File name: Pandora243s1_Toronto-CNTower_20250727_L2Fit_fout2c3d20240624p1-8.txt File generation date: 20250728T053800.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 243 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora243_OF_v3d20230125.txt Instrument calibration file used: Pandora243s1_CF_v3d20240624.txt Level 1 file used: Pandora243s1_Toronto-CNTower_20250727_L1_smca1c3d20240624p1-8.txt Full location name: CN Tower Observation Pod Roof, 290 Bremner Blvd, Toronto, ON M5V 3L9 Short location name: Toronto-CNTower Country of location: Canada Location latitude [deg]: 43.6426 Location longitude [deg]: -79.3871 Location altitude [m]: 330 Local noon date: 20250727 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.1162 305.2567 305.3973 305.5378 305.6783 305.8188 305.9592 306.0997 306.2401 306.3806 306.5210 306.6614 306.8018 306.9422 307.0826 307.2230 307.3634 307.5037 307.6441 307.7844 307.9247 308.0650 308.2053 308.3456 308.4859 308.6261 308.7664 308.9066 309.0469 309.1871 309.3273 309.4675 309.6077 309.7479 309.8880 310.0282 310.1683 310.3084 310.4486 310.5887 310.7288 310.8688 311.0089 311.1490 311.2890 311.4291 311.5691 311.7091 311.8491 311.9891 312.1291 312.2691 312.4090 312.5490 312.6889 312.8289 312.9688 313.1087 313.2486 313.3884 313.5283 313.6682 313.8080 313.9479 314.0877 314.2275 314.3673 314.5071 314.6469 314.7866 314.9264 315.0662 315.2059 315.3456 315.4853 315.6250 315.7647 315.9044 316.0441 316.1837 316.3234 316.4630 316.6026 316.7422 316.8818 317.0214 317.1610 317.3006 317.4401 317.5796 317.7192 317.8587 317.9982 318.1377 318.2772 318.4167 318.5561 318.6956 318.8350 318.9744 319.1139 319.2533 319.3927 319.5320 319.6714 319.8108 319.9501 320.0895 320.2288 320.3681 320.5074 320.6467 320.7860 320.9252 321.0645 321.2037 321.3430 321.4822 321.6214 321.7606 321.8998 322.0390 322.1781 322.3173 322.4564 322.5956 322.7347 322.8738 323.0129 323.1520 323.2910 323.4301 323.5691 323.7082 323.8472 323.9862 324.1252 324.2642 324.4032 324.5422 324.6811 324.8201 324.9590 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250727T104517.8Z 9339.448123 78 1 30.09 2 83.66 69.59 112.17 51.54 0.00 1 0.00 1 0 33 7.295e-01 5.182e-02 5.202e-01 4.441e-02 8.686605e-01 2.649801e-02 9.966639e-03 -6.000000e+00 4.336546e-01 232.51 -2.00 3.56 -2.00 322.08 0.00e+00 -4.517276e-03 1.359661e-02 6.052972e-03 -6.000000e+00 2.186013e-02 286.45 -2.00 20.00 -2.00 321.57 0.00e+00 8.162 0.010 302.00 328.00 3 1.5280e+00 9.9550e-02 1.0014e-01 -6.0000e+00 1.0983e+00 1.3052e+00 1.2184e-01 7.0896e-02 -6.0000e+00 1.1993e+00 -1.5738e+00 8.2850e-02 2.5342e-02 -6.0000e+00 6.9913e-01 6.2847e-01 4.1590e-02 9.9904e-03 -6.0000e+00 2.9429e-01 1.6606e-05 -2.1149e-03 