File name: Pandora194s1_Tokyo-TMU_20240601_L2Fit_fout2c10d20220901p1-8.txt File generation date: 20240601T144804.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Shungo KATO Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 194 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora194_OF_v3d20210122.txt Instrument calibration file used: Pandora194s1_CF_v10d20220901.txt Level 1 file used: Pandora194s1_Tokyo-TMU_20240601_L1_smca1c10d20220901p1-8.txt Full location name: Tokyo Metropolitan University (TMU) Short location name: Tokyo-TMU Country of location: Japan Location latitude [deg]: 35.6200 Location longitude [deg]: 139.3834 Location altitude [m]: 135 Local noon date: 20240601 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: cso0 "Modification of session 8 for new VP" First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0446 305.1858 305.3270 305.4682 305.6094 305.7505 305.8917 306.0328 306.1740 306.3151 306.4562 306.5973 306.7384 306.8795 307.0205 307.1616 307.3026 307.4437 307.5847 307.7257 307.8667 308.0077 308.1487 308.2896 308.4306 308.5715 308.7125 308.8534 308.9943 309.1352 309.2761 309.4170 309.5578 309.6987 309.8395 309.9804 310.1212 310.2620 310.4028 310.5436 310.6844 310.8251 310.9659 311.1066 311.2474 311.3881 311.5288 311.6695 311.8102 311.9509 312.0915 312.2322 312.3728 312.5135 312.6541 312.7947 312.9353 313.0759 313.2165 313.3570 313.4976 313.6381 313.7787 313.9192 314.0597 314.2002 314.3407 314.4812 314.6216 314.7621 314.9025 315.0430 315.1834 315.3238 315.4642 315.6046 315.7449 315.8853 316.0257 316.1660 316.3063 316.4467 316.5870 316.7273 316.8676 317.0078 317.1481 317.2884 317.4286 317.5688 317.7090 317.8493 317.9895 318.1296 318.2698 318.4100 318.5501 318.6903 318.8304 318.9705 319.1106 319.2507 319.3908 319.5309 319.6709 319.8110 319.9510 320.0911 320.2311 320.3711 320.5111 320.6511 320.7910 320.9310 321.0710 321.2109 321.3508 321.4907 321.6306 321.7705 321.9104 322.0503 322.1901 322.3300 322.4698 322.6097 322.7495 322.8893 323.0291 323.1688 323.3086 323.4484 323.5881 323.7278 323.8676 324.0073 324.1470 324.2867 324.4263 324.5660 324.7057 324.8453 324.9849 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240531T211634.2Z 8917.886507 198 1 5.43 2 70.28 76.45 40.04 166.00 0.00 1 0.00 1 0 17 1.291e-01 1.189e-02 1.232e-01 7.909e-03 3.907657e-01 3.987832e-03 4.286640e-03 -6.000000e+00 7.413403e-02 232.06 -2.00 3.40 -2.00 319.29 0.00e+00 3.681171e-03 9.065079e-04 1.603814e-04 -6.000000e+00 2.951485e-03 287.77 -2.00 20.00 -2.00 318.94 0.00e+00 2.930 0.000 302.00 328.00 3 3.9277e+00 1.0981e-02 3.5064e-02 -6.0000e+00 1.8746e-01 -7.2854e-02 1.2526e-02 1.9644e-02 -6.0000e+00 2.0422e-01 2.4037e-02 9.9395e-03 9.7461e-03 -6.0000e+00 1.1969e-01 -1.8346e-02 5.3222e-03 2.8045e-03 -6.0000e+00 4.8870e-02 3.7342e-04 -5.3099e-04 2.2997e-04 2.8437e-05 -6.0000e+00 3.4639e-03 1.2171e-02 -1.0752e-04 12 9 9 12 1 1 999.00 20.30 0.53 0.01217 0.00818 2 6 1 5 0 1807.470 24.04 15.00 20.30 27.63 12.2 993.39 36088 7266 20083 -54926 52617 -23189 1615 79212 -17373 49054 -41288 -23522 -19475 -2397 -8642 2888 -13892 9310 20287 -21033 3160 -10317 11154 -793 4931 13246 -12196 3942 4462 2500 -16330 5630 -2498 -3183 6905 -11440 6253 -10677 -3088 -4542 -2839 -506 -3595 3542 -365 4693 -3922 8414 -1869 -1107 6608 -1006 8195 1355 3905 21 1040 124 1491 2836 1517 5158 1355 5742 -1020 -354 954 -519 824 -974 651 373 -549 -1298 -559 -1887 -2111 -1312 -245 1299 -3104 -1136 -2658 -671 -2315 840 611 1323 726 -101 784 -1031 -1062 -71 -1541 6 -489 883 170 -64 -708 -1538 -321 -1410 -462 -1480 -205 -473 1249 501 797 650 266 470 -1005 636 -959 1074 952 702 885 1725 678 -98 -106 -916 -698 -264 -878 655 -568 -318 -855 -4 725 -372 161 -5 62 -4 86 55 -483 529 163 418 -2330 690 -626 36 916 -590 908 -1911 -980 -931 -118 -547 187 -1157 661 1377 -2271 275 -1027 921 -78 487 1257 -1505 398 434 257 -2267 712 -383 -513 953 -1879 950 -2273 -738 -1175 -796 -147 -1124 1056 -115 1425 -1301 2472 -613 -373 2233 -401 3195 602 1758 10 506 61 705 1325 751 2698 749 3292 -630 -204 562 -312 491 -675 485 289 -425 -967 -381 -1171 -1319 -803 -162 898 -2554 -1020 -2396 -625 -2357 887 682 1508 830 -111 791 -974 -1018 -68 -1512 7 -564 1121 229 -84 -875 -1747 -369 -1719 -562 -1915 -276 -674 1749 767 1297 1075 426 704 -1417 906 -1412 1526 1454 1128 1424 2687 1036 -145 -161 -1332 -978 -384 -1320 1054 -981 -531 -1484 -7 1394 -712 315 -10 122 -7 168 102 -897 SS 20240531T221618.1Z 8917.927988 233 1 4.88 2 58.32 84.19 39.23 189.00 0.00 1 0.00 1 0 17 3.348e-02 1.199e-02 2.618e-02 7.793e-03 2.611032e-01 3.935952e-03 2.923832e-03 -6.000000e+00 1.923138e-02 232.06 -2.00 3.40 -2.00 317.49 0.00e+00 1.138045e-03 5.303223e-04 5.721363e-05 -6.000000e+00 7.655588e-04 287.77 -2.00 20.00 -2.00 317.13 0.00e+00 1.897 0.000 302.00 328.00 3 4.7819e+00 1.0478e-02 2.2880e-02 -6.0000e+00 4.8630e-02 -7.1403e-02 1.1712e-02 1.2974e-02 -6.0000e+00 5.2972e-02 2.3907e-02 7.1629e-03 6.3332e-03 -6.0000e+00 3.1046e-02 -1.4800e-02 3.5241e-03 1.7685e-03 -6.0000e+00 1.2681e-02 5.1297e-04 -5.6266e-06 2.2357e-04 1.7810e-05 -6.0000e+00 8.9821e-04 1.0547e-02 -7.3805e-05 12 9 9 12 1 1 999.00 20.47 0.22 0.01055 0.01050 1 4 1 5 0 2436.700 24.14 15.00 20.47 28.89 12.2 996.81 -4900 -14315 -8374 4108 -10300 15592 1571 -6471 -12630 -9306 -2164 5711 -1379 4128 3255 -2141 2684 -4313 -1063 433 -1828 3402 6214 5173 3356 -3070 -9463 -4769 647 3662 2310 1050 1608 -2849 -5723 -3244 -3097 -416 4476 1506 -1048 -582 -1739 49 2 3130 1733 94 1958 201 1666 -853 983 176 1240 985 1617 1592 -1164 677 273 3603 1459 