File name: Pandora243s1_Toronto-CNTower_20250913_L2Fit_fwvt1c3d20240624p1-8.txt File generation date: 20250914T052452.8Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 243 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora243_OF_v3d20230125.txt Instrument calibration file used: Pandora243s1_CF_v3d20240624.txt Level 1 file used: Pandora243s1_Toronto-CNTower_20250913_L1_smca1c3d20240624p1-8.txt Full location name: CN Tower Observation Pod Roof, 290 Bremner Blvd, Toronto, ON M5V 3L9 Short location name: Toronto-CNTower Country of location: Canada Location latitude [deg]: 43.6426 Location longitude [deg]: -79.3871 Location altitude [m]: 330 Local noon date: 20250913 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1621 1771 Nominal wavelengths inside fitting window [nm]: 492.0391 492.1598 492.2804 492.4010 492.5216 492.6421 492.7627 492.8832 493.0037 493.1242 493.2447 493.3651 493.4856 493.6060 493.7264 493.8468 493.9672 494.0875 494.2079 494.3282 494.4485 494.5688 494.6891 494.8093 494.9296 495.0498 495.1700 495.2902 495.4104 495.5305 495.6506 495.7708 495.8909 496.0110 496.1310 496.2511 496.3711 496.4911 496.6112 496.7311 496.8511 496.9711 497.0910 497.2109 497.3308 497.4507 497.5706 497.6904 497.8103 497.9301 498.0499 498.1697 498.2894 498.4092 498.5289 498.6486 498.7683 498.8880 499.0077 499.1273 499.2469 499.3666 499.4862 499.6057 499.7253 499.8448 499.9644 500.0839 500.2034 500.3229 500.4423 500.5618 500.6812 500.8006 500.9200 501.0394 501.1587 501.2781 501.3974 501.5167 501.6360 501.7553 501.8745 501.9938 502.1130 502.2322 502.3514 502.4705 502.5897 502.7088 502.8279 502.9471 503.0661 503.1852 503.3043 503.4233 503.5423 503.6613 503.7803 503.8993 504.0182 504.1371 504.2560 504.3749 504.4938 504.6127 504.7315 504.8504 504.9692 505.0880 505.2067 505.3255 505.4442 505.5630 505.6817 505.8004 505.9190 506.0377 506.1563 506.2750 506.3936 506.5121 506.6307 506.7493 506.8678 506.9863 507.1048 507.2233 507.3418 507.4602 507.5787 507.6971 507.8155 507.9339 508.0522 508.1706 508.2889 508.4072 508.5255 508.6438 508.7620 508.8803 508.9985 509.1167 509.2349 509.3531 509.4712 509.5894 509.7075 509.8256 509.9437 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20250913T123602.6Z 9387.525030 285 1 31.42 2 72.67 101.97 34.03 252.05 0.00 1 0.00 1 0 15 2.664e-03 2.670e-03 1.388e-03 1.385e-03 5.664840e+03 9.087326e+01 3.992286e+02 -6.000000e+00 1.505242e+02 284.37 -2.00 20.00 -2.00 505.28 0.00e+00 5.059322e-04 3.835696e-05 3.899403e-05 -6.000000e+00 7.524861e-05 284.37 -2.00 20.00 -2.00 500.42 0.00e+00 2.314836e-01 2.756295e-02 3.707488e-02 -6.000000e+00 5.303083e-02 229.16 -2.00 3.56 -2.00 502.02 0.00e+00 3.309 0.001 489.00 513.00 1 6.9458e+00 2.1145e-03 5.6273e-03 -6.0000e+00 4.0711e-03 2.0548e-03 5.4002e-04 9.4402e-04 -6.0000e+00 1.0506e-03 1.1588e-03 1.3613e-03 1.3922e-04 4.5198e-05 -6.0000e+00 2.8115e-04 