File name: Pandora243s1_Toronto-CNTower_20250606_L2Fit_fwvt1c7d20250508p1-8.txt File generation date: 20250821T075442.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c7p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 243 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora243_OF_v3d20230125.txt Instrument calibration file used: Pandora243s1_CF_v7d20250508.txt Level 1 file used: Pandora243s1_Toronto-CNTower_20250606_L1_smca1c7d20250508p1-8.txt Full location name: CN Tower Observation Pod Roof, 290 Bremner Blvd, Toronto, ON M5V 3L9 Short location name: Toronto-CNTower Country of location: Canada Location latitude [deg]: 43.6426 Location longitude [deg]: -79.3871 Location altitude [m]: 330 Local noon date: 20250606 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1621 1771 Nominal wavelengths inside fitting window [nm]: 492.0313 492.1519 492.2725 492.3931 492.5137 492.6342 492.7548 492.8753 492.9958 493.1163 493.2368 493.3572 493.4776 493.5981 493.7185 493.8388 493.9592 494.0796 494.1999 494.3202 494.4405 494.5608 494.6811 494.8013 494.9216 495.0418 495.1620 495.2822 495.4023 495.5225 495.6426 495.7627 495.8828 496.0029 496.1230 496.2430 496.3630 496.4830 496.6030 496.7230 496.8430 496.9629 497.0829 497.2028 497.3227 497.4425 497.5624 497.6823 497.8021 497.9219 498.0417 498.1615 498.2812 498.4010 498.5207 498.6404 498.7601 498.8798 498.9994 499.1191 499.2387 499.3583 499.4779 499.5974 499.7170 499.8365 499.9561 500.0756 500.1951 500.3145 500.4340 500.5534 500.6728 500.7922 500.9116 501.0310 501.1503 501.2697 501.3890 501.5083 501.6276 501.7468 501.8661 501.9853 502.1045 502.2237 502.3429 502.4621 502.5812 502.7003 502.8195 502.9386 503.0576 503.1767 503.2957 503.4148 503.5338 503.6528 503.7717 503.8907 504.0096 504.1286 504.2475 504.3664 504.4852 504.6041 504.7229 504.8417 504.9605 505.0793 505.1981 505.3168 505.4356 505.5543 505.6730 505.7917 505.9103 506.0290 506.1476 506.2662 506.3848 506.5034 506.6220 506.7405 506.8591 506.9776 507.0961 507.2145 507.3330 507.4514 507.5699 507.6883 507.8067 507.9250 508.0434 508.1617 508.2800 508.3984 508.5166 508.6349 508.7532 508.8714 508.9896 509.1078 509.2260 509.3442 509.4623 509.5804 509.6986 509.8167 509.9347 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20250606T102833.1Z 9288.436494 147 1 31.51 2 82.64 65.52 128.80 294.66 0.00 1 0.00 1 0 22 5.313e-03 5.262e-03 1.940e-03 1.935e-03 7.206203e+03 1.276644e+02 4.767486e+02 -6.000000e+00 2.981503e+02 282.46 -2.00 20.00 -2.00 505.38 0.00e+00 1.294750e-03 5.362550e-05 7.800712e-05 -6.000000e+00 1.492653e-04 282.46 -2.00 20.00 -2.00 500.82 0.00e+00 5.722283e-01 3.801631e-02 5.742365e-02 -6.000000e+00 1.062437e-01 232.21 -2.00 3.56 -2.00 502.37 0.00e+00 7.213 0.007 489.00 513.00 1 7.4834e+00 2.9102e-03 1.1228e-02 -6.0000e+00 8.1482e-03 -4.9114e-02 7.3636e-04 1.4306e-03 -6.0000e+00 2.1046e-03 3.8160e-04 1.0227e-03 1.9417e-04 6.0662e-05 -6.0000e+00 5.6057e-04 -9.2649e-03 8.0290e-05 12 8 8 10 0 0 97.12 27.62 6.27 -0.00926 -0.00217 9 9 1 4 0 3500.970 36.00 20.00 27.62 24.78 3.6 949.26 -1190 -853 -577 202 186 444 951 945 492 400 581 142 -655 -900 -653 -321 -605 193 193 162 305 1078 177 250 601 641 234 280 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-1005 -736 -616 -288 -319 -389 -314 -426 166 -147 96 -80 67 729 877 657 1119 1206 885 209 387 536 403 409 9 584 495 330 389 411 303 199 -361 -347 -594 -409 -400 -93 303 300 269 328 299 482 109 -53 -502 -591 -552 -297 -927 SQ 20250606T103853.3Z 9288.443672 151 1 14.72 2 80.92 67.19 130.45 297.00 0.00 1 0.00 1 0 22 4.377e-03 4.353e-03 5.917e-04 5.910e-04 6.738944e+03 3.835116e+01 4.542827e+02 -6.000000e+00 2.456325e+02 