2538 389 11 18 -2019 2377 656 1308 144 -888 443 195 -684 -1897 -1604 -2227 -1347 -1711 -1737 -1860 -2138 -1556 -506 -966 -179 1337 2316 -44 -585 -1754 -463 -423 -524 675 975 271 -241 -1898 -1608 -1743 -832 -799 -796 -1158 -149 -465 1719 2166 1712 -305 423 -81 1342 1048 -129 554 982 906 654 1033 632 56 -48 -703 -221 -454 355 -1361 -350 -922 148 -18 -641 860 201 144 -686 356 -923 55 -506 -1795 -1018 415 -1072 1197 147 -738 -1709 -1280 -275 690 -202 665 609 -425 532 -956 -239 100 -439 771 1400 1244 867 -878 -2877 -1305 157 943 586 294 487 -923 -1787 -973 -1019 -157 1933 715 -556 -322 -1003 28 1 1747 963 52 1044 110 957 -540 647 114 816 664 1102 1079 -797 455 192 2647 1193 2180 337 9 13 -1509 1842 546 1177 136 -843 398 175 -557 -1419 -1152 -1719 -1169 -1555 -1738 -1979 -2238 -1743 -601 -1139 -215 1580 2762 -49 -645 -1801 -463 -454 -584 830 1238 362 -314 -2346 -1944 -2033 -1016 -993 -1041 -1593 -212 -662 2555 3360 2668 -463 590 -110 1723 1369 -181 779 1457 1363 970 1482 924 79 -63 -904 -290 -644 535 -2055 -534 -1449 242 -29 -1107 1502 360 258 -1203 597 -1511 88 SS 20240531T222543.2Z 8917.934528 236 1 5.02 2 56.41 85.45 39.53 192.60 0.00 1 0.00 1 0 17 1.563e-02 8.481e-03 5.751e-03 2.135e-03 2.452282e-01 1.076825e-03 2.770428e-03 -6.000000e+00 8.976320e-03 232.06 -2.00 3.40 -2.00 317.00 0.00e+00 1.358570e-03 1.284403e-04 4.546644e-05 -6.000000e+00 3.573385e-04 287.77 -2.00 20.00 -2.00 316.64 0.00e+00 1.802 0.000 302.00 328.00 3 3.0711e+00 2.8516e-03 2.1662e-02 -6.0000e+00 2.2698e-02 -7.9134e-02 3.1853e-03 1.2216e-02 -6.0000e+00 2.4726e-02 3.0359e-02 1.8900e-03 5.9396e-03 -6.0000e+00 1.4491e-02 -1.8309e-02 9.0120e-04 1.6405e-03 -6.0000e+00 5.9186e-03 3.1958e-03 -2.4829e-04 6.0815e-05 1.7553e-05 -6.0000e+00 4.1931e-04 1.0527e-02 -1.0163e-04 12 9 1 12 1 1 39.75 20.51 0.44 0.01053 0.00866 11 26 1 5 0 417.490 24.25 15.00 20.51 29.36 12.2 996.53 -3322 -1371 -4063 -5719 -4577 -4141 -2162 -2487 -296 -4018 -5677 -5426 -2807 -439 817 -586 1009 1132 456 1664 102 1045 1261 1590 465 936 -1729 -1582 -1535 488 772 1911 2058 -484 -3252 -2253 -1943 -893 165 -504 -1194 -201 -360 206 873 11 -272 -294 -261 304 1095 947 1673 1740 630 708 795 251 454 604 1740 2008 2528 2098 577 -406 -818 -273 824 827 681 561 133 29 -480 -989 -2053 -2154 -1300 -1490 -1193 -1558 -2153 -1770 -588 -236 164 520 900 511 456 -695 -932 -616 -449 -647 584 773 -145 -519 -917 -1678 -1133 -942 -1144 -1048 -706 -388 272 717 1222 1007 1111 461 -252 -1 -114 601 866 958 836 835 725 459 517 40 76 377 57 -96 -177 -228 -735 -336 -224 -417 242 221 192 -3 -380 -566 -526 -435 -194 -608 -818 -577 -495 -267 -346 -45 -664 -943 -923 -524 -84 178 -143 253 295 125 468 30 300 368 488 152 315 -596 -514 -467 144 242 643 750 -185 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