File name: Pandora108s1_Toronto-West_20230623_L2Fit_fwvt1c1d20210713p1-8.txt
File generation date: 20230626T192411.1Z
Data description: Level 2 spectral fitting results file
Data file version: fwvt1c1p1-8
Local principal investigator: Vitali Fioletov
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 108
Spectrometer number: 1
Processing software version used: BlickP v1.8.49
Instrument operation file used: Pandora108_OF_v3d20210713.txt
Instrument calibration file used: Pandora108s1_CF_v1d20210713.txt
Level 1 file used: Pandora108s1_Toronto-West_20230623_L1_smca1c1d20210713p1-8.txt
Full location name: Ontario Ministry of the Environment, Toronto West (Etobicoke)
Short location name: Toronto-West
Country of location: Canada
Location latitude [deg]: 43.7094
Location longitude [deg]: -79.5435
Location altitude [m]: 141
Local noon date: 20230623
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: None
First and last pixel inside fitting window: 1652 1802
Nominal wavelengths inside fitting window [nm]: 492.0342 492.1551 492.2760 492.3969 492.5178 492.6386 492.7595 492.8803 493.0011 493.1219 493.2427 493.3634 493.4841 493.6049 493.7256 493.8463 493.9669 494.0876 494.2082 494.3288 494.4494 494.5700 494.6906 494.8111 494.9317 495.0522 495.1727 495.2931 495.4136 495.5341 495.6545 495.7749 495.8953 496.0157 496.1360 496.2564 496.3767 496.4970 496.6173 496.7376 496.8578 496.9781 497.0983 497.2185 497.3387 497.4589 497.5791 497.6992 497.8193 497.9394 498.0595 498.1796 498.2996 498.4197 498.5397 498.6597 498.7797 498.8997 499.0196 499.1395 499.2595 499.3794 499.4992 499.6191 499.7390 499.8588 499.9786 500.0984 500.2182 500.3380 500.4577 500.5774 500.6971 500.8168 500.9365 501.0562 501.1758 501.2955 501.4151 501.5347 501.6542 501.7738 501.8933 502.0129 502.1324 502.2519 502.3713 502.4908 502.6102 502.7296 502.8490 502.9684 503.0878 503.2071 503.3265 503.4458 503.5651 503.6844 503.8036 503.9229 504.0421 504.1613 504.2805 504.3997 504.5189 504.6380 504.7571 504.8763 504.9953 505.1144 505.2335 505.3525 505.4715 505.5906 505.7095 505.8285 505.9475 506.0664 506.1853 506.3042 506.4231 506.5420 506.6608 506.7797 506.8985 507.0173 507.1361 507.2548 507.3736 507.4923 507.6110 507.7297 507.8484 507.9670 508.0857 508.2043 508.3229 508.4415 508.5601 508.6786 508.7972 508.9157 509.0342 509.1527 509.2711 509.3896 509.5080 509.6264 509.7448 509.8632 509.9816
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Water vapor effective temperature [K]
Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Nitrogen dioxide effective temperature [K]
Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 49: Ozone effective temperature [K]
Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 57: Lower limit used for wavelength scaling [nm]
Column 58: Upper limit used for wavelength scaling [nm]
Column 59: Order of smoothing polynomial
Column 60: Smoothing polynomial coefficient, order 0
Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 65: Smoothing polynomial coefficient, order 1
Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 70: Mean value of measured data inside fitting window [same units as measurements]
Column 71: Wavelength change polynomial coefficient, order 0
Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 85: Wavelength effective temperature [°C], 999=no effective temperature given
Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 89: Number of bright count cycles
Column 90: Number of dark count cycles
Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 94: Integration time [ms]
Column 95: Temperature at electronics board [°C], 999=no temperature signal
Column 96: Spectrometer control temperature [°C], 999=no temperature signal
Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 98: Temperature in head sensor [°C], 999=no temperature signal
Column 99: Humidity in head sensor [%], -9=no humidity signal
Column 100: Pressure in head sensor [hPa], -9=no pressure signal
Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SQ 20230623T105018.9Z 8574.451608 78 1 50.18 2 79.17 67.85 118.59 22.41 0.00 1 0.00 1 0 22 2.140e-03 2.124e-03 7.564e-04 7.522e-04 1.123189e+04 5.360476e+01 7.431925e+02 -6.000000e+00 1.202136e+02 285.06 -2.00 20.00 -2.00 505.25 0.00e+00 1.909848e-03 2.082256e-05 1.181932e-04 -6.000000e+00 6.032765e-05 285.06 -2.00 20.00 -2.00 500.28 0.00e+00 4.996220e-01 1.519623e-02 7.166801e-02 -6.000000e+00 4.256129e-02 232.96 -2.00 3.57 -2.00 501.86 0.00e+00 5.123 0.003 489.00 513.00 1 6.1741e+00 1.1671e-03 9.8365e-03 -6.0000e+00 3.2658e-03 6.0702e-03 2.9571e-04 1.7659e-03 -6.0000e+00 8.4407e-04 1.8289e-03 -6.0600e-04 7.0866e-05 8.7825e-05 -6.0000e+00 2.1794e-04 1.5579e-02 -3.4130e-04 11 1 0 11 4 0 99.35 17.76 1.02 0.01558 0.01138 42 8 1 4 0 1194.650 23.11 15.00 17.76 25.95 28.5 988.72 -307 -273 -67 33 342 232 396 455 314 320 -10 137 -117 -95 -175 -68 -82 -93 95 112 51 128 286 91 320 248 130 41 -34 -241 -334 -137 -236 -186 98 65 -239 47 38 -123 -142 48 55 34 209 99 200 -57 111 -143 -313 -495 -409 -473 -362 -141 -156 -12 -26 258 220 283 332 163 235 67 104 -131 -46 -246 -237 -45 -150 -172 -237 23 -323 -151 -212 -101 -355 -234 -231 -302 -157 -145 -207 -169 16 -65 56 20 116 148 37 160 217 6 -176 -167 -444 -304 -467 -346 -253 -339 -135 -9 110 -122 87 -129 -39 129 271 329 429 472 260 162 248 429 0 323 190 115 247 141 190 32 225 67 -13 7 36 -212 49 -35 9 179 87 70 37 167 55 53 -80 -3 -137 -329 -158 -282 -251 -63 33 342 238 414 482 335 339 -11 141 -119 -95 -173 -67 -82 -95 99 119 55 137 307 98 345 268 141 44 -36 -248 -335 -136 -237 -192 104 70 -260 51 40 -129 -149 50 59 36 227 108 219 -62 118 -150 -321 -494 -400 -461 -359 -144 -163 -13 -28 275 235 303 356 163 252 71 109 -135 -47 -248 -236 -44 -149 -174 -241 23 -326 -150 -206 -97 -343 -226 -225 -296 -156 -145 -208 -170 16 -65 56 20 110 140 35 158 208 6 -160 -149 -392 -269 -425 -329 -251 -320 -128 -9 103 -113 81 -122 -37 124 263 320 420 467 259 160 241 409 0 302 178 109 234 134 180 30 212 63 -12 6 33 -193 45 -33 9 174 86 70 37 167 55 53 -79 -3 -131 -311 -150
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SQ 20230623T110150.7Z 8574.459614 84 1 49.56 2 77.23 69.68 117.82 25.32 0.00 1 0.00 1 0 15 2.463e-03 2.457e-03 1.570e-03 1.564e-03 8.835604e+03 1.084657e+02 5.839719e+02 -6.000000e+00 1.383447e+02 285.06 -2.00 20.00 -2.00 505.29 0.00e+00 1.627872e-03 4.330431e-05 1.021756e-04 -6.000000e+00 6.942421e-05 285.06 -2.00 20.00 -2.00 500.35 0.00e+00 4.807259e-01 3.134044e-02 6.099058e-02 -6.000000e+00 4.896223e-02 232.96 -2.00 3.57 -2.00 501.96 0.00e+00 4.401 0.002 489.00 513.00 1 7.6298e+00 2.4023e-03 8.3983e-03 -6.0000e+00 3.7574e-03 6.2195e-03 6.1077e-04 1.4656e-03 -6.0000e+00 9.7054e-04 4.7676e-04 -1.2152e-03 1.4990e-04 6.7318e-05 -6.0000e+00 2.5072e-04 1.3395e-02 -2.9208e-04 11 1 0 11 4 0 99.63 17.76 1.17 0.01339 0.00497 13 3 1 4 0 3812.080 23.11 15.00 17.76 26.03 28.6 989.43 -426 -259 -159 -27 222 290 444 471 127 475 -179 332 -132 -250 -124 -327 -29 -37 297 -18 160 -35 210 65 244 294 204 56 -230 -77 -269 -27 -249 -168 -63 64 -123 -86 94 -99 111 36 187 80 198 208 428 -23 52 42 -528 -338 -587 -415 -570 -47 -369 -124 247 222 340 278 487 19 175 -92 17 -113 -184 -171 -496 195 -412 -140 -304 125 -178 -104 54 -95 -235 -249 -196 -296 74 -190 -120 -342 147 7 -140 37 -6 264 -52 399 -14 -36 -339 -34 -201 -340 -405 -402 -137 -475 121 -5 -137 -120 -85 -10 -173 187 121 577 219 686 130 188 357 287 26 82 374 153 437 -55 258 -103 -8 24 -86 300 -224 126 -21 -148 17 241 -27 36 254 30 -10 -170 -67 -136 -50 -391 44 -407 -248 -155 -27 227 302 468 502 135 504 -188 345 -135 -254 -125 -329 -29 -38 311 -19 171 -37 224 70 261 316 219 60 -242 -79 -270 -27 -251 -172 -66 68 -131 -91 98 -103 115 38 195 84 210 221 454 -25 54 43 -533 -334 -570 -403 -558 -47 -379 -129 257 229 352 289 506 20 182 -95 17 -114 -183 -168 -486 189 -404 -138 -302 124 -176 -100 51 -91 -223 -237 -187 -285 72 -186 -118 -335 144 6 -137 36 -6 262 -51 387 -14 -33 -309 -31 -178 -302 -368 -377 -133 -468 119 -5 -133 -116 -82 -10 -172 186 122 577 221 691 132 189 355 282 25 79 361 149 425 -53 250 -99 -8 23 -81 280 -209 118 -20 -143 17 237 -27 36 254 30 -10 -171 -67 -134 -48 -374 41
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