File name: Pandora145s1_Toronto-Scarborough_20220104_L2Fit_fout2c7d20191218p1-8.txt File generation date: 20260322T214922.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c7p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 145 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora145_OF_v5d20190718.txt Instrument calibration file used: Pandora145s1_CF_v7d20191218.txt Level 1 file used: Pandora145s1_Toronto-Scarborough_20220104_L1_smca1c7d20191218p1-8.txt.bz2 Full location name: University of Toronto - Scarborough Short location name: Toronto-Scarborough Country of location: Canada Location latitude [deg]: 43.7843 Location longitude [deg]: -79.1874 Location altitude [m]: 137 Local noon date: 20220104 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: "Modification of session 3 for not so summer ref day" First and last pixel inside fitting window: 226 368 Nominal wavelengths inside fitting window [nm]: 305.0466 305.1875 305.3283 305.4691 305.6100 305.7508 305.8915 306.0323 306.1731 306.3139 306.4546 306.5953 306.7361 306.8768 307.0175 307.1582 307.2988 307.4395 307.5801 307.7208 307.8614 308.0020 308.1427 308.2833 308.4238 308.5644 308.7050 308.8455 308.9861 309.1266 309.2671 309.4076 309.5481 309.6886 309.8291 309.9696 310.1100 310.2504 310.3909 310.5313 310.6717 310.8121 310.9525 311.0928 311.2332 311.3736 311.5139 311.6542 311.7945 311.9348 312.0751 312.2154 312.3557 312.4959 312.6362 312.7764 312.9166 313.0569 313.1971 313.3373 313.4774 313.6176 313.7578 313.8979 314.0380 314.1781 314.3183 314.4584 314.5984 314.7385 314.8786 315.0186 315.1587 315.2987 315.4387 315.5787 315.7187 315.8587 315.9987 316.1386 316.2786 316.4185 316.5584 316.6984 316.8383 316.9782 317.1180 317.2579 317.3978 317.5376 317.6774 317.8173 317.9571 318.0969 318.2367 318.3764 318.5162 318.6560 318.7957 318.9354 319.0751 319.2148 319.3545 319.4942 319.6339 319.7736 319.9132 320.0528 320.1925 320.3321 320.4717 320.6113 320.7508 320.8904 321.0300 321.1695 321.3090 321.4486 321.5881 321.7276 321.8671 322.0065 322.1460 322.2854 322.4249 322.5643 322.7037 322.8431 322.9825 323.1219 323.2613 323.4006 323.5400 323.6793 323.8186 323.9579 324.0972 324.2365 324.3758 324.5151 324.6543 324.7935 324.9328 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220104T135342.2Z 8039.578960 89 1 30.75 2 81.77 132.71 99.43 113.20 0.00 1 0.00 1 0 17 5.313e-01 2.941e-02 3.637e-01 1.581e-02 8.807153e-01 8.920642e-03 1.029123e-02 -6.000000e+00 2.974847e-01 222.98 -2.00 3.57 -2.00 321.82 0.00e+00 5.992929e-03 4.394007e-03 4.851719e-03 -6.000000e+00 1.474757e-02 272.77 -2.00 20.00 -2.00 321.39 0.00e+00 6.562 0.005 302.00 328.00 3 2.6822e+00 3.0671e-02 8.2069e-02 -6.0000e+00 7.3739e-01 7.9585e-01 4.3175e-02 5.3814e-02 -6.0000e+00 