File name: Pandora243s1_Toronto-CNTower_20250604_L2Fit_fout2c7d20250508p1-8.txt
File generation date: 20250821T075537.6Z
Data description: Level 2 spectral fitting results file
Data file version: fout2c7p1-8
Local principal investigator: Vitali Fioletov
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 243
Spectrometer number: 1
Processing software version used: BlickP v1.8.75
Instrument operation file used: Pandora243_OF_v3d20230125.txt
Instrument calibration file used: Pandora243s1_CF_v7d20250508.txt
Level 1 file used: Pandora243s1_Toronto-CNTower_20250604_L1_smca1c7d20250508p1-8.txt
Full location name: CN Tower Observation Pod Roof, 290 Bremner Blvd, Toronto, ON M5V 3L9
Short location name: Toronto-CNTower
Country of location: Canada
Location latitude [deg]: 43.6426
Location longitude [deg]: -79.3871
Location altitude [m]: 330
Local noon date: 20250604
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: None
First and last pixel inside fitting window: 197 339
Nominal wavelengths inside fitting window [nm]: 305.1143 305.2548 305.3953 305.5359 305.6764 305.8169 305.9573 306.0978 306.2383 306.3787 306.5192 306.6596 306.8000 306.9404 307.0808 307.2212 307.3615 307.5019 307.6422 307.7826 307.9229 308.0632 308.2035 308.3438 308.4841 308.6243 308.7646 308.9048 309.0451 309.1853 309.3255 309.4657 309.6059 309.7461 309.8863 310.0264 310.1666 310.3067 310.4468 310.5869 310.7270 310.8671 311.0072 311.1472 311.2873 311.4273 311.5674 311.7074 311.8474 311.9874 312.1274 312.2674 312.4073 312.5473 312.6872 312.8271 312.9671 313.1070 313.2469 313.3868 313.5266 313.6665 313.8063 313.9462 314.0860 314.2258 314.3656 314.5054 314.6452 314.7850 314.9247 315.0645 315.2042 315.3439 315.4837 315.6234 315.7630 315.9027 316.0424 316.1820 316.3217 316.4613 316.6010 316.7406 316.8802 317.0197 317.1593 317.2989 317.4384 317.5780 317.7175 317.8570 317.9965 318.1360 318.2755 318.4150 318.5545 318.6939 318.8334 318.9728 319.1122 319.2516 319.3910 319.5304 319.6698 319.8091 319.9485 320.0878 320.2271 320.3664 320.5057 320.6450 320.7843 320.9236 321.0628 321.2021 321.3413 321.4805 321.6197 321.7589 321.8981 322.0373 322.1765 322.3156 322.4547 322.5939 322.7330 322.8721 323.0112 323.1503 323.2893 323.4284 323.5675 323.7065 323.8455 323.9845 324.1235 324.2625 324.4015 324.5405 324.6794 324.8184 324.9573
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Ozone effective temperature [K]
Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Sulfur dioxide effective temperature [K]
Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 46: Lower limit used for wavelength scaling [nm]
Column 47: Upper limit used for wavelength scaling [nm]
Column 48: Order of smoothing polynomial
Column 49: Smoothing polynomial coefficient, order 0
Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 54: Smoothing polynomial coefficient, order 1
Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 59: Smoothing polynomial coefficient, order 2
Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 64: Smoothing polynomial coefficient, order 3
Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 69: Mean value of measured data inside fitting window [same units as measurements]
Column 70: Wavelength change polynomial coefficient, order 0
Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 84: Wavelength effective temperature [°C], 999=no effective temperature given
Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 88: Number of bright count cycles
Column 89: Number of dark count cycles
Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 93: Integration time [ms]
Column 94: Temperature at electronics board [°C], 999=no temperature signal
Column 95: Spectrometer control temperature [°C], 999=no temperature signal
Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 97: Temperature in head sensor [°C], 999=no temperature signal
Column 98: Humidity in head sensor [%], -9=no humidity signal
Column 99: Pressure in head sensor [hPa], -9=no pressure signal
Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SS 20250604T110231.4Z 9286.460086 142 1 30.18 2 77.01 71.19 133.66 333.22 0.00 1 0.00 1 0 17 2.240e-01 7.788e-03 1.925e-01 4.769e-03 5.820448e-01 2.523861e-03 6.743444e-03 -6.000000e+00 1.290167e-01 232.08 -2.00 3.56 -2.00 320.64 0.00e+00 2.521902e-03 9.878251e-04 1.269937e-03 -6.000000e+00 5.615877e-03 282.26 -2.00 20.00 -2.00 320.03 0.00e+00 4.333 0.001 302.00 328.00 3 3.5848e+00 7.7622e-03 5.2538e-02 -6.0000e+00 3.2398e-01 1.0075e-01 9.9526e-03 3.2120e-02 -6.0000e+00 3.5100e-01 -1.3821e-01 9.4125e-03 1.6831e-02 -6.0000e+00 2.0824e-01 5.2538e-02 4.6817e-03 5.5008e-03 -6.0000e+00 8.7674e-02 1.1748e-04 -5.2216e-04 1.3384e-04 6.3849e-05 -6.0000e+00 6.0009e-03 8.3337e-04 0.0000e+00 11 8 0 10 0 0 96.38 27.76 0.76 0.00083 -0.00309 25 25 1 5 0 1206.970 36.00 20.01 27.76 27.05 3.6 965.69 -9755 -20330 -82656 -42107 -65787 -15939 71331 -13963 -116977 -113375 -96584 -30319 -56030 -26255 -47209 -10988 -17724 -40392 -22046 -17357 -13432 9275 -6792 -23710 -12774 -14908 12297 -29860 -13550 -15577 -830 4792 7234 3498 -9002 10581 -14006 -5986 -1100 9833 -2024 2188 3128 2435 -5620 949 5251 -1259 3056 864 6658 1996 1077 1416 550 2719 2097 412 3468 -1454 2272 -132 732 2749 1161 226 1579 1758 1256 445 1128 822 1640 1002 -877 -1057 840 -1366 -87 -277 -831 -190 -518 -269 -644 765 -171 196 -127 284 1629 -27 -503 -1172 -939 -416 -791 223 -439 -280 -1089 -580 -853 -650 -498 -1405 -950 -731 270 318 290 -204 149 222 872 38 287 56 213 196 352 -264 419 1102 -56 -32 647 -1 1467 739 -219 102 -78 -372 -201 -573 -50 473 225 -7 -381 -667 36 -49 -129 -1013 -320 -584 -88 332 -104 -2720 -2689 -2021 -381 -1147 -501 -1361 -256 -486 -1522 -738 -581 -437 242 -221 -992 -511 -638 400 -1417 -542 -703 -38 243 407 210 -578 571 -1094 -518 -111 1047 -267 294 435 346 -878 142 762 -200 483 150 1211 421 249 352 145 726 576 114 903 -396 624 -41 256 1042 456 86 584 670 537 221 605 457 887 513 -416 -451 330 -559 -40 -149 -520 -122 -360 -197 -508 635 -150 176 -114 242 1268 -20 -357 -866 -775 -392 -860 274 -580 -363 -1326 -635 -867 -677 -560 -1679 -1193 -980 358 468 467 -344 248 352 1287 54 413 85 343 329 586 -427 651 1634 -80 -45 934 -1 2249 1269 -412 203 -149 -754 -436 -1311 -116 1115 530 -17 -818 -1359 71
SS 20250604T111248.9Z 9286.467233 145 1 29.68 2 75.24 72.82 134.46 336.49 0.00 1 0.00 1 0 17 1.689e-01 6.915e-03 6.354e-02 3.104e-03 5.234666e-01 1.602190e-03 6.033114e-03 -6.000000e+00 9.728040e-02 232.08 -2.00 3.56 -2.00 320.12 0.00e+00 2.318442e-03 5.331723e-04 4.395022e-04 -6.000000e+00 4.234143e-03 282.26 -2.00 20.00 -2.00 319.46 0.00e+00 3.846 0.001 302.00 328.00 3 3.4798e+00 4.7495e-03 4.6614e-02 -6.0000e+00 2.4429e-01 5.2889e-02 5.7823e-03 2.8195e-02 -6.0000e+00 2.6465e-01 -7.6657e-02 5.0267e-03 1.4242e-02 -6.0000e+00 1.5701e-01 2.8061e-02 2.5779e-03 4.8293e-03 -6.0000e+00 6.6113e-02 2.1896e-04 -4.0362e-04 8.7321e-05 4.8833e-05 -6.0000e+00 4.5243e-03 1.5136e-04 0.0000e+00 11 8 0 10 0 0 41.50 27.79 0.76 0.00015 -0.00288 33 33 1 5 0 899.370 36.00 19.99 27.79 27.36 3.5 967.26 -26321 -9541 -58470 -60529 -40138 -83568 -68987 -46112 -76346 -49054 -48455 -37409 -14337 -34353 -12226 -23371 -5950 -650 -5988 -11725 7894 -17252 2314 -5659 -2746 -6083 -13615 -10101 -13627 -2982 -6708 -1068 3678 -3267 -5160 -545 4745 895 -400 2566 -1914 -153 2213 4077 2113 783 258 -249 -524 1781 2762 2648 2445 1613 1783 -209 -100 1461 123 470 821 1984 2363 2299 334 218 -494 532 1265 1669 524 1372 402 -728 -788 -656 -1289 -1370 -816 -2303 -1318 -1757 -2083 -1266 -721 348 588 630 841 780 854 231 -342 -6 -835 -567 625 758 473 -714 -1098 -176 -1055 -186 -800 -1193 -773 -431 56 52 298 344 297 257 146 290 248 -344 27 -122 165 61 479 458 -210 258 481 735 965 180 -509 -28 204 -31 -156 105 -101 -163 162 91 -531 -402 40 -268 -101 -1044 -1026 -510 -1670 -1316 -796 -1987 -1025 -1041 -827 -312 -1133 -392 -962 -225 -25 -263 -571 320 -903 106 -303 -152 -365 -878 -599 -825 -177 -481 -83 309 -302 -458 -47 441 103 -57 419 -359 -30 439 807 432 165 55 -55 -118 417 709 749 750 537 619 -76 -37 532 44 168 307 735 980 1047 157 98 -218 238 624 941 325 874 254 -439 -434 -324 -598 -642 -425 -1425 -929 -1400 -1646 -1047 -637 325 574 631 837 742 751 207 -293 -5 -748 -579 721 912 609 -912 -1314 -205 -1152 -207 -974 -1535 -962 -569 80 81 471 562 477 392 225 426 368 -538 41 -198 265 95 778 715 -314 370 661 1045 1521 293 -902 -53 392 -58 -316 223 -219 -363 359 194 -1077 -774 80
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