1.3828e-03 -6.5450e-05 10 0 0 10 0 0 99.91 27.82 2.12 0.00138 0.01083 9 9 1 4 0 3490.810 36.00 20.00 27.82 25.93 3.5 954.81 -67 -371 -32 203 -229 414 632 509 117 225 653 270 157 -179 128 -201 -51 97 33 -21 -13 565 82 36 280 172 69 292 -265 -320 -98 -323 -522 78 48 -349 -330 -47 -151 -303 -57 193 -200 184 192 230 323 105 -168 -393 -453 186 -176 -511 -198 -108 -130 -332 91 -89 349 141 255 111 -28 123 -175 -25 -251 -271 61 -170 -44 -185 -72 -365 -449 -340 -74 -295 -242 -157 -148 37 6 -472 -202 -214 259 139 35 220 104 11 91 119 149 3 -231 -426 -250 -494 -291 -294 -250 -706 -139 -78 166 70 238 -449 -221 61 344 504 734 326 391 -5 377 122 67 191 139 122 135 251 -42 461 317 -62 -38 342 -238 -205 -106 63 -13 167 339 288 196 198 123 -21 -322 -138 -268 111 -195 -63 -357 -32 206 -232 426 661 539 125 237 675 276 158 -179 126 -200 -51 100 35 -22 -14 605 89 38 292 180 72 310 -278 -326 -98 -321 -529 81 50 -367 -346 -48 -160 -318 -60 202 -205 190 200 241 337 108 -172 -406 -456 181 -169 -494 -195 -109 -130 -338 93 -91 354 144 260 114 -28 124 -174 -25 -251 -268 59 -166 -43 -184 -72 -356 -448 -334 -71 -284 -233 -151 -144 36 5 -459 -197 -209 251 135 34 217 104 11 90 116 142 2 -218 -394 -229 -457 -276 -280 -246 -710 -139 -78 162 69 234 -450 -223 60 340 500 731 328 393 -5 370 122 67 188 137 121 134 249 -42 454 311 -60 -37 323 -225 -195 -102 62 -13 163 335 286 196 199 124 -21 -321 -135 -257 105 -185 SQ 20250913T130055.7Z 9387.542311 298 1 31.95 2 68.31 106.66 38.23 257.80 0.00 1 0.00 1 0 15 5.086e-03 5.090e-03 4.023e-03 4.002e-03 5.028566e+03 2.630100e+02 3.654593e+02 -6.000000e+00 2.873554e+02 284.37 -2.00 20.00 -2.00 505.22 0.00e+00 6.703420e-04 1.106586e-04 4.263573e-05 -6.000000e+00 1.436217e-04 284.37 -2.00 20.00 -2.00 500.23 0.00e+00 4.253237e-01 8.043699e-02 3.046905e-02 -6.000000e+00 1.011465e-01 229.16 -2.00 3.56 -2.00 501.84 0.00e+00 2.682 0.000 489.00 513.00 1 8.4853e+00 6.1734e-03 4.6451e-03 -6.0000e+00 7.7662e-03 1.4084e-02 1.5778e-03 7.9462e-04 -6.0000e+00 2.0019e-03 2.6671e-04 -4.1985e-05 4.0306e-04 4.3163e-05 -6.0000e+00 5.3664e-04 -4.3289e-03 3.8553e-05 12 8 8 10 0 0 46.23 27.82 2.49 -0.00433 -0.00462 8 8 1 4 0 3992.790 36.00 20.00 27.82 25.94 3.5 955.33 -470 -430 313 -229 535 283 665 619 100 -330 11 -670 -290 115 485 -257 -1179 240 -374 666 -76 1144 280 399 368 775 154 353 610 -247 -333 831 -538 327 -208 -128 -1139 -503 975 129 298 64 -128 -450 512 -50 90 -801 -466 -1311 -573 -574 530 -608 -378 -756 -385 -347 500 -388 448 261 -244 -145 576 159 79 544 36 404 269 -939 596 -416 -673 466 -255 -957 -146 885 331 -457 -218 251 14 454 273 -227 -391 276 -224 85 485 -234 1142 -20 -91 -742 208 -898 -292 -231 99 -549 -538 -990 112 -600 163 141 -511 -153 -677 -7 325 -237 888 179 -150 69 130 -301 265 758 338 990 117 1082 -469 405 695 453 483 365 34 -1 -483 631 -421 -362 -59 -340 -64 308 965 -78 -1 -18 -457 -466 -467 -460 -425 315 -240 573 311 702 661 107 -352 11 -697 -297 121 507 -271 -1207 248 -397 711 -82 1222 302 430 399 837 167 377 636 -252 -333 820 -546 338 -223 -138 -1245 -540 1020 134 311 67 -136 -483 550 -55 97 -861 -491 -1360 -574 -560 504 -585 -370 -764 -398 -363 521 -408 466 273 -257 -152 599 164 80 541 36 392 259 -915 576 -410 -672 459 -250 -930 -138 826 311 -435 -208 241 14 444 269 -225 -387 272 -223 85 489 -239 1142 -20 -88 -706 191 -818 -262 -208 92 -530 -536 -958 107 -572 160 138 -484 -147 -660 -7 319 -235 875 178 -150 68 126 -288 250 709 319 929 111 1016 -446 381 648 419 440 328 31 -1 -445 588 -403 -351 -58 -335 -63 305 948 -77 -1 -18 -430 -433 -434 SQ 20250913T131039.0Z 9387.549062 304 1 29.37 2 66.64 108.57 39.90 259.84 0.00 1 0.00 1 0 15 2.987e-03 2.979e-03 1.991e-03 1.984e-03 4.658146e+03 1.291060e+02 3.227046e+02 -6.000000e+00 1.687599e+02 284.37 -2.00 20.00 -2.00 505.26 0.00e+00 5.736969e-04 5.494865e-05 4.097484e-05 -6.000000e+00 8.435693e-05 284.37 -2.00 20.00 -2.00 500.33 0.00e+00 1.591180e-01 3.969597e-02 3.277690e-02 -6.000000e+00 5.943333e-02 229.16 -2.00 3.56 -2.00 501.94 0.00e+00 2.503 0.000 489.00 513.00 1 7.5505e+00 3.0484e-03 4.5233e-03 -6.0000e+00 4.5629e-03 9.2744e-03 7.7726e-04 8.0027e-04 -6.0000e+00 1.1770e-03 7.1150e-04 6.6993e-04 2.0123e-04 3.7169e-05 -6.0000e+00 3.1521e-04 -2.9416e-03 -1.2119e-05 10 0 0 10 0 0 39.17 27.82 2.20 -0.00294 0.00171 9 9 1 4 0 3262.430 36.00 19.99 27.82 25.86 3.6 955.74 31 -327 -165 127 105 315 338 362 208 231 552 509 141 146 -393 -276 -3 235 250 -193 -356 782 -210 36 -4 190 -151 248 -148 -146 -42 -223 82 325 76 -651 -500 318 -399 208 136 318 -373 -157 -11 454 -41 -56 92 -123 -308 -771 -89 71 -246 -344 -76 -503 195 -20 161 186 -42 103 -205 4 252 108 160 -625 140 11 52 -108 -215 43 -4 11 221 -709 -357 54 -314 -16 -36 -517 135 -440 56 -321 -85 465 32 -312 -46 264 127 -161 -342 -244 -379 147 -311 -385 -101 -540 88 -6 392 -6 -144 -207 33 92 424 81 624 470 -69 -119 -180 214 188 334 -24 467 -44 303 -30 412 215 161 -165 455 158 -92 91 -117 72 187 16 -146 360 94 32 -212 -235 -591 28 1042 -564 30 -316 -164 130 110 325 354 383 221 242 571 518 147 151 -406 -286 -3 240 261 -206 -382 831 -225 38 -4 205 -163 262 -154 -147 -41 -221 82 333 80 -704 -538 337 -420 215 140 329 -393 -167 -11 486 -44 -59 96 -126 -306 -749 -84 67 -239 -344 -78 -524 203 -21 167 194 -44 108 -213 4 255 107 158 -612 134 10 50 -106 -214 42 -4 11 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1.715e-03 1.713e-03 7.052e-05 7.044e-05 2.596438e+03 4.290603e+00 1.842768e+02 -6.000000e+00 9.686478e+01 284.34 -2.00 20.00 -2.00 505.27 0.00e+00 5.228963e-04 1.949144e-06 3.344945e-05 -6.000000e+00 4.842262e-05 284.34 -2.00 20.00 -2.00 500.50 0.00e+00 4.636301e-02 1.390843e-03 1.941146e-02 -6.000000e+00 3.411969e-02 229.13 -2.00 3.56 -2.00 502.08 0.00e+00 1.906 0.000 489.00 513.00 1 -2.3324e-01 1.0670e-04 3.1927e-03 -6.0000e+00 2.6194e-03 -7.1377e-03 2.7383e-05 4.7401e-04 -6.0000e+00 6.7577e-04 1.8787e+00 9.4126e-04 7.2162e-06 2.4515e-05 -6.0000e+00 1.8095e-04 -1.2253e-03 -2.9116e-05 10 0 0 10 0 0 98.24 27.87 2.20 -0.00123 0.00530 2106 2106 1 4 0 2.590 36.00 19.99 27.87 29.23 3.6 980.56 -2 -88 -73 31 26 262 379 246 231 245 205 130 -81 -112 -30 -16 41 56 43 -93 1 189 178 181 211 147 27 13 -138 -198 35 80 -110 -13 -93 -274 -122 86 3 -88 -3 -33 -15 66 109 99 116 53 -32 -158 -295 -226 -270 -268 -192 -227 -272 -139 11 122 206 221 130 73 104 106 58 -18 -76 -208 -165 -25 -89 -168 -133 -222 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0.00 1 0.00 1 0 15 1.676e-03 1.673e-03 8.808e-05 8.797e-05 2.620254e+03 5.376284e+00 1.860584e+02 -6.000000e+00 9.465474e+01 284.34 -2.00 20.00 -2.00 505.27 0.00e+00 5.098904e-04 2.434573e-06 3.267214e-05 -6.000000e+00 4.731851e-05 284.34 -2.00 20.00 -2.00 500.48 0.00e+00 4.568819e-02 1.739179e-03 1.946940e-02 -6.000000e+00 3.334268e-02 229.13 -2.00 3.56 -2.00 502.07 0.00e+00 1.907 0.000 489.00 513.00 1 2.0207e-01 1.3345e-04 3.1922e-03 -6.0000e+00 2.5598e-03 -5.5553e-03 3.4228e-05 4.7647e-04 -6.0000e+00 6.6040e-04 1.2158e+00 9.6109e-04 9.0164e-06 2.4386e-05 -6.0000e+00 1.7682e-04 -1.0744e-03 -3.2972e-05 10 0 0 10 0 0 98.77 27.87 2.19 -0.00107 0.00559 2106 2106 1 4 0 2.590 36.00 19.99 27.87 29.23 3.6 980.56 6 -95 -64 30 31 270 362 219 231 226 215 142 -79 -91 -43 -5 48 59 35 -89 2 208 184 164 210 133 19 3 -126 -197 61 84 -115 -11 -105 -291 -113 74 10 -86 -18 -18 -25 62 94 69 98 36 -24 -163 -300 -218 -249 -246 -173 -223 -248 -154 19 123 197 214 127 79 119 92 39 -31 -71 -194 -167 -9 -99 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331.88 0.00 1 0.00 1 0 15 1.677e-03 1.674e-03 1.008e-04 1.007e-04 2.610322e+03 6.152796e+00 1.855520e+02 -6.000000e+00 9.471149e+01 284.34 -2.00 20.00 -2.00 505.27 0.00e+00 5.103653e-04 2.784297e-06 3.263026e-05 -6.000000e+00 4.734706e-05 284.34 -2.00 20.00 -2.00 500.48 0.00e+00 4.814301e-02 1.989226e-03 1.935556e-02 -6.000000e+00 3.336322e-02 229.13 -2.00 3.56 -2.00 502.07 0.00e+00 1.907 0.000 489.00 513.00 1 4.6478e-01 1.5260e-04 3.1882e-03 -6.0000e+00 2.5613e-03 -4.5061e-03 3.9140e-05 4.7447e-04 -6.0000e+00 6.6082e-04 9.3461e-01 1.0069e-03 1.0307e-05 2.4099e-05 -6.0000e+00 1.7693e-04 -7.7790e-04 -3.5981e-05 10 0 0 10 0 0 99.55 27.87 2.18 -0.00078 0.00621 2106 2106 1 4 0 2.590 36.00 19.99 27.87 29.23 3.6 980.56 4 -89 -57 45 5 256 371 240 208 195 204 133 -70 -106 -1 16 74 57 49 -85 -19 190 187 184 189 132 27 0 -154 -186 21 72 -111 -12 -93 -290 -130 99 12 -73 -7 -11 -15 51 90 90 76 35 -21 -151 -291 -221 -259 -261 -183 -219 -258 -153 0 117 224 218 123 85 97 108 89 -13 -66 -177 -182 -24 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5.46 2 58.54 240.92 104.17 331.92 0.00 1 0.00 1 0 15 1.668e-03 1.665e-03 1.087e-04 1.086e-04 2.622038e+03 6.634505e+00 1.863803e+02 -6.000000e+00 9.421456e+01 284.34 -2.00 20.00 -2.00 505.27 0.00e+00 5.181184e-04 3.005709e-06 3.313702e-05 -6.000000e+00 4.709613e-05 284.34 -2.00 20.00 -2.00 500.48 0.00e+00 5.110773e-02 2.147093e-03 1.950077e-02 -6.000000e+00 3.318252e-02 229.13 -2.00 3.56 -2.00 502.07 0.00e+00 1.909 0.000 489.00 513.00 1 6.1035e-01 1.6476e-04 3.1989e-03 -6.0000e+00 2.5475e-03 -4.1857e-03 4.2251e-05 4.7728e-04 -6.0000e+00 6.5714e-04 8.0754e-01 7.7960e-04 1.1120e-05 2.4436e-05 -6.0000e+00 1.7599e-04 -1.9079e-03 -1.7515e-05 10 0 0 10 0 0 57.09 27.87 2.17 -0.00191 0.00350 2106 2106 1 4 0 2.590 36.00 19.99 27.87 29.23 3.6 980.56 14 -70 -42 28 28 255 359 231 214 235 190 116 -75 -85 -18 6 33 37 44 -98 -6 198 203 172 212 141 21 21 -126 -167 41 99 -114 -19 -105 -304 -130 90 1 -93 -24 -32 -25 66 91 81 74 31 -12 -181 -287 -220 -250 -250 -202 -223 -274 -152 22 116 204 230 115 89 87 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9387.851886 543 9 5.46 2 58.57 240.96 104.18 331.95 0.00 1 0.00 1 0 15 1.670e-03 1.668e-03 9.729e-05 9.717e-05 2.614677e+03 5.932302e+00 1.861744e+02 -6.000000e+00 9.432125e+01 284.34 -2.00 20.00 -2.00 505.28 0.00e+00 5.132314e-04 2.688519e-06 3.294928e-05 -6.000000e+00 4.715041e-05 284.34 -2.00 20.00 -2.00 500.49 0.00e+00 5.394075e-02 1.920079e-03 1.939420e-02 -6.000000e+00 3.322229e-02 229.13 -2.00 3.56 -2.00 502.08 0.00e+00 1.910 0.000 489.00 513.00 1 3.9450e-01 1.4731e-04 3.1951e-03 -6.0000e+00 2.5506e-03 -5.0779e-03 3.7786e-05 4.7577e-04 -6.0000e+00 6.5796e-04 1.0017e+00 8.3860e-04 9.9605e-06 2.4136e-05 -6.0000e+00 1.7619e-04 -1.3326e-03 -2.5496e-05 10 0 0 10 0 0 95.16 27.87 2.18 -0.00133 0.00448 2106 2106 1 4 0 2.590 36.00 19.99 27.87 29.23 3.6 980.56 30 -70 -53 33 0 260 361 260 210 226 194 135 -73 -98 -30 0 49 66 31 -124 -1 192 181 185 228 137 15 8 -138 -190 22 98 -105 -21 -98 -298 -129 78 22 -93 -11 -21 -4 63 83 95 87 33 -27 -167 -281 -195 -244 -243 -185 -236 -255 -143 -14 130 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20250913T202648.5Z 9387.851951 543 10 5.46 2 58.59 240.98 104.19 331.97 0.00 1 0.00 1 0 15 1.662e-03 1.661e-03 9.936e-05 9.924e-05 2.615664e+03 6.056766e+00 1.856017e+02 -6.000000e+00 9.388632e+01 284.34 -2.00 20.00 -2.00 505.27 0.00e+00 5.110926e-04 2.746025e-06 3.284323e-05 -6.000000e+00 4.693332e-05 284.34 -2.00 20.00 -2.00 500.49 0.00e+00 5.299398e-02 1.961027e-03 1.947543e-02 -6.000000e+00 3.306981e-02 229.13 -2.00 3.56 -2.00 502.07 0.00e+00 1.911 0.000 489.00 513.00 1 4.3478e-01 1.5045e-04 3.1984e-03 -6.0000e+00 2.5389e-03 -5.0308e-03 3.8601e-05 4.7633e-04 -6.0000e+00 6.5496e-04 9.6219e-01 8.8489e-04 1.0167e-05 2.4116e-05 -6.0000e+00 1.7538e-04 -1.1821e-03 -2.7882e-05 10 0 0 10 0 0 97.22 27.87 2.18 -0.00118 0.00496 2106 2106 1 4 0 2.590 36.00 19.99 27.87 29.33 3.6 980.56 16 -68 -58 26 -4 274 362 224 226 211 196 128 -64 -83 -28 -23 47 50 46 -98 -14 194 184 175 215 144 14 