File name: Pandora243s1_Toronto-CNTower_20251219_L2Fit_fsus1c7d20250508p1-8.txt File generation date: 20251220T052341.2Z Data description: Level 2 spectral fitting results file Data file version: fsus1c7p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 243 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora243_OF_v3d20230125.txt Instrument calibration file used: Pandora243s1_CF_v7d20250508.txt Level 1 file used: Pandora243s1_Toronto-CNTower_20251219_L1_smca1c7d20250508p1-8.txt Full location name: CN Tower Observation Pod Roof, 290 Bremner Blvd, Toronto, ON M5V 3L9 Short location name: Toronto-CNTower Country of location: Canada Location latitude [deg]: 43.6426 Location longitude [deg]: -79.3871 Location altitude [m]: 330 Local noon date: 20251219 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 204 349 Nominal wavelengths inside fitting window [nm]: 306.0978 306.2383 306.3787 306.5192 306.6596 306.8000 306.9404 307.0808 307.2212 307.3615 307.5019 307.6422 307.7826 307.9229 308.0632 308.2035 308.3438 308.4841 308.6243 308.7646 308.9048 309.0451 309.1853 309.3255 309.4657 309.6059 309.7461 309.8863 310.0264 310.1666 310.3067 310.4468 310.5869 310.7270 310.8671 311.0072 311.1472 311.2873 311.4273 311.5674 311.7074 311.8474 311.9874 312.1274 312.2674 312.4073 312.5473 312.6872 312.8271 312.9671 313.1070 313.2469 313.3868 313.5266 313.6665 313.8063 313.9462 314.0860 314.2258 314.3656 314.5054 314.6452 314.7850 314.9247 315.0645 315.2042 315.3439 315.4837 315.6234 315.7630 315.9027 316.0424 316.1820 316.3217 316.4613 316.6010 316.7406 316.8802 317.0197 317.1593 317.2989 317.4384 317.5780 317.7175 317.8570 317.9965 318.1360 318.2755 318.4150 318.5545 318.6939 318.8334 318.9728 319.1122 319.2516 319.3910 319.5304 319.6698 319.8091 319.9485 320.0878 320.2271 320.3664 320.5057 320.6450 320.7843 320.9236 321.0628 321.2021 321.3413 321.4805 321.6197 321.7589 321.8981 322.0373 322.1765 322.3156 322.4547 322.5939 322.7330 322.8721 323.0112 323.1503 323.2893 323.4284 323.5675 323.7065 323.8455 323.9845 324.1235 324.2625 324.4015 324.5405 324.6794 324.8184 324.9573 325.0962 325.2351 325.3740 325.5129 325.6518 325.7906 325.9295 326.0683 326.2072 326.3460 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Bromine oxide slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of bromine oxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of bromine oxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of bromine oxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of bromine oxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Bromine oxide effective temperature [K] Column 28: Independent uncertainty of bromine oxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of bromine oxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of bromine oxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective bromine oxide fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for bromine oxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Formaldehyde slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of formaldehyde slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of formaldehyde slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of formaldehyde slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of formaldehyde slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Formaldehyde effective temperature [K] Column 39: Independent uncertainty of formaldehyde effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of formaldehyde effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of formaldehyde effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective formaldehyde fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for formaldehyde [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Nitrous acid slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of nitrous acid slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of nitrous acid slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of nitrous acid slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of nitrous acid slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Nitrous acid effective temperature [K] Column 50: Independent uncertainty of nitrous acid effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of nitrous acid effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of nitrous acid effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective nitrous acid fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for nitrous acid [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 56: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 57: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 58: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 59: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 60: Nitrogen dioxide effective temperature [K] Column 61: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 62: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 63: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 64: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 65: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 66: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 67: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 68: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 69: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 70: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 71: Ozone effective temperature [K] Column 72: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 