File name: Pandora145s1_Toronto-Scarborough_20210306_L2Fit_fout2c7d20191218p1-8.txt File generation date: 20260322T205436.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c7p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 145 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora145_OF_v5d20190718.txt Instrument calibration file used: Pandora145s1_CF_v7d20191218.txt Level 1 file used: Pandora145s1_Toronto-Scarborough_20210306_L1_smca1c7d20191218p1-8.txt.bz2 Full location name: University of Toronto - Scarborough Short location name: Toronto-Scarborough Country of location: Canada Location latitude [deg]: 43.7843 Location longitude [deg]: -79.1874 Location altitude [m]: 137 Local noon date: 20210306 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: "Modification of session 3 for not so summer ref day" First and last pixel inside fitting window: 226 368 Nominal wavelengths inside fitting window [nm]: 305.0466 305.1875 305.3283 305.4691 305.6100 305.7508 305.8915 306.0323 306.1731 306.3139 306.4546 306.5953 306.7361 306.8768 307.0175 307.1582 307.2988 307.4395 307.5801 307.7208 307.8614 308.0020 308.1427 308.2833 308.4238 308.5644 308.7050 308.8455 308.9861 309.1266 309.2671 309.4076 309.5481 309.6886 309.8291 309.9696 310.1100 310.2504 310.3909 310.5313 310.6717 310.8121 310.9525 311.0928 311.2332 311.3736 311.5139 311.6542 311.7945 311.9348 312.0751 312.2154 312.3557 312.4959 312.6362 312.7764 312.9166 313.0569 313.1971 313.3373 313.4774 313.6176 313.7578 313.8979 314.0380 314.1781 314.3183 314.4584 314.5984 314.7385 314.8786 315.0186 315.1587 315.2987 315.4387 315.5787 315.7187 315.8587 315.9987 316.1386 316.2786 316.4185 316.5584 316.6984 316.8383 316.9782 317.1180 317.2579 317.3978 317.5376 317.6774 317.8173 317.9571 318.0969 318.2367 318.3764 318.5162 318.6560 318.7957 318.9354 319.0751 319.2148 319.3545 319.4942 319.6339 319.7736 319.9132 320.0528 320.1925 320.3321 320.4717 320.6113 320.7508 320.8904 321.0300 321.1695 321.3090 321.4486 321.5881 321.7276 321.8671 322.0065 322.1460 322.2854 322.4249 322.5643 322.7037 322.8431 322.9825 323.1219 323.2613 323.4006 323.5400 323.6793 323.8186 323.9579 324.0972 324.2365 324.3758 324.5151 324.6543 324.7935 324.9328 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210306T150732.4Z 7735.630236 319 1 18.71 2 58.49 137.82 82.40 224.49 0.00 1 0.00 1 0 25 2.325e-02 6.516e-03 1.923e-02 3.848e-03 3.779460e-01 1.893616e-03 4.632451e-03 -6.000000e+00 1.283334e-02 225.42 -2.00 3.57 -2.00 317.89 0.00e+00 4.522091e-04 3.163059e-04 1.136055e-04 -6.000000e+00 5.485700e-04 273.53 -2.00 20.00 -2.00 317.35 0.00e+00 1.906 0.000 302.00 328.00 3 5.2718e+00 5.0156e-03 2.7287e-02 -6.0000e+00 3.1844e-02 7.9608e-02 5.6771e-03 1.9555e-02 -6.0000e+00 