File name: Pandora145s1_Toronto-Scarborough_20220305_L2Fit_fout2c7d20191218p1-8.txt
File generation date: 20260322T215941.3Z
Data description: Level 2 spectral fitting results file
Data file version: fout2c7p1-8
Local principal investigator: Vitali Fioletov
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 145
Spectrometer number: 1
Processing software version used: BlickP v1.8.88
Instrument operation file used: Pandora145_OF_v5d20190718.txt
Instrument calibration file used: Pandora145s1_CF_v7d20191218.txt
Level 1 file used: Pandora145s1_Toronto-Scarborough_20220305_L1_smca1c7d20191218p1-8.txt.bz2
Full location name: University of Toronto - Scarborough
Short location name: Toronto-Scarborough
Country of location: Canada
Location latitude [deg]: 43.7843
Location longitude [deg]: -79.1874
Location altitude [m]: 137
Local noon date: 20220305
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: "Modification of session 3 for not so summer ref day"
First and last pixel inside fitting window: 226 368
Nominal wavelengths inside fitting window [nm]: 305.0466 305.1875 305.3283 305.4691 305.6100 305.7508 305.8915 306.0323 306.1731 306.3139 306.4546 306.5953 306.7361 306.8768 307.0175 307.1582 307.2988 307.4395 307.5801 307.7208 307.8614 308.0020 308.1427 308.2833 308.4238 308.5644 308.7050 308.8455 308.9861 309.1266 309.2671 309.4076 309.5481 309.6886 309.8291 309.9696 310.1100 310.2504 310.3909 310.5313 310.6717 310.8121 310.9525 311.0928 311.2332 311.3736 311.5139 311.6542 311.7945 311.9348 312.0751 312.2154 312.3557 312.4959 312.6362 312.7764 312.9166 313.0569 313.1971 313.3373 313.4774 313.6176 313.7578 313.8979 314.0380 314.1781 314.3183 314.4584 314.5984 314.7385 314.8786 315.0186 315.1587 315.2987 315.4387 315.5787 315.7187 315.8587 315.9987 316.1386 316.2786 316.4185 316.5584 316.6984 316.8383 316.9782 317.1180 317.2579 317.3978 317.5376 317.6774 317.8173 317.9571 318.0969 318.2367 318.3764 318.5162 318.6560 318.7957 318.9354 319.0751 319.2148 319.3545 319.4942 319.6339 319.7736 319.9132 320.0528 320.1925 320.3321 320.4717 320.6113 320.7508 320.8904 321.0300 321.1695 321.3090 321.4486 321.5881 321.7276 321.8671 322.0065 322.1460 322.2854 322.4249 322.5643 322.7037 322.8431 322.9825 323.1219 323.2613 323.4006 323.5400 323.6793 323.8186 323.9579 324.0972 324.2365 324.3758 324.5151 324.6543 324.7935 324.9328
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Ozone effective temperature [K]
Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Sulfur dioxide effective temperature [K]
Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 46: Lower limit used for wavelength scaling [nm]
Column 47: Upper limit used for wavelength scaling [nm]
Column 48: Order of smoothing polynomial
Column 49: Smoothing polynomial coefficient, order 0
Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 54: Smoothing polynomial coefficient, order 1
Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 59: Smoothing polynomial coefficient, order 2
Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 64: Smoothing polynomial coefficient, order 3
Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 69: Mean value of measured data inside fitting window [same units as measurements]
Column 70: Wavelength change polynomial coefficient, order 0
Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 84: Wavelength effective temperature [°C], 999=no effective temperature given
Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 88: Number of bright count cycles
Column 89: Number of dark count cycles
Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 93: Integration time [ms]
Column 94: Temperature at electronics board [°C], 999=no temperature signal
Column 95: Spectrometer control temperature [°C], 999=no temperature signal
Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 97: Temperature in head sensor [°C], 999=no temperature signal
Column 98: Humidity in head sensor [%], -9=no humidity signal
Column 99: Pressure in head sensor [hPa], -9=no pressure signal
Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SS 20220305T132759.5Z 8099.561105 103 1 29.74 2 73.33 115.87 89.93 83.75 0.00 1 0.00 1 0 17 6.618e-02 4.658e-03 3.311e-02 1.949e-03 4.894291e-01 9.683119e-04 5.825358e-03 -6.000000e+00 3.652958e-02 225.38 -2.00 3.57 -2.00 319.55 0.00e+00 8.275138e-04 2.653734e-04 2.977282e-04 -6.000000e+00 1.561142e-03 273.45 -2.00 20.00 -2.00 319.03 0.00e+00 3.431 0.001 302.00 328.00 3 2.9064e+00 2.7095e-03 4.2293e-02 -6.0000e+00 9.0638e-02 3.7340e-02 3.2035e-03 2.5730e-02 -6.0000e+00 9.8764e-02 -2.0238e-02 2.7567e-03 1.3037e-02 -6.0000e+00 5.8607e-02 -2.6460e-03 1.4679e-03 3.9915e-03 -6.0000e+00 2.5073e-02 5.5384e-04 -3.9633e-04 5.1863e-05 3.8729e-05 -6.0000e+00 1.6436e-03 -4.4202e-03 1.1356e-05 10 0 0 10 0 0 99.71 17.86 0.32 -0.00442 -0.00740 58 58 1 5 0 512.710 22.71 15.00 17.86 7.76 17.9 1068.82 -154 -20115 -30144 -19992 -25497 -19889 -20543 -29013 -31774 -7544 -20968 -9110 -4184 -237 -4323 -2186 3123 -6700 1881 -4730 2114 -6710 3612 -1858 3524 -3659 2269 -4784 -1334 -1347 1458 4562 1313 125 -2469 -3469 -1086 -2134 -2897 457 -1871 -1658 -1226 -935 353 678 235 -193 457 -425 732 399 1068 661 1050 559 1134 383 428 326 1064 1609 1014 1952 360 -135 -660 -64 -14 565 354 331 239 848 424 -149 57 -780 -364 -296 -828 -1218 -1377 -1385 -828 -679 -475 65 401 558 546 533 215 607 632 158 434 910 312 7 -323 -194 -332 -181 -645 -1305 -466 -517 -368 -144 68 -28 -85 86 0 516 250 201 267 -77 -415 -131 200 121 440 48 475 929 560 71 -23 65 27 -37 -90 -208 -2 126 -94 -351 -120 -165 112 -2 -359 -642 -376 -451 -318 -355 -629 -815 -166 -538 -220 -116 -8 -182 -107 159 -370 113 -291 139 -432 238 -128 251 -298 178 -387 -109 -111 121 426 145 15 -292 -396 -132 -309 -521 96 -455 -430 -332 -258 96 187 66 -55 131 -127 216 131 378 254 424 235 490 167 181 135 446 728 517 1102 200 -78 -362 -35 -8 351 246 242 175 588 273 -93 32 -432 -216 -190 -616 -1032 -1188 -1253 -795 -699 -516 73 448 603 548 493 186 555 583 167 485 1151 407 9 -426 -231 -385 -211 -768 -1659 -614 -677 -514 -222 107 -47 -139 134 0 744 359 301 426 -123 -673 -206 322 188 649 69 681 1332 835 112 -40 117 51 -67 -177 -408 -5 258 -195 -705 -241 -313 204
SS 20220305T133311.3Z 8099.564714 106 1 29.83 2 72.48 116.90 89.01 84.61 0.00 1 0.00 1 0 17 4.563e-02 4.783e-03 2.336e-02 1.632e-03 4.670133e-01 8.062962e-04 5.581715e-03 -6.000000e+00 2.518738e-02 225.38 -2.00 3.57 -2.00 319.36 0.00e+00 5.103266e-04 2.081221e-04 2.774318e-04 -6.000000e+00 1.076421e-03 273.45 -2.00 20.00 -2.00 318.83 0.00e+00 3.276 0.001 302.00 328.00 3 2.7845e+00 2.2333e-03 4.0344e-02 -6.0000e+00 6.2495e-02 2.8233e-02 2.6193e-03 2.4456e-02 -6.0000e+00 6.8099e-02 -1.5603e-02 2.1716e-03 1.2302e-02 -6.0000e+00 4.0410e-02 -3.8966e-03 1.1607e-03 3.6486e-03 -6.0000e+00 1.7288e-02 7.4711e-04 -4.2944e-04 4.3470e-05 3.6225e-05 -6.0000e+00 1.1333e-03 -4.5371e-03 4.5726e-06 10 0 0 10 0 0 86.42 17.86 0.29 -0.00454 -0.00776 68 68 1 5 0 438.560 22.71 15.00 17.86 8.24 18.0 1071.93 -1334 -10466 -2604 -12476 -17793 -20987 -19735 -420 -17696 -4142 -21893 -6561 -16908 2160 -7724 4676 -3631 745 -1353 -565 -2064 -1937 1744 503 3210 -3927 3745 -2568 2219 -4003 1753 11 2296 587 -548 -2694 -4794 -2569 -992 -329 -1264 -827 -1047 -648 -1702 -403 -1639 80 -509 138 -71 1189 1252 1038 1336 299 1251 11 558 143 1322 427 1644 1457 1007 -351 121 -49 418 806 633 386 -150 583 70 213 -391 -528 -636 22 -841 -1055 -1517 -1376 -1169 -893 -194 -81 496 313 898 241 759 425 666 316 699 529 123 -226 -105 -370 -136 87 -514 -886 -946 -537 -360 -7 -86 -81 3 52 -52 367 613 204 145 -183 -320 -220 259 86 439 123 460 989 609 246 -36 -1 196 -18 -165 -206 -110 146 -80 -239 -217 -91 -19 -22 -218 -54 -278 -371 -431 -430 -9 -501 -112 -718 -194 -665 86 -414 261 -219 46 -92 -40 -154 -143 128 41 275 -384 347 -243 189 -366 170 1 292 83 -73 -352 -697 -430 -201 -80 -322 -223 -297 -187 -496 -118 -486 24 -152 42 -24 433 493 441 598 140 599 5 262 66 613 217 851 841 611 -205 66 -27 243 542 475 283 -111 440 50 134 -223 -292 -376 15 -671 -887 -1399 -1328 -1122 -919 -210 -91 553 338 897 238 695 383 649 327 820 661 169 -312 -136 -463 -155 99 -644 -1109 -1238 -740 -498 -11 -133 -133 4 85 -78 517 906 298 226 -303 -508 -359 408 130 635 181 643 1378 883 397 -60 -1 349 -31 -314 -415 -214 290 -160 -468 -425 -168 -35
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