583e-04 1.5648e-04 2.0272e-04 2.2022e-05 -6.0000e+00 1.7261e-03 1.3053e-02 -3.1606e-05 12 9 9 12 1 1 999.00 20.24 0.32 0.01305 0.01423 2 3 1 5 0 3108.200 23.93 15.00 20.24 26.52 11.8 1008.86 -4425 -2652 -26797 -1239 -17094 37633 -2508 20196 -35448 -6195 -10071 -23205 -3537 -1078 4707 -2862 -4167 -10931 3084 -1134 9411 8026 1319 1659 -2649 310 -1462 -2836 -399 -5884 10496 -169 2755 1050 -8070 508 -6002 -3136 2882 1364 -265 -582 -1979 -1954 3614 -693 2088 -1049 509 -1052 1600 1541 1794 711 508 3440 -1109 2578 -608 32 1978 1746 2472 3110 1786 -1297 -518 -41 1587 -794 1878 1168 181 1390 -480 -1461 -3227 -2694 6 -1779 487 -701 -2355 -3553 433 -8 -448 1299 249 272 764 240 -2361 -778 -2350 165 1491 458 729 -772 -408 -2936 -809 -1616 -456 -1020 -794 -809 290 866 634 1019 467 568 -5 -998 71 994 1463 884 1352 979 276 460 596 228 -134 -44 -74 -525 -232 -324 -552 296 -421 -844 -391 856 -23 387 -214 -235 -547 -210 -139 -1856 -63 -917 1125 -119 864 -2961 -408 -691 -1907 -276 -97 470 -346 -543 -1611 417 -167 1278 1101 199 265 -468 55 -266 -497 -65 -1019 1682 -33 582 232 -1841 105 -1463 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