File name: Pandora145s1_Toronto-Scarborough_20210326_L2Fit_fout2c7d20191218p1-8.txt File generation date: 20260322T205903.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c7p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 145 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora145_OF_v5d20190718.txt Instrument calibration file used: Pandora145s1_CF_v7d20191218.txt Level 1 file used: Pandora145s1_Toronto-Scarborough_20210326_L1_smca1c7d20191218p1-8.txt.bz2 Full location name: University of Toronto - Scarborough Short location name: Toronto-Scarborough Country of location: Canada Location latitude [deg]: 43.7843 Location longitude [deg]: -79.1874 Location altitude [m]: 137 Local noon date: 20210326 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: "Modification of session 3 for not so summer ref day" First and last pixel inside fitting window: 226 368 Nominal wavelengths inside fitting window [nm]: 305.0466 305.1875 305.3283 305.4691 305.6100 305.7508 305.8915 306.0323 306.1731 306.3139 306.4546 306.5953 306.7361 306.8768 307.0175 307.1582 307.2988 307.4395 307.5801 307.7208 307.8614 308.0020 308.1427 308.2833 308.4238 308.5644 308.7050 308.8455 308.9861 309.1266 309.2671 309.4076 309.5481 309.6886 309.8291 309.9696 310.1100 310.2504 310.3909 310.5313 310.6717 310.8121 310.9525 311.0928 311.2332 311.3736 311.5139 311.6542 311.7945 311.9348 312.0751 312.2154 312.3557 312.4959 312.6362 312.7764 312.9166 313.0569 313.1971 313.3373 313.4774 313.6176 313.7578 313.8979 314.0380 314.1781 314.3183 314.4584 314.5984 314.7385 314.8786 315.0186 315.1587 315.2987 315.4387 315.5787 315.7187 315.8587 315.9987 316.1386 316.2786 316.4185 316.5584 316.6984 316.8383 316.9782 317.1180 317.2579 317.3978 317.5376 317.6774 317.8173 317.9571 318.0969 318.2367 318.3764 318.5162 318.6560 318.7957 318.9354 319.0751 319.2148 319.3545 319.4942 319.6339 319.7736 319.9132 320.0528 320.1925 320.3321 320.4717 320.6113 320.7508 320.8904 321.0300 321.1695 321.3090 321.4486 321.5881 321.7276 321.8671 322.0065 322.1460 322.2854 322.4249 322.5643 322.7037 322.8431 322.9825 323.1219 323.2613 323.4006 323.5400 323.6793 323.8186 323.9579 324.0972 324.2365 324.3758 324.5151 324.6543 324.7935 324.9328 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210326T183030.4Z 7755.771185 510 1 2.82 2 43.96 204.97 113.31 43.14 0.00 1 0.00 1 0 25 9.700e-03 6.441e-03 4.098e-03 2.459e-03 2.270562e-01 1.225598e-03 2.837865e-03 -6.000000e+00 5.383002e-03 226.64 -2.00 3.57 -2.00 315.45 0.00e+00 -6.621654e-05 1.120489e-04 3.094834e-05 -6.000000e+00 2.307650e-04 275.42 -2.00 20.00 -2.00 314.93 0.00e+00 1.387 0.000 302.00 328.00 3 3.4829e+00 3.1509e-03 1.8119e-02 -6.0000e+00 1.3386e-02 2.6560e-02 3.5134e-03 1.1762e-02 -6.0000e+00 