282.47 -2.00 20.00 -2.00 505.35 0.00e+00 1.129051e-03 1.637072e-05 7.093632e-05 -6.000000e+00 1.229795e-04 282.47 -2.00 20.00 -2.00 500.79 0.00e+00 3.985868e-01 1.159902e-02 5.207186e-02 -6.000000e+00 8.755127e-02 232.21 -2.00 3.56 -2.00 502.34 0.00e+00 6.011 0.004 489.00 513.00 1 4.9544e+00 8.8815e-04 9.5280e-03 -6.0000e+00 6.7143e-03 -5.9393e-02 2.2525e-04 1.2962e-03 -6.0000e+00 1.7348e-03 5.7363e-03 1.2700e-03 5.9488e-05 6.0012e-05 -6.0000e+00 4.6187e-04 5.6348e-03 -2.8436e-05 12 9 1 12 1 1 42.07 27.62 5.47 0.00563 0.01444 26 55 1 4 0 545.150 35.75 20.00 27.62 24.75 3.6 949.52 -736 -646 -213 119 265 598 788 754 725 462 407 13 -44 -388 -272 -356 -159 -50 116 218 244 398 370 377 547 411 309 188 -220 -531 -563 -483 -506 -91 194 -156 17 93 -35 -168 -128 56 192 227 398 478 355 241 175 -280 -565 -714 -806 -692 -637 -284 -54 49 329 376 452 541 523 474 429 302 238 -3 -173 -484 -468 -327 -377 -363 -275 -299 -546 -628 -618 -695 -825 -573 -603 -669 -255 -347 -257 -435 -316 -13 -54 150 264 325 284 448 212 -72 -443 -754 -765 -831 -597 -488 -306 -280 -158 -181 -182 -206 -98 7 173 543 861 801 1132 1004 631 649 440 286 284 442 461 201 250 375 261 335 363 -83 -179 -86 -364 -468 -52 -64 34 270 261 291 352 327 174 99 -127 -344 -680 -447 -615 -683 -595 -201 114 257 581 780 755 715 461 401 12 -42 -377 -263 -345 -154 -49 115 220 244 398 371 380 553 417 313 189 -221 -521 -550 -472 -494 -90 197 -159 17 94 -35 -169 -129 57 193 231 408 485 360 246 176 -277 -555 -697 -777 -668 -618 -283 -54 49 331 378 454 546 531 482 435 303 240 -3 -170 -474 -462 -322 -368 -359 -275 -299 -542 -614 -597 -679 -795 -554 -589 -660 -250 -344 -256 -435 -316 -13 -55 150 267 329 286 442 208 -70 -423 -720 -725 -797 -578 -483 -309 -283 -160 -182 -182 -205 -98 7 176 555 885 829 1160 1037 656 669 454 292 287 444 466 205 255 383 267 341 368 -84 -178 -86 -365 -466 -52 -64 36 279 272 306 367 344 184 105 -133 -358 -698 -460 -626 SQ 20250606T104543.5Z 9288.448420 153 1 15.96 2 79.78 68.29 131.52 298.60 0.00 1 0.00 1 0 22 3.852e-03 3.832e-03 3.915e-04 3.911e-04 6.143895e+03 2.519273e+01 4.156157e+02 -6.000000e+00 2.161746e+02 282.47 -2.00 20.00 -2.00 505.34 0.00e+00 1.009616e-03 1.081878e-05 6.419288e-05 -6.000000e+00 1.082273e-04 282.47 -2.00 20.00 -2.00 500.76 0.00e+00 3.830972e-01 7.680443e-03 4.757568e-02 -6.000000e+00 7.704080e-02 232.21 -2.00 3.56 -2.00 502.31 0.00e+00 5.402 0.003 489.00 513.00 1 4.3340e+00 5.8806e-04 8.5891e-03 -6.0000e+00 5.9084e-03 -5.5370e-02 1.4943e-04 1.1804e-03 -6.0000e+00 1.5263e-03 1.1640e-02 9.9505e-04 3.9412e-05 5.3956e-05 -6.0000e+00 4.0647e-04 6.5362e-03 -2.4000e-05 12 9 1 12 1 1 25.96 27.63 4.55 0.00654 0.01344 55 105 1 4 0 284.940 35.75 20.00 27.63 24.92 3.6 949.93 -562 -610 -291 98 221 554 747 641 558 394 390 77 -155 -272 -293 -273 -140 58 109 137 201 453 294 358 476 362 307 118 -182 -481 -521 -369 -432 -63 32 -191 2 95 16 -93 -131 58 14 207 453 372 398 250 162 -212 -567 -565 -764 -680 -486 -240 -83 100 236 292 376 525 395 394 402 245 155 -65 -235 -387 -391 -386 -296 -270 -176 -262 -421 -422 -531 -538 -706 -524 -604 -482 -296 -305 -310 -263 -324 -139 43 142 246 260 324 314 251 -83 -382 -651 -806 -629 -596 -352 -209 -364 -201 -181 -223 -144 -29 17 204 465 723 709 938 912 716 384 391 304 297 406 334 141 304 364 253 307 223 -42 -163 -23 -351 -365 -57 -112 -24 240 270 222 326 377 210 80 -151 -314 -544 -468 -553 -523 -566 -277 95 217 546 740 642 560 394 384 76 -152 -263 -282 -263 -137 57 108 139 201 454 296 361 482 369 312 119 -182 -471 -508 -359 -427 -63 33 -195 2 96 16 -94 -131 58 14 211 459 379 405 256 163 -213 -556 -548 -742 -653 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