File name: Pandora243s1_Toronto-CNTower_20250913_L2Fit_fout2c7d20250508p1-8.txt
File generation date: 20251204T191637.2Z
Data description: Level 2 spectral fitting results file
Data file version: fout2c7p1-8
Local principal investigator: Vitali Fioletov
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 243
Spectrometer number: 1
Processing software version used: BlickP v1.8.75
Instrument operation file used: Pandora243_OF_v3d20230125.txt
Instrument calibration file used: Pandora243s1_CF_v7d20250508.txt
Level 1 file used: Pandora243s1_Toronto-CNTower_20250913_L1_smca1c7d20250508p1-8.txt
Full location name: CN Tower Observation Pod Roof, 290 Bremner Blvd, Toronto, ON M5V 3L9
Short location name: Toronto-CNTower
Country of location: Canada
Location latitude [deg]: 43.6426
Location longitude [deg]: -79.3871
Location altitude [m]: 330
Local noon date: 20250913
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: None
First and last pixel inside fitting window: 197 339
Nominal wavelengths inside fitting window [nm]: 305.1143 305.2548 305.3953 305.5359 305.6764 305.8169 305.9573 306.0978 306.2383 306.3787 306.5192 306.6596 306.8000 306.9404 307.0808 307.2212 307.3615 307.5019 307.6422 307.7826 307.9229 308.0632 308.2035 308.3438 308.4841 308.6243 308.7646 308.9048 309.0451 309.1853 309.3255 309.4657 309.6059 309.7461 309.8863 310.0264 310.1666 310.3067 310.4468 310.5869 310.7270 310.8671 311.0072 311.1472 311.2873 311.4273 311.5674 311.7074 311.8474 311.9874 312.1274 312.2674 312.4073 312.5473 312.6872 312.8271 312.9671 313.1070 313.2469 313.3868 313.5266 313.6665 313.8063 313.9462 314.0860 314.2258 314.3656 314.5054 314.6452 314.7850 314.9247 315.0645 315.2042 315.3439 315.4837 315.6234 315.7630 315.9027 316.0424 316.1820 316.3217 316.4613 316.6010 316.7406 316.8802 317.0197 317.1593 317.2989 317.4384 317.5780 317.7175 317.8570 317.9965 318.1360 318.2755 318.4150 318.5545 318.6939 318.8334 318.9728 319.1122 319.2516 319.3910 319.5304 319.6698 319.8091 319.9485 320.0878 320.2271 320.3664 320.5057 320.6450 320.7843 320.9236 321.0628 321.2021 321.3413 321.4805 321.6197 321.7589 321.8981 322.0373 322.1765 322.3156 322.4547 322.5939 322.7330 322.8721 323.0112 323.1503 323.2893 323.4284 323.5675 323.7065 323.8455 323.9845 324.1235 324.2625 324.4015 324.5405 324.6794 324.8184 324.9573
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Ozone effective temperature [K]
Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Sulfur dioxide effective temperature [K]
Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 46: Lower limit used for wavelength scaling [nm]
Column 47: Upper limit used for wavelength scaling [nm]
Column 48: Order of smoothing polynomial
Column 49: Smoothing polynomial coefficient, order 0
Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 54: Smoothing polynomial coefficient, order 1
Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 59: Smoothing polynomial coefficient, order 2
Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 64: Smoothing polynomial coefficient, order 3
Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 69: Mean value of measured data inside fitting window [same units as measurements]
Column 70: Wavelength change polynomial coefficient, order 0
Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 84: Wavelength effective temperature [°C], 999=no effective temperature given
Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 88: Number of bright count cycles
Column 89: Number of dark count cycles
Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 93: Integration time [ms]
Column 94: Temperature at electronics board [°C], 999=no temperature signal
Column 95: Spectrometer control temperature [°C], 999=no temperature signal
Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 97: Temperature in head sensor [°C], 999=no temperature signal
Column 98: Humidity in head sensor [%], -9=no humidity signal
Column 99: Pressure in head sensor [hPa], -9=no pressure signal
Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SS 20250913T161951.2Z 9387.680454 427 1 30.09 2 41.84 159.76 72.30 290.29 0.00 1 0.00 1 0 17 7.065e-03 5.279e-03 1.416e-03 9.202e-04 1.774470e-01 4.681415e-04 2.192815e-03 -6.000000e+00 4.027155e-03 229.15 -2.00 3.56 -2.00 315.22 0.00e+00 2.229965e-04 4.225172e-05 2.006958e-05 -6.000000e+00 1.786950e-04 284.36 -2.00 20.00 -2.00 314.56 0.00e+00 1.341 0.000 302.00 328.00 3 4.3322e+00 1.2053e-03 1.5939e-02 -6.0000e+00 1.0033e-02 9.6811e-03 1.3428e-03 9.2946e-03 -6.0000e+00 1.0890e-02 2.6286e-03 7.6776e-04 4.5498e-03 -6.0000e+00 6.4846e-03 -3.9846e-03 3.4159e-04 1.2691e-03 -6.0000e+00 2.7535e-03 1.6115e-03 -7.8792e-05 2.5623e-05 1.6067e-05 -6.0000e+00 1.8914e-04 -1.0441e-03 0.0000e+00 10 0 0 10 0 0 99.98 27.83 0.59 -0.00104 -0.00164 82 82 1 5 0 366.930 36.00 20.00 27.83 29.74 3.6 984.55 -525 -548 -1126 -2126 -2344 -1639 568 969 507 -591 -726 -890 280 485 67 195 259 231 819 733 442 886 923 1353 485 -14 -50 -80 245 561 1728 1490 82 -524 -1979 -2142 -617 -367 -474 -323 -679 -858 -584 -612 -272 -420 -850 -595 -703 337 611 773 652 871 702 710 154 579 456 505 786 990 1502 1032 190 -481 -433 608 386 272 299 159 202 -80 -210 -534 -309 -203 -182 -575 -814 -1236 -1673 -1525 -1031 -251 -159 66 328 520 2 -2 486 321 365 174 468 689 309 -361 -687 -156 -57 -320 -406 -635 -659 -385 -25 131 335 295 190 139 264 131 -47 32 54 -70 -87 -104 148 575 394 250 460 554 700 286 -122 50 108 17 -46 -84 -25 45 2 -203 -461 -368 -269 -168 -169 -343 -640 -629 -431 158 300 172 -206 -245 -311 98 190 29 90 122 111 373 344 209 411 440 674 253 -8 -26 -39 118 267 850 717 43 -270 -1033 -1128 -329 -229 -327 -238 -534 -696 -483 -506 -223 -341 -670 -450 -515 245 466 624 551 718 591 606 134 496 384 426 687 927 1415 1020 183 -447 -372 537 344 259 308 170 213 -82 -199 -481 -267 -166 -156 -522 -823 -1290 -1849 -1663 -1204 -295 -196 84 414 626 3 -2 494 335 379 198 556 850 400 -455 -860 -179 -63 -371 -486 -803 -870 -502 -34 187 474 416 268 190 328 161 -59 39 72 -95 -120 -142 197 768 498 318 553 667 891 366 -163 68 148 23 -67 -121 -36 68 4 -303 -670 -543 -389
SS 20250913T162459.3Z 9387.684020 430 1 30.40 2 41.54 161.63 73.14 291.04 0.00 1 0.00 1 0 17 1.332e-02 7.029e-03 7.756e-03 3.964e-03 1.809060e-01 2.001096e-03 2.217784e-03 -6.000000e+00 7.594744e-03 229.15 -2.00 3.56 -2.00 316.18 0.00e+00 6.449584e-04 2.192453e-04 7.254826e-05 -6.000000e+00 3.369761e-04 284.36 -2.00 20.00 -2.00 315.46 0.00e+00 1.334 0.000 302.00 328.00 3 6.5045e+00 5.2160e-03 1.5999e-02 -6.0000e+00 1.8922e-02 3.7915e-02 5.8337e-03 9.4678e-03 -6.0000e+00 2.0536e-02 5.3690e-03 3.3481e-03 4.6253e-03 -6.0000e+00 1.2229e-02 -7.6457e-03 1.5486e-03 1.3230e-03 -6.0000e+00 5.1932e-03 1.8080e-04 -1.2902e-04 1.1212e-04 1.5208e-05 -6.0000e+00 3.5667e-04 -1.5875e-03 0.0000e+00 12 9 1 12 1 1 99.84 27.83 0.82 -0.00159 -0.00256 7 8 1 5 0 3799.600 36.00 20.00 27.83 30.41 3.5 988.65 -1976 10 -2217 -1585 -3581 -3797 -4540 3295 6991 -697 671 -1065 2476 -2127 536 332 -1437 2519 128 963 -503 751 197 2054 -786 625 925 101 2736 1070 2123 299 724 -2013 -713 -4717 -1326 676 -55 -752 -912 -1523 -524 -473 -721 -170 -568 -1658 -388 1766 -336 477 955 1670 608 -306 225 56 253 -185 -259 285 1447 1420 779 258 299 111 -105 592 187 574 1250 764 -817 -308 -598 -994 -1780 -190 -444 -870 -1822 -800 -250 607 488 477 898 53 -324 -1084 -12 -1094 -90 -827 -30 763 878 406 -671 -785 -720 -610 -169 -494 -1129 -161 90 439 285 438 92 -269 -281 -207 -446 7 386 85 495 -96 241 904 1021 748 -153 408 572 -12 -623 -218 -134 -21 -22 171 485 130 45 184 -428 -1105 -158 -445 2 -518 -330 -676 -708 -918 688 1532 -167 153 -257 642 -649 177 117 -523 905 48 372 -197 287 78 834 -341 274 394 40 977 385 793 120 309 -873 -281 -1946 -588 343 -34 -479 -620 -1075 -374 -338 -513 -119 -387 -1099 -270 1206 -225 335 697 1262 473 -243 180 45 197 -145 -210 247 1336 1369 729 219 234 85 -87 548 188 594 1278 754 -758 -254 -490 -776 -1472 -158 -410 -881 -1964 -892 -298 705 596 598 1121 64 -391 -1195 -12 -1058 -91 -923 -37 1018 1120 505 -861 -931 -816 -725 -218 -672 -1478 -218 126 649 439 673 135 -364 -378 -261 -564 9 546 119 704 -136 332 1289 1373 959 -187 497 738 -16 -897 -319 -197 -29 -33 267 773 213 75 296 -671 -1688 -234
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