File name: Pandora163s1_Tsukuba-NIES-West_20251107_L2Fit_fout2c12d20240101p1-8.txt File generation date: 20251107T143555.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c12p1-8 Local principal investigator: Jinsoo Park Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 163 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora163_OF_v9d20190605.txt Instrument calibration file used: Pandora163s1_CF_v12d20240101.txt Level 1 file used: Pandora163s1_Tsukuba-NIES-West_20251107_L1_smca1c12d20240101p1-8.txt Full location name: National Institute for Environmental Studies (NIES), lidar building Short location name: Tsukuba-NIES-West Country of location: Japan Location latitude [deg]: 36.0506 Location longitude [deg]: 140.1202 Location altitude [m]: 30 Local noon date: 20251107 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on session 11 for fieldcal for VP from 20240101 First and last pixel inside fitting window: 225 366 Nominal wavelengths inside fitting window [nm]: 305.1227 305.2636 305.4045 305.5454 305.6863 305.8272 305.9680 306.1089 306.2497 306.3906 306.5314 306.6722 306.8130 306.9538 307.0946 307.2353 307.3761 307.5168 307.6575 307.7982 307.9390 308.0796 308.2203 308.3610 308.5017 308.6423 308.7829 308.9236 309.0642 309.2048 309.3454 309.4860 309.6265 309.7671 309.9076 310.0482 310.1887 310.3292 310.4697 310.6102 310.7506 310.8911 311.0316 311.1720 311.3124 311.4529 311.5933 311.7337 311.8740 312.0144 312.1548 312.2951 312.4355 312.5758 312.7161 312.8564 312.9967 313.1370 313.2772 313.4175 313.5577 313.6980 313.8382 313.9784 314.1186 314.2588 314.3990 314.5391 314.6793 314.8194 314.9596 315.0997 315.2398 315.3799 315.5200 315.6600 315.8001 315.9402 316.0802 316.2202 316.3602 316.5002 316.6402 316.7802 316.9202 317.0601 317.2001 317.3400 317.4799 317.6198 317.7597 317.8996 318.0395 318.1794 318.3192 318.4591 318.5989 318.7387 318.8785 319.0183 319.1581 319.2979 319.4376 319.5774 319.7171 319.8568 319.9965 320.1362 320.2759 320.4156 320.5553 320.6949 320.8346 320.9742 321.1138 321.2534 321.3930 321.5326 321.6722 321.8117 321.9513 322.0908 322.2304 322.3699 322.5094 322.6489 322.7883 322.9278 323.0673 323.2067 323.3461 323.4856 323.6250 323.7644 323.9038 324.0431 324.1825 324.3218 324.4612 324.6005 324.7398 324.8791 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20251106T215148.8Z 9441.910982 256 1 51.42 2 82.65 116.30 78.64 293.08 0.00 1 0.00 1 0 25 6.651e-01 2.816e-02 4.797e-01 2.146e-02 8.300885e-01 1.238720e-02 9.345349e-03 -6.000000e+00 3.816455e-01 224.93 -2.00 3.41 -2.00 322.10 0.00e+00 1.012542e-02 7.114456e-03 1.295565e-03 -6.000000e+00 1.763217e-02 285.11 -2.00 20.00 -2.00 321.63 0.00e+00 7.225 0.006 302.00 328.00 3 1.4139e+00 4.8569e-02 8.4056e-02 -6.0000e+00 9.4378e-01 1.0040e+00 6.2307e-02 4.6109e-02 -6.0000e+00 1.0288e+00 -1.2781e+00 5.0232e-02 2.2935e-02 -6.0000e+00 6.0813e-01 5.0376e-01 2.3954e-02 1.1854e-02 -6.0000e+00 2.6217e-01 3.8870e-05 -1.8498e-03 5.8840e-04 1.7149e-04 -6.0000e+00 1.7897e-02 9.3310e-03 0.0000e+00 12 8 8 10 0 0 37.85 21.23 0.57 0.00933 -0.00457 40 7 1 5 0 1284.860 24.96 20.00 21.23 18.96 17.9 916.63 -136800 99178 -58754 -81335 900000 -100235 -107732 900000 55407 -101747 -85379 -128611 -97267 900000 57698 126526 64625 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3547 3928 2383 177 -20 1119 5076 1262 4369 1314 3226 3230 4927 4079 4162 2437 1461 2500 595 1722 2456 1823 932 3914 2726 -1607 -1269 -3076 704 28 986 1203 787 -1658 -2672 1253 -2062 -2508 2587 -3505 -4080 -3544 -701 -673 -2180 -455 -769 90 -3339 -1817 -2597 -6220 -2218 -1783 239 1490 -811 -2426 -1889 -1499 1202 1449 576 564 -855 2296 4773 2490 4114 4728 1548 -90 1442 569 1919 2711 1419 1619 -594 -4990 901 3145 491 -422 -492 -2311 -4836 SS 20251106T220247.2Z 9441.918602 259 1 50.89 2 80.68 118.06 80.57 294.48 0.00 1 0.00 1 0 25 5.928e-01 9.319e-03 3.111e-01 5.504e-03 7.098650e-01 3.034689e-03 7.881366e-03 -6.000000e+00 3.330252e-01 224.92 -2.00 3.41 -2.00 321.68 0.00e+00 3.380279e-03 1.689851e-03 7.109586e-04 -6.000000e+00 1.610425e-02 285.11 -2.00 20.00 -2.00 321.16 0.00e+00 5.871 0.003 302.00 328.00 3 1.3160e+00 1.1449e-02 6.9314e-02 -6.0000e+00 8.2393e-01 1.4318e-01 1.7008e-02 3.9506e-02 -6.0000e+00 8.9572e-01 -2.2164e-01 1.7938e-02 2.1238e-02 -6.0000e+00 5.3292e-01 8.4532e-02 8.2579e-03 8.2572e-03 -6.0000e+00 2.3320e-01 2.0888e-04 -1.1493e-03 1.5342e-04 8.9835e-05 -6.0000e+00 1.5482e-02 1.0145e-02 0.0000e+00 11 9 0 11 8 0 21.59 21.23 0.48 0.01015 0.00151 107 19 1 5 0 475.410 25.07 20.00 21.23 19.61 17.9 921.78 -239667 -15099 -179018 -227001 -187519 -239769 -40868 -182637 900000 -193648 900000 -173252 184288 -135321 -65317 -38262 -70700 64898 -49859 27790 -65163 2122 -80654 63172 -50709 5323 42801 -18760 152968 -40022 94153 -4544 32970 -38289 -14775 -36972 11403 9462 -21435 23366 -5542 11598 5201 12503 7183 10114 6709 15418 -1365 491 8952 12046 3539 11428 3379 902 9233 2509 -5468 10872 -4729 4219 3325 4876 3727 4268 6354 1430 3257 332 5937 1643 3144 -385 4275 -888 -1337 101 -2770 157 -1950 -270 -1228 -766 -2268 241 100 -453 1782 777 -62 -107 -1166 -1615 -453 -410 -260 104 -82 -1278 7 19 -855 -1016 -2092 -1157 -760 -302 359 -354 775 -102 731 2 -603 732 -444 639 231 -266 -529 591 443 295 510 365 672 194 549 25 473 -177 -134 -313 118 -18 80 -29 -61 -67 -320 -52 -2922 -81 -1397 -2657 -1372 -3040 -219 -1692 900000 -2361 900000 -2281 989 -2112 -637 -336 -965 348 -657 176 -1049 18 -1652 339 -915 57 313 -247 821 -781 657 -102 584 -1397 -404 -1309 288 299 -1138 928 -324 610 304 691 428 602 428 951 -106 41 788 1150 404 1306 441 126 1204 