18 -129 -204 35 87 -102 -32 -118 -281 -106 85 21 -80 -25 -21 -8 69 95 97 98 54 -14 -172 -298 -208 -256 -246 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174 75 -47 -116 -225 -215 -125 -153 SQ 20250913T204432.2Z 9387.864262 552 1 5.46 2 61.45 244.88 105.52 335.60 0.00 1 0.00 1 0 15 1.756e-03 1.754e-03 6.735e-05 6.727e-05 2.840750e+03 4.127159e+00 2.011251e+02 -6.000000e+00 9.919166e+01 284.34 -2.00 20.00 -2.00 505.28 0.00e+00 6.016445e-04 1.862257e-06 3.791476e-05 -6.000000e+00 4.958476e-05 284.34 -2.00 20.00 -2.00 500.50 0.00e+00 5.860432e-02 1.328746e-03 2.126041e-02 -6.000000e+00 3.493688e-02 229.13 -2.00 3.56 -2.00 502.09 0.00e+00 2.082 0.000 489.00 513.00 1 -3.4963e-01 1.0194e-04 3.4983e-03 -6.0000e+00 2.6822e-03 -9.3161e-03 2.6132e-05 5.1846e-04 -6.0000e+00 6.9190e-04 2.0551e+00 8.0990e-04 6.8884e-06 2.6823e-05 -6.0000e+00 1.8529e-04 -1.9203e-03 -1.9952e-05 10 0 0 10 0 0 82.88 27.87 2.20 -0.00192 0.00370 1830 1830 1 4 0 2.980 36.00 20.00 27.87 29.65 3.5 981.33 -14 -90 -70 21 26 266 394 276 243 245 218 143 -72 -101 -44 -24 16 46 57 -79 11 210 202 193 219 163 28 18 -142 -208 8 51 -133 -44 -94 -260 -125 81 6 -89 -15 -34 -16 68 104 93 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-54 132 26 -90 104 151 128 218 231 77 -36 -124 -224 -235 -185 -184 SQ 20250913T204437.7Z 9387.864326 552 2 5.46 2 61.46 244.90 105.53 335.62 0.00 1 0.00 1 0 15 1.761e-03 1.759e-03 6.769e-05 6.762e-05 2.844071e+03 4.149220e+00 2.012208e+02 -6.000000e+00 9.949631e+01 284.34 -2.00 20.00 -2.00 505.28 0.00e+00 5.976241e-04 1.870955e-06 3.765189e-05 -6.000000e+00 4.973715e-05 284.34 -2.00 20.00 -2.00 500.51 0.00e+00 5.636959e-02 1.334431e-03 2.126421e-02 -6.000000e+00 3.504444e-02 229.13 -2.00 3.56 -2.00 502.09 0.00e+00 2.083 0.000 489.00 513.00 1 -3.3920e-01 1.0238e-04 3.4979e-03 -6.0000e+00 2.6905e-03 -9.2795e-03 2.6256e-05 5.1863e-04 -6.0000e+00 6.9404e-04 2.0339e+00 8.1958e-04 6.9245e-06 2.6571e-05 -6.0000e+00 1.8586e-04 -1.5594e-03 -2.2646e-05 10 0 0 10 0 0 90.14 27.87 2.20 -0.00156 0.00413 1830 1830 1 4 0 2.980 36.00 20.00 27.87 29.65 3.5 981.33 -9 -92 -69 22 33 260 397 258 235 252 217 138 -88 -103 -51 -19 41 57 45 -87 -6 199 203 180 231 160 28 23 -128 -203 11 61 -129 -28 -97 -273 -113 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245 220 148 271 200 -15 133 276 150 212 166 -74 -6 118 -28 -44 135 24 -79 113 139 124 215 213 72 -38 -127 -220 -230 -179 -183 SQ 20250913T204448.8Z 9387.864454 552 4 5.46 2 61.49 244.94 105.54 335.66 0.00 1 0.00 1 0 15 1.778e-03 1.777e-03 6.586e-05 6.579e-05 2.845038e+03 4.031837e+00 2.005484e+02 -6.000000e+00 1.004614e+02 284.34 -2.00 20.00 -2.00 505.28 0.00e+00 5.968305e-04 1.821289e-06 3.779892e-05 -6.000000e+00 5.021890e-05 284.34 -2.00 20.00 -2.00 500.51 0.00e+00 5.715535e-02 1.298706e-03 2.147992e-02 -6.000000e+00 3.538274e-02 229.13 -2.00 3.56 -2.00 502.10 0.00e+00 2.085 0.000 