3.4699e-02 -1.9666e-02 3.7251e-03 9.7825e-03 -6.0000e+00 2.0591e-02 3.2992e-03 1.9540e-03 2.8398e-03 -6.0000e+00 8.8081e-03 2.4058e-04 -4.3993e-04 1.0153e-04 2.8718e-05 -6.0000e+00 5.7741e-04 -4.4822e-03 -1.1224e-05 12 9 1 12 1 1 99.91 18.95 0.20 -0.00448 -0.00779 5 10 1 5 0 2999.540 23.01 15.00 18.95 3.45 15.2 986.99 -3015 -6164 5555 -3553 1582 -11420 3708 -4777 2526 -8148 -6647 -5848 -9466 -5724 -2557 -3514 -1099 4428 2810 2115 -3581 -521 2407 2382 2591 130 692 -627 2805 -1795 670 -3038 4299 -489 -1852 -2413 754 -734 -3339 -873 931 -461 -433 -378 -247 -245 -1760 -355 -1621 1212 1411 505 -192 1077 1008 727 772 1668 853 534 -408 567 1380 2230 787 -189 -287 84 993 332 -187 110 292 529 537 -479 -598 -1385 -272 -727 -1139 -355 -1883 -1916 -1596 -913 -339 -91 663 -63 1060 499 0 -338 800 -98 1002 873 567 -19 -199 -149 -874 -586 -633 -967 -310 -490 -213 540 53 264 95 99 -291 376 -16 68 -302 55 -333 -289 635 72 599 174 328 1213 638 157 479 -69 167 41 -94 -138 31 -14 -81 -358 -242 -57 -510 -180 -431 364 -245 91 -701 207 -331 185 -717 -574 -513 -998 -635 -325 -518 -169 678 462 365 -674 -94 426 454 527 29 153 -133 535 -354 141 -743 1090 -139 -499 -619 203 -234 -1228 -375 437 -215 -209 -185 -120 -120 -869 -171 -786 621 716 283 -116 683 667 461 503 1074 576 354 -278 384 1023 1797 622 -150 -212 60 747 272 -171 105 278 481 454 -389 -437 -968 -197 -607 -1023 -355 -1944 -2062 -1722 -1051 -409 -113 823 -77 1171 537 0 -345 810 -112 1202 1116 789 -26 -260 -186 -1008 -680 -803 -1236 -410 -682 -296 807 82 420 148 153 -413 520 -22 96 -437 84 -524 -444 936 102 847 236 443 1611 877 225 733 -110 258 66 -160 -239 56 -25 -147 -633 -407 -95 -825 SS 20210306T151332.3Z 7735.634402 323 1 6.65 2 57.77 139.36 83.15 225.59 0.00 1 0.00 1 0 17 1.479e-02 6.034e-03 9.696e-03 2.622e-03 3.627200e-01 1.292871e-03 4.454317e-03 -6.000000e+00 8.166754e-03 225.42 -2.00 3.57 -2.00 317.34 0.00e+00 3.910039e-05 1.852229e-04 9.791159e-05 -6.000000e+00 3.490619e-04 273.53 -2.00 20.00 -2.00 316.79 0.00e+00 1.868 0.000 302.00 328.00 3 3.7962e+00 3.3970e-03 2.6395e-02 -6.0000e+00 2.0265e-02 4.1508e-02 3.8235e-03 1.8668e-02 -6.0000e+00 2.2081e-02 -1.1402e-02 2.3699e-03 9.3226e-03 -6.0000e+00 1.3103e-02 1.8244e-03 1.2089e-03 2.6687e-03 -6.0000e+00 5.6058e-03 1.1392e-03 -2.6217e-04 6.8715e-05 2.7410e-05 -6.0000e+00 3.6739e-04 -5.0602e-03 -7.3319e-07 12 1 1 12 9 1 98.50 18.96 0.26 -0.00506 -0.00703 7 37 1 5 0 809.790 23.01 15.00 18.96 3.96 15.3 990.19 -656 -1969 -1198 -948 -6451 -7755 -1760 -3969 1964 -2570 -1877 -8227 -4116 -656 1045 -260 1360 -181 -862 2882 -1561 500 186 281 553 -448 -382 -219 -1521 1276 -238 791 1075 -790 -626 -2175 -933 -427 -306 -354 -356 -836 -59 -580 -196 -838 -395 -282 -720 328 659 885 984 1091 1026 467 1413 435 1163 123 761 