File name: Pandora108s1_Toronto-West_20211226_L2Fit_fout2c6d20211104p1-8.txt File generation date: 20240820T102610.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c6p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 108 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora108_OF_v3d20210713.txt Instrument calibration file used: Pandora108s1_CF_v6d20211104.txt Level 1 file used: Pandora108s1_Toronto-West_20211226_L1_smca1c6d20211104p1-8.txt Full location name: Ontario Ministry of the Environment, Toronto West (Etobicoke) Short location name: Toronto-West Country of location: Canada Location latitude [deg]: 43.7094 Location longitude [deg]: -79.5435 Location altitude [m]: 141 Local noon date: 20211226 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 231 373 Nominal wavelengths inside fitting window [nm]: 305.0401 305.1807 305.3213 305.4619 305.6025 305.7430 305.8836 306.0241 306.1647 306.3052 306.4457 306.5863 306.7268 306.8673 307.0078 307.1483 307.2887 307.4292 307.5697 307.7101 307.8506 307.9910 308.1315 308.2719 308.4123 308.5527 308.6931 308.8335 308.9739 309.1143 309.2546 309.3950 309.5353 309.6757 309.8160 309.9564 310.0967 310.2370 310.3773 310.5176 310.6579 310.7981 310.9384 311.0787 311.2189 311.3591 311.4994 311.6396 311.7798 311.9200 312.0602 312.2004 312.3406 312.4807 312.6209 312.7610 312.9012 313.0413 313.1814 313.3215 313.4617 313.6017 313.7418 313.8819 314.0220 314.1620 314.3021 314.4421 314.5821 314.7222 314.8622 315.0022 315.1422 315.2822 315.4221 315.5621 315.7020 315.8420 315.9819 316.1218 316.2618 316.4017 316.5416 316.6814 316.8213 316.9612 317.1010 317.2409 317.3807 317.5205 317.6604 317.8002 317.9400 318.0797 318.2195 318.3593 318.4990 318.6388 318.7785 318.9182 319.0580 319.1977 319.3374 319.4770 319.6167 319.7564 319.8960 320.0357 320.1753 320.3149 320.4545 320.5941 320.7337 320.8733 321.0129 321.1525 321.2920 321.4315 321.5711 321.7106 321.8501 321.9896 322.1291 322.2686 322.4080 322.5475 322.6869 322.8264 322.9658 323.1052 323.2446 323.3840 323.5234 323.6627 323.8021 323.9414 324.0808 324.2201 324.3594 324.4987 324.6380 324.7773 324.9166 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20211226T143151.7Z 8030.605459 324 1 2.77 2 77.22 141.16 61.43 245.78 0.00 1 0.00 1 0 25 3.799e-01 2.111e-02 3.516e-01 1.904e-02 5.853111e-01 1.047405e-02 6.694512e-03 -6.000000e+00 2.221359e-01 222.63 -2.00 3.57 -2.00 320.86 0.00e+00 5.036310e-03 4.320137e-03 5.046024e-04 -6.000000e+00 1.156182e-02 273.37 -2.00 20.00 -2.00 320.38 0.00e+00 4.401 0.002 302.00 328.00 3 2.7417e+00 3.2291e-02 5.2937e-02 -6.0000e+00 5.4888e-01 7.7997e-02 4.2465e-02 3.1915e-02 -6.0000e+00 6.0213e-01 -5.1868e-02 4.3873e-02 1.7236e-02 -6.0000e+00 3.5304e-01 1.0882e-02 2.1737e-02 8.3481e-03 -6.0000e+00 