489.00 513.00 1 -3.9283e-01 9.9635e-05 3.5094e-03 -6.0000e+00 2.7165e-03 -9.3806e-03 2.5545e-05 5.2153e-04 -6.0000e+00 7.0071e-04 2.1453e+00 7.5809e-04 6.7348e-06 2.6756e-05 -6.0000e+00 1.8766e-04 -2.2474e-03 -1.5336e-05 10 0 0 10 0 0 46.95 27.87 2.20 -0.00225 0.00301 1830 1830 1 4 0 2.980 36.00 20.00 27.87 29.65 3.5 981.33 -10 -89 -77 30 29 287 399 264 241 243 220 146 -81 -98 -32 -12 27 53 43 -87 -1 210 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20250913T214010.0Z 9387.902894 578 3 5.46 2 70.93 255.98 108.50 347.48 0.00 1 0.00 1 0 15 1.870e-03 1.866e-03 7.587e-05 7.580e-05 3.590646e+03 4.731620e+00 2.517584e+02 -6.000000e+00 1.056454e+02 284.34 -2.00 20.00 -2.00 505.29 0.00e+00 7.552230e-04 2.098909e-06 4.682894e-05 -6.000000e+00 5.281001e-05 284.34 -2.00 20.00 -2.00 500.53 0.00e+00 1.721804e-01 1.496305e-03 2.668449e-02 -6.000000e+00 3.720770e-02 229.13 -2.00 3.56 -2.00 502.11 0.00e+00 3.025 0.000 489.00 513.00 1 -2.5070e-01 1.1477e-04 4.8642e-03 -6.0000e+00 2.8566e-03 -1.0693e-02 2.9366e-05 6.6163e-04 -6.0000e+00 7.3682e-04 1.6160e+00 7.5712e-04 7.7337e-06 3.3234e-05 -6.0000e+00 1.9734e-04 -2.4240e-03 -1.1959e-05 10 0 0 10 0 0 24.58 27.88 2.19 -0.00242 0.00283 1292 1292 1 4 0 4.220 36.00 19.99 27.88 28.80 3.5 975.46 -47 -124 -71 27 40 293 417 262 265 262 218 125 -79 -114 -65 -35 14 54 66 -63 14 216 205 196 236 152 56 31 -128 -221 -18 36 -135 -39 -91 -260 -117 70 -5 -104 -36 -27 -21 83 146 109 126 85 -14 -156 -310 -255 -301 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147 114 222 216 104 -27 -124 -226 -246 -206 -208 SQ 20250913T214015.5Z 9387.902958 578 4 5.46 2 70.95 256.00 108.50 347.50 0.00 1 0.00 1 0 15 1.888e-03 1.884e-03 7.415e-05 7.407e-05 3.592947e+03 4.614546e+00 2.519042e+02 -6.000000e+00 1.066340e+02 284.34 -2.00 20.00 -2.00 505.28 0.00e+00 7.590488e-04 2.052443e-06 4.709565e-05 -6.000000e+00 5.330444e-05 284.34 -2.00 20.00 -2.00 500.53 0.00e+00 1.717029e-01 1.461732e-03 2.665972e-02 -6.000000e+00 3.755645e-02 229.13 -2.00 3.56 -2.00 502.11 0.00e+00 3.027 0.000 489.00 513.00 1 -2.9733e-01 1.1214e-04 4.8676e-03 -6.0000e+00 2.8833e-03 -1.0758e-02 2.8698e-05 6.6092e-04 -6.0000e+00 7.4374e-04 1.6926e+00 7.8106e-04 7.5609e-06 3.3674e-05 -6.0000e+00 1.9919e-04 -2.3532e-03 -1.3450e-05 10 0 0 10 0 0 19.08 27.88 2.19 -0.00235 0.00306 1292 1292 1 4 0 4.220 36.00 20.00 27.88 28.80 3.5 975.46 -45 -117 -74 33 35 289 403 289 267 247 221 137 -91 -116 -62 -44 22 57 61 -77 12 232 195 183 246 186 42 30 -136 -216 -18 34 -145 -32 -80 -261 -126 67 -14 -88 -28 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211 185 -60 -18 96 -60 -70 134 -3 -87 121 156 126 226 227 95 -23 -120 -238 -255 -221 -211 SQ 20250913T214021.0Z 9387.903021 578 5 5.47 2 70.97 256.02 108.50 347.52 0.00 1 0.00 1 0 15 1.898e-03 1.894e-03 7.318e-05 7.311e-05 3.585589e+03 4.559387e+00 2.510194e+02 -6.000000e+00 1.072056e+02 284.34 -2.00 20.00 -2.00 505.28 0.00e+00 7.587065e-04 2.025651e-06 4.709101e-05 -6.000000e+00 5.359005e-05 284.34 -2.00 20.00 -2.00 500.53 0.00e+00 1.692533e-01 1.442692e-03 2.671681e-02 -6.000000e+00 3.775746e-02 229.13 -2.00 3.56 -2.00 502.11 0.00e+00 3.030 0.000 489.00 513.00 1 -3.2382e-01 1.1068e-04 4.8720e-03 -6.0000e+00 2.8988e-03 -1.0611e-02 2.8312e-05 6.6138e-04 -6.0000e+00 7.4771e-04 1.7378e+00 7.5662e-04 7.4619e-06 3.3427e-05 -6.0000e+00 2.0026e-04 -2.2634e-03 -1.3389e-05 10 0 0 10 0 0 35.92 27.88 2.19 -0.00226 0.00298 1292 1292 1 4 0 4.220 36.00 20.00 27.88 28.80 3.5 975.46 -46 -124 -94 15 35 281 423 294 270 261 217 137 -99 -115 -60 -44 12 50 63 -51 14 223 213 190 248 185 49 28 -132 -229 -34 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261 171 251 232 152 262 209 -13 129 273 155 221 184 -57 -26 102 -59 -65 126 2 -78 121 176 110 225 228 94 -17 -120 -233 -267 -210 -229 SQ 20250913T214026.6Z 9387.903086 578 6 5.46 2 70.98 256.03 108.51 347.54 0.00 1 0.00 1 0 15 1.893e-03 1.890e-03 7.301e-05 7.294e-05 3.585697e+03 4.545726e+00 2.511912e+02 -6.000000e+00 1.069375e+02 284.34 -2.00 20.00 -2.00 505.28 0.00e+00 7.560925e-04 2.020597e-06 4.694535e-05 -6.000000e+00 5.345629e-05 284.34 -2.00 20.00 -2.00 500.53 0.00e+00 1.695463e-01 1.439442e-03 2.667471e-02 -6.000000e+00 3.766365e-02 229.13 -2.00 3.56 -2.00 502.11 0.00e+00 3.032 0.000 489.00 513.00 1 -3.2878e-01 1.1041e-04 4.8727e-03 -6.0000e+00 2.8916e-03 -1.0570e-02 2.8259e-05 6.6091e-04 -6.0000e+00 7.4587e-04 1.7459e+00 7.9309e-04 7.4436e-06 3.3432e-05 -6.0000e+00 1.9976e-04 -1.9834e-03 -1.6223e-05 10 0 0 10 0 0 24.34 27.88 2.19 -0.00198 0.00352 1292 1292 1 4 0 4.220 36.00 20.00 27.88 28.80 3.5 975.46 -62 -143 -79 34 42 305 418 288 275 257 229 129 -93 -120 -64 -46 2 62 65 -68 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-14 -44 31 64 -22 20 193 315 373 447 435 261 169 250 252 155 274 200 -15 125 267 145 203 170 -61 -19 93 -69 -64 125 0 -89 123 165 129 214 231 100 -10 -126 -231 -254 -206 -216 SQ 20250913T214032.1Z 9387.903150 578 7 5.46 2 71.00 256.05 108.51 347.56 0.00 1 0.00 1 0 15 1.901e-03 1.898e-03 7.306e-05 7.299e-05 3.593946e+03 4.551309e+00 2.519666e+02 -6.000000e+00 1.074100e+02 284.34 -2.00 20.00 -2.00 505.28 0.00e+00 7.564120e-04 2.022355e-06 4.687850e-05 -6.000000e+00 5.369197e-05 284.34 -2.00 20.00 -2.00 500.53 0.00e+00 1.693712e-01 1.440570e-03 2.666393e-02 -6.000000e+00 3.782887e-02 229.13 -2.00 3.56 -2.00 502.11 0.00e+00 3.035 0.000 489.00 513.00 1 -3.2754e-01 1.1050e-04 4.8753e-03 -6.0000e+00 2.9043e-03 -1.0607e-02 2.8281e-05 6.6126e-04 -6.0000e+00 7.4912e-04 1.7431e+00 7.5884e-04 7.4437e-06 3.3388e-05 -6.0000e+00 2.0064e-04 -2.3126e-03 -1.2006e-05 10 0 0 10 0 0 26.19 27.88 2.19 -0.00231 0.00295 1292 1292 1 4 0 4.220 36.00 20.00 27.88 28.80 3.5 975.46 -69 -142 -92 35 43 298 420 286 254 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