8.0798e-01 -9.4802e-01 4.5011e-02 3.2271e-02 -6.0000e+00 4.7697e-01 3.8089e-01 2.1484e-02 1.2100e-02 -6.0000e+00 2.0896e-01 2.1372e-05 -1.2223e-03 4.1664e-04 1.8512e-04 -6.0000e+00 1.3984e-02 -8.0639e-03 2.5366e-06 12 8 8 10 0 0 97.98 17.95 0.45 -0.00806 -0.01725 14 14 1 5 0 2196.040 22.80 15.00 17.95 4.52 17.2 955.98 900000 900000 -56709 900000 -103336 -88976 900000 -118352 900000 -181729 900000 -186725 900000 -103110 900000 -56449 900000 144494 -33786 900000 -27993 34930 -149421 259042 -86073 900000 -29039 -17057 -141001 900000 64608 58003 18953 24084 -16485 -14313 52569 14964 78304 12337 67524 6518 86658 16591 147835 31179 77754 25527 51788 11123 24011 21986 14558 67628 419 65274 -5284 81254 5149 41407 1629 61204 7328 26522 13490 22158 22329 15626 13741 3472 19376 12505 21709 -1658 27254 -7850 16435 -12523 17896 5817 -3355 -4588 -3091 686 515 5366 -4422 3958 -3236 6955 -4010 2500 -4061 1416 -4679 -1719 -5324 -2568 -1190 -2981 245 -3053 -209 -6291 -2030 -5054 1441 -2903 -434 -1951 -175 81 602 746 -3203 388 -146 1199 -771 3477 -955 3810 550 3611 -118 3223 1470 328 -434 828 1682 -476 255 -922 879 -100 1080 -371 1243 -1710 -488 -1421 -634 900000 900000 -872 900000 -1589 -1368 900000 -1820 900000 -4891 900000 -5744 900000 -2379 900000 -1421 900000 2222 -898 900000 -704 537 -10724 3984 -3971 900000 -771 -382 -9578 900000 994 973 556 741 -715 -560 1102 523 1752 638 2266 428 2666 1044 2480 1700 2718 1570 2607 902 1914 2029 1588 4728 56 5111 -786 5453 698 3705 216 4878 1158 4042 2369 3873 3871 2764 2712 885 4693 3382 5259 -470 5640 -1851 3056 -2921 3828 1581 -1200 -1940 -1446 327 260 2737 -2602 2202 -1928 3610 -2159 1179 -1988 684 -2759 -1176 -4477 -2278 -1177 -3079 231 -2640 -166 -5104 -1696 -4618 1295 -2713 -440 -2322 -236 120 916 1122 -4804 537 -203 1720 -1193 5364 -1507 5392 764 4725 -155 3965 1767 413 -641 1416 3224 -1016 576 -2086 2103 -255 2770 -972 3206 -4337 -1127 -3272 -1360 SS 20220104T141141.4Z 8039.591452 95 1 29.82 2 79.45 136.20 96.57 116.00 0.00 1 0.00 1 0 17 5.563e-01 1.020e-02 2.516e-01 5.553e-03 7.592581e-01 2.908057e-03 8.715111e-03 -6.000000e+00 3.043764e-01 222.98 -2.00 3.57 -2.00 321.30 0.00e+00 5.113241e-03 1.321009e-03 1.096970e-03 -6.000000e+00 1.308759e-02 272.77 -2.00 20.00 -2.00 320.87 0.00e+00 5.255 0.003 302.00 328.00 3 2.5047e+00 9.4309e-03 6.5432e-02 -6.0000e+00 7.5139e-01 2.1495e-01 1.3449e-02 4.1632e-02 -6.0000e+00 8.2011e-01 -2.3464e-01 1.5043e-02 2.4054e-02 -6.0000e+00 4.8734e-01 8.8671e-02 7.2534e-03 1.0232e-02 -6.0000e+00 2.0956e-01 1.0920e-04 -8.3533e-04 1.4032e-04 1.1107e-04 -6.0000e+00 1.3805e-02 -7.8441e-03 -5.5214e-06 12 8 8 10 0 0 99.85 17.95 0.45 -0.00784 -0.01412 38 38 1 5 0 784.560 22.80 14.99 17.95 5.24 17.2 957.91 -232103 -177446 -201040 -44087 -237401 -208042 -201975 -111162 -157426 -199425 -16184 -114654 -35914 -122363 -57410 -101062 -75235 -68631 7800 -38439 -6498 -56937 -24799 -28399 29764 -31087 -44443 -37498 -39229 -38403 -57995 -4869 2039 17322 -33162 33641 -20542 -8052 -5919 10099 343 946 14632 -2723 -873 4154 4268 11639 5397 3532 5888 2396 10949 9742 7316 5519 8841 1208 -1822 -205 744 2618 3493 8249 3464 7529 1277 6881 1468 1525 1712 4651 1826 2381 2218 -585 -1521 -4582 1638 -2505 -724 -809 -1726 -1231 -1430 -654 -737 -150 576 -125 354 -450 -612 10 -1363 -174 -1232 824 -736 -107 -619 -170 -603 -659 -1582 -1721 209 -1572 -171 -142 330 -57 4 30 178 -496 401 441 389 414 37 302 937 496 439 580 74 731 138 31 267 543 -113 -59 5 -13 -212 11 -111 -616 48 -88 -97 -2742 -1485 -2375 -239 -3623 -2253 -2188 -602 -1535 -2945 -88 -931 -194 -1922 -622 -2134 -1426 -1375 80 -666 -84 -1203 -389 -508 322 -657 -1107 -853 -892 -936 -2136 -132 62 507 -1544 765 -868 -353 -314 558 24 71 1022 -235 -75 349 370 983 517 337 617 297 1380 1367 1127 902 1449 213 -319 -34 125 474 726 1900 917 1894 338 1778 439 534 670 1857 744 906 768 -184 -446 -1403 530 -1026 -347 -413 -994 -746 -923 -447 -530 -111 422 -89 234 -280 -366 6 -953 -142 -1188 906 -850 -125 -684 -180 -568 -605 -1584 -1831 229 -1732 -205 -193 507 -95 8 49 281 -747 597 685 641 712 63 487 1436 740 630 804 99 991 216 55 500 1092 -242 -134 13 -31 -519 28 -277 -1480 114 -194 -202 SS 20220104T141706.9Z 8039.595218 98 1 29.73 2 78.78 137.27 95.72 116.86 0.00 1 0.00 1 0 25 4.695e-01 7.628e-03 2.424e-01 3.950e-03 7.339743e-01 2.054447e-03 8.386446e-03 -6.000000e+00 2.569291e-01 222.98 -2.00 3.57 -2.00 321.10 0.00e+00 2.528038e-03 8.880786e-04 8.910580e-04 -6.000000e+00 1.104720e-02 272.77 -2.00 20.00 -2.00 320.66 0.00e+00 4.966 0.002 302.00 328.00 3 2.3371e+00 6.4609e-03 6.2380e-02 -6.0000e+00 6.3426e-01 1.1681e-01 9.2042e-03 4.0386e-02 -6.0000e+00 6.9225e-01 -9.5985e-02 1.0472e-02 2.1751e-02 -6.0000e+00 4.1136e-01 2.6344e-02 5.0934e-03 7.8354e-03 -6.0000e+00 1.7691e-01 1.7644e-04 -8.1542e-04 9.9972e-05 7.9857e-05 -6.0000e+00 1.1652e-02 -8.0262e-03 1.0081e-05 11 9 0 11 8 0 99.51 17.95 0.29 -0.00803 -0.01415 44 44 1 5 0 675.470 22.80 14.99 17.95 5.57 17.3 960.52 106480 -222666 -118092 -193899 -118978 -210671 -85384 -214892 -92758 -158423 -90613 -28090 -95322 -16285 -38822 -11453 -76510 -24664 -59900 -7826 -54784 19384 -38087 4645 -35830 24932 -38985 -28400 15908 -36702 -11487 -9438 -2144 -3042 6503 -1139 -5228 -4387 2363 -6172 -395 -1223 -2224 4598 4827 6913 8306 7210 -767 3817 -3587 6684 1431 8125 325 1503 767 117 1970 1805 1684 4863 3652 2617 2855 307 2026 -728 2516 -553 2698 207 1397 -276 621 368 689 -207 -2326 -50 -1289 -142 -2827 -1300 -1634 21 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