1.4565e-02 -5.0738e-03 2.0196e-03 5.8396e-03 -6.0000e+00 8.6443e-03 9.5313e-04 9.2297e-04 1.6565e-03 -6.0000e+00 3.6972e-03 3.1375e-03 3.3924e-05 6.4770e-05 1.9506e-05 -6.0000e+00 2.4091e-04 -7.9733e-03 5.2729e-05 12 9 1 12 9 1 99.76 19.43 0.25 -0.00797 -0.00772 6 79 1 5 0 378.870 23.43 15.00 19.43 13.45 16.2 1044.02 176 -1124 1200 -3956 -1710 -4778 -1481 -648 1027 93 -723 -2102 -450 -492 -564 1174 -435 433 1166 2102 -182 864 779 1460 -543 782 -14 499 19 413 2828 1015 1859 199 -804 -1921 -1287 -1860 -100 -428 -678 -447 -1142 -903 -394 -328 -561 -302 -963 -364 285 739 607 812 242 863 1062 866 241 362 997 1086 1399 1486 -117 -431 151 -336 690 541 54 -152 -260 -29 303 -228 507 -128 429 -71 -1253 -442 -1820 -1568 -1161 -934 -937 -441 285 185 171 525 582 631 507 496 369 997 -34 -834 -66 -509 -266 164 -523 -886 -364 -757 -568 -65 -6 301 -25 176 160 428 584 555 227 28 -577 71 170 241 896 253 629 1226 758 207 457 65 113 -150 -10 -97 -8 -160 -88 -536 -159 -521 -458 45 -301 322 -1139 -416 -1109 -347 -170 299 27 -222 -645 -139 -174 -211 478 -186 188 521 960 -82 378 342 673 -270 400 -7 242 9 186 1298 477 938 107 -405 -919 -658 -1041 -63 -302 -502 -344 -867 -691 -312 -259 -435 -226 -703 -260 211 587 484 680 201 722 906 740 202 313 872 968 1293 1411 -114 -403 133 -298 599 515 55 -156 -269 -30 295 -209 450 -106 359 -64 -1233 -458 -1968 -1753 -1326 -1105 -1133 -551 356 225 199 598 623 636 532 551 437 1254 -44 -1064 -81 -598 -300 188 -639 -1113 -473 -998 -778 -91 -9 439 -35 238 211 540 723 715 303 39 -811 98 237 322 1166 328 762 1504 957 272 609 89 156 -207 -15 -145 -11 -244 -136 -818 -240 -761 -668 SS 20210326T183503.0Z 7755.774341 513 1 28.06 2 44.31 206.52 112.78 44.14 0.00 1 0.00 1 0 17 7.668e-03 5.573e-03 3.766e-04 2.008e-04 2.289971e-01 9.962852e-05 2.852334e-03 -6.000000e+00 4.256274e-03 226.64 -2.00 3.57 -2.00 315.87 0.00e+00 1.250792e-04 9.996219e-06 3.155042e-05 -6.000000e+00 1.824556e-04 275.42 -2.00 20.00 -2.00 315.33 0.00e+00 1.396 0.000 302.00 328.00 3 8.7741e-01 2.5762e-04 1.8252e-02 -6.0000e+00 1.0585e-02 2.6741e-02 2.8764e-04 1.1869e-02 -6.0000e+00 1.1516e-02 -8.2386e-03 1.6595e-04 5.8860e-03 -6.0000e+00 6.8345e-03 8.9308e-04 7.7334e-05 1.6722e-03 -6.0000e+00 2.9236e-03 4.2010e-02 7.5290e-05 5.3103e-06 1.8922e-05 -6.0000e+00 1.9046e-04 -8.4777e-03 7.6576e-05 10 0 0 10 0 0 99.99 19.43 0.32 -0.00848 -0.00791 1304 1304 1 5 0 21.460 23.43 15.00 19.43 13.80 16.4 1046.75 -1239 -1371 -759 -2361 -2984 -2069 -666 -11 506 24 -908 -1224 -462 -592 231 -94 -176 253 303 1122 756 397 1133 945 525 381 490 276 -232 679 1572 1405 1813 346 -1481 -1305 -1019 -819 -492 -469 -810 -1034 -708 -845 -291 -578 -591 -476 -663 -165 757 636 686 883 664 845 753 524 380 604 859 1019 931 1161 43 -282 99 -6 639 338 59 4 -73 202 