1.2846e-03 9.3101e-05 -6.0000e+00 2.1098e-02 -2.7181e-03 0.0000e+00 12 9 8 11 8 0 99.77 27.86 2.01 -0.00272 -0.01861 14 14 1 5 0 2148.780 36.00 20.00 27.86 29.16 3.5 978.28 37878 -45203 900000 -24931 900000 100532 -135731 69909 900000 900000 73128 12809 900000 900000 30756 39904 251860 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900000 5128 -397 4840 2042 1879 886 2281 -7543 14566 3340 15194 4633 545 3531 4289 5590 4470 -3975 5239 5502 3635 535 1225 5253 -501 5651 6852 8700 4788 2979 4644 1128 5159 1702 393 -5446 2395 5293 -6249 1135 5927 -323 -1262 2651 -2562 2888 -4233 -4605 -2891 -2897 378 5413 -6731 387 -1446 -7529 -9521 6539 -605 -459 -8049 -6258 2648 -43 -1722 8225 -7144 4877 1154 6757 845 -5149 -1859 1373 -3291 2185 5241 4698 6827 -2685 -83 -2900 -5713 7066 -4405 6206 -5919 6354 5836 3471 1318 2853 -5626 -6754 -1776 -3260 3517 2968 3174 -4725 SS 20250727T105518.6Z 9339.455077 81 1 30.23 2 81.96 71.24 110.82 53.64 0.00 1 0.00 1 0 25 5.751e-01 1.367e-02 2.411e-01 6.204e-03 7.798796e-01 3.421314e-03 9.026446e-03 -6.000000e+00 3.330414e-01 232.51 -2.00 3.56 -2.00 321.69 0.00e+00 8.593216e-03 1.923401e-03 2.164611e-03 -6.000000e+00 1.494519e-02 286.45 -2.00 20.00 -2.00 321.13 0.00e+00 6.681 0.006 302.00 328.00 3 7.6976e-01 1.3088e-02 7.7715e-02 -6.0000e+00 8.3535e-01 4.4330e-01 1.8594e-02 4.4245e-02 -6.0000e+00 9.0442e-01 -5.4241e-01 1.8160e-02 2.4843e-02 -6.0000e+00 5.3722e-01 2.0542e-01 8.2966e-03 1.1311e-02 -6.0000e+00 2.2661e-01 1.7786e-04 -7.0254e-04 1.6663e-04 1.5547e-04 -6.0000e+00 1.5471e-02 -1.8227e-03 0.0000e+00 12 8 8 10 0 0 61.32 27.87 1.04 -0.00182 -0.00710 46 46 1 5 0 657.110 36.00 20.00 27.87 29.36 3.5 979.08 -178994 -210053 -203104 -207742 900000 -235002 -190390 -198268 -194569 -97434 -185614 -40531 -11279 -101061 900000 -42277 -42903 192 -99555 -69989 -45443 -3398 -39891 22384 -23778 7935 -99068 -71610 -73050 -21923 -30383 8087 31095 -45013 33823 37949 52419 3500 5328 11427 -4368 13800 18730 26901 12150 8410 15846 13449 3508 14006 15737 11562 12942 18828 11965 7384 15593 5915 6005 10477 7984 8829 10602 11895 11167 9787 7069 3007 3086 5461 5710 4762 623 1526 -1855 695 -2143 -788 776 -2316 -534 -260 -776 -1517 249 -568 399 -292 633 1138 -867 -24 -2456 -2123 -2033 574 -1865 143 -776 -1611 -1285 -326 -828 -2425 -953 -1771 -1706 -1021 -1648 647 541 477 99 309 604 44 -632 -442 -110 -713 703 718 1128 993 656 576 1314 584 327 613 512 189 240 53 217 -490 -28 57 172 -296 -330 -370 -627 -1968 -3580 -3350 -3312 900000 -4393 -2408 -2943 -2995 -589 -2857 -245 -68 -1445 900000 -511 -590 2 -2846 -1539 -775 -41 -724 230 -403 101 -3655 -1949 -2076 -438 -827 181 639 -2042 655 711 951 123 222 525 -259 726 986 1334 713 529 958 878 