File name: Pandora194s1_Tokyo-TMU_20240706_L2Fit_fout2c10d20220901p1-8.txt File generation date: 20240706T145829.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Shungo KATO Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 194 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora194_OF_v3d20210122.txt Instrument calibration file used: Pandora194s1_CF_v10d20220901.txt Level 1 file used: Pandora194s1_Tokyo-TMU_20240706_L1_smca1c10d20220901p1-8.txt Full location name: Tokyo Metropolitan University (TMU) Short location name: Tokyo-TMU Country of location: Japan Location latitude [deg]: 35.6200 Location longitude [deg]: 139.3834 Location altitude [m]: 135 Local noon date: 20240706 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: cso0 "Modification of session 8 for new VP" First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0446 305.1858 305.3270 305.4682 305.6094 305.7505 305.8917 306.0328 306.1740 306.3151 306.4562 306.5973 306.7384 306.8795 307.0205 307.1616 307.3026 307.4437 307.5847 307.7257 307.8667 308.0077 308.1487 308.2896 308.4306 308.5715 308.7125 308.8534 308.9943 309.1352 309.2761 309.4170 309.5578 309.6987 309.8395 309.9804 310.1212 310.2620 310.4028 310.5436 310.6844 310.8251 310.9659 311.1066 311.2474 311.3881 311.5288 311.6695 311.8102 311.9509 312.0915 312.2322 312.3728 312.5135 312.6541 312.7947 312.9353 313.0759 313.2165 313.3570 313.4976 313.6381 313.7787 313.9192 314.0597 314.2002 314.3407 314.4812 314.6216 314.7621 314.9025 315.0430 315.1834 315.3238 315.4642 315.6046 315.7449 315.8853 316.0257 316.1660 316.3063 316.4467 316.5870 316.7273 316.8676 317.0078 317.1481 317.2884 317.4286 317.5688 317.7090 317.8493 317.9895 318.1296 318.2698 318.4100 318.5501 318.6903 318.8304 318.9705 319.1106 319.2507 319.3908 319.5309 319.6709 319.8110 319.9510 320.0911 320.2311 320.3711 320.5111 320.6511 320.7910 320.9310 321.0710 321.2109 321.3508 321.4907 321.6306 321.7705 321.9104 322.0503 322.1901 322.3300 322.4698 322.6097 322.7495 322.8893 323.0291 323.1688 323.3086 323.4484 323.5881 323.7278 323.8676 324.0073 324.1470 324.2867 324.4263 324.5660 324.7057 324.8453 324.9849 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240705T214337.4Z 8952.905294 103 1 50.19 2 65.99 78.48 64.31 73.66 0.00 1 0.00 1 0 25 1.815e-01 1.822e-02 2.088e-01 1.483e-02 3.416000e-01 7.712595e-03 3.859552e-03 -6.000000e+00 1.062220e-01 232.44 -2.00 3.40 -2.00 319.50 0.00e+00 6.309387e-03 1.790243e-03 1.394929e-04 -6.000000e+00 4.172922e-03 290.87 -2.00 20.00 -2.00 319.20 0.00e+00 2.439 0.000 302.00 328.00 3 6.1525e+00 2.1266e-02 2.9873e-02 -6.0000e+00 2.6906e-01 2.0236e-02 2.4155e-02 1.7439e-02 -6.0000e+00 2.9129e-01 -3.2777e-02 1.9042e-02 8.7682e-03 -6.0000e+00 1.7052e-01 1.0913e-02 1.0256e-02 2.6082e-03 -6.0000e+00 7.1577e-02 6.4433e-05 -4.7034e-05 4.4377e-04 2.6887e-05 -6.0000e+00 4.8805e-03 1.4235e-02 -1.2480e-04 12 9 8 11 8 0 99.96 21.40 0.58 0.01423 0.01388 20 4 1 5 0 2508.700 25.17 15.00 21.40 36.43 14.8 994.47 23744 90409 -23891 -17542 53895 48643 -50201 -4425 -32836 106519 58823 59149 -16183 -36226 10115 5515 -625 -19028 10917 4919 13796 5110 14731 9401 8665 14104 -25 23046 -21770 -13212 15140 15446 26552 -16266 -8325 -7930 13448 -21167 -2844 5642 -10997 17270 -3327 10930 -5245 1763 1902 6283 -9735 1808 6609 -1595 5923 3743 2672 2391 995 -927 -5755 5615 -1783 2872 4177 3207 1956 -3969 -1043 481 1751 360 5709 -2937 -1210 320 -1413 -2867 -986 5120 -4941 3487 3590 1186 239 -3517 -4437 -1441 -597 1095 2527 332 837 2258 -774 -1446 677 -1715 2215 304 213 1292 -1489 -4596 -3328 -1571 -1302 -2164 299 409 -59 409 303 2265 360 205 -662 1962 -1565 202 1384 888 1567 1076 629 -770 -823 -351 -267 1068 -697 -496 -460 30 25 176 -1146 441 -7 -826 197 -400 1065 -100 900000 544 1308 -1037 -677 909 895 -2574 -157 -1684 1541 1237 1322 -915 -3048 638 413 -53 -2076 933 466 1215 484 1278 890 854 1354 -3 1939 -2776 -1598 1533 1747 2967 -2866 -1270 -1189 1786 -4648 -621 1306 -3268 4064 -1002 2917 -1669 531 570 1793 -3251 551 2059 -583 2134 1452 1075 981 419 -394 -2520 2207 -793 1333 2109 1754 1077 -2155 -518 235 921 218 3558 -2062 -824 205 -930 -1717 -532 2555 -2973 2214 2575 962 208 -3342 -4569 -1540 -666 1232 2789 357 826 2005 -658 -1242 621 -1810 2531 393 290 1686 -1852 -5384 -3687 -1799 -1611 -2836 401 576 -90 662 520 3825 594 315 -948 2622 -2205 295 2150 1454 2562 1726 983 -1165 -1188 -480 -353 1447 -1049 -804 -783 53 46 331 -2327 919 -15 -1815 425 -839 2108 -192 900000 SS 20240705T220544.3Z 8952.920652 117 1 49.09 2 61.56 81.31 60.11 76.17 0.00 1 0.00 1 0 17 2.543e-02 7.399e-03 8.606e-03 1.438e-03 2.876491e-01 7.187383e-04 3.182554e-03 -6.000000e+00 1.462542e-02 232.44 -2.00 3.40 -2.00 318.71 0.00e+00 1.738011e-03 1.333470e-04 9.255961e-05 -6.000000e+00 5.814669e-04 290.88 -2.00 20.00 -2.00 318.33 0.00e+00 2.090 0.000 302.00 328.00 3 3.5583e+00 1.9521e-03 2.5269e-02 -6.0000e+00 3.7017e-02 -9.0089e-02 2.1986e-03 1.4407e-02 -6.0000e+00 4.0313e-02 3.4010e-02 1.5221e-03 7.0820e-03 -6.0000e+00 2.3620e-02 -2.3486e-02 7.9719e-04 2.0020e-03 -6.0000e+00 9.6373e-03 1.4008e-03 2.9986e-04 4.2439e-05 2.0122e-05 -6.0000e+00 6.8230e-04 1.3835e-02 1.9745e-06 11 8 0 10 0 0 99.93 21.42 0.40 0.01384 0.01609 88 19 1 5 0 557.680 25.17 15.00 21.42 37.97 14.8 995.87 -8834 -5087 -839 -10567 -10070 -6891 -7612 -4004 -8239 -8514 -6633 -7924 -5892 -3123 -31 -569 -2521 -224 418 1212 1921 337 -95 0 52 -1465 -3139 -1339 -2615 194 -200 1449 1738 -920 -2291 -3523 -1923 -1531 -306 -22 -874 -1188 -1267 -461 79 851 45 756 -259 370 1493 1583 911 1369 