885 1536 1444 105 99 469 -249 770 168 5 -76 83 -325 93 160 80 -630 -250 -386 -809 -502 -2063 -1752 -1494 -887 -149 -571 -82 415 177 420 485 481 930 569 755 810 182 -582 -181 -658 -472 -167 -506 -1174 -755 -530 -326 120 21 -152 27 412 -3 658 543 249 240 -95 -467 15 557 197 897 310 791 978 1057 -185 -84 240 144 -15 -218 -34 -149 -49 -348 -176 -134 -407 -352 -53 -183 -116 -88 -552 -633 -144 -377 201 -297 -214 -1021 -565 -95 174 -50 275 -39 -198 664 -388 120 45 74 144 -123 -107 -58 -409 328 -67 229 345 -276 -204 -682 -313 -154 -135 -174 -195 -455 -33 -331 -111 -480 -223 -157 -399 182 387 568 634 748 734 325 1001 311 849 89 557 657 1248 1217 92 81 374 -195 632 151 4 -72 79 -312 83 134 64 -478 -197 -332 -756 -499 -2151 -1896 -1645 -1043 -177 -701 -101 491 202 459 508 485 993 652 926 1025 242 -776 -235 -810 -554 -198 -631 -1499 -1000 -708 -459 175 32 -238 41 610 -5 899 732 336 346 -141 -713 22 799 284 1264 420 1047 1282 1441 -268 -125 369 218 -23 -353 -56 -252 -85 -608 -299 -225 -651 -562 SS 20210306T151902.9Z 7735.638228 326 1 31.81 2 57.13 140.80 83.84 226.58 0.00 1 0.00 1 0 17 2.989e-02 6.422e-03 2.086e-02 3.867e-03 3.675906e-01 1.900063e-03 4.477466e-03 -6.000000e+00 1.650210e-02 225.42 -2.00 3.57 -2.00 318.08 0.00e+00 1.228847e-04 3.350108e-04 1.135867e-04 -6.000000e+00 7.053280e-04 273.53 -2.00 20.00 -2.00 317.53 0.00e+00 1.836 0.000 302.00 328.00 3 5.8721e+00 5.0635e-03 2.6405e-02 -6.0000e+00 4.0948e-02 9.0163e-02 5.7472e-03 1.8977e-02 -6.0000e+00 4.4616e-02 -2.0079e-02 3.8364e-03 9.5243e-03 -6.0000e+00 2.6476e-02 3.0638e-03 2.0188e-03 2.7551e-03 -6.0000e+00 1.1328e-02 1.4263e-04 -2.2345e-04 1.0271e-04 2.6686e-05 -6.0000e+00 7.4229e-04 -5.0329e-03 1.4510e-05 11 8 0 10 0 0 99.90 18.97 0.18 -0.00503 -0.00671 8 8 1 5 0 3975.410 23.01 14.99 18.97 4.47 15.4 993.85 161 -12613 14969 -18475 2279 -8 -10066 2852 -4425 -3566 -6285 -1710 -8437 3528 -3451 -2794 -4800 3506 914 1708 552 5911 314 810 1343 -3581 495 221 831 -1296 3337 -731 2639 -2489 1216 -2923 -3019 -1112 -1245 -1575 -884 468 298 -594 1633 689 -2157 -357 -198 -1013 174 -507 869 2055 -80 1180 1318 798 1389 -943 82 -47 2142 687 805 -63 1076 -942 491 424 219 808 648 -103 -182 -169 -1056 -1157 135 -255 -1452 -849 -1684 -1644 -928 -563 -248 350 762 398 795 247 -7 -941 277 107 685 949 421 -224 -112 -499 -640 -492 -329 -1191 -680 -410 -229 28 438 361 378 -37 -388 -378 -690 80 -69 70 215 -71 733 202 543 662 418 477 502 76 259 -70 -279 107 44 152 105 664 -436 72 -372 -216 -878 9 -820 847 -1283 123 0 -611 173 -329 -284 -511 -135 -756 333 -411 -378 -704 498 140 271 91 910 52 143 253 -746 100 42 147 -231 617 -157 610 -647 284 -673 -752 -317 -433 -657 -376 207 137 -279 744 319 -1016 -163 -89 -466 84 -270 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