269 1059 1323 1133 1370 2038 1454 969 1914 783 766 1267 1043 1287 1757 2209 2181 1906 1432 669 773 1539 1747 1512 200 450 -509 167 -507 -194 220 -818 -218 -122 -399 -832 144 -351 255 -193 411 703 -508 -13 -1359 -1247 -1376 447 -1589 138 -823 -1709 -1266 -284 -726 -2192 -832 -1644 -1681 -1086 -1965 860 808 760 161 484 899 64 -940 -692 -183 -1226 1165 1137 1715 1459 931 793 1752 837 542 1059 982 392 527 125 548 -1210 -71 145 435 -715 -808 -848 -1391 SS 20250727T121603.3Z 9339.511150 128 1 5.65 2 67.72 84.42 98.69 69.13 0.00 1 0.00 1 0 17 6.921e-02 1.240e-02 6.291e-02 1.001e-02 3.344929e-01 5.076517e-03 3.950391e-03 -6.000000e+00 3.994323e-02 232.51 -2.00 3.56 -2.00 318.31 0.00e+00 -1.581566e-04 9.633914e-04 1.712936e-04 -6.000000e+00 1.765954e-03 286.45 -2.00 20.00 -2.00 317.49 0.00e+00 2.615 0.000 302.00 328.00 3 4.2359e+00 1.3816e-02 3.0951e-02 -6.0000e+00 1.0027e-01 7.6898e-03 1.5701e-02 1.7827e-02 -6.0000e+00 1.0850e-01 -3.1709e-03 1.0241e-02 8.5935e-03 -6.0000e+00 6.4509e-02 -3.8009e-03 5.2979e-03 2.3307e-03 -6.0000e+00 2.7255e-02 4.1212e-04 2.7171e-04 2.8581e-04 2.4281e-05 -6.0000e+00 1.8543e-03 -3.5780e-03 0.0000e+00 12 9 9 12 1 1 999.00 27.87 0.71 -0.00358 -0.00154 1 11 1 5 0 2825.220 36.00 20.00 27.87 30.20 3.5 986.00 1992 4348 -18400 17223 1338 48268 -12758 -11696 29876 17567 11216 5037 -14364 15334 -3417 -214 -2310 -3502 5739 -2870 2354 -5324 22799 2928 1174 -6617 -3532 8823 -4124 -1010 -455 -8049 11513 1808 -7981 10105 -2582 4191 -5151 -3108 -2057 658 -519 1941 -2628 1157 2198 -55 -2629 -1313 -2275 1820 1483 2508 2658 -2901 -861 -167 447 5163 612 -2361 729 -217 2530 -5264 807 1720 3184 1833 642 641 -229 135 473 -1379 -2926 -2405 -1229 777 771 -2486 -311 -1649 -686 -916 1482 1456 1644 1244 1002 133 -1038 -653 61 304 -1229 1075 -142 -769 -1290 -826 -497 -987 -558 609 -650 -1001 -675 2245 -303 -101 1356 -684 477 888 -407 -2 161 -818 437 -162 446 293 398 -1040 974 222 -177 616 -1129 572 571 -507 91 -769 -536 1250 832 177 -519 -710 -158 105 242 -1294 774 64 1461 -785 -811 1517 1047 712 369 -1487 1378 -427 -28 -329 -533 835 -474 372 -910 3095 520 225 -1422 -724 1491 -753 -184 -91 -1902 2451 425 -1933 2082 -681 1228 -1825 -1250 -886 288 -237 869 -1232 523 968 -25 -1195 -608 -1147 950 827 1467 1605 -1743 -516 -99 280 3080 365 -1579 518 -166 1853 -3856 528 1116 2228 1481 526 544 -194 118 377 -1005 -1984 -1583 -865 613 686 -2338 -305 -1723 -764 -1016 1685 1702 1911 1386 1110 136 -999 -622 62 346 -1479 1408 -198 -1052 -1658 -968 -593 -1147 -702 797 -903 -1371 -977 3396 -468 -157 2147 -1032 656 1235 -576 -3 238 -1296 693 -253 676 424 586 -1486 1301 304 -246 918 -1813 934 954 -839 159 -1429 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