841 652 211 -224 -375 513 1243 2604 2656 2890 912 42 -400 -430 908 1108 769 654 471 387 -213 -956 -1981 -1655 -1250 -790 -997 -1477 -1982 -1507 -739 61 166 691 900 464 267 -438 -811 -302 -575 -458 530 693 -34 -630 -1203 -1781 -1349 -914 -1140 -1060 -866 -718 232 436 1005 851 931 128 -199 -87 166 581 909 739 898 946 555 210 188 -318 28 151 -52 19 -381 -364 -639 -300 -170 -235 375 176 104 -83 -169 -246 -252 -465 -287 -47 -617 -524 -333 -394 -225 -540 -589 -449 -566 -473 -287 -3 -66 -315 -29 56 168 271 48 -14 0 9 -254 -552 -219 -410 30 -33 260 341 -190 -451 -694 -411 -384 -91 -8 -334 -479 -528 -193 33 356 19 308 -105 152 648 740 456 720 458 365 121 -128 -211 286 718 1613 1798 1890 602 28 -254 -271 615 774 586 519 371 293 -165 -668 -1276 -1031 -834 -598 -774 -1272 -1824 -1452 -761 67 191 814 1054 521 277 -418 -717 -264 -545 -483 620 896 -47 -838 -1498 -2047 -1488 -1061 -1439 -1407 -1205 -1046 356 655 1577 1339 1400 196 -282 -118 228 838 1410 1213 1363 1536 878 319 272 -440 37 207 -78 31 -640 -625 -1037 -510 -307 -444 723 348 206 -159 -312 -438 -446 SS 20240705T221006.8Z 8952.923690 120 1 49.36 2 60.68 81.88 59.28 76.66 0.00 1 0.00 1 0 17 2.382e-02 7.467e-03 4.349e-03 7.944e-04 2.784791e-01 3.974592e-04 3.072512e-03 -6.000000e+00 1.369958e-02 232.44 -2.00 3.40 -2.00 318.58 0.00e+00 1.868668e-03 7.095271e-05 8.272614e-05 -6.000000e+00 5.446750e-04 290.88 -2.00 20.00 -2.00 318.20 0.00e+00 2.033 0.000 302.00 328.00 3 2.5417e+00 1.0788e-03 2.4504e-02 -6.0000e+00 3.4673e-02 -9.7968e-02 1.2151e-03 1.3872e-02 -6.0000e+00 3.7762e-02 3.1422e-02 8.1858e-04 6.8138e-03 -6.0000e+00 2.2125e-02 -2.1599e-02 4.2516e-04 1.9284e-03 -6.0000e+00 9.0267e-03 4.1640e-03 2.0374e-04 2.3438e-05 1.8718e-05 -6.0000e+00 6.3918e-04 1.4003e-02 -1.4639e-05 11 8 0 10 0 0 99.08 21.43 0.43 0.01400 0.01553 273 59 1 5 0 180.770 25.28 15.00 21.43 38.21 14.9 995.93 -5055 -5214 -5029 -8544 -9329 -9136 -7617 -5935 -6240 -7350 -6891 -6741 -4550 -2549 -1262 -1439 -143 -331 584 1166 63 596 81 424 -1713 -1045 -2058 -1882 -2597 -469 1225 1519 1927 -1398 -3174 -2449 -2071 -641 -55 -140 -1479 -823 -1031 -493 397 678 357 136 177 403 1419 1557 1867 1509 1104 916 35 141 -258 532 1317 2187 2829 2669 936 3 -506 -300 866 973 883 635 376 290 -394 -1026 -1964 -1919 -1251 -1210 -1163 -1382 -2084 -1442 -719 -114 231 783 939 496 331 -566 -813 -817 -502 -337 509 640 -48 -678 -1285 -1586 -1304 -705 -1110 -1042 -809 -574 150 667 1057 887 843 257 -118 -34 124 618 760 762 812 890 618 330 150 -380 -70 284 63 -11 -359 -476 -647 -246 -238 -298 293 260 187 31 -189 -249 -311 -285 -327 -326 -541 -533 -500 -435 -375 -440 -551 -511 -520 -393 -253 -143 -182 -19 -46 84 175 10 91 13 70 -306 -193 -383 -331 -435 -77 213 289 400 -307 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