File name: Pandora243s1_Toronto-CNTower_20250612_L2Fit_fout2c7d20250508p1-8.txt File generation date: 20250821T080512.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c7p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 243 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora243_OF_v3d20230125.txt Instrument calibration file used: Pandora243s1_CF_v7d20250508.txt Level 1 file used: Pandora243s1_Toronto-CNTower_20250612_L1_smca1c7d20250508p1-8.txt Full location name: CN Tower Observation Pod Roof, 290 Bremner Blvd, Toronto, ON M5V 3L9 Short location name: Toronto-CNTower Country of location: Canada Location latitude [deg]: 43.6426 Location longitude [deg]: -79.3871 Location altitude [m]: 330 Local noon date: 20250612 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.1143 305.2548 305.3953 305.5359 305.6764 305.8169 305.9573 306.0978 306.2383 306.3787 306.5192 306.6596 306.8000 306.9404 307.0808 307.2212 307.3615 307.5019 307.6422 307.7826 307.9229 308.0632 308.2035 308.3438 308.4841 308.6243 308.7646 308.9048 309.0451 309.1853 309.3255 309.4657 309.6059 309.7461 309.8863 310.0264 310.1666 310.3067 310.4468 310.5869 310.7270 310.8671 311.0072 311.1472 311.2873 311.4273 311.5674 311.7074 311.8474 311.9874 312.1274 312.2674 312.4073 312.5473 312.6872 312.8271 312.9671 313.1070 313.2469 313.3868 313.5266 313.6665 313.8063 313.9462 314.0860 314.2258 314.3656 314.5054 314.6452 314.7850 314.9247 315.0645 315.2042 315.3439 315.4837 315.6234 315.7630 315.9027 316.0424 316.1820 316.3217 316.4613 316.6010 316.7406 316.8802 317.0197 317.1593 317.2989 317.4384 317.5780 317.7175 317.8570 317.9965 318.1360 318.2755 318.4150 318.5545 318.6939 318.8334 318.9728 319.1122 319.2516 319.3910 319.5304 319.6698 319.8091 319.9485 320.0878 320.2271 320.3664 320.5057 320.6450 320.7843 320.9236 321.0628 321.2021 321.3413 321.4805 321.6197 321.7589 321.8981 322.0373 322.1765 322.3156 322.4547 322.5939 322.7330 322.8721 323.0112 323.1503 323.2893 323.4284 323.5675 323.7065 323.8455 323.9845 324.1235 324.2625 324.4015 324.5405 324.6794 324.8184 324.9573 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250612T140604.9Z 9294.587556 360 1 3.11 2 44.11 101.66 128.07 264.72 0.00 1 0.00 1 0 17 1.231e-02 8.214e-03 1.028e-02 6.210e-03 1.990426e-01 3.195292e-03 2.443820e-03 -6.000000e+00 7.104261e-03 232.60 -2.00 3.56 -2.00 315.51 0.00e+00 3.656089e-04 2.998162e-04 7.071918e-05 -6.000000e+00 3.097114e-04 283.11 -2.00 20.00 -2.00 314.85 0.00e+00 1.391 0.000 302.00 328.00 3 5.0920e+00 8.3180e-03 1.7175e-02 -6.0000e+00 1.7858e-02 1.7375e-02 9.2373e-03 1.0568e-02 -6.0000e+00 1.9336e-02 5.0789e-03 5.2827e-03 5.1232e-03 -6.0000e+00 1.1472e-02 -2.4293e-03 2.3652e-03 1.4037e-03 -6.0000e+00 4.8294e-03 6.8099e-04 1.4007e-04 1.7367e-04 1.7361e-05 -6.0000e+00 3.2980e-04 -3.3739e-04 0.0000e+00 12 9 1 12 1 1 999.00 27.61 0.49 -0.00034 0.00072 1 19 1 5 0 1553.680 35.75 20.00 27.61 22.35 3.6 932.69 -2634 -809 -1387 2023 -4714 -1223 -3487 3146 673 -631 266 -2571 695 556 -2069 2139 -142 510 -333 2147 -96 2091 1666 873 642 390 1591 -2100 266 214 3099 1603 -1693 -1404 -3234 -3797 -1038 1389 268 -241 -2576 736 719 -651 -285 -1018 -1367 -811 -461 -127 732 692 1398 1214 602 280 721 -486 1036 44 765 113 1503 754 1074 -37 2631 306 1 -837 148 762 -145 -355 -93 -115 -934 395 -375 208 -428 -1909 -2477 -1128 -1222 181 -493 -408 -272 24 560 3 -38 -24 -518 -407 640 629 1454 -395 -663 -269 -511 -136 -907 -760 -375 173 399 632 605 1691 -1373 -11 -231 776 -69 571 956 -207 -141 -81 -102 583 -72 249 422 576 64 676 -324 401 -472 156 -1137 -410 132 282 102 -333 -109 -469 241 -701 -222 -378 521 -1160 -288 -910 861 206 -182 81 -766 224 202 -862 909 -58 214 -145 941 -43 910 751 417 320 200 784 -989 114 91 1356 756 -882 -720 -1558 -1859 -552 785 171 -177 -1929 550 550 -505 -219 -782 -1021 -620 -341 -94 569 535 1126 1024 521 247 641 -433 891 39 648 104 1464 731 1002 -33 2282 266 1 -799 151 800 -153 -359 -92 -101 -798 317 -321 187 -431 -2014 -2627 -1236 -1442 214 -617 -524 -348 30 656 3 -39 -23 -550 -449 773 795 1901 -510 -804 -316 -575 -161 -1114 -980 -479 229 552 880 878 2424 -1931 -15 -298 978 -84 720 1295 -289 -202 -114 -141 759 -93 307 518 709 80 890 -428 537 -645 219 -1644 -618 202 423 154 -516 -162 -681 340 SS 20250612T141513.9Z 9294.593911 366 1 31.54 2 42.49 103.63 129.65 266.15 0.00 1 0.00 1 0 17 2.677e-02 1.170e-02 2.063e-02 8.185e-03 2.122334e-01 4.149191e-03 2.612260e-03 -6.000000e+00 1.545265e-02 232.60 -2.00 3.56 -2.00 316.88 0.00e+00 9.305161e-04 5.278870e-04 1.486784e-04 -6.000000e+00 6.735523e-04 283.11 -2.00 20.00 -2.00 316.13 0.00e+00 1.355 0.000 302.00 328.00 3 7.3768e+00 1.0983e-02 1.7450e-02 -6.0000e+00 3.8844e-02 8.5216e-02 1.2283e-02 1.1359e-02 -6.0000e+00 4.2056e-02 -5.1659e-03 7.1834e-03 5.5262e-03 -6.0000e+00 2.4952e-02 -5.3452e-03 3.4202e-03 1.5963e-03 -6.0000e+00 1.0506e-02 6.8022e-05 -4.8318e-05 2.3418e-04 1.7461e-05 -6.0000e+00 7.1719e-04 -1.7108e-03 0.0000e+00 12 8 8 10 0 0 98.94 27.62 0.83 -0.00171 -0.00207 8 8 1 5 0 3941.900 36.00 19.99 27.62 22.14 3.7 931.65 -5259 -663 4763 11111 -13483 -9528 -9299 1720 -4969 -813 -4647 5106 1471 227 -6052 1045 2728 -1120 1973 -1094 4590 -919 5057 -849 -845 -2687 491 441 -2165 -885 1294 -1973 706 -3292 -5880 -2387 -3165 3469 677 654 176 -292 248 1730 5264 1697 1844 -622 -686 150 -580 1069 -1729 958 2396 -1912 2280 861 -6 -1226 1319 483 1072 1251 1051 364 426 -732 -841 -1185 409 663 -1228 -731 -2195 -974 -4284 -1272 -3052 -1909 -2075 -2287 -1087 -114 -105 747 1677 386 1255 -578 -581 -687 -684 -835 852 1265 1865 1661 665 -676 -722 -88 -732 -706 -2418 -118 -1114 547 996 938 786 631 829 920 271 -1130 -1163 -1380 -786 625 1228 -384 1839 -184 90 246 -919 -1757 455 856 57 -274 -363 -348 -632 -125 307 -387 798 346 -861 -137 278 -824 -105 705 1387 -1918 -1286 -1350 275 -840 -147 -850 884 297 52 -1672 287 753 -332 584 -344 1367 -285 1522 -284 -293 -974 168 139 -655 -264 400 -671 250 -1201 -2028 -800 -1190 1429 342 377 109 -187 162 1113 3252 1079 1135 -379 -407 89 -366 703 -1224 690 1733 -1464 1693 641 -5 -913 996 395 940 1147 935 296 320 -545 -675 -1078 396 661 -1237 -702 -1975 -773 -3173 -871 -2247 -1561 -1891 -2285 -1133 -123 -122 833 2140 512 1647 -737 -679 -730 -661 -784 833 1354 2196 2158 912 -912 -910 -101 -810 -819 -3102 -155 -1545 779 1475 1470 1172 942 1293 1322 358 -1420 -1463 -1821 -1109 930 1852 -581 2652 -258 119 309 -1105 -2138 575 1145 80 -395 -531 -527 -1018 -210 527 -685 1402 594 -1446 -221 436 SS 20250612T142028.9Z 9294.597556 369 1 29.91 2 41.57 104.79 130.55 266.98 0.00 1 0.00 1 0 17 9.826e-03 5.818e-03 5.211e-03 2.569e-03 1.989744e-01 1.310845e-03 2.411614e-03 -6.000000e+00 5.670666e-03 232.60 -2.00 3.56 -2.00 316.24 0.00e+00 2.508730e-04 1.432136e-04 5.148784e-05 -6.000000e+00 2.472395e-04 283.11 -2.00 20.00 -2.00 315.52 0.00e+00 1.335 0.000 302.00 328.00 3 5.8651e+00 3.4382e-03 1.6750e-02 -6.0000e+00 1.4254e-02 3.8095e-02 3.8326e-03 1.0522e-02 -6.0000e+00 1.5435e-02 -2.3051e-03 2.2039e-03 5.1039e-03 -6.0000e+00 9.1574e-03 -2.9761e-03 1.0184e-03 1.3989e-03 -6.0000e+00 3.8545e-03 3.2965e-04 -1.1337e-05 7.2816e-05 1.6594e-05 -6.0000e+00 2.6328e-04 5.8533e-04 0.0000e+00 10 0 0 10 0 0 99.99 27.62 0.50 0.00059 0.00050 45 45 1 5 0 664.490 36.00 19.99 27.62 22.20 3.7 932.48 -2445 -3906 -1520 989 -2140 2267 -2086 2267 881 -738 -3180 -121 -376 1231 -476 -327 -648 -64 1473 225 1172 2261 716 2178 326 43 -295 575 -860 541 1312 1087 399 -221 -2512 -2521 -594 -494 -1317 194 -573 -1014 -1075 217 -735 206 -968 -1005 -881 573 38 475 607 646 784 1040 1330 872 322 107 1041 1018 1905 965 875 216 -1184 0 362 -40 290 29 607 -51 -965 -1320 -724 -592 -990 -65 -893 -928 -1708 -1237 -1188 -12 -10 279 340 844 95 -190 -111 113 -261 381 -27 971 493 -477 -688 -43 -420 -368 -216 -885 -408 -80 10 140 692 370 360 -319 -222 -86 223 102 -105 -4 188 -89 261 706 566 17 197 -42 267 230 -28 212 100 -149 38 41 -21 47 -32 21 -397 -331 -374 -516 -880 -329 187 -373 374 -389 454 195 -169 -722 -28 -96 350 -153 -112 -227 -23 535 85 441 831 276 869 138 19 -125 223 -314 194 491 433 171 -94 -1008 -1021 -263 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