73: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 74: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 75: rms-based uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 76: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 77: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 78: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 79: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 80: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 81: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 82: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 83: Sulfur dioxide effective temperature [K] Column 84: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 85: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 86: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 87: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 88: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 89: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 90: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 91: Lower limit used for wavelength scaling [nm] Column 92: Upper limit used for wavelength scaling [nm] Column 93: Order of smoothing polynomial Column 94: Smoothing polynomial coefficient, order 0 Column 95: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 96: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 97: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 98: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 99: Smoothing polynomial coefficient, order 1 Column 100: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 101: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 102: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 103: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 104: Smoothing polynomial coefficient, order 2 Column 105: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 106: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 107: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 108: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 109: Smoothing polynomial coefficient, order 3 Column 110: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 111: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 112: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 113: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 114: Smoothing polynomial coefficient, order 4 Column 115: Independent uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 116: Structured uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 117: Common uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 118: rms-based uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 119: Mean value of measured data inside fitting window [same units as measurements] Column 120: Offset polynomial coefficient, order 0 Column 121: Independent uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 122: Structured uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 123: Common uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 124: rms-based uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 125: Wavelength change polynomial coefficient, order 0 Column 126: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 127: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 128: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 129: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 130: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 131: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 132: Resolution change polynomial coefficient, order 0 Column 133: Independent uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 134: Structured uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 135: Common uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 136: rms-based uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 137: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 138: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 139: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 140: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 141: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 142: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 143: Atmospheric variability [%], 999=no atmospheric variability was determined Column 144: Wavelength effective temperature [°C], 999=no effective temperature given Column 145: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 146: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 147: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 148: Number of bright count cycles Column 149: Number of dark count cycles Column 150: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 151: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 152: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 153: Integration time [ms] Column 154: Temperature at electronics board [°C], 999=no temperature signal Column 155: Spectrometer control temperature [°C], 999=no temperature signal Column 156: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 157: Temperature in head sensor [°C], 999=no temperature signal Column 158: Humidity in head sensor [%], -9=no humidity signal Column 159: Pressure in head sensor [hPa], -9=no pressure signal Columns 160-305: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 306-451: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20251219T165146.4Z 9484.702620 204 1 28.32 2 67.28 174.26 72.70 178.97 0.00 1 0.00 1 0 49 1.046e-01 2.044e-02 1.490e-01 