File name: Pandora194s1_Tokyo-TMU_20240702_L2Fit_fout2c10d20220901p1-8.txt File generation date: 20240702T145600.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Shungo KATO Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 194 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora194_OF_v3d20210122.txt Instrument calibration file used: Pandora194s1_CF_v10d20220901.txt Level 1 file used: Pandora194s1_Tokyo-TMU_20240702_L1_smca1c10d20220901p1-8.txt Full location name: Tokyo Metropolitan University (TMU) Short location name: Tokyo-TMU Country of location: Japan Location latitude [deg]: 35.6200 Location longitude [deg]: 139.3834 Location altitude [m]: 135 Local noon date: 20240702 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: cso0 "Modification of session 8 for new VP" First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0446 305.1858 305.3270 305.4682 305.6094 305.7505 305.8917 306.0328 306.1740 306.3151 306.4562 306.5973 306.7384 306.8795 307.0205 307.1616 307.3026 307.4437 307.5847 307.7257 307.8667 308.0077 308.1487 308.2896 308.4306 308.5715 308.7125 308.8534 308.9943 309.1352 309.2761 309.4170 309.5578 309.6987 309.8395 309.9804 310.1212 310.2620 310.4028 310.5436 310.6844 310.8251 310.9659 311.1066 311.2474 311.3881 311.5288 311.6695 311.8102 311.9509 312.0915 312.2322 312.3728 312.5135 312.6541 312.7947 312.9353 313.0759 313.2165 313.3570 313.4976 313.6381 313.7787 313.9192 314.0597 314.2002 314.3407 314.4812 314.6216 314.7621 314.9025 315.0430 315.1834 315.3238 315.4642 315.6046 315.7449 315.8853 316.0257 316.1660 316.3063 316.4467 316.5870 316.7273 316.8676 317.0078 317.1481 317.2884 317.4286 317.5688 317.7090 317.8493 317.9895 318.1296 318.2698 318.4100 318.5501 318.6903 318.8304 318.9705 319.1106 319.2507 319.3908 319.5309 319.6709 319.8110 319.9510 320.0911 320.2311 320.3711 320.5111 320.6511 320.7910 320.9310 321.0710 321.2109 321.3508 321.4907 321.6306 321.7705 321.9104 322.0503 322.1901 322.3300 322.4698 322.6097 322.7495 322.8893 323.0291 323.1688 323.3086 323.4484 323.5881 323.7278 323.8676 324.0073 324.1470 324.2867 324.4263 324.5660 324.7057 324.8453 324.9849 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240701T202635.4Z 8948.851799 172 1 49.70 2 80.64 68.32 38.02 103.47 0.00 1 0.00 1 0 17 5.159e-01 1.646e-02 3.945e-01 9.555e-03 7.141796e-01 5.494380e-03 7.456393e-03 -6.000000e+00 3.064785e-01 232.48 -2.00 3.40 -2.00 321.88 0.00e+00 1.093595e-02 2.328507e-03 8.976777e-04 -6.000000e+00 1.262299e-02 290.53 -2.00 20.00 -2.00 321.54 0.00e+00 5.843 0.003 302.00 328.00 3 2.1309e+00 1.7722e-02 6.9255e-02 -6.0000e+00 7.7526e-01 2.6043e-01 2.6375e-02 3.9194e-02 -6.0000e+00 8.4052e-01 -4.7129e-01 3.1464e-02 2.2480e-02 -6.0000e+00 4.8868e-01 1.9288e-01 1.5158e-02 7.8082e-03 -6.0000e+00 2.0430e-01 9.7901e-05 -4.7167e-04 2.9742e-04 9.2350e-05 -6.0000e+00 1.4313e-02 1.4954e-02 -1.3517e-04 12 9 8 11 8 0 98.28 20.85 0.55 0.01495 0.01141 44 10 1 5 0 1129.430 24.56 15.00 20.85 33.81 14.5 992.24 -141368 -209470 -146361 900000 87177 900000 900000 -273942 -160464 -80018 -77247 -113488 -94502 65459 -120588 -100974 -5806 -54918 -4066 309 78197 60257 186480 -66512 -51452 -39995 900000 23699 9204 58507 -13766 -9980 -48145 18255 -34070 -22037 5990 -4933 33805 -9839 89175 -30046 41216 35588 36215 72349 26134 42369 -17306 29540 18830 14000 16690 -1756 13899 8350 33575 4190 4380 8957 5015 12390 9630 16541 6656 1134 -6882 7010 3877 7608 4437 9775 6112 1196 3325 -4801 3462 -5914 -3989 1993 4878 2577 -2747 -1224 -1509 1700 934 -1048 2312 151 3759 -2707 -1664 -4742 -6289 -2475 -405 1906 -770 367 -4232 -983 -1402 -718 -1109 -2334 -258 -2422 -163 33 779 580 247 181 -1625 551 -1288 986 -786 1997 926 976 752 931 1415 -1154 -32 96 -115 693 900 1034 -910 217 -491 83 -66 118 152 -32 -377 -804 900000 -1316 -3723 -1486 900000 812 900000 900000 -8810 -1765 -745 -719 -1057 -880 609 -2551 -2136 -54 -930 -45 3 728 561 1736 -1464 -1002 -711 900000 221 101 545 -268 -228 -1874 386 -1153 -653 147 -159 887 -466 1736 -2060 1465 1524 1585 2290 1362 1972 -1547 1788 1420 1238 1569 -214 1514 987 3126 515 522 1017 626 1615 1488 2695 1252 221 -1448 1344 863 1877 1231 2648 1673 321 789 -1113 706 -1393 -1073 609 1699 1046 -1279 -595 -788 916 533 -625 1326 85 1893 -1368 -815 -2556 -3970 -1772 -333 1757 -783 364 -4058 -815 -1086 -571 -955 -2147 -248 -2571 -189 43 1122 876 374 264 -2290 742 -1818 1442 -1243 3149 1442 1456 1088 1300 1901 -1536 -41 136 -188 1270 1802 2198 -2088 529 -1286 226 -183 330 420 -83 -930 -1877 900000 SS 20240701T203622.6Z 8948.858595 177 1 49.41 2 78.78 69.61 36.12 105.44 0.00 1 0.00 1 0 17 4.912e-01 1.353e-02 2.992e-01 8.220e-03 6.250132e-01 4.507845e-03 6.347118e-03 -6.000000e+00 2.829837e-01 232.48 -2.00 3.40 -2.00 321.63 0.00e+00 8.643027e-03 1.829645e-03 6.336138e-04 -6.000000e+00 1.173220e-02 290.53 -2.00 20.00 -2.00 321.25 0.00e+00 4.960 0.002 302.00 328.00 3 2.4380e+00 1.3835e-02 5.8694e-02 -6.0000e+00 7.1586e-01 7.0874e-02 1.9725e-02 3.2685e-02 -6.0000e+00 7.8019e-01 -1.9378e-01 2.3255e-02 1.7656e-02 -6.0000e+00 4.5677e-01 7.2215e-02 1.1325e-02 5.7268e-03 -6.0000e+00 1.8946e-01 1.8702e-04 -6.9677e-05 2.5205e-04 6.5407e-05 -6.0000e+00 1.3410e-02 1.3428e-02 -1.7691e-05 12 8 8 10 0 0 99.98 20.85 0.55 0.01343 0.01290 143 31 1 5 0 345.450 24.56 15.00 20.85 33.57 14.5 991.22 900000 -165322 900000 -211724 900000 -194681 -130433 -137894 -185943 -46307 -177187 40039 -100888 -51772 -103452 -50579 123275 -53109 171373 -42710 -19953 -85510 -55904 6897 -42785 -13318 -57721 -32146 -43865 11788 -25494 4614 -15844 -40675 -14351 -30732 58082 -7410 6765 -1820 8841 -839 11764 17808 4026 7627 -7793 20026 4342 -4753 20464 12592 18547 2234 16646 618 3053 1621 3368 7143 345 15437 7561 9726 1790 3407 2400 -250 9033 4811 6864 3670 -345 -4015 -388 -3823 -5689 -920 -2729 4052 -3171 -173 -3027 -193 -1130 -1357 2127 1036 3295 857 -171 -2511 -2022 -2547 -3738 -126 301 1892 305 -767 -1480 -1633 -1216 -2625 -1248 -2875 -680 -2121 -127 1156 466 1040 428 598 -410 -959 -1344 -524 869 348 1936 1164 1404 235 55 -1092 519 495 428 1071 -361 278 -810 -8 -479 -249 399 -36 720 -288 -12 -636 -265 900000 -1766 900000 -3817 900000 -2600 -1045 -1306 -3115 -371 -2968 321 -1176 -490 -2110 -737 988 -1006 1373 -840 -320 -2616 -1303 90 -966 -233 -1598 -679 -1054 180 -687 111 -542 -1896 -491 -1231 1058 -308 296 -102 496 -56 728 1077 287 544 -670 1357 361 -464 1729 1284 1945 298 2013 90 445 261 521 1064 58 2498 1514 2135 442 803 564 -62 2301 1472 2249 1285 -123 -1399 -119 -1090 -1564 -249 -862 1425 -1398 -84 -1637 -107 -682 -876 1396 706 2183 557 -104 -1467 -1136 -1510 -2549 -97 266 1878 329 -822 -1480 -1469 -1019 -2313 -1172 -2894 -710 -2415 -157 1574 700 1613 660 879 -575 -1312 -1894 -774 1350 561 3022 1764 2055 336 75 -1465 673 692 680 1890 -702 566 -1755 -19 -1181 -640 1039 -96 1877 -723 -29 -1431 -589 SS 20240701T204230.9Z 8948.862857 180 1 49.51 2 77.61 70.42 34.94 106.75 0.00 1 0.00 1 0 17 3.435e-01 8.877e-03 1.521e-01 3.316e-03 5.768240e-01 1.783307e-03 6.110442e-03 -6.000000e+00 2.011272e-01 232.48 -2.00 3.40 -2.00 321.09 0.00e+00 8.089890e-03 6.530347e-04 5.147933e-04 -6.000000e+00 7.899152e-03 290.53 -2.00 20.00 -2.00 320.78 0.00e+00 4.526 0.001 302.00 328.00 3 1.9658e+00 5.3145e-03 5.3897e-02 -6.0000e+00 5.0951e-01 -5.0942e-03 7.2292e-03 3.0620e-02 -6.0000e+00 5.5153e-01 -7.8538e-02 8.3970e-03 1.7026e-02 -6.0000e+00 3.2285e-01 2.5197e-02 4.2315e-03 5.6889e-03 -6.0000e+00 1.3555e-01 4.6709e-04 -4.0137e-04 9.8884e-05 5.4477e-05 -6.0000e+00 9.2357e-03 1.3596e-02 -6.5159e-05 11 9 0 11 8 0 99.61 20.85 0.30 0.01360 0.01058 104 23 1 5 0 475.990 24.65 15.00 20.85 33.57 14.6 991.46 -100813 -152683 -87571 -104356 -116403 -56760 -140685 -53271 -120789 -57738 -132208 -36634 -120964 -48014 5214 -27050 30190 -48251 19988 -34784 -16934 -34788 -30775 -16011 -31829 8135 -17584 -16550 -40705 -13298 -12898 -17291 10428 -2613 16600 -14411 -10739 -22551 -4950 -283 -4140 6192 -2697 5623 3952 8132 -1915 3015 4600 2106 8276 4041 8324 2502 3654 364 -549 166 -1072 4438 587 4228 4002 8118 1919 463 1957 -833 5001 1261 2182 -7 205 -97 -973 -2265 -3367 -2491 -1556 -148 -1156 -1314 -1874 -1642 -580 235 1118 111 1207 60 254 -672 -1608 -1187 -1128 407 108 1074 105 418 -854 -1451 -743 -1150 -842 -1463 -1252 -1044 124 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