File name: Pandora243s1_Toronto-CNTower_20250516_L2Fit_fwvt1c7d20250508p1-8.txt File generation date: 20250821T074727.1Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c7p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 243 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora243_OF_v3d20230125.txt Instrument calibration file used: Pandora243s1_CF_v7d20250508.txt Level 1 file used: Pandora243s1_Toronto-CNTower_20250516_L1_smca1c7d20250508p1-8.txt Full location name: CN Tower Observation Pod Roof, 290 Bremner Blvd, Toronto, ON M5V 3L9 Short location name: Toronto-CNTower Country of location: Canada Location latitude [deg]: 43.6426 Location longitude [deg]: -79.3871 Location altitude [m]: 330 Local noon date: 20250516 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1621 1771 Nominal wavelengths inside fitting window [nm]: 492.0313 492.1519 492.2725 492.3931 492.5137 492.6342 492.7548 492.8753 492.9958 493.1163 493.2368 493.3572 493.4776 493.5981 493.7185 493.8388 493.9592 494.0796 494.1999 494.3202 494.4405 494.5608 494.6811 494.8013 494.9216 495.0418 495.1620 495.2822 495.4023 495.5225 495.6426 495.7627 495.8828 496.0029 496.1230 496.2430 496.3630 496.4830 496.6030 496.7230 496.8430 496.9629 497.0829 497.2028 497.3227 497.4425 497.5624 497.6823 497.8021 497.9219 498.0417 498.1615 498.2812 498.4010 498.5207 498.6404 498.7601 498.8798 498.9994 499.1191 499.2387 499.3583 499.4779 499.5974 499.7170 499.8365 499.9561 500.0756 500.1951 500.3145 500.4340 500.5534 500.6728 500.7922 500.9116 501.0310 501.1503 501.2697 501.3890 501.5083 501.6276 501.7468 501.8661 501.9853 502.1045 502.2237 502.3429 502.4621 502.5812 502.7003 502.8195 502.9386 503.0576 503.1767 503.2957 503.4148 503.5338 503.6528 503.7717 503.8907 504.0096 504.1286 504.2475 504.3664 504.4852 504.6041 504.7229 504.8417 504.9605 505.0793 505.1981 505.3168 505.4356 505.5543 505.6730 505.7917 505.9103 506.0290 506.1476 506.2662 506.3848 506.5034 506.6220 506.7405 506.8591 506.9776 507.0961 507.2145 507.3330 507.4514 507.5699 507.6883 507.8067 507.9250 508.0434 508.1617 508.2800 508.3984 508.5166 508.6349 508.7532 508.8714 508.9896 509.1078 509.2260 509.3442 509.4623 509.5804 509.6986 509.8167 509.9347 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20250516T110949.7Z 9267.465159 242 1 31.08 2 77.60 75.17 83.09 217.87 0.00 1 0.00 1 0 15 4.488e-03 4.516e-03 3.431e-03 3.415e-03 3.593877e+03 2.153252e+02 2.547006e+02 -6.000000e+00 2.496903e+02 280.25 -2.00 20.00 -2.00 505.24 0.00e+00 8.492777e-04 9.339024e-05 4.815340e-05 -6.000000e+00 1.254591e-04 280.25 -2.00 20.00 -2.00 500.23 0.00e+00 4.680225e-01 6.874652e-02 2.658205e-02 -6.000000e+00 8.981325e-02 230.86 -2.00 3.56 -2.00 501.86 0.00e+00 4.524 0.002 489.00 513.00 1 8.6391e+00 5.2580e-03 6.7290e-03 -6.0000e+00 6.8821e-03 2.4957e-02 1.3545e-03 7.0935e-04 -6.0000e+00 1.7805e-03 1.7706e-04 1.4792e-03 3.4790e-04 3.4364e-05 -6.0000e+00 4.7336e-04 -7.3576e-05 -5.5884e-05 11 8 0 10 0 0 99.90 27.57 2.31 -0.00007 0.01019 8 8 1 4 0 3884.170 35.75 20.00 27.57 25.01 3.6 949.09 -605 -554 15 127 -14 220 861 799 -541 -415 841 -103 -127 -494 58 -410 -517 181 -402 400 1 881 -619 394 217 -119 106 -776 -600 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-19 671 139 -251 -363 612 39 367 783 357 -147 251 177 611 393 -350 180 767 -59 -552 613 206 -344 332 479 91 -168 -779 -296 -38 -368 -230 -137 -241 -173 -213 102 367 -79 -48 -1 75 SQ 20250516T111919.0Z 9267.471748 245 1 29.58 2 75.93 76.71 84.12 219.62 0.00 1 0.00 1 0 15 3.158e-03 3.159e-03 2.677e-03 2.666e-03 3.367776e+03 1.682557e+02 2.540032e+02 -6.000000e+00 1.756766e+02 280.25 -2.00 20.00 -2.00 505.27 