2.078e-02 -4.416428e-06 7.554169e-06 5.550042e-07 3.560305e-07 4.366867e-05 222.29 -2.00 3.56 -2.00 322.96 0.00e+00 6.901314e-03 3.068316e-03 3.986647e-04 1.481004e-05 1.203391e-02 272.72 -2.00 20.00 -2.00 323.40 0.00e+00 1.122096e-02 4.000682e-03 7.419191e-05 2.414204e-05 2.203524e-02 272.72 -2.00 20.00 -2.00 322.52 0.00e+00 8.506967e-03 7.738322e-03 8.958711e-04 5.907702e-06 2.248811e-02 272.72 -2.00 20.00 -2.00 322.81 0.00e+00 3.950038e-01 3.652717e-02 3.048676e-03 1.999521e-03 1.304910e-01 206.86 20.56 0.00 0.16 223.59 320.30 0.00e+00 3.218601e-03 3.145989e-03 7.846311e-04 7.876700e-06 3.190363e-03 272.72 -2.00 20.00 -2.00 319.39 0.00e+00 2.568 0.000 303.00 329.40 4 7.0817e+00 6.9702e-02 2.4837e-02 1.8406e-03 4.0215e-01 1.2595e-01 1.2336e-01 1.5217e-02 2.4946e-04 4.3394e-01 -1.0571e-01 6.9846e-02 1.0666e-02 1.0741e-04 2.3504e-01 1.5687e-01 3.7337e-02 7.3412e-03 8.9590e-05 7.9914e-02 -6.6414e-02 2.1615e-02 1.3425e-03 7.4112e-05 5.9913e-02 2.2708e-05 5.0165e-02 2.5307e-02 1.0779e-03 2.1601e-05 5.5107e-03 1.9243e-04 7.0326e-04 4.3560e-05 8.5119e-07 3.1327e-03 -4.8106e-03 0.0000e+00 3.8869e+00 1.6909e+00 3.0031e-02 4.2679e-04 6.5317e+00 12 8 8 10 0 0 96.30 26.95 0.42 -0.00481 -0.00334 8 8 1 5 0 3539.210 35.50 20.00 26.95 2.98 3.7 788.66 -41111 -25506 -23715 -51451 -34488 -669 2549 55246 1578 1301 4788 19622 3495 19382 -7921 7375 -5726 795 1521 -14748 -10749 -2281 20947 -6283 -19139 15055 -10173 -2140 14531 2301 -11213 4797 12600 22689 6794 -2887 7272 12962 6674 7515 1552 3908 3445 -169 -3171 2320 1425 -1423 4953 -1716 -5318 9838 -1320 2572 3267 -1707 -2431 -6896 968 -1262 -1244 -2561 -2683 -858 731 -821 -1960 -185 -1425 -1816 -5393 -5977 3306 3357 242 4137 -1881 -681 477 3475 -3364 -1537 3183 -2606 -2730 -1530 1435 -3208 -60 1490 2980 -2349 625 -1596 1280 -104 1468 -2374 1938 794 2546 2007 -2870 -83 2599 3702 1423 -1825 -3117 1622 -1679 786 1189 996 -927 1827 1922 -3240 -3175 -754 1034 -1899 -1666 1694 1178 -2237 1514 -701 -276 -963 -1544 1040 -1509 3035 -285 951 -1626 532 -186 -697 -728 1365 680 433 530 -1124 -2060 -1095 -1018 -3498 -2036 -29 137 1384 124 109 403 1369 313 1352 -794 607 -584 77 150 -1742 -1096 -196 1349 -675 -2740 1562 -1493 -264 1456 305 -2087 901 2525 4385 1653 -806 1809 3015 1672 1842 403 986 900 -49 -1038 764 502 -532 1930 -660 -2292 3485 -528 1028 1408 -853 -1196 -3541 429 -601 -588 -1336 -1600 -545 471 -527 -1212 -103 -721 -847 -2579 -3165 1841 2141 178 3094 -1563 -593 433 3167 -3344 -1482 2776 -2221 -2139 -1108 1014 -2614 -53 1490 3290 -2894 731 -1781 1262 -97 1381 -2485 2034 886 2942 2461 -3977 -119 3703 5071 1877 -2306 -3797 1890 -2108 1021 1615 1367 -1270 2344 2323 -3903 -3668 -816 1121 -2295 -2180 2295 1667 -3356 2274 -1142 -468 -1684 -2765 1803 -2585 4755 -443 1425 -2557 876 -336 -1373 -1549 3028 1576 1029 1253 -2687 SS 20251219T181253.4Z 9484.758951 253 1 30.78 2 68.38 194.31 74.69 196.89 0.00 1 0.00 1 0 49 5.568e-02 5.903e-03 7.703e-02 6.723e-03 -1.877078e-06 2.440400e-06 3.278810e-07 3.560792e-07 2.371643e-05 222.30 -2.00 3.56 -2.00 323.01 0.00e+00 -5.513444e-04 9.908994e-04 1.892609e-04 1.478538e-05 6.404680e-03 272.72 -2.00 20.00 -2.00 323.40 0.00e+00 2.054720e-03 1.281226e-03 2.101431e-05 2.421309e-05 1.189290e-02 272.72 -2.00 20.00 -2.00 322.57 0.00e+00 7.189983e-04 2.482796e-03 1.073082e-04 6.405739e-06 1.196754e-02 272.72 -2.00 20.00 -2.00 322.84 0.00e+00 4.323406e-01 1.262488e-02 2.994283e-04 1.999448e-03 6.924176e-02 228.17 6.75 0.00 0.14 118.65 320.47 0.00e+00 1.663862e-03 1.082986e-03 1.153198e-04 7.889537e-06 1.757252e-03 272.72 -2.00 20.00 -2.00 319.53 0.00e+00 2.690 0.000 303.00 329.40 4 5.8808e+00 2.7010e-02 2.5072e-02 1.8411e-03 2.1317e-01 9.0969e-02 4.7849e-02 2.9382e-03 2.4431e-04 2.3025e-01 -7.2209e-02 2.5595e-02 3.0092e-03 1.0945e-04 1.2519e-01 6.2415e-02 1.6416e-02 3.7886e-03 1.1120e-04 4.4157e-02 -1.2889e-02 8.8453e-03 5.1576e-04 8.6874e-05 3.5210e-02 7.7372e-05 8.8533e-03 4.6873e-03 4.0972e-04 1.6217e-05 1.6592e-03 -4.0724e-04 2.1711e-04 1.4645e-05 8.5235e-07 1.6630e-03 -2.7230e-03 0.0000e+00 8.3034e-01 4.9921e-01 4.0358e-04 6.0180e-04 3.3832e+00 12 8 8 10 0 0 99.96 27.06 0.95 -0.00272 -0.00583 10 10 1 5 0 3077.270 35.50 20.00 27.06 2.79 3.7 786.07 -18549 30144 8474 -24561 24278 -741 8039 8676 3164 2518 -22217 21706 4038 -4203 1589 -3267 -332 -641 7567 6999 -3253 1214 1326 -8326 6004 79 3670 -1922 -3054 -2299 774 -1075 1298 3943 -3988 1687 2447 490 919 -717 -23 -3248 -1450 -1539 450 651 802 1242 -4 12 -1846 1501 -1013 427 2256 1374 -206 874 903 -1882 952 -1638 -868 -556 754 402 574 -660 -2541 6 -1005 896 -260 1780 -1448 762 -488 269 282 1117 -533 434 -570 -884 997 -89 -453 -477 -806 -362 174 24 1018 -187 -198 -18 281 -587 -434 20 731 24 601 -447 506 -55 -767 -289 679 263 185 -715 167 379 -335 533 527 -343 -26 205 -835 -81 651 204 -29 -72 137 -425 496 -156 -51 141 -329 -192 -329 438 5 171 -304 70 19 69 75 -768 627 78 -449 422 173 -782 464 -25 297 387 171 147 -1825 1147 270 -310 109 -248 -26 -53 602 553 -269 92 106 -827 577 9 418 -219 -356 -296 114 -197 271 874 -1008 416 601 123 232 -183 -6 -858 -390 -449 139 216 283 452 -1 5 -714 546 -375 162 918 624 -104 437 427 -877 431 -832 -500 -347 480 252 341 -364 -1278 3 -452 434 -148 1133 -1068 590 -402 213 237 972 -481 424 -535 -768 783 -66 -339 -390 -747 -377 184 27 1114 -194 -204 -17 277 -632 -490 21 823 30 782 -631 724 -77 -1022 -355 783 306 225 -934 227 518 -448 684 642 -442 -32 240 -1009 -97 841 284 -41 -108 215 -710 861 -278 -93 255 -576 -321 -524 673 9 294 -571 143 39 150 169 -1792 1439 179