File name: Pandora243s1_Toronto-CNTower_20260114_L2Fit_fwvt1c7d20250508p1-8.txt
File generation date: 20260115T053358.1Z
Data description: Level 2 spectral fitting results file
Data file version: fwvt1c7p1-8
Local principal investigator: Vitali Fioletov
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 243
Spectrometer number: 1
Processing software version used: BlickP v1.8.75
Instrument operation file used: Pandora243_OF_v3d20230125.txt
Instrument calibration file used: Pandora243s1_CF_v7d20250508.txt
Level 1 file used: Pandora243s1_Toronto-CNTower_20260114_L1_smca1c7d20250508p1-8.txt
Full location name: CN Tower Observation Pod Roof, 290 Bremner Blvd, Toronto, ON M5V 3L9
Short location name: Toronto-CNTower
Country of location: Canada
Location latitude [deg]: 43.6426
Location longitude [deg]: -79.3871
Location altitude [m]: 330
Local noon date: 20260114
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: None
First and last pixel inside fitting window: 1621 1771
Nominal wavelengths inside fitting window [nm]: 492.0313 492.1519 492.2725 492.3931 492.5137 492.6342 492.7548 492.8753 492.9958 493.1163 493.2368 493.3572 493.4776 493.5981 493.7185 493.8388 493.9592 494.0796 494.1999 494.3202 494.4405 494.5608 494.6811 494.8013 494.9216 495.0418 495.1620 495.2822 495.4023 495.5225 495.6426 495.7627 495.8828 496.0029 496.1230 496.2430 496.3630 496.4830 496.6030 496.7230 496.8430 496.9629 497.0829 497.2028 497.3227 497.4425 497.5624 497.6823 497.8021 497.9219 498.0417 498.1615 498.2812 498.4010 498.5207 498.6404 498.7601 498.8798 498.9994 499.1191 499.2387 499.3583 499.4779 499.5974 499.7170 499.8365 499.9561 500.0756 500.1951 500.3145 500.4340 500.5534 500.6728 500.7922 500.9116 501.0310 501.1503 501.2697 501.3890 501.5083 501.6276 501.7468 501.8661 501.9853 502.1045 502.2237 502.3429 502.4621 502.5812 502.7003 502.8195 502.9386 503.0576 503.1767 503.2957 503.4148 503.5338 503.6528 503.7717 503.8907 504.0096 504.1286 504.2475 504.3664 504.4852 504.6041 504.7229 504.8417 504.9605 505.0793 505.1981 505.3168 505.4356 505.5543 505.6730 505.7917 505.9103 506.0290 506.1476 506.2662 506.3848 506.5034 506.6220 506.7405 506.8591 506.9776 507.0961 507.2145 507.3330 507.4514 507.5699 507.6883 507.8067 507.9250 508.0434 508.1617 508.2800 508.3984 508.5166 508.6349 508.7532 508.8714 508.9896 509.1078 509.2260 509.3442 509.4623 509.5804 509.6986 509.8167 509.9347
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Water vapor effective temperature [K]
Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Nitrogen dioxide effective temperature [K]
Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 49: Ozone effective temperature [K]
Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 57: Lower limit used for wavelength scaling [nm]
Column 58: Upper limit used for wavelength scaling [nm]
Column 59: Order of smoothing polynomial
Column 60: Smoothing polynomial coefficient, order 0
Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 65: Smoothing polynomial coefficient, order 1
Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 70: Mean value of measured data inside fitting window [same units as measurements]
Column 71: Wavelength change polynomial coefficient, order 0
Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 85: Wavelength effective temperature [°C], 999=no effective temperature given
Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 89: Number of bright count cycles
Column 90: Number of dark count cycles
Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 94: Integration time [ms]
Column 95: Temperature at electronics board [°C], 999=no temperature signal
Column 96: Spectrometer control temperature [°C], 999=no temperature signal
Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 98: Temperature in head sensor [°C], 999=no temperature signal
Column 99: Humidity in head sensor [%], -9=no humidity signal
Column 100: Pressure in head sensor [hPa], -9=no pressure signal
Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SQ 20260114T151414.0Z 9510.634884 237 1 30.59 2 71.63 147.55 73.11 197.08 0.00 1 0.00 1 0 15 3.665e-03 3.680e-03 2.611e-03 2.601e-03 1.800413e+03 1.515583e+02 1.295464e+02 -6.000000e+00 1.964040e+02 271.11 -2.00 20.00 -2.00 505.26 0.00e+00 4.932409e-04 6.966271e-05 3.028161e-05 -6.000000e+00 1.002568e-04 271.11 -2.00 20.00 -2.00 500.28 0.00e+00 3.531747e-01 5.207560e-02 1.636224e-02 -6.000000e+00 7.307495e-02 223.32 -2.00 3.56 -2.00 501.91 0.00e+00 3.133 0.001 489.00 513.00 1 8.5474e+00 3.9809e-03 4.5593e-03 -6.0000e+00 5.5857e-03 1.6199e-02 1.0267e-03 4.3657e-04 -6.0000e+00 1.4473e-03 2.3954e-04 2.1596e-03 2.6642e-04 2.0007e-05 -6.0000e+00 3.8610e-04 3.5049e-04 -9.6243e-05 10 0 0 10 0 0 99.90 27.17 2.06 0.00035 0.01533 8 8 1 4 0 3823.030 35.50 20.00 27.17 9.08 3.6 834.29 -94 -656 -495 647 276 540 33 298 248 -7 644 -109 -578 -368 -148 -175 220 310 -158 176 314 1180 239 0 304 -112 67 73 -207 144 51 10 -308 223 -92 -475 -494 -98 -181 -441 52 606 326 -638 -406 64 766 252 37 29 -363 -104 1 -321 -415 -428 -532 32 38 326 -154 82 -2 -55 91 71 -179 291 -48 -807 17 -258 236 -73 -602 227 -138 32 109 -245 -26 -453 258 -174 41 136 -59 43 -130 -5 261 -165 -471 355 -499 509 49 -266 -164 -553 -320 343 -410 -496 -19 -549 -469 -583 132 -12 -196 72 -44 9 236 812 310 645 788 -252 745 -159 119 58 -282 232 469 768 -63 381 214 -89 48 577 -261 -284 -543 753 -552 397 -9 -105 228 81 -464 1 -386 -452 -423 567 324 -92 -653 -505 644 284 567 36 322 268 -8 679 -114 -599 -375 -150 -177 224 322 -169 191 341 1275 260 0 333 -118 73 80 -220 148 52 10 -315 234 -100 -500 -519 -102 -194 -470 55 638 332 -663 -425 67 793 260 37 31 -368 -102 1 -312 -410 -435 -531 32 38 329 -156 83 -2 -56 92 71 -176 282 -48 -805 16 -253 231 -70 -582 218 -131 32 105 -236 -25 -439 250 -163 38 130 -57 41 -125 -5 253 -162 -470 355 -501 501 48 -253 -152 -503 -287 308 -378 -473 -18 -547 -466 -572 127 -11 -190 71 -44 9 240 825 318 660 803 -257 741 -157 116 57 -276 227 459 748 -62 370 208 -86 45 536 -243 -265 -515 720 -544 376 -9 -101 221 79 -456 1 -374 -428 -410 536 306
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SQ 20260114T163212.8Z 9510.689038 288 1 30.10 2 66.05 166.10 79.06 213.37 0.00 1 0.00 1 0 15 2.029e-03 2.034e-03 1.089e-03 1.086e-03 1.237349e+03 6.074320e+01 9.343912e+01 -6.000000e+00 1.087632e+02 271.10 -2.00 20.00 -2.00 505.25 0.00e+00 4.885019e-04 2.907398e-05 2.835205e-05 -6.000000e+00 5.550969e-05 271.10 -2.00 20.00 -2.00 500.38 0.00e+00 2.738182e-01 2.157598e-02 1.111303e-02 -6.000000e+00 4.044404e-02 223.32 -2.00 3.56 -2.00 501.99 0.00e+00 2.446 0.000 489.00 513.00 1 7.3184e+00 1.6493e-03 3.5419e-03 -6.0000e+00 3.0917e-03 1.3259e-02 4.2599e-04 3.1049e-04 -6.0000e+00 8.0049e-04 9.0557e-04 9.3736e-04 1.1168e-04 1.6859e-05 -6.0000e+00 2.1387e-04 -1.1763e-03 -3.5017e-05 10 0 0 10 0 0 99.93 27.16 2.23 -0.00118 0.00533 19 19 1 4 0 1584.070 35.50 20.00 27.16 10.10 3.7 843.32 -206 -216 -205 56 -150 134 479 326 227 249 460 146 51 -32 -107 -176 -42 125 -4 -93 -70 366 270 123 337 77 35 70 -197 -43 138 -202 -227 58 -119 -450 -53 122 -36 -64 79 327 -64 -2 -53 4 -82 15 -263 -153 -267 -220 39 -147 -211 -257 -93 -64 75 257 80 -15 81 204 -2 -22 49 31 -162 -85 -120 -181 89 -170 -213 -38 -227 -349 55 -288 -170 -156 -393 -162 151 -166 -7 -2 335 69 52 139 -31 -59 36 -30 252 -368 -250 -62 4 -315 -162 -192 -217 -647 -166 -191 8 36 -29 -120 -114 101 218 338 215 409 406 110 143 228 254 53 82 1 107 291 -65 565 110 110 -238 223 -43 214 -27 203 -24 157 143 176 183 63 190 -111 -196 -154 -360 -348 -129 -204 -209 -204 57 -153 140 508 350 244 266 483 151 52 -33 -107 -177 -42 129 -5 -97 -74 384 284 130 356 82 37 74 -202 -44 138 -202 -230 60 -124 -477 -56 127 -37 -65 81 332 -66 -2 -56 4 -86 16 -269 -153 -268 -215 37 -142 -207 -259 -93 -65 77 261 82 -15 82 208 -3 -22 48 31 -161 -84 -117 -176 87 -168 -207 -38 -224 -341 53 -275 -163 -150 -381 -158 149 -161 -7 -2 325 67 51 138 -31 -60 36 -30 247 -354 -242 -58 3 -296 -156 -184 -215 -652 -166 -189 7 35 -28 -120 -111 100 217 338 217 412 407 110 140 227 250 52 80 1 106 288 -64 553 108 107 -228 209 -40 200 -26 197 -23 152 140 173 181 63 189 -111 -193 -148 -341 -334 -123
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