File name: Pandora243s1_Toronto-CNTower_20250925_L2Fit_fwvt1c7d20250508p1-8.txt
File generation date: 20251204T191622.6Z
Data description: Level 2 spectral fitting results file
Data file version: fwvt1c7p1-8
Local principal investigator: Vitali Fioletov
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 243
Spectrometer number: 1
Processing software version used: BlickP v1.8.75
Instrument operation file used: Pandora243_OF_v3d20230125.txt
Instrument calibration file used: Pandora243s1_CF_v7d20250508.txt
Level 1 file used: Pandora243s1_Toronto-CNTower_20250925_L1_smca1c7d20250508p1-8.txt
Full location name: CN Tower Observation Pod Roof, 290 Bremner Blvd, Toronto, ON M5V 3L9
Short location name: Toronto-CNTower
Country of location: Canada
Location latitude [deg]: 43.6426
Location longitude [deg]: -79.3871
Location altitude [m]: 330
Local noon date: 20250925
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: None
First and last pixel inside fitting window: 1621 1771
Nominal wavelengths inside fitting window [nm]: 492.0313 492.1519 492.2725 492.3931 492.5137 492.6342 492.7548 492.8753 492.9958 493.1163 493.2368 493.3572 493.4776 493.5981 493.7185 493.8388 493.9592 494.0796 494.1999 494.3202 494.4405 494.5608 494.6811 494.8013 494.9216 495.0418 495.1620 495.2822 495.4023 495.5225 495.6426 495.7627 495.8828 496.0029 496.1230 496.2430 496.3630 496.4830 496.6030 496.7230 496.8430 496.9629 497.0829 497.2028 497.3227 497.4425 497.5624 497.6823 497.8021 497.9219 498.0417 498.1615 498.2812 498.4010 498.5207 498.6404 498.7601 498.8798 498.9994 499.1191 499.2387 499.3583 499.4779 499.5974 499.7170 499.8365 499.9561 500.0756 500.1951 500.3145 500.4340 500.5534 500.6728 500.7922 500.9116 501.0310 501.1503 501.2697 501.3890 501.5083 501.6276 501.7468 501.8661 501.9853 502.1045 502.2237 502.3429 502.4621 502.5812 502.7003 502.8195 502.9386 503.0576 503.1767 503.2957 503.4148 503.5338 503.6528 503.7717 503.8907 504.0096 504.1286 504.2475 504.3664 504.4852 504.6041 504.7229 504.8417 504.9605 505.0793 505.1981 505.3168 505.4356 505.5543 505.6730 505.7917 505.9103 506.0290 506.1476 506.2662 506.3848 506.5034 506.6220 506.7405 506.8591 506.9776 507.0961 507.2145 507.3330 507.4514 507.5699 507.6883 507.8067 507.9250 508.0434 508.1617 508.2800 508.3984 508.5166 508.6349 508.7532 508.8714 508.9896 509.1078 509.2260 509.3442 509.4623 509.5804 509.6986 509.8167 509.9347
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Water vapor effective temperature [K]
Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Nitrogen dioxide effective temperature [K]
Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 49: Ozone effective temperature [K]
Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 57: Lower limit used for wavelength scaling [nm]
Column 58: Upper limit used for wavelength scaling [nm]
Column 59: Order of smoothing polynomial
Column 60: Smoothing polynomial coefficient, order 0
Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 65: Smoothing polynomial coefficient, order 1
Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 70: Mean value of measured data inside fitting window [same units as measurements]
Column 71: Wavelength change polynomial coefficient, order 0
Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 85: Wavelength effective temperature [°C], 999=no effective temperature given
Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 89: Number of bright count cycles
Column 90: Number of dark count cycles
Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 94: Integration time [ms]
Column 95: Temperature at electronics board [°C], 999=no temperature signal
Column 96: Spectrometer control temperature [°C], 999=no temperature signal
Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 98: Temperature in head sensor [°C], 999=no temperature signal
Column 99: Humidity in head sensor [%], -9=no humidity signal
Column 100: Pressure in head sensor [hPa], -9=no pressure signal
Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SQ 20250925T124450.4Z 9399.531138 89 1 30.91 2 73.72 107.80 114.15 96.07 0.00 1 0.00 1 0 15 7.492e-03 7.429e-03 6.766e-03 6.711e-03 8.872581e+03 4.787528e+02 5.813198e+02 -6.000000e+00 4.208178e+02 282.94 -2.00 20.00 -2.00 505.26 0.00e+00 6.573537e-04 1.851181e-04 5.635185e-05 -6.000000e+00 2.108556e-04 282.94 -2.00 20.00 -2.00 500.11 0.00e+00 2.748153e-01 1.366293e-01 6.155123e-02 -6.000000e+00 1.489841e-01 227.78 -2.00 3.56 -2.00 501.74 0.00e+00 3.508 0.001 489.00 513.00 1 9.6140e+00 1.0495e-02 7.1904e-03 -6.0000e+00 1.1433e-02 2.5161e-02 2.6538e-03 1.4724e-03 -6.0000e+00 2.9510e-03 7.7371e-05 5.0060e-04 6.6405e-04 4.9221e-05 -6.0000e+00 7.9039e-04 5.0218e-04 -7.6529e-06 12 8 8 10 0 0 -24.98 27.46 2.35 0.00050 0.00397 8 8 1 4 0 3863.080 35.75 20.00 27.46 23.25 3.6 937.24 -417 -577 -464 1253 -178 -103 339 -710 683 -608 1057 -20 346 -448 355 -1468 506 -375 237 -119 -894 1286 -139 1136 1262 216 -368 35 -708 926 317 -402 -1047 1059 -333 -1067 -336 -278 698 72 770 274 147 -590 250 -217 372 1223 -835 587 -357 -652 -962 117 -976 -346 116 300 788 -735 642 562 -941 421 1109 1017 447 -672 -1276 564 591 -404 -1059 405 -369 -172 -262 -2091 -1045 412 1797 -98 -864 1470 45 179 -42 -2028 74 -298 -591 -167 188 177 -111 -103 208 -1116 257 25 -341 -1130 798 -1129 667 -222 641 -1167 1202 92 -775 -421 96 232 1065 200 215 -47 818 -238 985 -316 786 474 -274 553 1633 -362 686 1103 115 -1357 -660 74 1350 -836 641 499 105 -557 -738 -808 1464 -124 -37 -266 -76 663 -619 -1032 -450 -418 -585 -482 1249 -185 -109 365 -782 742 -664 1118 -21 358 -460 359 -1514 518 -395 254 -130 -990 1396 -154 1238 1378 238 -407 39 -761 952 320 -408 -1085 1105 -363 -1187 -370 -303 745 76 811 291 158 -645 274 -239 406 1310 -899 608 -363 -648 -943 114 -975 -354 121 316 830 -786 677 594 -1014 447 1164 1056 460 -688 -1296 555 577 -397 -1054 401 -373 -173 -260 -2084 -1015 391 1681 -93 -840 1408 44 177 -40 -1955 69 -281 -561 -160 181 171 -106 -96 188 -994 220 22 -301 -961 684 -1027 619 -212 609 -1121 1115 86 -737 -403 93 225 1029 196 212 -47 808 -235 948 -303 733 442 -258 518 1515 -343 641 1023 107 -1270 -603 67 1190 -758 582 463 100 -538 -723 -798 1422 -123 -37 -263 -74 630 -584 -966 -419
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SQ 20250925T143806.2Z 9399.609794 145 1 31.33 2 56.04 132.43 95.34 114.18 0.00 1 0.00 1 0 15 5.956e-03 5.892e-03 5.255e-03 5.220e-03 8.066062e+03 3.606693e+02 5.801187e+02 -6.000000e+00 3.345216e+02 282.93 -2.00 20.00 -2.00 505.21 0.00e+00 7.018141e-04 1.440111e-04 4.886340e-05 -6.000000e+00 1.676335e-04 282.93 -2.00 20.00 -2.00 500.14 0.00e+00 1.669369e-01 1.055531e-01 4.499645e-02 -6.000000e+00 1.184688e-01 227.77 -2.00 3.56 -2.00 501.75 0.00e+00 1.784 0.000 489.00 513.00 1 9.5701e+00 8.0973e-03 4.7725e-03 -6.0000e+00 9.0906e-03 1.2768e-02 2.0634e-03 1.1805e-03 -6.0000e+00 2.3472e-03 1.0330e-04 1.4400e-03 5.1664e-04 6.4436e-05 -6.0000e+00 6.2829e-04 -1.4879e-03 -1.7456e-05 12 8 8 10 0 0 98.26 27.39 2.61 -0.00149 0.00850 8 8 1 4 0 3916.000 35.50 20.00 27.39 23.77 3.7 941.71 117 -136 -759 235 -377 700 873 86 1393 503 436 -237 -125 -371 -437 132 327 -759 -362 194 458 223 714 445 103 -357 314 -304 -392 -325 -40 -809 628 -521 784 -929 -289 292 -376 -797 -541 336 -946 38 -224 886 361 152 676 -276 6 -1137 456 369 190 199 124 -445 -16 79 -35 -63 310 1521 -259 -410 -190 -399 580 -210 -757 -331 -83 -727 -357 -614 -106 -1049 936 -588 -511 -273 -304 5 339 348 -787 69 -211 50 -142 1245 548 675 87 400 619 -526 196 -3 -466 -1770 -507 -321 648 -273 -1479 184 475 -117 -127 443 -173 -552 1223 836 6 -167 -288 -637 1147 210 774 666 718 614 -1718 -467 -36 -350 127 557 216 -322 -232 -749 -247 -338 752 990 -57 392 -932 344 747 -481 -323 83 -503 1493 26 115 -135 -780 247 -410 770 976 92 1483 535 458 -247 -136 -397 -464 140 350 -792 -385 208 493 242 770 482 112 -391 340 -328 -414 -333 -40 -813 632 -546 834 -1018 -315 312 -400 -843 -569 351 -1012 40 -243 953 389 162 706 -284 6 -1120 435 353 185 199 128 -468 -16 83 -37 -66 326 1579 -272 -427 -194 -402 571 -206 -739 -321 -81 -721 -356 -614 -105 -1022 882 -558 -484 -259 -291 5 329 341 -783 68 -208 50 -141 1226 549 678 87 390 586 -489 176 -3 -410 -1594 -463 -304 631 -274 -1429 173 465 -115 -119 419 -166 -537 1175 810 6 -166 -286 -630 1096 199 719 616 666 572 -1641 -440 -34 -328 118 509 194 -288 -207 -675 -225 -314 704 938 -55 381 -921 338 730 -473 -313 79 -471 1353 24
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