File name: Pandora243s1_Toronto-CNTower_20250816_L2Fit_fout2c7d20250508p1-8.txt File generation date: 20250821T084446.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c7p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 243 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora243_OF_v3d20230125.txt Instrument calibration file used: Pandora243s1_CF_v7d20250508.txt Level 1 file used: Pandora243s1_Toronto-CNTower_20250816_L1_smca1c7d20250508p1-8.txt Full location name: CN Tower Observation Pod Roof, 290 Bremner Blvd, Toronto, ON M5V 3L9 Short location name: Toronto-CNTower Country of location: Canada Location latitude [deg]: 43.6426 Location longitude [deg]: -79.3871 Location altitude [m]: 330 Local noon date: 20250816 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.1143 305.2548 305.3953 305.5359 305.6764 305.8169 305.9573 306.0978 306.2383 306.3787 306.5192 306.6596 306.8000 306.9404 307.0808 307.2212 307.3615 307.5019 307.6422 307.7826 307.9229 308.0632 308.2035 308.3438 308.4841 308.6243 308.7646 308.9048 309.0451 309.1853 309.3255 309.4657 309.6059 309.7461 309.8863 310.0264 310.1666 310.3067 310.4468 310.5869 310.7270 310.8671 311.0072 311.1472 311.2873 311.4273 311.5674 311.7074 311.8474 311.9874 312.1274 312.2674 312.4073 312.5473 312.6872 312.8271 312.9671 313.1070 313.2469 313.3868 313.5266 313.6665 313.8063 313.9462 314.0860 314.2258 314.3656 314.5054 314.6452 314.7850 314.9247 315.0645 315.2042 315.3439 315.4837 315.6234 315.7630 315.9027 316.0424 316.1820 316.3217 316.4613 316.6010 316.7406 316.8802 317.0197 317.1593 317.2989 317.4384 317.5780 317.7175 317.8570 317.9965 318.1360 318.2755 318.4150 318.5545 318.6939 318.8334 318.9728 319.1122 319.2516 319.3910 319.5304 319.6698 319.8091 319.9485 320.0878 320.2271 320.3664 320.5057 320.6450 320.7843 320.9236 321.0628 321.2021 321.3413 321.4805 321.6197 321.7589 321.8981 322.0373 322.1765 322.3156 322.4547 322.5939 322.7330 322.8721 323.0112 323.1503 323.2893 323.4284 323.5675 323.7065 323.8455 323.9845 324.1235 324.2625 324.4015 324.5405 324.6794 324.8184 324.9573 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250816T110623.0Z 9359.462767 228 1 28.86 2 83.42 77.50 19.77 176.49 0.00 1 0.00 1 0 17 6.136e-01 5.529e-02 5.119e-01 4.841e-02 8.194792e-01 2.867838e-02 9.258580e-03 -6.000000e+00 3.669214e-01 231.73 -2.00 3.56 -2.00 321.89 0.00e+00 -3.951478e-03 1.392749e-02 5.717146e-03 -6.000000e+00 1.906735e-02 286.77 -2.00 20.00 -2.00 321.31 0.00e+00 7.921 0.009 302.00 328.00 3 2.5971e+00 1.0523e-01 9.5236e-02 -6.0000e+00 9.2425e-01 1.3242e+00 1.3396e-01 6.7142e-02 -6.0000e+00 1.0090e+00 -1.4121e+00 9.5025e-02 2.6378e-02 -6.0000e+00 5.9239e-01 5.0575e-01 4.5297e-02 7.4328e-03 -6.0000e+00 2.5109e-01 7.1899e-06 4.0804e-04 1.3866e-03 8.8830e-05 -6.0000e+00 1.8050e-02 1.0137e-03 0.0000e+00 12 8 8 10 0 0 -8.76 28.08 3.00 0.00101 0.00408 10 10 1 5 0 2885.330 36.25 20.00 28.08 32.32 3.4 999.21 900000 74884 12166 900000 900000 -107548 900000 -37573 900000 77167 900000 -58748 76116 900000 900000 900000 27428 20662 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900000 3352 -2213 5922 6810 4282 7615 8888 1048 4930 2522 4134 4162 4185 2391 3109 -6521 74 6758 -5375 3643 2380 5582 -2875 5086 2574 4264 1149 8280 7022 3850 -5196 -3724 1280 -6699 -14645 -269 7151 2867 -742 2642 646 10102 6415 -5105 -5706 -1185 -8584 -3819 498 -8333 11825 -505 -1123 1529 -2354 -6843 -1613 -2474 7086 -4695 -248 4078 -5677 2426 2976 -420 3916 3526 -3806 -20 -893 1756 90 6044 -16240 -683 6048 4237 -2090 12095 9096 2293 -10542 -3129 2517 6087 -2570 -555 1375 -148 1445 368 -2391 385 3418 -6648 -2 499 SS 20250816T111647.1Z 9359.469990 231 1 30.25 2 81.58 79.25 19.74 183.35 0.00 1 0.00 1 0 25 5.986e-01 1.662e-02 3.268e-01 9.592e-03 7.516244e-01 5.326454e-03 8.729670e-03 -6.000000e+00 3.463968e-01 231.73 -2.00 3.56 -2.00 321.68 0.00e+00 4.525025e-03 2.936166e-03 3.845465e-03 -6.000000e+00 1.625376e-02 286.77 -2.00 20.00 -2.00 321.11 0.00e+00 6.421 0.005 302.00 328.00 3 2.3934e+00 1.9696e-02 7.5904e-02 -6.0000e+00 8.6933e-01 4.0123e-01 2.8250e-02 4.6545e-02 -6.0000e+00 9.4273e-01 -4.8245e-01 2.7541e-02 2.5222e-02 -6.0000e+00 5.6116e-01 1.7855e-01 1.2620e-02 7.9595e-03 -6.0000e+00 2.3856e-01 4.6481e-05 -1.8413e-04 2.6153e-04 1.1456e-04 -6.0000e+00 1.6347e-02 -9.6954e-05 0.0000e+00 12 8 8 10 0 0 25.94 28.08 1.58 -0.00010 -0.00148 27 27 1 5 0 1120.160 36.25 20.00 28.08 32.66 3.4 1001.32 -153851 900000 -221184 900000 -221440 -215993 -148192 102123 -221986 -147874 -200347 900000 -52790 -101732 -89067 -62640 -46008 900000 2286 -81187 261650 -28177 71972 -89749 8501 -42887 -61189 -95662 15517 -15621 119709 -20564 -17732 35099 -50682 30601 9518 -11031 25089 11262 -4954 1093 8284 42507 43835 1127 14892 4758 18385 3199 -1202 15353 30344 13713 29581 20046 13107 11836 14652 -1369 14476 4225 9263 5829 16125 8723 3845 -4830 893 6080 9677 11487 2230 3033 2131 3890 -251 -2627 -2369 -2717 922 -3799 -251 -2960 -3081 2050 797 1651 498 -907 -1689 -2556 4399 -3717 -2705 -1498 -661 767 -286 -2493 -430 -1052 -2119 -2704 -1026 -61 -3192 -146 -1289 742 421 -492 365 525 112 -244 479 192 931 -209 1409 -674 950 1529 -154 1382 965 -125 392 1486 701 711 -213 -146 -480 -104 -228 -101 118 102 -848 59 -408 -1438 900000 -4699 900000 -3951 -3671 -1385 955 -5282 -1759 -4256 900000 -493 -1642 -1589 -1011 -704 900000 25 -2139 2446 -431 673 -2898 108 -948 -1773 -3755 203 -321 1119 -654 -630 755 -2416 658 285 -485 938 568 -324 72 527 1947 2008 81 960 356 1272 281 -125 1507 2808 1628 3152 2436 1740 1560 1808 -196 1854 671 1610 1182 3060 1745 816 -1178 232 1728 2886 3457 715 896 572 920 -59 -666 -695 -962 370 -1829 -127 -1632 -1823 1224 504 1057 320 -564 -985 -1419 2237 -2178 -1803 -1158 -593 782 -318 -2801 -441 -970 -1807 -2366 -952 -59 -3386 -163 -1615 941 599 -749 554 772 156 -332 660 279 1427 -334 2171 -1014 1359 2097 -228 1946 1330 -185 605 2577 1354 1476 -471 -345 -1224 -255 -570 -256 297 266 -2091 136 -910 SS 20250816T113115.1Z 9359.480035 236 1 30.13 2 79.00 81.68 20.06 192.77 0.00 1 0.00 1 0 17 3.337e-01 7.582e-03 7.569e-02 2.578e-03 6.186706e-01 1.358932e-03 7.137331e-03 -6.000000e+00 1.919793e-01 231.73 -2.00 3.56 -2.00 320.73 0.00e+00 2.240058e-03 5.694295e-04 1.278412e-03 -6.000000e+00 8.525855e-03 286.77 -2.00 20.00 -2.00 320.07 0.00e+00 5.052 0.002 302.00 328.00 3 2.0135e+00 4.3481e-03 5.9147e-02 -6.0000e+00 4.8093e-01 8.5028e-02 5.6584e-03 3.3998e-02 -6.0000e+00 5.2078e-01 -1.3959e-01 5.2780e-03 1.7356e-02 -6.0000e+00 3.0989e-01 5.2528e-02 2.5965e-03 5.3083e-03 -6.0000e+00 1.3112e-01 2.8986e-04 -5.5834e-04 7.0630e-05 6.5422e-05 -6.0000e+00 8.9398e-03 9.9151e-04 0.0000e+00 11 8 0 10 0 0 -11.82 27.99 0.80 0.00099 -0.00320 76 76 1 5 0 396.400 36.25 19.99 27.99 33.52 3.4 1007.69 -137171 -104667 -72448 -134191 -145205 -145819 -87172 -65735 -98343 -86497 -77399 -59075 -65606 -47615 -34290 -42538 -21234 -10389 12643 -15980 -43357 -10858 13181 -16011 -33522 -14490 -32492 -23268 -26737 -11649 -4709 1559 -4017 -2675 -8029 -14502 -7639 -9854 -4456 4850 1693 871 1689 2149 3478 2771 5508 731 -2462 -387 637 3968 2639 2437 3220 2842 2176 1601 -475 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