0.00e+00 7.441920e-04 7.310198e-05 4.603122e-05 -6.000000e+00 8.827478e-05 280.25 -2.00 20.00 -2.00 500.27 0.00e+00 3.881499e-01 5.373747e-02 2.258274e-02 -6.000000e+00 6.320182e-02 230.87 -2.00 3.56 -2.00 501.91 0.00e+00 4.023 0.001 489.00 513.00 1 8.3669e+00 4.1176e-03 5.9749e-03 -6.0000e+00 4.8428e-03 2.0982e-02 1.0563e-03 6.3567e-04 -6.0000e+00 1.2532e-03 2.5094e-04 2.0204e-03 2.7129e-04 3.3303e-05 -6.0000e+00 3.3301e-04 3.0580e-03 -9.0688e-05 10 0 0 10 0 0 99.36 27.59 2.23 0.00306 0.01707 8 8 1 4 0 3697.350 36.00 19.99 27.59 24.10 3.6 942.67 326 -88 -74 219 45 -78 591 259 708 -404 358 174 -681 -226 -45 -395 -128 -40 -44 -66 140 450 247 265 238 -291 131 78 -144 216 -601 -287 -393 359 61 -865 316 203 -104 116 320 544 -42 102 -197 91 -288 218 -181 -103 -103 -49 -158 -463 -458 -565 121 -49 -166 378 58 60 192 376 165 21 213 -425 -588 -726 -459 354 472 204 -45 -171 -309 -86 53 -271 -152 -302 -577 -247 402 121 464 478 92 -206 246 293 368 -274 -216 98 122 -408 428 2 320 -88 -698 -246 -377 -820 -238 -201 300 -51 -78 27 -343 181 224 -71 -73 138 465 -333 326 154 543 95 -141 80 -47 49 46 397 -158 -209 -20 524 7 158 291 96 -98 342 198 137 96 132 116 81 -7 -304 -441 438 -645 318 -87 -75 219 46 -82 631 281 763 -436 379 181 -706 -230 -45 -401 -131 -42 -47 -71 153 490 269 289 261 -307 144 84 -153 222 -610 -289 -402 376 66 -915 330 210 -112 123 337 574 -43 106 -207 95 -302 225 -184 -107 -104 -48 -153 -451 -455 -577 120 -49 -169 382 59 61 196 382 167 21 210 -416 -569 -726 -453 346 464 194 -44 -165 -295 -84 52 -261 -146 -292 -540 -232 380 115 445 458 88 -199 238 286 364 -275 -216 96 117 -383 389 2 295 -79 -640 -233 -368 -816 -235 -196 288 -49 -75 26 -343 182 227 -72 -75 141 475 -340 326 151 527 93 -138 78 -46 48 45 386 -154 -201 -19 486 6 147 274 92 -96 338 190 133 94 129 113 79 -7 -289 -427 415 -618 SQ 20250516T113001.0Z 9267.479179 249 1 13.88 2 74.04 78.44 85.33 221.56 0.00 1 0.00 1 0 15 1.763e-03 1.757e-03 1.361e-04 1.360e-04 4.086725e+03 8.491932e+00 2.937670e+02 -6.000000e+00 9.806091e+01 280.26 -2.00 20.00 -2.00 505.28 0.00e+00 8.076228e-04 3.727945e-06 4.997920e-05 -6.000000e+00 4.926086e-05 280.26 -2.00 20.00 -2.00 500.48 0.00e+00 2.819536e-01 2.706149e-03 2.996829e-02 -6.000000e+00 3.524631e-02 230.87 -2.00 3.56 -2.00 502.07 0.00e+00 3.574 0.001 489.00 513.00 1 2.3894e+00 2.0727e-04 5.6690e-03 -6.0000e+00 2.7012e-03 2.8068e-03 5.3062e-05 7.6531e-04 -6.0000e+00 6.9816e-04 1.0586e-01 8.1903e-04 1.3843e-05 3.9857e-05 -6.0000e+00 1.8596e-04 -6.4908e-04 9.3687e-06 12 1 1 12 1 1 71.22 27.60 2.13 -0.00065 0.00503 401 580 1 4 0 34.510 35.75 20.00 27.60 23.40 3.7 940.39 31 -67 -71 61 11 221 360 246 236 238 208 138 -45 -88 -18 -16 75 70 47 -99 -5 208 185 174 228 149 23 -3 -134 -217 35 112 -85 -34 -95 -287 -120 61 8 -84 -33 -34 -29 39 121 98 88 46 -22 -173 -319 -240 -255 -265 -168 -214 -266 -160 -15 106 188 224 152 85 94 99 39 -47 -93 -197 -205 -3 -79 -181 -125 -231 -270 -88 -41 -128 -264 -188 -278 -269 -102 -119 -167 -163 -75 3 130 68 158 69 39 150 131 -91 -165 -255 -303 -208 -324 -292 -317 -500 -274 -35 1 68 78 -41 -2 126 269 320 394 370 230 90 228 249 165 269 206 -35 115 268 144 190 183 -60 -18 198 10 -38 180 62 -78 95 158 140 187 191 66 -43 -131 -215 -234 -179 -188 30 -65 -70 61 11 227 372 257 247 247 215 140 -45 -88 -18 -16 76 71 48 -103 -5 218 193 181 238 155 24 -3 -138 -220 35 112 -85 -35 -98 -298 -126 63 8 -86 -33 -34 -30 41 125 102 91 47 -22 -175 -319 -236 -250 -260 -166 -213 -270 -162 -15 108 191 229 155 87 96 100 39 -47 -92 -195 -200 -3 -78 -178 -124 -230 -265 -86 -39 -124 -256 -181 -271 -261 -100 -117 -165 -161 -74 3 129 68 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