File name: Pandora145s1_Toronto-Scarborough_20201222_L2Fit_fwvt1c7d20191218p1-8.txt
File generation date: 20260322T204437.5Z
Data description: Level 2 spectral fitting results file
Data file version: fwvt1c7p1-8
Local principal investigator: Vitali Fioletov
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 145
Spectrometer number: 1
Processing software version used: BlickP v1.8.88
Instrument operation file used: Pandora145_OF_v5d20190718.txt
Instrument calibration file used: Pandora145s1_CF_v7d20191218.txt
Level 1 file used: Pandora145s1_Toronto-Scarborough_20201222_L1_smca1c7d20191218p1-8.txt.bz2
Full location name: University of Toronto - Scarborough
Short location name: Toronto-Scarborough
Country of location: Canada
Location latitude [deg]: 43.7843
Location longitude [deg]: -79.1874
Location altitude [m]: 137
Local noon date: 20201222
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: "Modification of session 3 for not so summer ref day"
First and last pixel inside fitting window: 1647 1796
Nominal wavelengths inside fitting window [nm]: 492.0727 492.1938 492.3149 492.4360 492.5570 492.6780 492.7990 492.9200 493.0410 493.1620 493.2829 493.4039 493.5248 493.6457 493.7666 493.8874 494.0083 494.1291 494.2499 494.3707 494.4915 494.6123 494.7330 494.8538 494.9745 495.0952 495.2159 495.3365 495.4572 495.5778 495.6984 495.8190 495.9396 496.0602 496.1807 496.3013 496.4218 496.5423 496.6628 496.7832 496.9037 497.0241 497.1445 497.2649 497.3853 497.5057 497.6260 497.7464 497.8667 497.9870 498.1073 498.2275 498.3478 498.4680 498.5882 498.7084 498.8286 498.9488 499.0689 499.1890 499.3092 499.4293 499.5493 499.6694 499.7894 499.9095 500.0295 500.1495 500.2695 500.3894 500.5094 500.6293 500.7492 500.8691 500.9890 501.1089 501.2287 501.3485 501.4683 501.5881 501.7079 501.8277 501.9474 502.0672 502.1869 502.3066 502.4262 502.5459 502.6655 502.7852 502.9048 503.0244 503.1439 503.2635 503.3830 503.5026 503.6221 503.7416 503.8610 503.9805 504.0999 504.2194 504.3388 504.4582 504.5775 504.6969 504.8162 504.9356 505.0549 505.1742 505.2934 505.4127 505.5319 505.6511 505.7703 505.8895 506.0087 506.1279 506.2470 506.3661 506.4852 506.6043 506.7234 506.8424 506.9615 507.0805 507.1995 507.3185 507.4374 507.5564 507.6753 507.7942 507.9131 508.0320 508.1509 508.2697 508.3885 508.5074 508.6261 508.7449 508.8637 508.9824 509.1012 509.2199 509.3386 509.4572 509.5759 509.6945 509.8132 509.9318
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Water vapor effective temperature [K]
Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Nitrogen dioxide effective temperature [K]
Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 49: Ozone effective temperature [K]
Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 57: Lower limit used for wavelength scaling [nm]
Column 58: Upper limit used for wavelength scaling [nm]
Column 59: Order of smoothing polynomial
Column 60: Smoothing polynomial coefficient, order 0
Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 65: Smoothing polynomial coefficient, order 1
Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 70: Mean value of measured data inside fitting window [same units as measurements]
Column 71: Wavelength change polynomial coefficient, order 0
Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 85: Wavelength effective temperature [°C], 999=no effective temperature given
Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 89: Number of bright count cycles
Column 90: Number of dark count cycles
Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 94: Integration time [ms]
Column 95: Temperature at electronics board [°C], 999=no temperature signal
Column 96: Spectrometer control temperature [°C], 999=no temperature signal
Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 98: Temperature in head sensor [°C], 999=no temperature signal
Column 99: Humidity in head sensor [%], -9=no humidity signal
Column 100: Pressure in head sensor [hPa], -9=no pressure signal
Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SQ 20201222T125623.3Z 7661.539159 37 1 30.66 2 89.61 123.88 135.72 25.67 0.00 1 0.00 1 0 29 1.591e-02 1.563e-02 1.497e-03 1.489e-03 8.223011e+03 8.921052e+01 5.280972e+02 -6.000000e+00 8.123806e+02 273.52 -2.00 20.00 -2.00 505.44 0.00e+00 4.589068e-03 3.965299e-05 2.281739e-04 -6.000000e+00 4.287954e-04 273.52 -2.00 20.00 -2.00 501.21 0.00e+00 1.190248e+00 2.791947e-02 8.458496e-02 -6.000000e+00 3.083621e-01 222.50 -2.00 3.57 -2.00 502.68 0.00e+00 20.135 0.159 489.00 513.00 1 5.3126e+00 2.1225e-03 3.7186e-02 -6.0000e+00 2.3506e-02 -4.2764e-02 5.4439e-04 2.6441e-03 -6.0000e+00 6.2117e-03 4.9229e-04 2.3482e-03 1.2189e-04 1.0245e-04 -6.0000e+00 1.3547e-03 2.8559e-02 -1.8704e-04 12 8 8 10 0 0 93.87 19.39 11.04 0.02856 0.04485 11 11 1 4 0 2787.180 23.32 15.00 19.39 7.43 16.1 948.70 -5879 -4359 -2639 -1084 -384 617 1235 1336 1005 382 -549 -893 -1743 -2183 -2207 -1724 -1396 1 836 771 1092 1169 1051 1412 2118 1812 1700 784 -621 -2270 -2493 -1922 -456 1029 1994 1637 1070 162 182 28 776 979 1417 2116 2501 2427 1806 1476 566 -820 -1594 -2576 -2448 -1928 -130 532 1405 1737 1764 1298 1694 2086 2098 2080 1288 962 45 -479 -1371 -1617 -1956 -960 -742 -137 58 -51 -995 -1693 -2276 -2368 -1941 -1635 -1162 -1247 -426 -804 -668 -878 -417 -316 420 1207 1888 1747 1781 1414 571 -967 -2211 -2573 -2808 -1788 -502 554 959 418 -826 -1166 -1397 -280 457 986 1793 2258 2809 2835 2993 2070 1739 681 156 -115 491 618 881 866 511 239 452 144 -247 -761 -1604 -1879 -2324 -1339 -452 39 328 414 516 519 818 945 605 130 -913 -2333 -2500 -2892 -5206 -3905 -2313 -974 -352 573 1164 1269 953 359 -513 -829 -1605 -1997 -2019 -1584 -1303 0 772 719 1017 1091 986 1333 2008 1729 1623 747 -581 -2084 -2277 -1765 -424 991 1962 1618 1052 159 177 28 758 969 1360 2054 2453 2394 1783 1447 551 -789 -1568 -2508 -2371 -1894 -125 526 1410 1752 1779 1313 1718 2132 2157 2139 1324 977 46 -481 -1376 -1603 -1939 -952 -744 -139 56 -51 -995 -1679 -2254 -2343 -1927 -1637 -1164 -1211 -417 -795 -659 -863 -407 -310 413 1205 1907 1762 1758 1367 564 -945 -2136 -2456 -2695 -1742 -484 556 985 432 -856 -1195 -1434 -289 462 1010 1846 2336 2909 2966 3178 2237 1873 729 165 -120 510 650 934 924 550 258 488 151 -256 -809 -1705 -1994 -2490 -1401 -482 43 359 459 576 583 889 1031 663 142 -984 -2583 -2740 -3206
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SQ 20201222T130213.9Z 7661.543216 45 1 29.77 2 88.74 124.90 135.24 27.56 0.00 1 0.00 1 0 22 6.227e-03 6.160e-03 9.259e-04 9.233e-04 9.664824e+03 5.711785e+01 6.569501e+02 -6.000000e+00 3.180315e+02 273.52 -2.00 20.00 -2.00 505.40 0.00e+00 2.958321e-03 2.460990e-05 1.649083e-04 -6.000000e+00 1.678632e-04 273.52 -2.00 20.00 -2.00 500.98 0.00e+00 1.411296e+00 1.752461e-02 8.016744e-02 -6.000000e+00 1.207111e-01 222.50 -2.00 3.57 -2.00 502.49 0.00e+00 18.177 0.117 489.00 513.00 1 4.7323e+00 1.3333e-03 3.1387e-02 -6.0000e+00 9.2016e-03 -3.0290e-02 3.4277e-04 2.4831e-03 -6.0000e+00 2.4314e-03 1.1576e-03 3.9099e-04 7.4441e-05 1.0791e-04 -6.0000e+00 5.3032e-04 1.4836e-02 -9.9097e-05 12 8 8 10 0 0 18.88 19.38 2.51 0.01484 0.01755 16 16 1 4 0 1859.880 23.32 14.99 19.38 7.61 16.0 949.22 -1830 -1241 -778 -53 465 592 943 802 668 477 75 -156 -414 -568 -703 -551 -413 1 306 272 202 345 377 424 670 705 631 37 -209 -993 -911 -761 -362 107 784 694 248 60 -95 -291 -184 377 553 648 807 815 577 470 156 -524 -886 -1326 -1057 -883 -270 255 293 429 562 353 648 579 777 738 696 341 100 -95 -401 -698 -952 -506 -326 -75 -215 -206 -385 -707 -938 -885 -935 -771 -634 -622 -451 -239 -337 -411 -196 -264 -79 126 627 605 643 282 288 -383 -992 -1162 -1057 -953 -368 -148 419 307 -179 -383 -501 -302 -60 280 690 894 1183 1449 1276 822 735 472 463 124 52 74 457 98 418 459 292 45 7 -107 -348 -499 -775 -690 -212 433 173 313 211 377 423 546 267 142 -444 -941 -1020 -1329 -1629 -1124 -712 -49 438 571 902 777 646 456 73 -150 -393 -533 -660 -520 -397 1 302 265 198 337 369 419 666 703 629 37 -202 -954 -865 -729 -346 107 783 696 247 59 -93 -284 -180 373 555 661 813 825 582 469 158 -519 -875 -1285 -1014 -859 -264 258 297 437 571 359 659 596 803 763 714 345 100 -94 -395 -694 -945 -492 -320 -75 -217 -206 -378 -684 -923 -868 -901 -751 -620 -615 -452 -236 -332 -413 -196 -264 -78 127 638 613 636 278 277 -368 -936 -1081 -984 -909 -357 -148 420 310 -180 -381 -496 -302 -62 290 704 917 1216 1498 1344 861 767 497 478 126 53 76 472 102 437 479 306 46 8 -110 -354 -506 -790 -706 -222 459 183 336 229 410 454 589 289 152 -480 -998 -1068 -1402
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