342 -780 1318 -718 668 614 986 776 861 1271 323 835 100 1815 532 963 -113 1071 -212 -314 25 -847 56 -828 -127 -629 -415 -1335 147 64 -294 1107 460 -34 -56 -621 -947 -306 -324 -238 108 -89 -1358 6 16 -694 -876 -1962 -1130 -788 -339 451 -507 1204 -166 1158 2 -876 1030 -655 989 380 -444 -854 901 657 423 706 485 888 286 934 47 980 -390 -312 -784 285 -44 205 -74 -154 -176 -782 -119 SS 20251106T221302.5Z 9441.925724 264 1 50.65 2 78.87 119.75 82.36 295.80 0.00 1 0.00 1 0 25 2.768e-01 4.732e-03 1.840e-01 2.510e-03 6.179192e-01 1.344039e-03 6.841282e-03 -6.000000e+00 1.552306e-01 224.92 -2.00 3.41 -2.00 321.19 0.00e+00 1.107068e-03 6.540159e-04 5.211732e-04 -6.000000e+00 6.976766e-03 285.11 -2.00 20.00 -2.00 320.61 0.00e+00 4.997 0.002 302.00 328.00 3 1.1649e+00 4.6211e-03 5.8785e-02 -6.0000e+00 3.8306e-01 2.7947e-03 6.4622e-03 3.2456e-02 -6.0000e+00 4.1597e-01 -3.2614e-02 6.6686e-03 1.7481e-02 -6.0000e+00 2.4852e-01 6.7545e-03 3.1940e-03 5.7840e-03 -6.0000e+00 1.0846e-01 6.1959e-04 -6.7537e-04 7.0755e-05 6.0628e-05 -6.0000e+00 7.1949e-03 9.9602e-03 0.0000e+00 11 1 0 11 8 0 4.26 21.23 0.38 0.00996 0.00489 199 36 1 5 0 254.480 25.07 19.99 21.23 20.46 18.0 929.48 -60247 -113784 -20530 -101252 -42572 -78671 -131393 -115405 -65635 -84857 -71231 -65478 -75459 -71721 -15688 -31687 1010 -10911 -3759 -8604 6415 -17495 -24659 -10030 -17908 -5438 -21398 -26872 -28134 -18352 -7823 1938 14612 65 -2702 -16466 -4118 -2927 -1549 -4227 316 5167 -1076 -2961 -225 2415 1434 -2796 -856 1301 2746 -602 27 136 190 355 2485 98 2285 1473 1020 943 2612 2779 649 115 -503 1722 1148 2086 1604 -21 -171 144 138 -1065 -1456 -2378 20 -802 -246 -1074 -1057 -821 -692 18 34 615 393 966 815 299 198 237 269 73 436 78 -102 -200 -526 -287 -197 -828 -1646 -1262 -723 -185 291 342 399 275 311 43 180 74 351 55 -242 -443 32 64 477 276 267 -204 476 472 114 484 -88 -289 -121 -203 -176 -116 306 24 -100 -106 87 -73 -188 -683 -50 -518 -114 -315 -1023 -899 -350 -585 -460 -481 -789 -925 -143 -395 10 -136 -52 -131 85 -300 -495 -194 -408 -114 -524 -671 -723 -485 -226 60 454 2 -96 -701 -180 -157 -101 -332 26 434 -100 -285 -21 230 141 -300 -95 154 363 -92 4 24 36 70 486 19 427 279 207 217 676 788 189 32 -143 510 395 810 672 -9 -71 56 48 -340 -452 -793 7 -366 -129 -637 -671 -553 -499 14 27 493 309 713 560 194 127 164 214 67 462 84 -116 -218 -574 -280 -184 -832 -1797 -1441 -870 -239 379 499 628 443 490 64 254 102 499 83 -389 -727 51 98 701 392 401 -294 677 738 186 871 -171 -588 -259 -467 -432 -294 786 61 -254 -258 197 -158 SS 20251106T221851.9Z 9441.929767 267 1 50.71 2 77.85 120.73 83.37 296.56 0.00 1 0.00 1 0 25 1.868e-01 4.483e-03 9.380e-02 1.781e-03 5.748235e-01 9.445026e-04 6.514159e-03 -6.000000e+00 1.047715e-01 224.92 -2.00 3.41 -2.00 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