1.5041e-01 2.3423e-04 -4.7773e-05 5.9211e-04 8.3788e-05 -6.0000e+00 1.1305e-02 2.3446e-02 -2.0451e-04 12 9 9 12 1 1 999.00 18.23 0.21 0.02345 0.02309 2 11 1 5 0 866.120 23.64 15.00 18.23 8.24 18.1 999.59 900000 -99835 900000 -101041 900000 -217 900000 900000 -145200 900000 -122119 900000 -136374 900000 -84501 900000 32013 35510 900000 1775 900000 -59672 900000 -63862 900000 -21239 900000 68686 9390 33299 -49682 115701 -42734 158639 -31275 149837 8433 57094 5927 11762 30292 -14096 23182 -11337 40544 -15128 38382 7736 10723 9757 7862 10288 -581 20557 -10631 15338 -9051 14461 -4408 3165 60 9894 10461 -3611 8328 -9219 16401 -6037 9410 -1205 4358 1396 -642 2689 -7708 6911 -8796 9367 -7169 10564 -2217 943 -1657 -637 -71 -2604 1671 -2981 3142 -2092 3320 209 -755 1181 -2563 2328 -2437 2320 -3026 212 -3337 1328 951 -817 -159 -2244 1737 -2674 2868 -1309 226 -135 1778 129 92 1102 -1581 54 -1636 183 -702 929 -566 2705 1033 -362 70 -290 410 -550 1567 -927 1115 427 581 222 -136 0 -1221 438 -176 321 -1139 900000 -1849 900000 -1871 900000 -4 900000 900000 -3048 900000 -2337 900000 -4199 900000 -2522 900000 593 658 900000 40 900000 -2420 900000 -2990 900000 -750 900000 1272 252 775 -2906 2143 -3133 2938 -2126 2775 434 2201 439 972 2334 -1779 2153 -1512 3379 -2193 3438 954 1340 1309 1184 1668 -114 3553 -2612 3038 -2317 2957 -1054 701 14 2357 2773 -1217 2603 -3351 4586 -2146 3158 -506 1903 651 -303 1166 -3412 2413 -3355 3028 -2995 4354 -1186 551 -1074 -434 -51 -2036 1311 -2514 2494 -1689 2396 146 -511 801 -1984 1950 -2424 2470 -3627 246 -3794 1326 889 -782 -160 -2435 1901 -3237 3557 -1848 339 -213 2747 195 132 1514 -2238 78 -2528 287 -1112 1413 -846 3817 1428 -491 92 -396 608 -906 2722 -1726 2113 852 1223 486 -306 0 -2805 963 -373 646 -2275 SS 20211226T143615.0Z 8030.608507 327 1 13.20 2 76.73 142.07 62.15 246.67 0.00 1 0.00 1 0 17 2.943e-01 1.209e-02 2.293e-01 8.685e-03 5.680374e-01 4.639221e-03 6.579741e-03 -6.000000e+00 1.692126e-01 222.63 -2.00 3.57 -2.00 320.86 0.00e+00 7.615906e-04 1.871727e-03 1.203699e-03 -6.000000e+00 7.972965e-03 273.37 -2.00 20.00 -2.00 320.37 0.00e+00 4.249 0.001 302.00 328.00 3 2.7131e+00 1.4303e-02 5.1226e-02 -6.0000e+00 4.1828e-01 8.8939e-02 1.8574e-02 3.0775e-02 -6.0000e+00 4.5707e-01 -6.6188e-02 1.8827e-02 1.6306e-02 -6.0000e+00 2.6934e-01 1.5533e-02 9.3863e-03 5.0584e-03 -6.0000e+00 1.1459e-01 2.8664e-04 -4.0257e-04 2.6702e-04 6.7455e-05 -6.0000e+00 8.4919e-03 2.2978e-02 -7.9830e-05 12 9 9 12 1 1 99.85 18.23 0.31 0.02298 0.01995 18 14 1 5 0 685.220 23.64 15.00 18.23 8.31 18.1 999.98 -148883 900000 -72352 -29781 -85704 -64511 900000 -96979 900000 -130038 900000 -95219 900000 -77197 10171 -22923 -36870 60010 -48374 84447 -37132 67445 -23483 49919 -21775 -10808 12710 1953 34517 -8529 50682 -20949 37306 -10782 11353 -13471 9024 3699 609 11301 -11364 13237 -6646 12447 -3094 7740 4805 3127 6826 -56 9089 -3739 11174 -1439 6627 -1146 2807 -285 338 5497 25 6947 -845 6912 -3417 4774 -563 4189 1470 -18 2122 -1245 1342 -2516 1796 -5071 465 -4118 372 -634 -372 172 -2980 73 -2830 1855 -1556 1046 -1084 970 741 -1222 152 -1369 2049 -368 1809 -225 756 -1468 -189 -780 -62 1207 -2976 -666 -2134 380 -839 1433 -174 1 452 -85 1105 10 1345 -596 162 -1090 724 86 719 240 -105 856 -26 1479 -562 599 -594 327 171 -17 -381 -938 774 -254 351 -1036 773 -765 577 -2697 900000 -786 -252 -961 -588 900000 -1471 900000 -3252 900000 -2032 900000 -2083 149 -532 -1080 789 -1840 998 -1374 968 -811 957 -872 -414 398 66 848 -327 1293 -1197 1412 -676 565 -844 500 254 52 1037 -1442 1435 -905 1455 -423 973 630 426 930 -9 1410 -723 2052 -321 1455 -281 684 -72 82 1259 6 1766 -258 2177 -1233 1566 -189 1380 542 -8 971 -614 644 -1189 755 -2054 167 -1537 146 -291 -197 102 -1987 50 -2127 1425 -1290 874 -919 783 561 -882 104 -962 1532 -318 1750 -249 895 -1771 -213 -809 -59 1149 -3130 -728 -2472 459 -1101 2030 -271 2 732 -133 1627 14 1896 -885 252 -1785 1172 136 1096 357 -151 1177 -35 2020 -856 1000 -1080 621 337 -34 -842 -2175 1813 -608 839 -2427 1704 -1624 1183 SS 20211226T144619.5Z 8030.615503 333 1 5.93 2 75.63 144.16 63.82 248.69 0.00 1 0.00 1 0 25 2.752e-01 9.126e-03 2.067e-01 5.580e-03 5.343486e-01 2.926625e-03 6.231675e-03 -6.000000e+00 1.584381e-01 222.63 -2.00 3.57 -2.00 320.58 0.00e+00 3.592992e-03 1.101534e-03 4.983873e-04 -6.000000e+00 7.112672e-03 273.37 -2.00 20.00 -2.00 320.08 0.00e+00 3.946 0.001 302.00 328.00 3 1.7496e+00 8.7648e-03 4.7542e-02 -6.0000e+00 3.9129e-01 5.6522e-02 1.1102e-02 2.8260e-02 -6.0000e+00 4.2748e-01 -1.9057e-02 1.1024e-02 1.5342e-02 -6.0000e+00 2.5178e-01 -3.6056e-03 5.5895e-03 6.2809e-03 -6.0000e+00 1.0605e-01 1.0268e-03 -6.4021e-04 1.6889e-04 6.9243e-05 -6.0000e+00 7.8761e-03 2.3340e-02 -1.1175e-04 12 9 1 12 1 1 99.39 18.23 0.15 0.02334 0.01853 25 45 1 5 0 220.710 23.64 15.00 18.23 8.41 18.1 1000.32 188027 -36455 26766 93849 -80096 900000 -87917 900000 -99910 900000 -65660 89799 -536 -6582 23976 -23187 63682 -35462 45711 -34045 45774 -17774 19865 288 1234 14872 -17143 33779 -27510 28065 -20066 26201 -5241 965 -4558 -5016 15169 -7853 11260 -10283 7587 -8126 5947 -1293 3115 4676 -1205 4435 -6142 7515 -3915 6396 -1520 5185 608 1941 516 7102 1764 -2592 5085 -1547 4412 -249 1781 171 1339 991 -37 1879 -1372 2409 -2704 710 -2733 -1030 -2620 -1190 399 -2735 401 -2703 339 -2465 308 -641 489 -525 445 1154 -411 840 -1450 1457 -906 388 600 1062 278 -408 52 -1083 1215 -978 -834 -2053 31 -482 888 772 347 493 -208 594 -662 1181 -145 218 -238 -390 -322 224 499 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