File name: Pandora243s1_Toronto-CNTower_20250915_L2Fit_fwvt1c3d20240624p1-8.txt
File generation date: 20250916T051756.3Z
Data description: Level 2 spectral fitting results file
Data file version: fwvt1c3p1-8
Local principal investigator: Vitali Fioletov
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 243
Spectrometer number: 1
Processing software version used: BlickP v1.8.75
Instrument operation file used: Pandora243_OF_v3d20230125.txt
Instrument calibration file used: Pandora243s1_CF_v3d20240624.txt
Level 1 file used: Pandora243s1_Toronto-CNTower_20250915_L1_smca1c3d20240624p1-8.txt
Full location name: CN Tower Observation Pod Roof, 290 Bremner Blvd, Toronto, ON M5V 3L9
Short location name: Toronto-CNTower
Country of location: Canada
Location latitude [deg]: 43.6426
Location longitude [deg]: -79.3871
Location altitude [m]: 330
Local noon date: 20250915
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: None
First and last pixel inside fitting window: 1621 1771
Nominal wavelengths inside fitting window [nm]: 492.0391 492.1598 492.2804 492.4010 492.5216 492.6421 492.7627 492.8832 493.0037 493.1242 493.2447 493.3651 493.4856 493.6060 493.7264 493.8468 493.9672 494.0875 494.2079 494.3282 494.4485 494.5688 494.6891 494.8093 494.9296 495.0498 495.1700 495.2902 495.4104 495.5305 495.6506 495.7708 495.8909 496.0110 496.1310 496.2511 496.3711 496.4911 496.6112 496.7311 496.8511 496.9711 497.0910 497.2109 497.3308 497.4507 497.5706 497.6904 497.8103 497.9301 498.0499 498.1697 498.2894 498.4092 498.5289 498.6486 498.7683 498.8880 499.0077 499.1273 499.2469 499.3666 499.4862 499.6057 499.7253 499.8448 499.9644 500.0839 500.2034 500.3229 500.4423 500.5618 500.6812 500.8006 500.9200 501.0394 501.1587 501.2781 501.3974 501.5167 501.6360 501.7553 501.8745 501.9938 502.1130 502.2322 502.3514 502.4705 502.5897 502.7088 502.8279 502.9471 503.0661 503.1852 503.3043 503.4233 503.5423 503.6613 503.7803 503.8993 504.0182 504.1371 504.2560 504.3749 504.4938 504.6127 504.7315 504.8504 504.9692 505.0880 505.2067 505.3255 505.4442 505.5630 505.6817 505.8004 505.9190 506.0377 506.1563 506.2750 506.3936 506.5121 506.6307 506.7493 506.8678 506.9863 507.1048 507.2233 507.3418 507.4602 507.5787 507.6971 507.8155 507.9339 508.0522 508.1706 508.2889 508.4072 508.5255 508.6438 508.7620 508.8803 508.9985 509.1167 509.2349 509.3531 509.4712 509.5894 509.7075 509.8256 509.9437
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Water vapor effective temperature [K]
Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Nitrogen dioxide effective temperature [K]
Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 49: Ozone effective temperature [K]
Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 57: Lower limit used for wavelength scaling [nm]
Column 58: Upper limit used for wavelength scaling [nm]
Column 59: Order of smoothing polynomial
Column 60: Smoothing polynomial coefficient, order 0
Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 65: Smoothing polynomial coefficient, order 1
Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 70: Mean value of measured data inside fitting window [same units as measurements]
Column 71: Wavelength change polynomial coefficient, order 0
Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 85: Wavelength effective temperature [°C], 999=no effective temperature given
Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 89: Number of bright count cycles
Column 90: Number of dark count cycles
Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 94: Integration time [ms]
Column 95: Temperature at electronics board [°C], 999=no temperature signal
Column 96: Spectrometer control temperature [°C], 999=no temperature signal
Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 98: Temperature in head sensor [°C], 999=no temperature signal
Column 99: Humidity in head sensor [%], -9=no humidity signal
Column 100: Pressure in head sensor [hPa], -9=no pressure signal
Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SQ 20250915T110614.6Z 9389.462669 224 1 29.60 2 89.22 86.84 19.85 136.72 0.00 1 0.00 1 0 36 1.387e-02 1.372e-02 8.094e-04 8.047e-04 1.581860e+04 5.730761e+01 9.803185e+02 -6.000000e+00 7.828782e+02 284.21 -2.00 20.00 -2.00 505.46 0.00e+00 3.470716e-03 2.257146e-05 2.065737e-04 -6.000000e+00 3.913963e-04 284.21 -2.00 20.00 -2.00 501.19 0.00e+00 5.046026e-01 1.545204e-02 1.241442e-01 -6.000000e+00 2.757320e-01 228.98 -2.00 3.56 -2.00 502.67 0.00e+00 19.113 0.135 489.00 513.00 1 3.6670e+00 1.1830e-03 3.4245e-02 -6.0000e+00 2.1170e-02 -4.5534e-02 2.9416e-04 3.3206e-03 -6.0000e+00 5.4577e-03 3.2686e-03 1.9797e-03 7.6872e-05 1.2601e-04 -6.0000e+00 1.4630e-03 -3.5124e-03 2.8464e-05 12 8 8 10 0 0 4.82 27.82 16.98 -0.00351 0.01022 35 35 1 4 0 845.550 36.00 20.00 27.82 22.03 3.8 930.68 -2827 -2470 -1003 320 1113 1921 2472 2593 2227 1460 1128 150 -469 -818 -1217 -1124 -725 180 539 853 948 1139 942 1146 1480 1336 1061 510 -476 -1728 -2234 -2166 -1657 -305 590 566 569 131 -240 -443 -245 173 416 1032 1439 1582 1367 1068 522 -457 -1416 -2200 -2432 -2278 -1566 -281 507 787 1244 1231 1422 1480 1538 1604 1285 841 285 -269 -885 -1195 -1633 -1453 -1325 -955 -628 -980 -1432 -1820 -2206 -2353 -2200 -1847 -1852 -1352 -1176 -1228 -1154 -1167 -1033 -780 -315 386 814 1064 1246 983 354 -436 -1419 -2520 -2753 -2614 -1657 -782 -54 -147 -340 -821 -853 -750 -200 270 1054 1849 2348 2757 3046 3031 2408 1579 1098 810 646 1007 1347 1202 1278 1423 1066 872 466 -169 -693 -978 -1368 -1252 -576 -226 373 878 702 598 796 747 827 720 73 -947 -1763 -2090 -2160 -2448 -2165 -895 283 1006 1767 2307 2368 2044 1339 1026 140 -436 -756 -1125 -1044 -660 166 508 816 912 1099 914 1084 1406 1278 1016 487 -450 -1662 -2124 -2064 -1555 -291 576 561 564 130 -236 -435 -241 172 405 1015 1429 1580 1368 1064 516 -446 -1364 -2154 -2363 -2228 -1513 -277 509 800 1268 1222 1413 1480 1548 1618 1296 844 283 -265 -871 -1202 -1640 -1459 -1303 -949 -629 -983 -1427 -1792 -2155 -2288 -2136 -1798 -1819 -1337 -1176 -1242 -1171 -1183 -1042 -784 -317 390 829 1082 1244 956 345 -415 -1334 -2358 -2574 -2480 -1568 -770 -54 -150 -351 -849 -878 -775 -208 276 1084 1900 2415 2847 3177 3207 2584 1700 1171 851 671 1041 1397 1258 1345 1503 1131 927 496 -179 -729 -1026 -1445 -1337 -608 -243 406 965 765 660 884 835 924 803 81 -1047 -1936 -2290 -2385
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SQ 20250915T111150.0Z 9389.466551 232 1 30.08 2 88.21 87.80 19.20 139.73 0.00 1 0.00 1 0 22 8.451e-03 8.381e-03 4.549e-04 4.533e-04 1.393596e+04 3.189344e+01 8.899099e+02 -6.000000e+00 4.771417e+02 284.21 -2.00 20.00 -2.00 505.42 0.00e+00 2.374520e-03 1.268439e-05 1.463668e-04 -6.000000e+00 2.385509e-04 284.21 -2.00 20.00 -2.00 501.03 0.00e+00 7.591468e-01 8.763712e-03 1.029016e-01 -6.000000e+00 1.680756e-01 228.98 -2.00 3.56 -2.00 502.54 0.00e+00 16.585 0.088 489.00 513.00 1 2.9987e+00 6.7107e-04 2.7517e-02 -6.0000e+00 1.2904e-02 -4.5597e-02 1.6775e-04 2.7847e-03 -6.0000e+00 3.3274e-03 9.0021e-03 1.3771e-03 4.3600e-05 1.0953e-04 -6.0000e+00 8.9166e-04 4.1565e-04 -7.5884e-06 12 8 8 10 0 0 43.37 27.81 11.09 0.00042 0.00997 74 74 1 4 0 406.400 36.00 20.00 27.81 22.22 3.7 931.68 -1675 -1345 -689 177 544 1162 1667 1516 1284 988 715 196 -272 -539 -748 -661 -462 49 390 383 524 735 578 674 870 715 618 251 -348 -929 -1204 -1120 -917 -225 241 116 226 139 -69 -303 -219 99 233 611 935 924 878 647 249 -398 -1013 -1417 -1505 -1451 -868 -322 93 436 582 746 837 941 1042 1001 832 481 150 -88 -493 -851 -961 -853 -784 -573 -314 -540 -892 -1102 -1250 -1326 -1441 -1185 -1219 -905 -695 -760 -680 -718 -597 -415 -125 236 514 712 789 753 306 -253 -858 -1492 -1832 -1530 -1124 -510 -280 -338 -241 -442 -512 -393 -118 158 530 1110 1535 1741 1931 1857 1458 986 647 503 402 589 739 676 684 874 553 599 491 -63 -466 -539 -845 -835 -290 -20 108 499 463 378 493 553 494 412 99 -583 -1040 -1341 -1305 -1476 -1200 -630 162 513 1090 1587 1462 1215 953 682 186 -255 -503 -697 -618 -438 46 376 376 505 711 562 659 854 707 610 247 -337 -902 -1152 -1072 -873 -220 236 116 225 138 -67 -297 -215 98 232 617 932 927 882 646 251 -396 -989 -1388 -1459 -1414 -842 -320 93 440 590 756 851 960 1047 1009 837 490 151 -88 -489 -839 -942 -836 -775 -573 -316 -545 -894 -1089 -1222 -1289 -1403 -1157 -1202 -899 -699 -757 -680 -718 -594 -412 -124 236 520 720 785 746 295 -243 -810 -1395 -1712 -1446 -1072 -496 -278 -344 -248 -453 -521 -401 -122 161 546 1146 1586 1809 2026 1936 1536 1039 675 526 416 606 764 704 703 900 572 619 506 -65 -484 -556 -876 -858 -303 -21 115 536 495 409 538 607 543 452 108 -630 -1112 -1428 -1396
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