130 113 358 -57 389 -135 -773 -922 -1787 -1543 -1178 -1024 -752 -473 31 -20 63 348 380 854 847 515 483 751 -5 -486 -209 -151 24 233 -297 -778 -558 -648 -250 -41 32 -165 -70 84 101 487 688 452 295 26 -442 -155 228 243 564 483 571 1302 682 213 46 27 72 25 15 -162 -118 78 -178 -470 -276 -379 -265 -263 -322 -182 -546 -600 -415 -137 -2 120 6 -228 -302 -125 -183 74 -34 -65 96 119 451 313 162 460 406 239 168 217 124 -96 266 636 612 851 161 -700 -578 -483 -416 -280 -317 -567 -756 -531 -641 -218 -434 -434 -338 -458 -119 529 479 543 692 538 693 632 441 312 488 705 892 838 1119 42 -256 86 -5 546 313 57 4 -76 201 128 106 299 -47 325 -120 -736 -922 -1935 -1728 -1332 -1247 -921 -599 40 -24 76 399 392 873 902 574 566 930 -6 -622 -263 -183 26 265 -373 -993 -740 -858 -343 -58 47 -249 -101 118 136 605 881 573 402 37 -619 -224 321 329 751 615 716 1589 849 286 62 38 101 36 22 -251 -180 122 -284 -734 -432 -573 -388 SS 20210326T183931.3Z 7755.777446 516 1 28.69 2 44.68 208.02 112.26 45.12 0.00 1 0.00 1 0 17 7.717e-03 5.560e-03 3.218e-04 1.770e-04 2.303157e-01 8.774640e-05 2.865123e-03 -6.000000e+00 4.282910e-03 226.64 -2.00 3.57 -2.00 315.75 0.00e+00 1.452970e-04 8.589651e-06 3.107687e-05 -6.000000e+00 1.835984e-04 275.42 -2.00 20.00 -2.00 315.21 0.00e+00 1.405 0.000 302.00 328.00 3 6.4908e-01 2.2637e-04 1.8353e-02 -6.0000e+00 1.0651e-02 2.2674e-02 2.5293e-04 1.1926e-02 -6.0000e+00 1.1588e-02 -7.3760e-03 1.4582e-04 5.9197e-03 -6.0000e+00 6.8774e-03 1.7744e-03 6.7509e-05 1.6829e-03 -6.0000e+00 2.9419e-03 5.2254e-02 4.6906e-05 4.6604e-06 1.9293e-05 -6.0000e+00 1.9166e-04 -8.4631e-03 6.9419e-05 10 0 0 10 0 0 99.94 19.45 0.32 -0.00846 -0.00811 1293 1293 1 5 0 21.650 23.43 15.00 19.45 14.57 16.5 1052.04 -1371 -1436 -694 -2315 -2799 -2189 -598 -37 634 12 -1051 -1230 -621 -512 340 -70 -194 202 368 1132 747 477 1166 1009 507 498 655 252 -35 782 1677 1555 1816 352 -1412 -1216 -973 -768 -473 -447 -906 -1127 -766 -891 -334 -590 -587 -525 -636 -113 771 660 649 889 603 828 726 475 363 608 901 1000 918 1079 13 -320 90 -25 659 335 15 -29 -104 187 157 115 388 -20 459 -98 -747 -903 -1774 -1496 -1185 -1045 -739 -483 31 -18 32 355 351 825 822 527 449 748 -27 -479 -241 -159 4 256 -274 -779 -594 -672 -252 -40 46 -151 -46 120 128 512 678 405 317 48 -430 -156 239 214 587 488 592 1289 670 203 33 8 59 -2 6 -156 -131 74 -192 -442 -296 -354 -276 -310 -359 -177 -569 -597 -429 -120 -8 160 3 -281 -324 -179 -156 117 -27 -77 82 143 451 307 193 469 430 229 235 310 113 -15 327 726 673 849 176 -665 -536 -460 -419 -290 -304 -641 -834 -581 -683 -252 -447 -437 -377 -444 -82 546 503 521 708 498 692 621 407 304 500 752 892 844 1010 12 -297 79 -21 574 317 15 -30 -110 191 151 105 331 -17 390 -89 -729 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