File name: Pandora243s1_Toronto-CNTower_20250919_L2Fit_fwvt1c3d20240624p1-8.txt
File generation date: 20250920T163126.3Z
Data description: Level 2 spectral fitting results file
Data file version: fwvt1c3p1-8
Local principal investigator: Vitali Fioletov
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 243
Spectrometer number: 1
Processing software version used: BlickP v1.8.75
Instrument operation file used: Pandora243_OF_v3d20230125.txt
Instrument calibration file used: Pandora243s1_CF_v3d20240624.txt
Level 1 file used: Pandora243s1_Toronto-CNTower_20250919_L1_smca1c3d20240624p1-8.txt
Full location name: CN Tower Observation Pod Roof, 290 Bremner Blvd, Toronto, ON M5V 3L9
Short location name: Toronto-CNTower
Country of location: Canada
Location latitude [deg]: 43.6426
Location longitude [deg]: -79.3871
Location altitude [m]: 330
Local noon date: 20250919
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: None
First and last pixel inside fitting window: 1621 1771
Nominal wavelengths inside fitting window [nm]: 492.0391 492.1598 492.2804 492.4010 492.5216 492.6421 492.7627 492.8832 493.0037 493.1242 493.2447 493.3651 493.4856 493.6060 493.7264 493.8468 493.9672 494.0875 494.2079 494.3282 494.4485 494.5688 494.6891 494.8093 494.9296 495.0498 495.1700 495.2902 495.4104 495.5305 495.6506 495.7708 495.8909 496.0110 496.1310 496.2511 496.3711 496.4911 496.6112 496.7311 496.8511 496.9711 497.0910 497.2109 497.3308 497.4507 497.5706 497.6904 497.8103 497.9301 498.0499 498.1697 498.2894 498.4092 498.5289 498.6486 498.7683 498.8880 499.0077 499.1273 499.2469 499.3666 499.4862 499.6057 499.7253 499.8448 499.9644 500.0839 500.2034 500.3229 500.4423 500.5618 500.6812 500.8006 500.9200 501.0394 501.1587 501.2781 501.3974 501.5167 501.6360 501.7553 501.8745 501.9938 502.1130 502.2322 502.3514 502.4705 502.5897 502.7088 502.8279 502.9471 503.0661 503.1852 503.3043 503.4233 503.5423 503.6613 503.7803 503.8993 504.0182 504.1371 504.2560 504.3749 504.4938 504.6127 504.7315 504.8504 504.9692 505.0880 505.2067 505.3255 505.4442 505.5630 505.6817 505.8004 505.9190 506.0377 506.1563 506.2750 506.3936 506.5121 506.6307 506.7493 506.8678 506.9863 507.1048 507.2233 507.3418 507.4602 507.5787 507.6971 507.8155 507.9339 508.0522 508.1706 508.2889 508.4072 508.5255 508.6438 508.7620 508.8803 508.9985 509.1167 509.2349 509.3531 509.4712 509.5894 509.7075 509.8256 509.9437
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Water vapor effective temperature [K]
Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Nitrogen dioxide effective temperature [K]
Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 49: Ozone effective temperature [K]
Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 57: Lower limit used for wavelength scaling [nm]
Column 58: Upper limit used for wavelength scaling [nm]
Column 59: Order of smoothing polynomial
Column 60: Smoothing polynomial coefficient, order 0
Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 65: Smoothing polynomial coefficient, order 1
Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 70: Mean value of measured data inside fitting window [same units as measurements]
Column 71: Wavelength change polynomial coefficient, order 0
Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 85: Wavelength effective temperature [°C], 999=no effective temperature given
Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 89: Number of bright count cycles
Column 90: Number of dark count cycles
Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 94: Integration time [ms]
Column 95: Temperature at electronics board [°C], 999=no temperature signal
Column 96: Spectrometer control temperature [°C], 999=no temperature signal
Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 98: Temperature in head sensor [°C], 999=no temperature signal
Column 99: Humidity in head sensor [%], -9=no humidity signal
Column 100: Pressure in head sensor [hPa], -9=no pressure signal
Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SQ 20250919T124903.8Z 9393.534072 2 1 30.59 2 71.67 106.51 47.55 118.01 0.00 1 0.00 1 0 15 5.079e-03 5.069e-03 3.897e-03 3.881e-03 3.384589e+03 2.456241e+02 2.549376e+02 -6.000000e+00 2.861636e+02 283.70 -2.00 20.00 -2.00 505.25 0.00e+00 7.799000e-04 1.071406e-04 4.368589e-05 -6.000000e+00 1.431895e-04 283.70 -2.00 20.00 -2.00 500.30 0.00e+00 3.031734e-01 7.768132e-02 2.136413e-02 -6.000000e+00 1.009906e-01 228.50 -2.00 3.56 -2.00 501.90 0.00e+00 3.138 0.001 489.00 513.00 1 8.3744e+00 5.9688e-03 4.8127e-03 -6.0000e+00 7.7522e-03 1.4947e-02 1.5251e-03 5.8595e-04 -6.0000e+00 1.9994e-03 2.8293e-04 5.1817e-04 3.9583e-04 3.1881e-05 -6.0000e+00 5.3587e-04 -4.2550e-03 9.3134e-06 12 8 8 10 0 0 87.90 27.77 2.21 -0.00426 -0.00066 9 9 1 4 0 3398.300 36.00 20.01 27.77 20.53 3.8 921.02 765 -141 -47 219 -113 -190 470 -222 147 315 748 201 -334 -1239 293 207 -838 -109 -587 900 -145 268 307 171 22 1174 -402 -22 -485 -576 3 517 -519 -147 -319 -121 -241 269 157 -134 552 425 152 -437 65 378 577 -196 -416 7 -330 -640 118 -471 73 -115 471 101 116 216 1304 -6 -359 1041 -188 -854 -102 -520 -588 490 -287 691 231 -726 -560 -466 -563 -484 -112 -398 -737 23 -219 -603 -101 -30 -638 -300 765 -218 1120 1216 205 -256 430 550 161 162 -856 -67 -110 -211 -421 -729 -1037 -844 -271 32 382 246 109 -1367 -141 469 550 215 526 385 200 953 408 654 80 269 231 -235 299 -283 133 771 -362 -331 -376 195 31 -486 -481 361 -23 282 651 56 1083 84 317 396 179 -776 -268 -603 -1005 737 -139 -47 227 -121 -198 496 -237 157 333 776 206 -339 -1254 290 206 -852 -112 -621 953 -156 288 329 185 23 1258 -435 -23 -508 -588 3 510 -525 -152 -341 -130 -260 286 165 -140 571 442 160 -468 70 407 617 -209 -438 7 -329 -625 113 -453 71 -116 481 105 121 225 1345 -6 -379 1084 -197 -891 -104 -524 -585 477 -279 664 224 -721 -560 -466 -556 -470 -107 -379 -703 22 -211 -587 -99 -30 -638 -300 754 -217 1109 1214 199 -252 419 527 152 156 -812 -62 -101 -194 -398 -681 -1002 -826 -263 31 360 232 103 -1338 -138 462 545 215 528 388 201 942 399 629 77 256 221 -226 287 -273 127 733 -346 -313 -351 178 28 -446 -449 341 -22 274 637 56 1067 84 316 394 176 -757 -254 -567 -949
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SQ 20250919T130059.2Z 9393.542351 8 1 30.51 2 69.61 108.80 45.74 121.04 0.00 1 0.00 1 0 15 3.840e-03 3.866e-03 3.510e-03 3.495e-03 2.900242e+03 2.191808e+02 2.070512e+02 -6.000000e+00 2.163347e+02 283.69 -2.00 20.00 -2.00 505.26 0.00e+00 5.293025e-04 9.642450e-05 3.303550e-05 -6.000000e+00 1.082524e-04 283.69 -2.00 20.00 -2.00 500.28 0.00e+00 2.035723e-01 6.992281e-02 2.072572e-02 -6.000000e+00 7.635756e-02 228.50 -2.00 3.56 -2.00 501.92 0.00e+00 2.841 0.000 489.00 513.00 1 8.2914e+00 5.3527e-03 4.3600e-03 -6.0000e+00 5.8612e-03 1.5562e-02 1.3802e-03 5.3280e-04 -6.0000e+00 1.5119e-03 3.2405e-04 8.4013e-04 3.5664e-04 2.6037e-05 -6.0000e+00 4.0513e-04 -1.2372e-03 -1.9348e-05 11 8 0 10 0 0 57.55 27.78 2.31 -0.00124 0.00459 9 9 1 4 0 3389.570 36.00 20.00 27.78 21.45 3.6 924.54 210 -632 -682 -52 -357 205 334 565 45 248 208 252 -437 142 -512 152 -132 579 -824 -301 362 990 -339 82 470 99 -152 -410 -60 278 -73 -27 -12 135 20 605 -654 179 -145 157 -295 462 206 414 372 194 355 -535 441 -530 -612 -1284 273 -95 -742 -574 -164 -92 104 926 216 274 82 433 -81 -184 -12 -259 -339 308 -545 49 79 154 -503 -209 -118 17 394 -37 -42 -656 -107 -440 358 666 -110 -106 791 118 -336 79 8 90 -230 168 191 154 -638 -43 164 181 -429 -409 -289 -933 67 -323 232 -311 74 -2 563 -332 349 -134 366 508 281 235 -252 103 -71 -233 434 -219 -192 607 600 -121 333 101 528 -43 -248 -115 45 335 -171 -154 238 85 -335 302 566 -64 -564 -374 -554 193 -299 199 -611 -677 -53 -375 219 363 619 49 270 223 267 -459 146 -527 156 -137 610 -901 -333 400 1087 -359 87 498 105 -161 -430 -65 289 -75 -27 -13 144 21 636 -695 187 -150 160 -302 471 212 431 391 205 373 -561 451 -533 -600 -1296 268 -94 -713 -567 -166 -94 106 939 220 280 84 444 -83 -187 -12 -255 -330 294 -520 46 76 149 -492 -204 -114 16 366 -34 -39 -617 -101 -420 343 641 -108 -104 765 116 -332 79 8 91 -232 167 186 146 -595 -39 147 163 -400 -394 -287 -944 67 -320 226 -304 73 -2 566 -341 358 -132 362 503 278 230 -244 102 -70 -230 427 -218 -191 598 589 -120 326 98 502 -40 -233 -108 43 311 -162 -148 230 82 -329 296 554 -63 -549 -357 -518 177 -275
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